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Origin of saline fluids in epithermal base metal


deposits

Conference Paper · June 2014

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3 authors, including:

Bertrand Rottier Kalin Kouzmanov


University of Bayreuth University of Geneva
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Goldschmidt Conference

Origin of saline fluids in epithermal


base metal deposits
B. ROTTIER 1*, K. KOUZMANOV 1, L. FONTBOTÉ 1
1
University of Geneva, CH-1205 Geneva, Switzerland
(*correspondence: Bertrand.Rottier@unige.ch)

Certain epithermal base metal deposits have fluid


inclusion salinities as high as 22 wt% NaCl equiv. [1].
Typical intermediate density fluids exolving directly from a
magma have salinities between 3 and 8 wt% NaCl equiv.
Fluid salinities above this values are generally explained by
boiling and/or mixing with basinal brines. However, in some
epithermal base metal deposits, neither boiling nor mixing
with basinal brines could be evidenced [1]. Other studies [2,
3] suggest deep mixing of magmatic brines with meteoric
water to explain the rise and recording of these “high salinity”
fluids in the epithermal environment.
Based on fluid inclusion analyses from the early
mineralizing stages at Cerro de Pasco, central Peru, we
propose another mechanism to explain such “high salinity”
fluids in the shallow epithermal environment. Early
mineralization is characterised by an early stage of pyrrhotite-
dominated pipes that grade outwards into massive Fe-rich
sphalerite and galena rims. During a subsequent mineralizing
event, a massive pyrite-quartz body was emplaced followed
by a new stage of polymetallic mineralization.
In the present work, primary and pseudo-secondary fluid
inclusion assemblages (FIAs) in quartz and Fe-rich sphalerite
from the first stage and in quartz from the second one, have
been studied. No evidence of boiling has been observed. FIAs
show a progressive salinity decrease with time from 16.2 to
2.7 wt% NaCl equiv. at relatively constant homogenization
temperature (280-220°C). Oxygen isotope analyses in quartz
from the pyrite-quartz body revealed a strong magmatic
signature of the fluids [4]. The results are compatible with
mixing between two magmatic fluids, a brine previously
exsolved from the magma and stored at depth, and a low-
salinity one (~3 wt% NaCl equiv.), exsolving directly from a
new magma batch. This mechanism, can explain the rise of
fluids derived from magmatic brines, known to be rich in base
metals and therefore explaining the high Zn-Pb-(Ag) grades
of such deposits, whithout invoking mixing with meteoric
fluids at considerable depth.

[1] Albinson et al. (2001) Econ. Geol. SP8, 1-32. [2]


Simmons (1991) Econ. Geol. 86, 1579-1601. [3] Bendezu
(2007), Terre & environnmenent, 66, 167p. [4] Baumgartner
et al. (2008) Econ. Geol. 103, 493-537.

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