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Contents
I Background
1 Arrehnius Theory
2 Brønsted-Lowry Theory
II Acid-Base Theories
2 Lux-Flood Theory
Ø What is self-ionization?
Aqueous system:
2 H2 O H 3O+ + OH - Kw = 1.0x10-14 at 24.8 °C, 1
atm
2 Non-aqueous solvolysis
Alcoholysis
In water:
B(OH)3+H2O→H++B(OH)4–, so B(OH)3 is an
Arrehnius acid.
NH3 + H+ → NH4+
Inductive effect
Steric effect
N N N
B
R R R
R
R R
N > N > N
R R R
I (internal)-strain: oxygen basicity drops with
the decreasing ring size.
O O
Me Me O
N Me N N
> >
(base) (acid)
Irving-William series
Class (a):
4 Al3+, H+
Borderline:
O << S > Se ~ Te
R R' RX
0
Pd
R R
Pd Pd
R' X
EX R'E
2 polarizability
-PA
B(g) + H+(g) BH+(g)
proton affinity
Acidity of Oxides
For instance
1 general guidelines
2 sulfuric acid
H
O O O 2-
S S S
H O H O O
O O O
O O O
m.p. 10.371 ˚C 0 ˚C
3 ammonia
ammonia water
b.p. -33.38 ˚C 100 ˚C
m.p. -77.7 ˚C 0 ˚C
4 oxoacids
Oxoacids are customarily written as HmXO(m+n).
The functional formula is XOn(OH)m. Hydrated
oxometals such as uranyl UO22+, vanadyl VO2+.
Acidity:
HClO4 > HClO3 > HClO2 > HClO > HBrO >
HIO
5 binary oxides
5 solid acids:
Clays and Zeolites are porous solids. The
clays have layer structures, and the zeolites
are aluminosilicates with channels. They have
replaceable cations and may be exchanged
with H+, thereby forming solid acids.
6 superacids: