Benzene Toluene

A B C A B C
13.7819 2726.81 217.572 13.932 3056.96 217.625

(a) Find y1 and P

T
Species xi Pi P yi
(Celcius)

Benzene 180.4528
0.33 100 109.3034 0.5448
Toluene 74.2597

(b) find x1 and P, given y1=0,33 and T=100

T
Species yi Pi xi P yi
(Celcius)

Benzene 180.4528
0.33 100 0.1686 92.1595 0.3300
Toluene 74.2597

CARA LAIN
x y P
0.168529 0.33 92.15638
0.168529
0

© given x1=0,33 and P=120 kPa, Find y1 and T

P dari
Species xi P (kPa) Ti T Pi yi
asumsi
Benzene 85.5952 197.1485
0.33 120 103.3068 120.0000 0.5422
Toluene 116.6696 82.0015
 ASETONITRILE NITROMETHANE
A B C A B C
14.2724 2945.4700 224.0000 14.2043 2972.6400 209.0000

Species T (Celcius) Pi xi P yi
Asetonitrile 83.2069 0.0000 41.9827 0.0000
75
Nitromethane 41.9827 0.1000 46.1051 0.1805
0.2000 50.2275 0.3313
0.3000 54.3500 0.4593
0.4000 58.4724 0.5692
0.5000 62.5948 0.6646
0.6000 66.7172 0.7483
0.7000 70.8396 0.8222
0.8000 74.9620 0.8880
0.9000 79.0844 0.9469
1.0000 83.2069 1.0000

Species P (kPa) Ti T P1 P2 xi
Asetonitrile 69.8446 69.8446 70.0000 34.5960 1.0000
70
Bitromethane 89.5836 70.0000 70.3719 34.8021 0.9895
71.0000 72.8029 36.1519 0.9235
72.0000 75.3006 37.5439 0.8596
73.0000 77.8662 38.9790 0.7977
74.0000 80.5012 40.4583 0.7378
75.0000 83.2069 41.9827 0.6796
76.0000 85.9845 43.5532 0.6233
77.0000 88.8354 45.1709 0.5686
78.0000 91.7611 46.8368 0.5156
79.0000 94.7628 48.5519 0.4641
80.0000 97.8420 50.3173 0.4142
81.0000 101.0001 52.1340 0.3656
82.0000 104.2384 54.0031 0.3184
83.0000 107.5585 55.9258 0.2726
84.0000 110.9618 57.9031 0.2280
85.0000 114.4496 59.9361 0.1846
86.0000 118.0235 62.0260 0.1424
87.0000 121.6850 64.1739 0.1013
88.0000 125.4354 66.3810 0.0613
89.5836 131.5604 70.0000 0.0000
 P-x-y
85.0000
80.0000
75.0000
70.0000
65.0000
60.0000
55.0000
50.0000
45.0000
40.0000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000 1.2000
x y

yi
90.0000
1.0000
0.9948 t-x-y
0.9605
0.9247
0.8874 85.0000
0.8484
0.8079
0.7656
0.7216
0.6759 80.0000
0.6283
0.5789
0.5275
0.4742
75.0000
0.4188
0.3614
0.3018
0.2401
0.1761 70.0000
0.1098
0.0000

65.0000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
65.0000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
 x
y

0.8000 1.0000 1.2000

0.8000 1.0000 1.2000
 METHANOL AIR
A B C A B C
16.5785 3638.2700 239.5000 16.3872 3885.7000 230.1700

1 Bubble P
tentukan P dan y
T
Species x Pi P y
(Celcius)
Methanol 253.8413
0.3000 90.0000 125.2672 0.6079
Air 70.1640

2 Dew P
tentukan P dan x

T xi xi
Species y1 Pi P
(Celcius) (tebakan) (hitungan)

Methanol 253.8413 0.0000 70.1640 0.0829

0.3000 90.0000
Air 70.1640 0.0829 85.3950 0.1009
0.1009 88.7013 0.1048
0.1048 89.4190 0.1057
0.1057 89.5748 0.1059
0.1059 89.6086 0.1059
0.1059 89.6160 0.1059
0.1059 89.6176 0.1059
0.1059 89.6179 0.1059
0.1059 89.6180 0.1059
0.1059 89.6180 0.1059
0.1059 89.6180 0.1059

3 Dew T
y2 0.7000
Species y1 P (kPa) T1 T Pi x1
Methanol 66.8027 304.9716
0.3000 110.0000 95.5687 0.1082
Air 102.3185 86.3417

Cara lain
T P1 P2 x y
66.8027 109.9998 27.1895 1.0000 1.0000
69.8027 123.4315 30.9907 0.8547 0.9591
 72.8027 138.1971 35.2319 0.7261 0.9123
75.8027 154.3966 39.9529 0.6121 0.8591
78.8027 172.1351 45.1960 0.5105 0.7989
81.8027 191.5222 51.0060 0.4198 0.7310
84.8027 212.6724 57.4305 0.3386 0.6547
87.8027 235.7052 64.5196 0.2657 0.5693
90.8027 260.7451 72.3262 0.1999 0.4740
93.8027 287.9212 80.9060 0.1405 0.3679
95.5687 304.9716 86.3417 0.1082 0.3000
96.8027 317.3679 90.3177 0.0867 0.2501
99.8027 349.2244 100.6226 0.0377 0.1198
102.3185 377.9020 110.0000 0.0000 0.0000

CARA LAIN DI BUKU VAN NESS 356

alfa P1 sat dari T dengan P2 alfa hitung gallat x
tebakan alfa Antoine
5.0000 418.0000 105.5881 123.2585 3.3912 1.6087540891 0.1082
3.3912 294.1259 94.4550 82.8796 3.5488 -0.1575897756
3.5488 306.2603 95.6989 86.7541 3.5302 0.0186251181
3.5302 304.8262 95.5540 86.2952 3.5324 -0.0021556266
3.5324 304.9922 95.5708 86.3483 3.5321 0.0002500967
3.5321 304.9729 95.5688 86.3421 3.5321 -0.0000290081
3.5321 304.9752 95.5690 86.3428 3.5321 0.0000033647
3.5321 304.9749 95.5690 86.3428 3.5321 -0.0000003903
3.5321 304.9749 95.5690 86.3428 3.5321 0.0000000453
3.5321 304.9749 95.5690 86.3428 3.5321 -0.0000000053
3.5321 304.9749 95.5690 86.3428 3.5321 0.0000000006
3.5321 304.9749 95.5690 86.3428 3.5321 -0.0000000001
3.5321 304.9749 95.5690 86.3428 3.5321 0.0000000000
 gallat

0.0068761626488
0.0003240225544
0.0000152687802
0.0000007195044
0.0000000339049
0.0000000015977
0.0000000000753
0.0000000000035
0.0000000000002
0.0000000000000
0.0000000000000
0.0000000000000

y1 (hitungan) gallat y
0.3000 0.0000
Dari buku Van Ness

10.4 Species % mol T (0F)

Methane 10%
Ethane 20% 50
Propane 70%

Determine (a) dewpoint Pressure (b) the bubblepoint pressure

(a)
P (psia) 100 P (psia) 150 P (psia)
Species yi
Ki yi/Ki Ki yi/Ki Ki
Methane 0.1000 20.0000 0.0050 13.2000 0.0076 16.0187
Ethane 0.2000 3.2500 0.0615 2.2500 0.0889 2.6645
Propane 0.7000 0.9200 0.7609 0.6500 1.0769 0.7619
Ʃ yi/Ki 0.8274 1.1734
Jadi, dew point pressure nya adalah 129,2740 kPa

(b)
P (psia) 380 P (psia) 400 P (psia)
Species xi
Ki Kixi Ki Kixi Ki
Methane 0.1000 5.6000 0.5600 5.2500 0.5250 5.4921
Ethane 0.2000 1.1100 0.2220 1.0700 0.2140 1.0977
Propane 0.7000 0.3350 0.2345 0.3200 0.2240 0.3304
Ʃ Kixi 1.0165 0.9630
Jadi, bubblepoint pressure nya adalah 386,1682 kPa

10.5 Species T (0C) P (kPa) zi

1 Acetone 0.45
2 Acetonitrile 80 110 0.35
3 Nitromethane 0.2
determine L, V, xi, yi
Acetone Acetonitrile Nitromethane
A B C A B C A
14.3145 2756.22 228.06 14.895 3413.1 250.523 14.7513

Pi (dari
Species xi=zi Pi P buble yi=zi
buku)
1 Acetone 0.4500 214.3214 195.7500 0.4500
2 Acetonitrile 0.3500 96.4127 97.8400 132.3955 0.3500
3 Nitromethane 0.2000 50.4017 50.3200 0.2000
Ʃ
10.6 Species % mol T (0F) P (psia)
methane 10%
ethane 20% 50 200
Propane 70%

(berdasarka
n grafik yi saat yi saat yi saat
Species zi pada T=500F V=0,35 V=0,25 V=0,2725 xi
dan P=200
psia) 0.3500 0.2500 0.2725
methane 10% 10.0000 0.2410 0.3077 0.2897 0.0290
ethane 20% 1.7600 0.2780 0.2958 0.2916 0.1657
Propane 70% 0.5200 0.4375 0.4136 0.4188 0.8053
Ʃ 0.9565 1.0171 1.0000 1.0000

Berdasarkan hasil perhitungan, yang memenuhi adalah V=0,2725 dengan komposisi x i seperti pada tabel
 129.2740
yi/Ki
0.0062
0.0751
0.9187
1.0000

386.1682
Kixi
0.5492
0.2195
0.2313
1.0000

Nitromethane
B C
3331.7 227.6

P dew Ki V yi L xi
1.7795 0.5087 0.2636 0.2859
101.5158 0.8895 0.7364 0.3389 0.3810
0.4575 0.1524 0.3331
1.0000 1.0000
mposisi x i seperti pada tabel