Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II.

Europe

SAFETY DATA SHEET

.

1. Identification of the preparation and of the company

.

Product name and/or code : HEMPADUR 85539

8553950700
Company details : Hempel A/S Emergency telephone number
Lundtoftevej 150 (with hours of operation)
DK-2800 Kgs. Lyngby +45 45 93 38 00 (08.00 -
Denmark 17.00)
Tel.: + 45 45 93 38 00 See section 4 First aid
hempel@dk.hempel.com measures.
Product type : modified epoxy primer (base for multi-component product)
Field of application : Metal industry
ready-for-use mixture : 85530 = 85539 4 vol. / 97530 1 vol. 85531 = 85539 4 vol. / 97531 1 vol.
Date of issue : 7/10/2007.
Date of previous issue : No previous validation.
.

2. Hazards identification
.

Irritant Dangerous for the Highly flammable

environment.
Highly flammable. Irritating to eyes and skin. May cause sensitization by skin contact. Toxic to aquatic organisms, may
cause long-term adverse effects in the aquatic environment.
.

3. Composition/information on ingredients
.

Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances Directive
67/548/EEC.
Ingredient name CAS no. % EC number Classification

bisphenol A-(epichlorhydrin) epoxy resin MW =< 700 25068-38-6 25 - 50 500-033-5 Xi; R36/38
R43
N; R51/53
butanone 78-93-3 5 - 10 201-159-0 F; R11
Xi; R36
R66, R67
.
Notes
(*) See full text of phrases under chapter 16. Occupational exposure limits, if available, are listed in section 8.
.

4. First aid measures

.

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never
give anything by mouth to an unconscious person.
Inhalation : Remove to fresh air. Keep person warm and at rest. If unconscious, place in
recovery position and seek medical advice.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of
water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek
immediate medical attention.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognized skin cleanser. Do not use solvents or thinners.

Date of issue : 7/10/2007. Page: 1/5

HEMPADUR 85539 8553950700

Ingestion : If swallowed, seek medical advice immediately and show this container or label.
Keep person warm and at rest. Do not induce vomiting unless directed to do so by
medical personnel. Lower the head so that vomit will not re-enter the mouth and
throat.
.

5. Fire-fighting measures
.

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be
taken involving any personal risk or without suitable training. Fire will produce dense black smoke. Exposure to
decomposition products may cause a health hazard. Cool closed containers exposed to fire with water. Do not release
runoff from fire to sewers or waterways. Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used : waterjet.
Fire degradation products : Decomposition products may include the following materials: carbon oxides sulfur
oxides halogenated compounds metal oxide/oxides
.

6. Accidental release measures

.

Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Refer to protective measures listed
in sections 7 and 8.
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous
earth, and place in container for disposal according to local regulations (see section 13). Do not allow to enter drains
or watercourses. Clean preferably with a detergent; avoid use of solvents. If the product contaminates lakes, rivers, or
sewers, inform the appropriate authorities in accordance with local regulation.
.

7. Handling and storage

.

Handling
Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the
creation of flammable or explosive concentrations of vapors in air and avoid vapor concentrations higher than the
occupational exposure limits. In addition, the product should be used only in areas from which all naked lights and
other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard.
To dissipate static electricity during transfer, ground drum and connect to receiving container with bonding strap. No
sparking tools should be used. Contains epoxy constituents. Avoid all possible skin contact with epoxy and amine
containing products, they may cause allergic reactions.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should
be prohibited in area where this material is handled, stored and processed. Appropriate personal protective
equipment: see Section 8. Always keep in containers made from the same material as the original one.
Storage
Store in accordance with local regulations for flammable liquids. Store in a cool, well-ventilated area away from
incompatible materials and ignition sources. Keep out of the reach of children. Keep away from: Oxidizing agents,
strong alkalis, strong acids. No smoking. Prevent unauthorized access. Containers that are opened must be carefully
resealed and kept upright to prevent leakage.
.

8. Exposure controls/personal protection

.

Engineering measures : Arrange sufficient ventilation by local exhaust ventilation and good general
ventilation to keep the airborne concentrations of vapors or dust lowest possible
and below their respective threshold limit value. Ensure that eyewash stations and
safety showers are proximal to the work-station location.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before
eating, smoking, using lavatory, and at the end of day.
Ingredient name Occupational exposure limits

butanone EU OEL (Europe, 5/2006).

short term: 900 mg/m³ 15 minute(s).
short term: 300 ppm 15 minute(s).
8 hours: 600 mg/m³ 8 hour(s).
8 hours: 200 ppm 8 hour(s).

Personal protective equipment

General : Gloves must be worn for all work that may result in soiling.
Apron/coveralls/protective clothing must be worn when soiling is so great that
regular work clothes do not adequately protect skin against contact with the
product. Safety eyewear should be used when there is a likelihood of exposure.

Date of issue : 7/10/2007. Page: 2/5

HEMPADUR 85539 8553950700

Respiratory protection : If working areas have insufficient ventilation: When the product is applied by
means that will not generate an aerosol such as, brush or roller wear half or totally
covering mask equipped with gas filter of type A, when grinding use particle filter
of type P. When the product is applied by spraying and for continuous or
prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or
compressed air or a full face, powered air purifying filter. Be sure to use an
approved/certified respirator or equivalent.
This product contains low-boiling point liquids. Any respiratory protective
equipment should be air-fed.
Skin protection : Wear suitable protective clothing. Always wear protective clothing when spraying.
Hand protection : Wear suitable gloves. For prolonged or repeated handling, use gloves. Barrier
creams may help to protect the exposed areas of the skin, but should not be
applied once exposure has occurred. Barrier creams may not be used under or
instead of gloves.
Since the actual work situation is unknown. Supplier of gloves should be
contacted in order to find the appropriate type.
Eye protection : Use safety eyewear designed to protect against splash of liquids. Safety glasses
with side shields.
.

9. Physical and chemical properties

.

Physical state : Liquid.

Density : 1.87 g/cm3
Solubility : Soluble in the following materials: cold water and hot water.
Flash point : Closed cup: 14°C (57.2°F)
Explosion limits : 1.8 - 11.5 vol %
Solvent(s) % by weight : Weighted average: 10 %
Water % by weight : Weighted average: 0 %
VOC content : Weighted average: 193 g/l (Calculated value for the mixture)
TOC Content : Weighted average: 132 g/l
Solvent Gas : Weighted average: 0.064 m3/l
.

10. Stability and reactivity

.

Stable under recommended storage and handling conditions (see section 7).
Reactive or incompatible with the following materials: acids.
When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides sulfur oxides halogenated compounds
metal oxide/oxides
.

11. Toxicological information

.

Effects and symptoms

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane
and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may
cause some of the above effects by absorption through the skin. Symptoms and signs include headaches, dizziness,
fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged
contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis
and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible damage.
Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the
lungs via vomiting.
Epoxy and amine containing products can cause skin disorders such as allergic eczema. The allergy may arise after
only a short exposure period.
Sensitization : Contains bisphenol A-(epichlorhydrin) epoxy resin MW =< 700. May produce an
allergic reaction.
Acute toxicity
Ingredient name Result Dose Species
butanone LD50 Oral 2737 mg/kg Rat
LD50 Skin 6480 mg/kg Rabbit
LDLo Oral 714.3 mg/kg Human

Date of issue : 7/10/2007. Page: 3/5

HEMPADUR 85539 8553950700

12. Ecological information

.

Do not allow to enter drains or watercourses. Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Ingredient name Result Species Exposure
butanone Acute EC50 5091 mg/L Intoxication Daphnia 48 hours
Acute LC50 3220 mg/L Mortality Fish 96 hours

13. Disposal considerations

.

The generation of waste should be avoided or minimized wherever possible.

Residues of the product is listed as hazardous waste. Dispose of according to all state and local applicable
regulations.
Spillage, remains, discarded clothes and similar should be discarded in a fireproof container.
European waste catalogue no. (EWC) and national waste group, catalouge, code or number is given below.
European waste catalogue : 08 01 11
(EWC)
.

14. Transport information

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train,
IMDG for transport by sea.
The transport classification is according to ADR 2007, IMDG edition 2006 (incl. Amdt. 33-06).
UN no. Proper shipping name Class PG* Label Additional information

ADR/RID UN1263 PAINT 3 II Remarks

Class H-15
3

IMDG UN1263 PAINT. (bisphenol A-(epichlorhydrin) 3 II Emergency schedules

Class epoxy resin MW =< 700) (EmS)
3 F-E, S-E

(P)
PG* : Packing group
.

15. Regulatory information

.

Classification and labeling have been determined according to EU Directives 67/548/EEC and 1999/45/EC (including
amendments) and take into account the intended product use.
Product use : Industrial applications, Used by spraying.
Symbol : Highly flammable, Irritant, Dangerous for the environment.
Contains : bisphenol A-(epichlorhydrin) epoxy resin MW =< 700
Risk phrases : R11- Highly flammable.
R36/38- Irritating to eyes and skin.
R43- May cause sensitization by skin contact.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety phrases : S23- Do not breathe vapor or spray.
S24- Avoid contact with skin.
S37- Wear suitable gloves.
S51- Use only in well-ventilated areas.
Additional warning phrases : Contains epoxy constituents. See information supplied by the manufacturer.
.

16. Additional information

Full text of R-phrases referred to in
the Safety Data Sheet
: R11- Highly flammable.
R36- Irritating to eyes.
R36/38- Irritating to eyes and skin.
R43- May cause sensitization by skin contact.
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapors may cause drowsiness and dizziness.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Date of issue : 7/10/2007. Page: 4/5

HEMPADUR 85539 8553950700

Notice to reader
Modified data or content compared with the previous version are maked with a triangular marker in the upper-left
corner within the Safety Data Sheet.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national
legislation. It provides guidance on health, safety and environmental aspects for handling the product in a safe way
and should not be construed as any guarantee of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the
national regulations.

Date of issue : 7/10/2007. Page: 5/5

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II. Europe

SAFETY DATA SHEET

.

1. Identification of the preparation and of the company

.

Product name and/or code : HEMPEL'S CURING AGENT 97530

9753000000
Company details : Hempel A/S Emergency telephone number
Lundtoftevej 150 (with hours of operation)
DK-2800 Kgs. Lyngby +45 45 93 38 00 (08.00 -
Denmark 17.00)
Tel.: + 45 45 93 38 00 See section 4 First aid
hempel@dk.hempel.com measures.
Product type : curing agent
Field of application : used only as part of two- or multi component products.
ready-for-use mixture : (see base component)
Date of issue : 7/11/2007.
Date of previous issue : No previous validation.
.

2. Hazards identification
.

Corrosive, Toxic Dangerous for the Highly flammable

environment.
Highly flammable. May cause cancer. Possible risk of irreversible effects. Toxic: danger of very serious irreversible
effects through inhalation, in contact with skin and if swallowed. Harmful by inhalation, in contact with skin and if
swallowed. Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with
skin and if swallowed. Causes burns. May cause sensitization by skin contact. Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
.

3. Composition/information on ingredients
.

Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances Directive
67/548/EEC.
Ingredient name CAS no. % EC number Classification

benzyl alcohol 100-51-6 15 - 25 202-859-9 Xn; R20/22

4,4'-diaminodiphenylmethane 101-77-9 15 - 25 202-974-4 Carc. Cat. 2; R45
Muta. Cat. 3; R68
T; R39/23/24/25
Xn; R48/20/21/22
R43
N; R51/53
2,2,4- and 2,4,4- trimethylhexamethylene diamine 25620-58-0 12.5 - 15 247-134-8 Xn; R22
C; R34
R43
N; R51/53
butanone 78-93-3 5 - 10 201-159-0 F; R11
Xi; R36
R66, R67
phenol 108-95-2 5 - 10 203-632-7 Muta. Cat. 3; R68
T; R23/24/25
Xn; R48/20/21/22
C; R34
solvent naphtha (petroleum), light arom. 64742-95-6 0.3 - 0.5 265-199-0 R10
Xn; R20, R65
Xi; R36/37/38
N; R51/53
.
Notes
(*) See full text of phrases under chapter 16. Occupational exposure limits, if available, are listed in section 8.

Date of issue : 7/11/2007. Page: 1/6

HEMPEL'S CURING AGENT 97530 9753000000

4. First aid measures

.

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never
give anything by mouth to an unconscious person.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. Give nothing by mouth. If unconscious, place in recovery
position and get medical attention immediately.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of
water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek
immediate medical attention.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognized skin cleanser. Do not use solvents or thinners. In case of
burns flush with water until the pain ceases. While flushing remove clothing from
the affected area unless it is burnt into the skin. If hospital treatment is necessary
flushing must continue during transfer and until the hospital staff takes over the
treatment.
Ingestion : If swallowed, seek medical advice immediately and show this container or label.
Keep person warm and at rest. Do not induce vomiting unless directed to do so by
medical personnel. Lower the head so that vomit will not re-enter the mouth and
throat.
Notes to physician : If gasses have been inhaled, from the decomposition of the product, symptoms
may be delayed.
.

5. Fire-fighting measures
.

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be
taken involving any personal risk or without suitable training. Fire will produce dense black smoke. Exposure to
decomposition products may cause a health hazard. Cool closed containers exposed to fire with water. Do not release
runoff from fire to sewers or waterways. Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used : waterjet.
Fire degradation products : Decomposition products may include the following materials: carbon oxides
nitrogen oxides halogenated compounds metal oxide/oxides
.

6. Accidental release measures

.

Avoid all direct contact with the spilled material. Exclude sources of ignition and be aware of explosion hazard.
Ventilate the area. Avoid breathing vapor or mist. Refer to protective measures listed in sections 7 and 8.
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous
earth, and place in container for disposal according to local regulations (see section 13). Do not allow to enter drains
or watercourses. Clean preferably with a detergent; avoid use of solvents. If the product contaminates lakes, rivers, or
sewers, inform the appropriate authorities in accordance with local regulation.
.

7. Handling and storage

.

Handling
Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the
creation of flammable or explosive concentrations of vapors in air and avoid vapor concentrations higher than the
occupational exposure limits. In addition, the product should be used only in areas from which all naked lights and
other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard.
To dissipate static electricity during transfer, ground drum and connect to receiving container with bonding strap. No
sparking tools should be used.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should
be prohibited in area where this material is handled, stored and processed. Appropriate personal protective
equipment: see Section 8. Always keep in containers made from the same material as the original one.
Storage
Store in accordance with local regulations for flammable liquids. Store in a cool, well-ventilated area away from
incompatible materials and ignition sources. Keep out of the reach of children. Keep away from: Oxidizing agents,
strong alkalis, strong acids. No smoking. Prevent unauthorized access. Containers that are opened must be carefully
resealed and kept upright to prevent leakage.

Date of issue : 7/11/2007. Page: 2/6

HEMPEL'S CURING AGENT 97530 9753000000

8. Exposure controls/personal protection

.

Engineering measures : Arrange sufficient ventilation by local exhaust ventilation and good general
ventilation to keep the airborne concentrations of vapors or dust lowest possible
and below their respective threshold limit value. Ensure that eyewash stations and
safety showers are proximal to the work-station location.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before
eating, smoking, using lavatory, and at the end of day.
Ingredient name Occupational exposure limits

4,4'-diaminodiphenylmethane ACGIH TLV (United States, 1/2006). Skin

TWA: 0.81 mg/m³ 8 hour(s).
TWA: 0.1 ppm 8 hour(s).
butanone EU OEL (Europe, 5/2006).
short term: 900 mg/m³ 15 minute(s).
short term: 300 ppm 15 minute(s).
8 hours: 600 mg/m³ 8 hour(s).
8 hours: 200 ppm 8 hour(s).
phenol EU OEL (Europe, 5/2006). Skin
8 hours: 7.8 mg/m³ 8 hour(s).
8 hours: 2 ppm 8 hour(s).
solvent naphtha (petroleum), light arom. EU OEL (Europe, 1/2001).
TWA: 120 mg/m³ 8 hour(s). Form: Tentativ
TWA: 25 ppm 8 hour(s). Form: Tentativ

Personal protective equipment

General : Gloves must be worn for all work that may result in soiling.
Apron/coveralls/protective clothing must be worn when soiling is so great that
regular work clothes do not adequately protect skin against contact with the
product. Safety eyewear should be used when there is a likelihood of exposure.
Respiratory protection : If working areas have insufficient ventilation: When the product is applied by
means that will not generate an aerosol such as, brush or roller wear half or totally
covering mask equipped with gas filter of type A, when grinding use particle filter
of type P. When the product is applied by spraying and for continuous or
prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or
compressed air or a full face, powered air purifying filter. Be sure to use an
approved/certified respirator or equivalent.

This product contains low-boiling point liquids. Any respiratory protective

equipment should be air-fed.
Skin protection : Wear suitable protective clothing. Always wear protective clothing when spraying.
Chemical-resistant apron.
Hand protection : Wear suitable gloves. For prolonged or repeated handling, use gloves. Barrier
creams may help to protect the exposed areas of the skin, but should not be
applied once exposure has occurred. Barrier creams may not be used under or
instead of gloves.
Since the actual work situation is unknown. Supplier of gloves should be
contacted in order to find the appropriate type. The manufacturer of constituent
material 4,4'-diaminodiphenylmethane has conducted a serie of glove permeability
studies, on a selected range of glove types in accordance with EN-374-3. The
objective was to determine their suitability for adequate skin protection throughout
an 8-hour shift with the result that the several glove types are recommended.
However taken into account all the constituents of the product only one type can
be recommended: PE/EVAL composite, minimum thickness 0.070 mm;
commercial available brands are silver shield and 4H.

Eye protection : Use safety eyewear designed to protect against splash of liquids. Chemical splash
goggles or face shield.
.

9. Physical and chemical properties

.

Physical state : Liquid.

Density : 1.04 g/cm3
Solubility : Soluble in the following materials: cold water and hot water.
Flash point : Closed cup: -4°C (24.8°F)
Explosion limits : 1.36 - 15 vol %

Date of issue : 7/11/2007. Page: 3/6

HEMPEL'S CURING AGENT 97530 9753000000

Solvent(s) % by weight : Weighted average: 32 %

Water % by weight : Weighted average: 0 %
VOC content : Weighted average: 199 g/l (Calculated value for the mixture)
TOC Content : Weighted average: 147 g/l
Solvent Gas : Weighted average: 0.087 m3/l
.

10. Stability and reactivity

.

Stable under recommended storage and handling conditions (see section 7).
Highly reactive or incompatible with the following materials: oxidizing materials.
Reactive or incompatible with the following materials: acids.
Slightly reactive or incompatible with the following materials: reducing materials and organic materials.
When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides nitrogen oxides halogenated compounds
metal oxide/oxides
.

11. Toxicological information

.

Effects and symptoms

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane
and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may
cause some of the above effects by absorption through the skin. Symptoms and signs include headaches, dizziness,
fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged
contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis
and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible damage.
Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the
lungs via vomiting.
Inhalation of a corrosive substance may result in health effects such as stinging, coughing and in extreme cases,
dyspnoea or loss of consciousness with a risk of lung damage, possibly lung oedema. Cauterization of skin and
mucous membrane. If splashed in the eyes, the liquid may cause ireversible damage. Accidental swallowing may
cause stinging and cauterization to mouth, oesophagus and stomach. Symptoms and signs include bloody vomiting,
chock and loss of consciousness.
Chronic effects : Repeated exposure to a harmful material may produce general deterioration of
health by an accumulation in human organs.
Carcinogenic effects : Contains substance(s) that may cause cancer.
Mutagenic effects : Contains substance(s) that may cause heritable genetic damage.
Sensitization : Contains 4,4'-diaminodiphenylmethane, . May produce an allergic reaction.
Acute toxicity
Ingredient name Result Dose Species
benzyl alcohol LD50 Oral 1230 mg/kg Rat
LD50 Skin 2000 mg/kg Rabbit
LDLo Intraperitoneal 650 mg/kg Rat
4,4'-diaminodiphenylmethane LD50 Oral 517 mg/kg Rat
LD50 Skin 200 mg/kg Rabbit
2,2,4- and 2,4,4- trimethylhexamethylene diamine LD50 Oral 910 mg/kg Rat
butanone LD50 Oral 2737 mg/kg Rat
LD50 Skin 6480 mg/kg Rabbit
LDLo Oral 714.3 mg/kg Human
phenol LD50 Oral 317 mg/kg Rat
LD50 Skin 630 mg/kg Rabbit
solvent naphtha (petroleum), light arom. LD50 Oral 8400 mg/kg Rat
.

12. Ecological information

.

Do not allow to enter drains or watercourses. Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Ingredient name Result Species Exposure
benzyl alcohol Acute LC50 460 mg/L Mortality Fish 96 hours
butanone Acute EC50 5091 mg/L Intoxication Daphnia 48 hours
Acute LC50 3220 mg/L Mortality Fish 96 hours
phenol Acute EC50 5.55 mg/L Intoxication Daphnia 48 hours
Acute LC50 5.02 mg/L Mortality Fish 96 hours

Date of issue : 7/11/2007. Page: 4/6

HEMPEL'S CURING AGENT 97530 9753000000

13. Disposal considerations

.

The generation of waste should be avoided or minimized wherever possible.

Residues of the product is listed as hazardous waste. Dispose of according to all state and local applicable
regulations.
Spillage, remains, discarded clothes and similar should be discarded in a fireproof container.
European waste catalogue no. (EWC) and national waste group, catalouge, code or number is given below.
European waste catalogue : 08 01 11
(EWC)
.

14. Transport information

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train,
IMDG for transport by sea.
The transport classification is according to ADR 2007, IMDG edition 2006 (incl. Amdt. 33-06).
UN no. Proper shipping name Class PG* Label Additional information

ADR/RID UN3469 PAINT, FLAMMABLE, CORROSIVE 3 II Remarks

Class H-111
3 8

IMDG UN3469 PAINT, FLAMMABLE, CORROSIVE. 3 II Emergency schedules

Class (4,4'-diaminodiphenylmethane) (EmS)
3 8 F-E, S-C

(P)
PG* : Packing group
.

15. Regulatory information

.

Classification and labeling have been determined according to EU Directives 67/548/EEC and 1999/45/EC (including
amendments) and take into account the intended product use.
Product use : Industrial applications, Used by spraying.
Symbol : Highly flammable, Corrosive, Toxic, Dangerous for the environment.
Contains : 4,4'-diaminodiphenylmethane
2,2,4- and 2,4,4- trimethylhexamethylene diamine
phenol
Risk phrases : R11- Highly flammable.
R45- May cause cancer.
R68- Possible risk of irreversible effects.
R39/23/24/25- Toxic: danger of very serious irreversible effects through inhalation,
in contact with skin and if swallowed.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R48/20/21/22- Harmful: danger of serious damage to health by prolonged
exposure through inhalation, in contact with skin and if swallowed.
R34- Causes burns.
R43- May cause sensitization by skin contact.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety phrases : S53- Avoid exposure - obtain special instructions before use.
S23- Do not breathe vapor or spray.
S26- In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S45- In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
Additional warning phrases : Restricted to professional users. Attention - Avoid exposure - obtain special
instructions before use.
Other EU regulations
Restrictions on the Marketing : Restricted to professional users.
and Use Directive

Date of issue : 7/11/2007. Page: 5/6

HEMPEL'S CURING AGENT 97530 9753000000

16. Additional information

Full text of R-phrases referred to in
the Safety Data Sheet
: R11- Highly flammable.
R10- Flammable.
R45- May cause cancer.
R68- Possible risk of irreversible effects.
R23/24/25- Toxic by inhalation, in contact with skin and if swallowed.
R39/23/24/25- Toxic: danger of very serious irreversible effects through inhalation, in contact with skin
and if swallowed.
R20- Harmful by inhalation.
R22- Harmful if swallowed.
R20/22- Harmful by inhalation and if swallowed.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R48/20/21/22- Harmful: danger of serious damage to health by prolonged exposure through inhalation,
in contact with skin and if swallowed.
R65- Harmful: may cause lung damage if swallowed.
R34- Causes burns.
R36- Irritating to eyes.
R36/37/38- Irritating to eyes, respiratory system and skin.
R43- May cause sensitization by skin contact.
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapors may cause drowsiness and dizziness.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Notice to reader
Modified data or content compared with the previous version are maked with a triangular marker in the upper-left
corner within the Safety Data Sheet.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national
legislation. It provides guidance on health, safety and environmental aspects for handling the product in a safe way
and should not be construed as any guarantee of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the
national regulations.

Date of issue : 7/11/2007. Page: 6/6