Appendiks A

APPENDIX A
PERHITUNGAN NERACA MASSA
A.1 Production Capacity Calculation

Determination of the amount of raw materials such as rice straw that is based on production capacit
Biogasoline production capacity of this plant for 1,206,000
Table A.1 Annual Data Demand Supply (ESDM, 2013)

Basis 1 Tahun
Unit kiloliters
production import export
RON 92 421243.9 268000 13347.6
RON 88 10776439 18340000 -
RON 95 23053 60000 -
Tabel A.2
Unit (KL) Target of fulfillment
total requirement 30371268
0.01
production 11197682.9
import 18668000 density of pertamax kg / m3
percentage of fulfillment 36.8693295914 max
Deficit (m3) 19173585.1 min
sumber : (pertamina, 2016)
Base =
Time of operation =
density of Gasoline =
Plant capacity per year (m3) =
Capacity (kg) =
Plant capacity every day, kg =
plant capacity per hour, kg/hour =
Overall conversion
requirement of rice
of torrefied straw
biomass, =
kg / hr =
requirement of rice straw ton/hr =
requirement of rice straw ton/year =
Land (Ha) =
Productivity of rice straw (tons / year) =
A.2 Principal Component Mass Balance Calculations

Area 1 Pretreatment of Raw Material
A.2.1 Rotary Knife Cutter (F-101)
140
Function: for downsizing (size reduction) of the feed of 70-140 cm 2-5 cm
Information : Assumption :
Stream 2, rice straw 1. The continuous steady state of operating conditions
Stream 3, Rice straw that had been 2. The entire flow is considered ideal
3. No accumulation
Total Feed Inlet 141233.9973884 kg/hr

Tabel A.3 Proximate Analysis Rice Straw (Jenkens et al., 2008)
Input (Aliran 2)
Component Contents
Mass (kg/hr) Moles (kgmol/hr)
(%mass)
Moisture 0.2400 33896.1594 2824.6799
Volatile gas 0.6547 70274.0825 70274.0825
Fixed Carbon 0.1586 17023.7811 1063.9863
Ash 0.1867 20039.9744
Total Feed 1.2400 141233.9974
A.2.2 Torification
Function : straw rice combustion to became coal like material atau torrified biomass
Information :
Stream 3, Rice straw that had been cut
Stream 4, Volatile gas
Stream 5, Torrified biomass
Assumption :
1. The continuous steady state of operating conditions
2. The entire flow is considered ideal
3. No accumulation
4. Torrification products in the form of solids and gases with a ratio of 7: 3 (Bong, 2012)
Tabel A.4 Torrification mass balance calculation based on proximate analysis (R-101)
Input
Stream 3
Component
% mass Mass (kg/hr) Moles (kgmol/hr)
Volatile gas 0.6547 92465.8981 -
Fixed Carbon 0.1586 22399.7120 -
Ash 0.1867 26368.3873 -
141
Total 1.0000 141233.9974 -
Total overall 141233.997388393
Output
Stream 5
Component Moles
% mass Mass (kg/hr)
(kgmol/hr)
Volatile gas 0.5067 50095.6989

Fixed Carbon 0.4933 22399.7120 1866.6427
Ash 26368.3873 26368.3873
Total 98863.7982
Total overall 141233.9974
Information
In torrification, no reaction occurs in the reactor, but the warming causes the content of the v
substances in the straw evaporates and there is no ending up in torrified biomass. Products to
biomass = 70% of the straw input while volatile product gas that evaporates = 30% of rice straw inp
Stream 5 (Torrified Biomass) =70% x total overall input straw rice

= 98863.79817188 kg/hr
In torrification, fixed carbon and ash does not evaporate, only the volatile gas that evaporates so th
volatile substances from the constituent of torrified straw biomass can be calculated
volatile gas in torrified biomass = stream 5 total output - fixed carbon mass - ash
= 50095.69887366
volatile content that still remain will evaporate and become gas in stream 4
able A.5. Torifikasi mass balance calculation on the basis of analysis Ultimate (R-101)
Input
Component Stream 3
C 0.4870 67426.1017 5618.8418
H 0.0592 5473.4338 5473.4338
O 0.4420 40865.8404 2554.1150
N 0.0105 970.7949 69.3425
S 0.0014 129.4393 4.0450
ash 26368.3873
1.0000 141233.9974
total overall 141233.9974
www.ecn.nl/phyllis
Output
Component
142
Component Stream 5
C 0.4540 45143.1593 3761.9299
H 0.0630 3156.0290 3156.0290
O 0.4710 23595.0742 1474.6921
N 0.0100 500.9570 35.7826
S 0.0020 100.1914 3.1310
ash 26368.3873
1.0000 98863.7982
total overall 141233.9974
Bergman, et. Al.
A.2.3 Gasifier (R-102)

Function: reacting raw materials to produce syngas through a gasification process
Keterangan : Assumption :
Stream 10, torrified biomass 1. The continuous steady state of operating conditions
Stream 14, saturated steam 2. The entire flow is considered ideal
Stream 15, Ash 3. No accumulation
Stream16, Syngas from gasifier 4. isothermal operating conditions at a temperature of 890 ° C an
Stream 17, sand 5. Gasifier used is fluidized bed combustion by indirect use of sa
medium). sand entrained flow gasification syngas as much as 5%
the reactor
Table A.6 molecular weight compounds in the gasification reaction

Molecular weight
Component
(Kg/Kgmol)
Carbon monoxideCO 28
carbon Dioxide CO2 44
Water H2O 18
methane CH4 16
Hydrogen H2 2
Carbon C 12
ethene C2H4 28
Hydrochloric aci HCl 36.5
hydrogen SulfideH2S 34
Oxygen O2 32
143
sulfur S 32
Reaksi :
1 C+ H2O--> CO+ H2
2 CO + H2O --> H2 + CO2
3 C + 2H2 --> CH4
4 C+ 0.5O2 --> CO
5 C+ O2 --> CO2
6 2CO + 4H2 --> C2H4 + H2O
7 CH4 + H2O --> CO + 3H2
8 S + H2 --> H2S
9 C+CO2 --> 2CO
Comparison of composition H2O: feed ash free = 1.3
steam 94244.0341173 Kg/hr = 5235.779673183

Feed biomass 98863.79817188 Kg/hr
Requirement of s 18.0284127785 kg sands/feed torrified biomass
= 1782357.362297
Feed ash free 72495.41085946
Table A.7 Ultimate Analysis Torrified Biomass (Syu,2012)
Input
Component Stream 10
%mass (kg/hr) Mol (kgmol/hr)
C 0.4540 45143.1593 3761.9299
H 0.0630 3156.0290 3156.0290
O 0.4710 23595.0742 1474.6921
N 0.0100 500.9570 35.7826
S 0.0020 100.1914 3.1310
ash 0.0000 26368.3873
Sand 0.0000 0.0000
Steam 0.0000 0.0000
Total (ash free) 72495.4109
Total Feed 282225.7004
Reaction
1 Convertion C 0.6080 (Williams, 2015)
C H2O →
m 3761.9299 5235.7797
r 2287.2378 2287.2378
s 1474.6921 2948.5419
144
C 0.5O2 →
m 1474.6921 737.3461
r 1297.7291 648.8645
s 176.9631 88.4815
3 Convertion C 0.5000 (Lettner, 2007)

C O2 →
m 176.9631 88.4815
r 88.4815 88.4815
s 88.4815 0.0000

C 2H2 →
m 88.4815 2287.2378
r 2.6544 5.3089
s 85.8271 2281.9289
5 Convertion C 1 (Lettner, 2007)

C CO2 →
m 85.8271 88.4815
r 85.8271 85.8271
s 0.0000 2.6544

CO H2O →
m 171.6542 2948.5419
r 154.4887 154.4887
s 17.1654 2794.0531
7 Convertion C 0.3 (Lettner, 2007)

2CO 4H2 →
m 17.1654 2281.9289
r 5.1496 10.2992
s 12.0158 2271.6297
8 Convertion CO 1 (Williams, 2015)

S H2 →
m 3.1310 1578.0145
r 3.1310 3.1310
s 0.0000 1574.8835
9 Convertion CH4 0.9 (Williams, 2015)
CH4 H2O →
145
m 2.6544 2794.0531
r 2.3890 2.3890
s 0.2654 2791.6641
Table A.8 composition of gasification outlet

Stream 16 Stream 15
Component
Mol (kgmol/jam) Mass (kg/hr) Mol (kgmol/hr)
H2 4008.1689 8016.3379 0.0000
CO 3599.3717 100782.4069 0.0000
CO2 157.1432 6914.3005 0.0000
CH4 0.2654 4.2471 0.0000
C2H4 2.5748 72.0947 0.0000
O2 0.0000 0.0000 0.0000
H2O 2796.8137 50342.6474 0.0000
N 35.7826 500.9570 0.0000
H2S 3.1310 106.4534 0.0000
Ash 0.0000
Sand 0.0000 89117.8681 0.0000
Total 255857.3131
Total Overall 282225.7004
A.2.4 Cyclone (s-201)

Function: Separation Products (Syngas) from sand
Stream 16, Syngas from gasifier 1. The steady state operating conditions
Stream 18, free sand syngas 2. The entire flow is considered ideal
Stream 17, sand 3. No Accumulation
4. Separation effic 1
Table A.9 Mass Balance Calculation in CYCLONE (s-201)

Input Output
Component Stream 16 Stream 18 Stream 17
Mass (kg/hr) Mass (kg/hr) Mass (kg/hr)
H2 8016.3379 8016.3379 0.0000
CO 100782.4069 100782.4069 0.0000
CO2 6914.3005 6914.3005 0.0000
CH4 4.2471 4.2471 0.0000
146
C2H4 72.0947 72.0947 0.0000
O2 0.0000 0.0000 0.0000
H2O 50342.6474 50342.6474 0.0000
N 500.9570 500.9570 0.0000
H2S 106.4534 106.4534 0.0000
Pasir 89117.8681 0.0000 89117.8681
Ash 0.0000 0.0000 0.0000
Total 255857.3131 166739.4450 89117.8681
Total overall 255857.3131 255857.3131
A.2.5 Entrainment (T-201)

Function: To Separate Tar From Raw Syngas
Stream 19, syngas 1. The steady state operating conditions
Stream 21, free tar syngas 2. The entire flow is considered ideal
Stream 20, tar 3. No Accumulation
4. Asumption all tar condensated
Tabel A.10 Entrainment mass balance calculations(T-201)

Inlet Outlet
H2 8016.3379 8016.3379 0.0000
CO 100782.4069 100782.4069 0.0000
CO2 6914.3005 6914.3005 0.0000
CH4 4.2471 4.2471 0.0000
C2H4 72.0947 0.0000 72.0947
O2 0.0000 0.0000 0.0000
H2O 50342.6474 50342.6474 0.0000
N 500.9570 500.9570 0.0000
H2S 106.4534 106.4534 0.0000
Total 166739.4450 166667.3502 72.0947
Total overall 166739.4450 166739.4450
A.2.6 Mixer M-201
147
Function : for mixing steam and syngas to steam reformer
Information : Assumption :
Stream 13, steam 2. The entire flow is considered ideal
Stream 61, syngas and excess stea 3. No Accumulation
Tabel A.10 Perhitungan neraca massa pada MIxer (M-201)

Inlet Outlet
H2 8016.3379 0.0000 8016.3379
CO 100782.4069 0.0000 100782.4069
CO2 6914.3005 0.0000 6914.3005
CH4 4.2471 0.0000 4.2471
C2H4 0.0000 0.0000 0.0000
O2 0.0000 0.0000 0.0000
H2O 50342.6474 5034.2647 55376.9121
N 500.9570 0.0000 500.9570
H2S 106.4534 0.0000 106.4534
Total 166667.3502 5034.2647 171701.6150
Total overall 171701.6150 171701.6150
Excess H2O 0.1
A.2.6 Steam Reformer R-202

Function: remove CH4 who converted to CO and H2
Information :
Stream 23, syngas
Stream 24, Free CH4 syngas
Assumption :
1. The steady state operating conditions
148
3. No Accumulation
4. CH4 converted 100%
5. The catalyst used selectively against the conversion of CH4 to CO and H2 so as not to
cause any other reaction that mass balance the other components in the syngas fixed
Table A.11 Mass Balance Calculation in Steam Reformer (R-202)

Input Output
Component Stream 23 Stream 24
Moles (kgmol/hr)Mass (kg/hr) Moles (kgmol/hr)
H2 4008.1689 8016.3379 4008.9653
CO 3599.3717 100782.4069 3599.6371
CO2 157.1432 6914.3005 157.1432
CH4 0.2654 4.2471 0.0000
C2H4 0.0000 0.0000 0.0000
O2 0.0000 0.0000 0.0000
H2O 3076.4951 55376.9121 3076.2297
N 35.7826 500.9570 35.7826
H2S 3.1310 106.4534 3.1310
Total 171701.6150 171701.6150
Reaction
1CH4 Conversion 1
CH4 H2O →
m 0.2654 3076.4951
r 0.2654 0.2654
s 0.0000 3076.2297
Information
H2O used in the reaction is H2O contained in the syngas and gas resulting product (CO and H2) is
to the gas CO and H2 at Stream 23
A.2.7 Water Gas Shift (Low Temperature) (R-203)

Function: To Improve H2/CO ratio through CO converted to CO2
Keterangan :
Stream 25, syngas
Stream 26, syngas with ratio CO/H2 = 2
Assumption:
149
3. No Accumulation
Table A.12 Mass Balance Calculation in Reactor WGS (R-203)

Input Output
H2 4008.9653 8017.9306 5085.2568
CO 3599.6371 100789.8394 2523.3456
CO2 157.1432 6914.3005 1233.4347
CH4 0.0000 0.0000 0.0000
C2H4 0.0000 0.0000 0.0000
O2 0.0000 0.0000 0.0000
H2O 3076.2297 55372.1341 1999.9382
N 35.7826 500.9570 35.7826
H2S 3.1310 106.4534 3.1310
Total 171701.6150
Reaction
1 CO Convertion 0.299
CO H2O →
m 3599.6371 3076.2297
r 1076.2915 1076.2915
s 2523.3456 1999.9382
Information
Conversion of CO in the reaction had been trial to get the ratio CO / H2 in syngas with range 2
A.2.8 CO2 Absorber (T-202)

Function : CO2 adsorption
T-
2
0
2
Information :
Stream 27, Syngas
Stream 40, Free CO2 Syngas
Stream 28, Absorbent (MDEA) and CO2
Stream 39, Absorbent (MDEA) from stripper
Assumption:
150
3. No Accumulation
4. Absorbent Efficiency 1
5. Molecular Weight 119.163 kg/kgmol
6 MDEA Concentration (wt%) 19.2
7. Calculation of absorbent based on Acid Gas loading
Table A.13. MDEA Calculation

moles acid
gas/moles amine MDEA Needed
H2S 0.89 mol H2S/0,89 3.5180
CO2 0.79 mol CO2/0,79 1561.3097
Table A.14 Mass Balance Calculation in Absorber Tower (R-204)

Inlet
H2 5085.2568 10170.5136 0.0000
CO 2523.3456 70653.6774 0.0000
CO2 1233.4347 54271.1265 0.0000
CH4 0.0000 0.0000 0.0000
C2H4 0.0000 0.0000 0.0000
O2 0.0000 0.0000 0.0000
H2O 1999.9382 35998.8872 0.0000
N 35.7826 500.9570 0.0000
H2S 3.1310 106.4534 0.0000
Absorbent MDE 0.0000 0.0000 1564.8277
Rich MDEA 0.0000
10880.8889 171701.6150
Total 358171.1775
Outlet
H2 5085.2568 10170.5136 0.0000
CO 2523.3456 70653.6774 0.0000
CO2 0.0000 0.0000 0.0000
CH4 0.0000 0.0000 0.0000
C2H4 0.0000 0.0000 0.0000
O2 0.0000 0.0000 0.0000
H2O 0.0000 0.0000 1999.9382
N 35.7826 500.9570 0.0000
151
H2S 0.0000 0.0000 0.0000
Absorbent MDE 0.0000 0.0000 0.0000
Rich MDEA 0.0000 0.0000 1564.8277
81325.1480
Total 358171.1775
A.2.9 Stripper Column (T-203)

Function: To regenerate absorbent and release CO2 dan H2S
T-203
Information : Assumption:
Stream 29, Liquid absorbent with 1. The steady state operating conditions
Stream 30, CO2, water, and H2S 2. The entire flow is considered ideal
Stream 38, Absorbent 3. No Accumulation
4. Oil Assumtion =
5. Stripper Efficiency
Table A.15 Mass Balance Calculation in Stripper Column (T-202)

Inlet Outlet
H2 0.0000 0.0000 0.0000
CO 0.0000 0.0000 0.0000
CO2 0.0000 54271.1265 0.0000
CH4 0.0000 0.0000 0.0000
C2H4 0.0000 0.0000 0.0000
O2 0.0000 0.0000 0.0000
H2O 35998.8872 35998.8872
N 0.0000 0.0000 0.0000
H2S 0.0000 106.4534 0.0000
Absorbent MDEA 0.0000 186469.5625
Rich MDEA 240847.1424 0.0000 0.0000
Total 276846.0296 90376.4670 0.0000
Total Overall 276846.0296 276846.0296
A.2.10 Reflux Drum (V-202)

Function: Refluxing part of H2O back into the striper and the other half in blowdown
so the MDEA absorbent concentration in stripper still constant.
152
Stream 31, H2O, CO2 and stripper output H2S 1. The steady state operating conditions
Stream 32, H2S and CO2 gas 2. The entire flow is considered ideal
Stream 33, Blowdown H2O 3. No Accumulation
Stream 34, H2O returned to stripper
Calculation :
MDEA Absorbent in Stripper (kg/hr) = 186469.5625482
consist of MDEA 19.2% x MDEA Solution =
H2O (100-19.2)% x MDEA Solution =
Total
Syngas input H2O 35998.88716115

So the amount H2O in stripper is H2O from MDEA solution and H2O from syngas
= 186666.2937001
H2O in stripper vaporated 90%
Table A.16 Mass Balance Calculation in Reflux Drum (V-202)

Inlet Outlet
H2 0.0000 0.0000 0.0000
CO 0.0000 0.0000 0.0000
CO2 54271.1265 54271.1265 0.0000
CH4 0.0000 0.0000 0.0000
C2H4 0.0000 0.0000 0.0000
O2 0.0000 0.0000 0.0000
H2O 167999.6643 0.0000 35998.8872
N 0.0000 0.0000 0.0000
H2S 106.4534 106.4534 0.0000
Absorbent MDE 0.0000 0.0000 0.0000
Rich MDEA 0.0000 0.0000 0.0000
Total 222377.2442 54377.5799 35998.8872
Total Overall 222377.2442 222377.2442
A.2.11 Fischer Tropsch SAS Reactor (R-204 dan R-205)

Function: To convert syngas become hydrocarbon mixture chain C1-C20
R-204-R-205
153
Stream 46, Hydrocarbon 2. The entire flow is considered ideal
3. No Accumulation
Selektivitas Produk (Sasol, 2012)
perhitungan konversi didasari oleh trial and er
data selektifitas proses High Temperature
(Proses trial error dapat dilihat di sheet Detail
dengan link berikut
detail perhitungan
Table A.17 Mass Balance Calculation in Fischer Tropsch SAS Reactor (R-206 dan R-207)
Inlet
Component Mr (kg/kgmol) Stream 41
Mol (kgmol/hr) Mass (kg/hr)
CO 28 2523.3456 70653.6774
H2 2 5085.2568 10170.5136
CH4 16 0.0000 0.0000
C2H6 30 0.0000 0.0000
C2H4 28 0.0000 0.0000
C3H8 44 0.0000 0.0000
C3H6 42 0.0000 0.0000
C4H8 56 0.0000 0.0000
C4H10 58 0.0000 0.0000
C5H12 72 0.0000 0.0000
C6H14 86 0.0000 0.0000
C6H6 78 0.0000 0.0000
C7H16 100 0.0000 0.0000
C8H18 114 0.0000 0.0000
C9H20 128 0.0000 0.0000
C10H22 142 0.0000 0.0000
C11H24 156 0.0000 0.0000
C12H26 170 0.0000 0.0000
154
C13H28 184 0.0000 0.0000
C14H30 198 0.0000 0.0000
C15H32 212 0.0000 0.0000
C16H34 226 0.0000 0.0000
C17H36 240 0.0000 0.0000
C18H38 254 0.0000 0.0000
C19H40 268 0.0000 0.0000
C20H42 282 0.0000 0.0000
C30H62 422 0.0000 0.0000
C3H6O 58 0.0000 0.0000
C3H6O2 74 0.0000 0.0000
H20 18 0.0000 0.0000
Total 80824.1910
Reaction
CO 3H2 ->
m 2523.3456 5085.2568
r 17.5505 52.6516
s 2505.7951 5032.6052
2CO 5H2 ->
m 2505.7951 5032.6052
r 13.9417 34.8542
s 2491.8534 4997.7509
2CO 4H2 ->
m 2491.8534 4997.7509
r 6.9389 13.8778
s 2484.9145 4983.8731
3CO 7H2 ->
m 2484.9145 4983.8731
r 24.8552 57.9954
s 2460.0593 4925.8777
3CO 6H2 ->
m 2460.0593 4925.8777
155
r 24.6006 49.2012
s 2435.4587 4876.6765
4CO 9H2 ->
m 2435.4587 4876.6765
r 141.5439 318.4737
s 2293.9148 4558.2028
4CO 8H2 ->
m 2293.9148 4558.2028
r 13.4947 26.9893
s 2280.4202 4531.2135
5CO 11H2 ->
m 2280.4202 4531.2135
r 47.6567 104.8448
s 2232.7635 4426.3687
6CO 13H2 ->
m 2232.7635 4426.3687
r 22.3276 48.3765
s 2210.4358 4377.9922
7CO 15H2 ->
m 2210.4358 4377.9922
r 80.1344 171.7167
s 2130.3014 4206.2755
6CO 9H2 ->
m 2130.3014 4206.2755
r 2.1303 3.1955
s 2128.1711 4203.0800
8CO 17H2 ->
m 2128.1711 4203.0800
r 294.9782 626.8286
156
s 1833.1929 3576.2514
9CO 19H2 ->
m 1833.1929 3576.2514
r 239.5249 505.6636
s 1593.6680 3070.5878
10CO 21H2 ->
m 1593.6680 3070.5878
r 57.3520 120.4391
s 1536.3161 2950.1487
11CO 23H2 ->
m 1536.3161 2950.1487
r 32.0019 66.9130
s 1504.3142 2883.2357
12CO 25H2 ->
m 1504.3142 2883.2357
r 31.2634 65.1321
s 1473.0508 2818.1036
13CO 27H2 ->
m 1473.0508 2818.1036
r 1.9619 4.0747
s 1471.0889 2814.0289
14CO 29H2 ->
m 1471.0889 2814.0289
r 55.0092 113.9477
s 1416.0797 2700.0812
15CO 31H2 ->
m 1416.0797 2700.0812
r 94.9542 196.2386
s 1321.1255 2503.8426
157
16CO 33H2 ->
m 1321.1255 2503.8426
r 85.9117 177.1930
s 1235.2138 2326.6497
17CO 35H2 ->
m 1235.2138 2326.6497
r 80.3386 165.4030
s 1154.8752 2161.2467
18CO 37H2 ->
m 1154.8752 2161.2467
r 69.4745 142.8088
s 1085.4006 2018.4379
19CO 39H2 ->
m 1085.4006 2018.4379
r 65.3720 134.1846
s 1020.0287 1884.2533
20CO 41H2 ->
m 1020.0287 1884.2533
r 45.6118 93.5042
s 974.4168 1790.7491
30CO 61H2 ->
m 974.4168 1790.7491
r 676.9493 1376.4636
s 297.4675 414.2854
3CO 5H2 ->
m 297.4675 414.2854
r 7.1302 11.8836
s 290.3373 402.4018
158
3CO 4H2 ->
m 290.3373 402.4018
r 37.9998 50.6664
s 252.3376 351.7354
A.2.12 Flash Separator (T-204)

Function: separate hydrocarbon mixture chain C1-C20
T-204
Stream 48, hydrocarbon mixture chain C1-C20 1. The steady state operating conditions
Stream 49, hydrocarbon mixture chain C1-C4 2. The entire flow is considered ideal
Stream 50, hydrocarbon mixture chain C4-C20 3. No Accumulation
perhitungan berdasarkan flash calculation (vannes, 2006) dapat dilihat d
Tabel A.18 Mass Balance Calculation Flash Separator (T-204)

Inlet Outlet
CO 7065.4514 7062.8216 2.6299
H2 703.4708 703.4708 0.0000
CH4 280.8086 279.6344 1.1742
C2H6 209.1255 197.1529 11.9726
C2H4 97.1445 93.6958 3.4487
C3H8 364.5426 291.2062 73.3364
C3H6 344.4084 284.5780 59.8304
C3H6O 137.8503 24.6144 113.2359
C3H6O2 937.3276 3.5438 933.7838
C4H8 188.9253 107.6429 81.2825
C4H10 2052.3861 1240.1630 812.2231
C5H12 686.2567 171.5160 514.7407
iC5H12 0.0000 0.0000
C6H14 320.0294 30.2638 289.7657
iC6H14 0.0000 0.0000
C6H6 27.6939 0.0000 27.6939
159
C6H12 0.0000 0.0000
C7H16 1144.7778 38.1541 1106.6238
C8H18 4203.4390 47.2905 4156.1484
C9H20 3406.5757 12.8875 3393.6882
C10H22 814.3979 1.0458 813.3521
C11H24 453.8448 0.2068 453.6380
C12H26 442.8980 0.0778 442.8202
C13H28 27.7686 0.0014 27.7672
C14H30 777.9876 0.0120 777.9756
C15H32 1342.0187 0.0087 1342.0100
C16H34 1213.5034 0.0027 1213.5007
C17H36 1134.1920 0.0007 1134.1913
C18H38 980.3629 0.0002 980.3627
C19H40 922.0891 0.0000 922.0891
C20H42 643.1266 0.0000 643.1266
C30H62 9522.4206 0.0000 9522.4206
H20 40379.3669 841.2927 39538.0742
80824.1910 11431.2842 69392.9067
Total Overall 80824.1910 80824.1910
A.2.13 Gravity settling (T-206)

Function : separation of hydrocarbon and water based on difference in density with 98% water sepa
T-
206
Stream 50, hydrocarbon mixture chain C5 - C20 and 1. The steady state operating conditions
Stream 65,hydrocarbon mixture chain C5-C20 2. The entire flow is considered ideal
Stream 56, water 3. No Accumulation
densitas air 1000 kg/m3

rataan densitas C1-C30 792 kg/m3
diasumsikan air pada bottom product sebesar 98% air pada aliran 50
Tabel A.19 Mass balance calculation in Gravity Settling (T-206)

inlet outlet
Mass (kg/hr)
CO 2.6299 2.6299 0.0000
160
H2 0.0000 0.0000 0.0000
CH4 1.1742 1.1742 0.0000
C2H6 11.9726 11.9726 0.0000
C2H4 3.4487 3.4487 0.0000
C3H8 73.3364 73.3364 0.0000
C3H6 59.8304 59.8304 0.0000
C3H6O 113.2359 113.2359 0.0000
C3H6O2 933.7838 933.7838 0.0000
C4H8 81.2825 81.2825 0.0000
C4H10 812.2231 812.2231 0.0000
C5H12 514.7407 514.7407 0.0000
iC5H12 0.0000 0.0000 0.0000
C6H14 289.7657 289.7657 0.0000
iC6H14 0.0000 0.0000 0.0000
C6H6 27.6939 27.6939 0.0000
C6H12 0.0000 0.0000 0.0000
C7H16 1106.6238 1106.6238 0.0000
C8H18 4156.1484 4156.1484 0.0000
C9H20 3393.6882 3393.6882 0.0000
C10H22 813.3521 813.3521 0.0000
C11H24 453.6380 453.6380 0.0000
C12H26 442.8202 442.8202 0.0000
C13H28 27.7672 27.7672 0.0000
C14H30 777.9756 777.9756 0.0000
C15H32 1342.0100 1342.0100 0.0000
C16H34 1213.5007 1213.5007 0.0000
C17H36 1134.1913 1134.1913 0.0000
C18H38 980.3627 980.3627 0.0000
C19H40 922.0891 922.0891 0.0000
C20H42 643.1266 643.1266 0.0000
C30H62 9522.4206 9522.4206 0.0000
H20 39538.0742 790.7615 38747.3128
Total 69392.9067 69392.9067
75% Bottom Product yang dihasilkan akan dialirkan ke unit utilitas setelah melalui proses pemurnia
Produk air yang dibuang ke lingku 9686.828189717 kg/hr
A.2.13 Distillation (T-207) 59
Function: Separate hydrocarbon mixture chain C5-C20
T-207
161
Stream 50, hydrocarbon mixture chain C5 - C20 1. The steady state operating conditions
Stream 65, hydrocarbon mixture chain C5 - C12 2. The entire flow is considered ideal
Stream 56, hydrocarbon mixture chain C13 - C20 3. No Accumulation
Komposisi 65 dan 58 ditentukan maka kondisi operasi destilator dapat ditetapkan

detail perhitungan pada Sheet Destilasi T-207
Tabel A.19 Mass balance Calculation in Distillation (T-207)
Input Output
Component 57 59 58
CO 2.6299 2.6299 0.0000
H2 0.0000 0.0000 0.0000
CH4 1.1742 1.1742 0.0000
C2H6 11.9726 11.9726 0.0000
C2H4 3.4487 3.4487 0.0000
C3H8 73.3364 73.3364 0.0000
C3H6 59.8304 59.8304 0.0000
C3H6O 113.2359 113.2359 0.0000
C3H6O2 933.7838 933.7838 0.0000
C4H8 81.2825 81.2825 0.0000
C4H10 812.2231 812.2231 0.0000
C5H12 514.7407 514.7407 0.0000
iC5H12 0.0000 0.0000 0.0000
C6H14 289.7657 289.7657 0.0000
iC6H14 0.0000 0.0000 0.0000
C6H6 27.6939 27.6939 0.0000
C6H12 0.0000 0.0000 0.0000
C7H16 1106.6238 1106.6238 0.0000
C8H18 4156.1484 4156.1484 0.0000
C9H20 3393.6882 3393.6882 0.0000
C10H22 813.3521 813.3521 0.0000
C11H24 453.6380 453.6380 0.0000
C12H26 442.8202 398.5382 44.2820
C13H28 27.7672 2.7767 24.9905
C14H30 777.9756 777.9756
C15H32 1342.0100 1342.0100
C16H34 1213.5007 1213.5007
C17H36 1134.1913 1134.1913
C18H38 980.3627 980.3627
C19H40 922.0891 922.0891
C20H42 643.1266 643.1266
C30H62 9522.4206 9522.4206
162
H20 790.7615 790.7615
0 30645.5940 13249.8833 17395.7107
Total Overall 30645.5940 30645.5940
59
A.2.14 C5-C6 Isomerization (R-206) 66
R-206
Function: isomerization hydrocarbon mixture chain C5-C6
Information :
Stream 114; C3H6O, C3H6O2, C5H12, C6H14, iC6H14, and C6H12
Stream 115; C3H6O, C3H6O2, iC5H12, C6H14, iC6H14, and few C6H12
Assumption:
3. No Accumulation
Tabel A.20 Mass balance calculation in C-C6 isomerization reactor (T-207)

Inlet Outlet
Component 59 66
Mass (kg/hr) Mass (kg/hr)
CO 2.6299 2.6299
H2 0.0000 0.0000
CH4 1.1742 1.1742
C2H6 11.9726 11.9726
C2H4 3.4487 3.4487
C3H8 73.3364 73.3364
C3H6 59.8304 59.8304
C3H6O 113.2359 113.2359
C3H6O2 933.7838 933.7838
C4H8 81.2825 81.2825
C4H10 812.2231 812.2231
C5H12 514.7407 25.7370
C6H14 289.7657 14.4883
C6H6 27.6939 27.6939
C6H12 0.0000 0.0000
C7H16 1106.6238 1106.6238
C8H18 4156.1484 4156.1484
C9H20 3393.6882 3393.6882
C10H22 813.3521 813.3521
163
C11H24 453.6380 453.6380
C12H26 398.5382 398.5382
C13H28 2.7767 2.7767
C14H30 0.0000 0.0000
C15H32 0.0000 0.0000
C16H34 0.0000 0.0000
C17H36 0.0000 0.0000
C18H38 0.0000 0.0000
C19H40 0.0000 0.0000
C20H42 0.0000 0.0000
C30H62 0.0000 0.0000
H20 0.0000 0.0000
iC5H12 0.0000 489.0037
iC6H14 0.0000 275.2774
Total Overall 13249.8833 13249.8833
Molekul BM (kg/kmol)
C6H14 86
C5H14 74
1 Reaction
Conversion 0.95
C6H14 => iC6H14
m (kmol/hr) 3.3694
r 3.2009 3.2009
s 0.1685 3.2009
2 Conversion 0.9500
C5H12 => iC5H12
m (kmol/hr) 6.9560
r 6.6082 6.6082
s 0.3478 6.6082
A.2.15 C7-C12 Isomerization Reactor (R-208)

R-207
Function: isomerization hydrocarbon mixture chain C7-C11
164
Stream 66; C7-C11 1. The steady state operating conditions
Stream 67; C7-C12 and iC7-iC9 2. The entire flow is considered ideal
3. No Accumulation
Tabel A.21 Mass balance calculation in C7-C12 Isomerization (R-208)

Inlet Outlet
Component 66 67
Mass (kg/hr) Mass (kg/hr)
CO 2.6299 2.6299
H2 0.0000 0.0000
CH4 1.1742 1.1742
C2H6 11.9726 11.9726
C2H4 3.4487 3.4487
C3H8 73.3364 73.3364
C3H6 59.8304 59.8304
C3H6O 113.2359 113.2359
C3H6O2 933.7838 933.7838
C4H8 81.2825 81.2825
C4H10 812.2231 812.2231
C5H12 25.7370 25.7370
C6H14 14.4883 14.4883
C6H6 27.6939 27.6939
C6H12 0.0000 0.0000
C7H16 1106.6238 110.6624
C8H18 4156.1484 415.6148
C9H20 3393.6882 339.3688
C10H22 813.3521 813.3521
C11H24 453.6380 453.6380
C12H26 398.5382 398.5382
C13H28 2.7767 2.7767
C14H30 0.0000 0.0000
C15H32 0.0000 0.0000
C16H34 0.0000 0.0000
C17H36 0.0000 0.0000
C18H38 0.0000 0.0000
C19H40 0.0000 0.0000
C20H42 0.0000 0.0000
C30H62 0.0000 0.0000
H20 0.0000 0.0000
iC5H12 489.0037 489.0037
iC6H14 275.2774 275.2774
165
iC7H16 0.0000 995.9614
iC8H18 0.0000 3740.5336
iC9H20 0.0000 3054.3194
Total 13249.8833 13249.8833
Senyawa BM
C7H16 100
C8H18 112
C9H20 128
Reaction
Conversion for all reactions : 0.9
1 C7H16 => iC7H16
m (kmol/hr) 11.0662
r 9.9596 9.9596
s 1.1066 9.9596
2 C8H18 => iC8H18
m (kmol/hr) 37.1085
r 33.3976 33.3976
s 3.7108 33.3976
3 C9H20 => iC9H20
m (kmol/hr) 26.5132
r 23.8619 23.8619
s 2.6513 23.8619
catalyst to feed ratio 0.1

catalyst 1324.988325182 kg
regeneration time/yr 2
kebutuhan katalis/yr 2649.976650364 kg
A.2.16 Flash Separator T-209

Fungsi: Pemisahan light hydrocarbon vapour C1-C5 dengan liquid hydrocarbon
Prinsip Perhitungan menggunakan persamaan dibawah
72 (overhead)
T-209
(vannnes, 2010)
70 (bottom
Detail perhitungan )
166
inlet outlet
Component
68 70 72
CO 2.6299 0.0081 2.6218
H2 0.0000 0.0000 0.0000
CH4 1.1742 0.0395 1.1347
C2H6 11.9726 4.0092 7.9634
C2H4 3.4487 0.8063 2.6424
C3H8 73.3364 49.5860 23.7504
C3H6 59.8304 38.0181 21.8123
C3H6O 113.2359 110.3427 2.8932
C3H6O2 933.7838 933.3566 0.4273
C4H8 81.2825 70.0867 11.1958
C4H10 812.2231 685.8970 126.3261
C5H12 25.7370 24.7426 0.9945
C6H14 14.4883 14.3080 0.1803
C6H6 27.6939 27.6939 0.0000
C6H12 0.0000 0.0000 0.0000
C7H16 110.6624 110.2041 0.4583
C8H18 415.6148 415.0452 0.5697
C9H20 339.3688 339.2134 0.1554
C10H22 813.3521 813.2260 0.1261
C11H24 453.6380 453.6130 0.0249
C12H26 398.5382 398.5298 0.0084
C13H28 2.7767 2.7767 0.0000
C14H30 0.0000 0.0000 0.0000
C15H32 0.0000 0.0000 0.0000
C16H34 0.0000 0.0000 0.0000
C17H36 0.0000 0.0000 0.0000
C18H38 0.0000 0.0000 0.0000
C19H40 0.0000 0.0000 0.0000
C20H42 0.0000 0.0000 0.0000
C30H62 0.0000 0.0000 0.0000
H20 0.0000 0.0000 0.0000
iC5H12 489.0037 464.4550 24.5487
iC6H14 275.2774 274.7578 0.5195
iC7H16 995.9614 995.9614 0.0000
iC8H18 3740.5336 3736.3108 4.2228
iC9H20 3054.3194 3054.3194 0.0000
Total 13249.8833 13249.8833
A.2.17 Demetanizer (T-204)

T-205
Fungsi: separate methane from hydrocarbon mixture chain C1-C4
167
Stream 52; CO, H2 and hydrocarbon mixture chain 1. The steady state operating conditions
Chain 53; CO, H2, C1 2. The entire flow is considered ideal
Stream 54; hydrocarbon mixture chain C2-C4 3. No Accumulation
4. Assume separation 90%
Prinsip Perhitungan
(vannes, 2010)
Tabel A.23 Mass balance calculation in Demetanizer (T-205)

Inlet Outlet
CO 7062.8216 7062.8216 0.0000
H2 703.4708 703.4708 0.0000
CH4 279.6344 279.6344 0.0000
C2H6 197.1529 157.7223 39.4306
C2H4 93.6958 4.6848 89.0110
C3H8 291.2062 14.5603 276.6459
C3H6 284.5780 14.2289 270.3491
C3H6O 24.6144 1.2307 23.3836
C3H6O2 3.5438 0.1772 3.3666
C4H8 107.6429 0.0000 107.6429
C4H10 1240.1630 0.0000 1240.1630
C5H12 171.5160 0.0000 171.5160
iC5H12 0.0000 0.0000 0.0000
C6H14 30.2638 0.0000 30.2638
iC6H14 0.0000 0.0000 0.0000
C6H6 0.0000 0.0000 0.0000
C6H12 0.0000 0.0000 0.0000
C7H16 38.1541 0.0000 38.1541
C8H18 47.2905 0.0000 47.2905
C9H20 12.8875 0.0000 12.8875
C10H22 1.0458 0.0000 1.0458
C11H24 0.2068 0.0000 0.2068
168
C12H26 0.0778 0.0000 0.0778
C13H28 0.0014 0.0000 0.0014
C14H30 0.0120 0.0000 0.0120
C15H32 0.0087 0.0000 0.0087
C16H34 0.0027 0.0000 0.0027
C17H36 0.0007 0.0000 0.0007
C18H38 0.0002 0.0000 0.0002
C19H40 0.0000 0.0000 0.0000
C20H42 0.0000 0.0000 0.0000
C30H62 0.0000 0.0000 0.0000
H20 841.2927 168.2585 673.0341
8406.7895 3024.4947
Total Overall 11431.2842 11431.2842
58 62
R-208
A.2.18 Fluid Catalytic Cracking (R-208)
Function: Break hydrocarbon mixture chain to a simple one
Stream 59; hydrocarbon mixture chain C13-C20 and 1. The steady state operating conditions
Stream 62; hydrocarbon mixture chain C3-C20 and C2. The entire flow is considered ideal
3. No Accumulation
Tabel A.24 Mass balance calculation in Fluid Catalytic Cracking (R-208)

Inlet
Component Mr (kg/kgmol) 58
Mass (kg/hr) Mol (kgmol/hr)
CO 28 0.0000 0.0000
H2 2 0.0000 0.0000
CH4 16 0.0000 0.0000
C2H6 30 0.0000 0.0000
C2H4 28 0.0000 0.0000
C3H4 40 0.0000 0.0000
C3H8 44 0.0000 0.0000
C3H6 42 0.0000 0.0000
C4H8 56 0.0000 0.0000
C4H10 58 0.0000 0.0000
C5H12 72 0.0000 0.0000
iC5H12 72 0.0000 0.0000
169
C6H14 86 0.0000 0.0000
iC6H14 86 0.0000 0.0000
C6H6 78 0.0000 0.0000
C6H12 84 0.0000 0.0000
C7H16 100 0.0000 0.0000
C8H18 114 0.0000 0.0000
C9H20 128 0.0000 0.0000
C10H22 142 0.0000 0.0000
C11H24 156 0.0000 0.0000
C12H26 170 44.2820 0.2605
C13H28 184 24.9905 0.1358
C14H30 198 777.9756 3.9292
C15H32 212 1342.0100 6.3302
C15H30 210 0.0000
C16H34 226 1213.5007 5.3695
C17H36 240 1134.1913 4.7258
C18H38 254 980.3627 3.8597
C19H40 268 922.0891 3.4406
C20H42 282 643.1266 2.2806
C30H62 422 9522.4206 22.5650
C3H6O 58 0.0000 0.0000
C3H6O2 74 0.0000 0.0000
H2O 18 790.7615 43.9312
Total 17395.7107
Reaction
1 Conversion 0.9
C13H28 => C9H20
m 0.1358
r 0.1222 0.1222
s 0.0136 0.1222
2 Conversion 0.9
C14H30 => C10H22
m 3.9292
r 3.5363 3.5363
s 0.3929 3.5363
3 Conversion 0.9
C15H32 => C11H24
m 6.3302
r 5.6972 5.6972
s 0.6330 5.6972
170
4 Conversion 0.9
C16H34 => C12H26
m 5.3695
r 4.8325 4.8325
s 0.5369 4.8325
5 Conversion 0.94
C17H36 => C13H28
m 4.7258
r 4.4422 4.4422
s 0.2835 4.4422
6 Conversion 0.92
C18H38 => C14H30
m 3.8597
r 3.5509 3.5509
s 0.3088 3.5509
7 Conversion 0.92
C19H40 => C15H32
m 3.4406
r 3.1654 3.1654
s 0.2753 3.1654
8 Conversion 0.92
C20H42 => C16H34
m 2.2806
r 2.0981 2.0981
s 0.1824 2.0981
9 Conversion 0.92
C30H62 => C15H32
m 22.5650
r 20.7598 20.7598
s 1.8052 20.7598
10 Conversion 0.92
C13H28 => C10H22
m 6.8801
r 6.3297 6.3297
s 0.5504 6.3297
11 Conversion 0.92
171
C14H30 => C11H24
m 3.9438
r 3.6283 3.6283
s 0.3155 3.6283
12 Conversion 0.9
C15H32 => C12H26
m 24.5582
r 22.1024 22.1024
s 2.4558 22.1024
13 Conversion 0.92
C16H34 => C13H28
m 2.6351
r 2.4243 2.4243
s 0.2108 2.4243
14 Conversion 0.93
C15H30 => C12H26
m 20.7598
r 19.3066 19.3066
s 1.4532 19.3066
Catalyst to Feed ratio 0.04

Catalyst 695.8284290637 kg
waktu regenerasi/tahun 2
data konversi dan katalis diambil merujuk pada www.kbrtechnology.com
Kebutuhan katalis 6558 1391.656858127 kg/tahun
A.2.19 Separator T-208 T-208

Function : To separate mixtures of C3-C20 hydrocarbon chain.
Stream 63; hydrocarbon mixture chain C13-C20 and 1. The steady state operating conditions
Stream 64; hydrocarbon mixture chain C9-C30 2. The entire flow is considered ideal
Stream 65; hydrocarbon mixture chain C3-C4 3. No Accumulation
inlet outlet
Component
172
CO 0.0000 0.0000 0.0000
H2 0.0000 0.0000 0.0000
CH4 0.0000 0.0000 0.0000
C2H6 0.0000 0.0000 0.0000
C2H4 0.0000 0.0000 0.0000
C3H4 772.2638 733.9515 38.3123
C3H8 0.0000 0.0000 0.0000
C3H6 1448.3567 1416.9191 31.4377
C4H8 1536.9155 1434.9228 101.9927
C4H10 0.0000 0.0000 0.0000
C5H12 0.0000 0.0000 0.0000
iC5H12 0.0000 0.0000 0.0000
C6H14 0.0000 0.0000 0.0000
iC6H14 0.0000 0.0000 0.0000
C6H6 0.0000 0.0000 0.0000
C6H12 0.0000 0.0000 0.0000
C7H16 0.0000 0.0000 0.0000
C8H18 0.0000 0.0000 0.0000
C9H20 59.9262 4.8856 55.0406
C10H22 1400.9660 47.9088 1353.0573
C11H24 1454.7846 20.7637 1434.0210
C12H26 7861.0525 49.7444 7811.3081
C13H28 101.2753 0.2380 101.0373
C14H30 62.4704 0.0510 62.4194
C15H32 520.6335 0.2046 520.4289
C15H30 305.1688 0.0932 305.0756
C16H34 47.6424 0.0082 47.6343
C17H36 68.0515 0.0046 68.0469
C18H38 78.4290 0.0020 78.4270
C19H40 73.7671 0.0007 73.7664
C20H42 51.4501 0.0003 51.4498
C30H62 761.7937 0.0000 761.7936
C3H6O 0.0000 0.0000 0.0000
C3H6O2 0.0000 0.0000 0.0000
H2O 790.7615 247.2370 543.5244
17395.7087 3956.9353 13438.7734
Total (kg/hr) 17395.7087 17395.7087
69 (overhead)
64 (T-301)
A.2.20 Distillation
Function : Separate product and water
173
Distribusi produk pada vapour dan liquid ditentukan
selanjutnya dilakukan proses trial and eror untuk menentukan suhu dan tekanan operasi overhead, b
detail perhitungan dapat dilihat pada link berikut
inlet outlet
component
64 69 (vapour) 71 (liquid)
CO 0.0000 0.0000
H2 0.0000 0.0000
CH4 0.0000 0.0000
C2H6 0.0000 0.0000
C2H4 0.0000 0.0000
C3H4 38.3123 38.3123
C3H8 0.0000 0.0000
C3H6 31.4377 31.4377
C4H8 101.9927 101.9927
C4H10 0.0000 0.0000
C5H12 0.0000 0.0000
iC5H12 0.0000 0.0000
C6H14 0.0000 0.0000
iC6H14 0.0000 0.0000
C6H6 0.0000 0.0000
C6H12 0.0000 0.0000
C7H16 0.0000 0.0000
C8H18 0.0000 0.0000
C9H20 55.0406 55.0406
C10H22 1353.0573 1353.0573
C11H24 1434.0210 1434.0210
C12H26 7811.3081 7811.3081
C13H28 101.0373 101.0373
C14H30 62.4194 62.4194
C15H32 520.4289 520.4289
C15H30 305.0756 305.0756
C16H34 47.6343 47.6343
C17H36 68.0469 68.0469
C18H38 78.4270 78.4270
C19H40 73.7664 73.7664
C20H42 51.4498 51.4498
174
C30H62 761.7936 761.7936
C3H6O 0.0000 0.0000
C3H6O2 0.0000 0.0000
H2O 543.5244 200.0000 343.5244
Total 13438.7734 13438.7734
Blending
73=70+69
inlet outlet
component stream 69 stream 70 stream 73
kg/hr
CO 0.0000 0.0081 0.0081
H2 0.0000 0.0000 0.0000
CH4 0.0000 0.0395 0.0395
C2H6 0.0000 4.0092 4.0092
C2H4 0.0000 0.8063 0.8063
C3H4 38.3123 0.0000 38.3123
C3H8 0.0000 49.5860 49.5860
C3H6 31.4377 38.0181 69.4558
C3H6O 0.0000 110.3427 110.3427
C3H6O2 0.0000 933.3566 933.3566
C4H8 101.9927 70.0867 172.0794
C4H10 0.0000 685.8970 685.8970
C5H12 0.0000 24.7426 24.7426
C6H6 0.0000 27.6939 27.6939
C6H14 0.0000 14.3080 14.3080
C6H12 0.0000 0.0000 0.0000
C7H16 0.0000 110.2041 110.2041
C8H18 0.0000 415.0452 415.0452
C9H20 55.0406 339.2134 394.2540
C10H22 1353.0573 813.2260 2166.2833
C11H24 1434.0210 453.6130 1887.6340
C12H26 7811.3081 398.5298 8209.8379
C13H28 0.0000 2.7767 2.7767
C14H30 0.0000 0.0000 0.0000
C15H32 0.0000 0.0000 0.0000
C15H30 0.0000 0.0000
C16H34 0.0000 0.0000 0.0000
C17H36 0.0000 0.0000 0.0000
C18H38 0.0000 0.0000 0.0000
C19H40 0.0000 0.0000 0.0000
C20H42 0.0000 0.0000 0.0000
175
C30H62 0.0000 0.0000 0.0000
H2O 200.0000 0.0000 200.0000
iC5H12 0.0000 464.4550 464.4550
iC6H14 0.0000 274.7578 274.7578
iC7H16 995.9614 995.9614
iC8H18 3736.3108 3736.3108
iC9H20 3054.3194 3054.3194
Total 24042.4769 24042.4769
LPG Product Massflow (Kg/hr)

C2H6 39.4306
C2H4 89.0110
C3H8 276.6459
C3H6 270.3491
C4H8 107.6429
C4H10 1240.1630
Total 2023.2425 densitas LPG
Dry Ice (kg/hr) 54271.1265

SNG (kg/hr), m3/ 279.6344
density of CH4 k 0.66
SNG, m3/hr 423.6885016699
Perhitungan Round Of Octane Number Berdasarkan Korelasi RON sebagai fungsi fraksi massa dan
176
componen Tb, Celcius T=Tb/100 RON
normal parafin 208 2.08 83.0478096
Isoparafin 80.34 0.8034 103.6537964389
Aromatic 85.22 0.8522 233.68362192
Total 82.6134764001
177
178
ENDIX A
N NERACA MASSA
s rice straw that is based on production capacity.

1,206,000 barrel/year
mand Supply (ESDM, 2013)

Tahun
loliters
domestic sales
846442
29501773
-
Target of fulfillment
0.01
density of pertamax kg / m3
770
715
sumber : (pertamina, 2016)
1
300
742.5
191735.851
142363869.3675
474546.231225
19772.75963438
0.2
98863.79817188
141.2339973884
1016884.781196
337558
8438950
179
of 70-140 cm 2-5 cm
steady state of operating conditions

is considered ideal
Output (Aliran 3)
Mass (kg/hr) Moles

(kgmol/hr)
33896.1594 2824.6799
70274.0825 70274.0825
17023.7811 1063.9863
20039.9744
141233.9974
material atau torrified biomass
Stream 3, Rice straw that had been cut

Stream 4, Volatile gas
Stream 5, Torrified biomass
98863.7981719
es with a ratio of 7: 3 (Bong, 2012)
ased on proximate analysis (R-101)
180
(Source : Jenkens, et. al.
put
Stream 4
Mass (kg/hr)
42370.1992
0.0000
0.0000
42370.1992
but the warming causes the content of the volatile

ending up in torrified biomass. Products torrified
uct gas that evaporates = 30% of rice straw input
rate, only the volatile gas that evaporates so that the

torrified straw biomass can be calculated
stream 5 total output - fixed carbon mass - ash mass
ecome gas in stream 4
e basis of analysis Ultimate (R-101)
Moles (kgmol/hr)
Output
181
Stream 4
% mass Mass (kg/hr) (kgmol/hr)
0.5259 22282.9424 1856.9119
0.0547 2317.4048 2317.4048
0.4076 17270.7662 1079.4229
0.0111 469.8379 33.5598
0.0007 29.2479 0.9140
0.0000
42370.1992
3.9974
hrough a gasification process
steady state of operating conditions

is considered ideal
ating conditions at a temperature of 890 ° C and 1.5 bar

fluidized bed combustion by indirect use of sand (heating
trained flow gasification syngas as much as 5% of the total sand in
182
kgmol/hr
Stream 14 Stream 17
(kg/hr) (kg/hr)
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 89117.8681
94244.0341 0.0000
94244.0341 89117.8681
CO H2
2287.2378 2287.2378
2287.2378 2287.2378
183
CO
1297.7291
1297.7291
CO2
88.4815
88.4815
CH4
2.6544
2.6544
2CO
171.6542
171.6542
CO2 H2
154.4887 154.4887
154.4887 154.4887
C2H4 2H2O
2.5748 5.1496
2.5748 5.1496
H2S
3.1310
3.1310
CO 3H2
184
2.3890 7.1670
2.3890 7.1670
Stream 15
Mass (kg/hr)
0.0000 1.1135746203
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
26368.3873
0.0000
26368.3873
5.7004
e operating conditions
is considered ideal
185
is considered ideal
186
is considered ideal
187
n of CH4 to CO and H2 so as not to
components in the syngas fixed
Output
Stream 24
Mass (kg/hr)
8017.9306
100789.8394
6914.3005
0.0000
0.0000
0.0000
55372.1341
500.9570
106.4534
171701.6150
CO 3H2
0.2654 0.7963
0.2654 0.7963
ngas and gas resulting product (CO and H2) is added
188
Output
Stream 26
Mass (kg/hr)
10170.5136 2.0152834939
70653.6774
54271.1265
0.0000
0.0000
0.0000
35998.8872
500.9570
106.4534
171701.6150
CO2 H2
1076.2915 1076.2915
1076.2915 1076.2915
t the ratio CO / H2 in syngas with range 2
189
2.015283494
Total MDEA
kg mol/hr
1564.8277
let
Stream 39
Mass (kg/hr)
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
186469.5625
0.0000
186469.5625
90376.4670149
tlet
Stream 28
Mass (kg/hr)
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
35998.8872
0.0000
190
0.0000
0.0000
240847.1424
276846.0296
is considered ideal
500000
0.99
r and the other half in blowdown
191
3. No Accumulation
35802.1560
150667.4065
186469.5625
solution and H2O from syngas
Outlet
Stream 34
Mass (kg/hr)
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
132000.7772
0.0000
0.0000
0.0000
0.0000
132000.7772
222377.2442
xture chain C1-C20
192
is considered ideal
perhitungan konversi didasari oleh trial and error berdasarkan

data selektifitas proses High Temperature
(Proses trial error dapat dilihat di sheet Detail Perhitungan)
dengan link berikut
detail perhitungan
ropsch SAS Reactor (R-206 dan R-207)

Outlet
Stream 46
Mol (kgmol/hr) Mass (kg/hr)
252.3376 7065.4514
351.7354 703.4708
17.5505 280.8086
6.9708 209.1255
3.4694 97.1445
8.2851 364.5426
8.2002 344.4084
3.3737 188.9253
35.3860 2052.3861
9.5313 686.2567
3.7213 320.0294
0.3551 27.6939
11.4478 1144.7778
36.8723 4203.4390
26.6139 3406.5757
5.7352 814.3979
2.9093 453.8448
2.6053 442.8980
193
0.1509 27.7686
3.9292 777.9876
6.3303 1342.0187
5.3695 1213.5034
4.7258 1134.1920
3.8597 980.3629
3.4406 922.0891
2.2806 643.1266
22.5650 9522.4206
2.3767 137.8503
12.6666 937.3276
2243.2982 40379.3669
80824.1910
CH4 H2O
17.5505 17.5505
17.5505 17.5505
C2H6 2H2O
6.9708 13.9417
6.9708 13.9417
C2H4 2H2O
3.4694 6.9389
3.4694 6.9389
C3H8 3H2O
8.2851 24.8552
8.2851 24.8552
C3H6 3H2O
194
8.2002 24.6006
8.2002 24.6006
C4H10 4H2O
35.3860 141.5439
35.3860 141.5439
C4H8 4H2O
3.3737 13.4947
3.3737 13.4947
C5H12 5H2O
9.5313 47.6567
9.5313 47.6567
C6H14 6H2O
3.7213 22.3276
3.7213 22.3276
C7H16 7H2O
11.4478 80.1344
11.4478 80.1344
C6H6 6H2O
0.3551 2.1303
0.3551 2.1303
C8H18 8H2O
36.8723 294.9782
195
36.8723 294.9782
C9H20 9H2O
26.6139 239.5249
26.6139 239.5249
C10H22 10H2O
5.7352 57.3520
5.7352 57.3520
C11H24 11H2O
2.9093 32.0019
2.9093 32.0019
C12H26 12H2O
2.6053 31.2634
2.6053 31.2634
C13H28 13H2O
0.1509 1.9619
0.1509 1.9619
C14H30 14H2O
3.9292 55.0092
3.9292 55.0092
C15H32 15H2O
6.3303 94.9542
6.3303 94.9542
196
C16H34 16H2O
5.3695 85.9117
5.3695 85.9117
C17H36 17H2O
4.7258 80.3386
4.7258 80.3386
C18H38 18H2O
3.8597 69.4745
3.8597 69.4745
C19H40 19H2O
3.4406 65.3720
3.4406 65.3720
C20H42 20H2O
2.2806 45.6118
2.2806 45.6118
C30H62 30H20
22.5650 676.9493
22.5650 676.9493
C3H6O 2H20
2.3767 4.7535
2.3767 4.7535
197
C3H6O2 H2O
12.6666 12.6666
12.6666 12.6666

3. No Accumulation
sheet Flash Calculation T-204
7065.45144016
198
d on difference in density with 98% water separation efficiency

3. No Accumulation
(Aspen Hysis)
199
ke unit utilitas setelah melalui proses pemurnian
200
3. No Accumulation
si destilator dapat ditetapkan
201
H14, and few C6H12
CO
H2
CH4
C2H6
C2H4
erization reactor (T-207) 28 C3H8
2
202
data konversi dari (isomalk, 2005)
203
is considered ideal
omerization (R-208)
204
data konversi dari (Isomalk 2, 2005)
dengan liquid hydrocarbon
205
3. No Accumulation
4. Assume separation 90%
206
3. No Accumulation
44.28
lytic Cracking (R-208)
Outlet
62
Mass (kg/hr) Mol (kgmol/hr)
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
772.2638 19.3066
0.0000 0.0000
1448.3567 34.4847
1536.9155 27.4449
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
207
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
59.9262 0.1222
1400.9660 9.8660
1454.7846 9.3255
7861.0525 46.2415
101.2753 0.5504
62.4704 0.3155
520.6335 2.4558
305.1688 1.4532
47.6424 0.2108
68.0515 0.2835
78.4290 0.3088
73.7671 0.2753
51.4501 0.1824
761.7937 1.8052
0.0000 0.0000
0.0000 0.0000
790.7615 43.9312
17395.7087
C4H8
0.1222
0.1222
C4H8
3.5363
3.5363
C4H8
5.6972
5.6972
208
C4H8
4.8325
4.8325
C4H8
4.4422
4.4422
C4H8
3.5509
3.5509
C4H8
3.1654
3.1654
C4H8
2.0981
2.0981
C15H30
20.7598
20.7598
C3H6
6.3297
6.3297
209
C3H6
3.6283
3.6283
C3H6
22.1024
22.1024
C3H6
2.4243
2.4243
C3H4
19.3066
19.3066
www.kbrtechnology.com
detail perhitungan

3. No Accumulation
210
nentukan suhu dan tekanan operasi overhead, bottom dan feed
211
Compound Percent
impurities 0.6747
oxygenate 4.3411
parafin condensat 3.6715
aromatic 0.1152
n-parafin 54.8927
heavy condensate 0.0115
212
water 0.8319
35.4614
i-paraffin
100.0000
0.743 kg/m3
Korelasi RON sebagai fungsi fraksi massa dan boiling point
(al-bahri,2012)
213
214
water
volatile
215
1
0
0
216
wet 23.9
daf 83.9
217
Detail Perhitungan Reaktor Sasol Advanced Synthol
Temperature C 300 (sasol, 2014)

Pressure(bar) 25 (sasol, 2014)
XCO 0.90
CO sisa 252.33
H2O 2243.30
H2/CO 2.02 (sasol, 2014)
Tabel selektifitas produk, konversi terhadap produk ditrial sehingga selektifitas sesuai dengan literatu
Distribusi Hidrokarbon
C1 17.55 7.00 =
nC2-nC5 60.17 24.00 =
C=2-C=4 15.04 6.00 =
C6-C12 90.26 36.00 =
C13-C20 30.09 12.00 =
heavy 22.56 9.00 =
oxygenant 15.04 6.00 =
Total 250.72 100.00
R-207 dan R-208 sasol

input
Aliran 54.00
komponen Mr mol Massa(kg/hr)
CO 28.00 2523.35 70653.68
165
H2 2.00 5085.26 10170.51
CH4 16.00
C2H6 30.00
C2H4 28.00
C3H8 44.00
C3H6 42.00
C4H8 56.00
C4H10 58.00
C5H12 72.00
C6H14 86.00
C6H6 78.00
C7H16 100.00
C8H18 114.00
C9H20 128.00
C10H22 142.00
C11H24 156.00
C12H26 170.00
C13H28 184.00
C14H30 198.00
C15H32 212.00
C16H34 226.00
C17H36 240.00
C18H38 254.00
C19H40 268.00
C20H42 282.00
C30H62 422.00
C3H6O 58.00
C3H6O2 74.00
H20 18.00
80824.19
Rangkuman konversi pada masing masing reaksi

NO X chosen constraint
1.00 0.01
2.00 0.01
3.00 0.00
4.00 0.01 > 0.01
5.00 0.01 > 0.01
6.00 0.06 > 0.03
7.00 0.01
8.00 0.02 > 0.02
9.00 0.01 < 0.01
166
10.00 0.04 > 0.02
11.00 0.00 > 0.00
12.00 0.14 > 0.10
13.00 0.13 > 0.10
14.00 0.04 > 0.02
15.00 0.02 > 0.02
16.00 0.02 > 0.02
17.00 0.00
18.00 0.04
19.00 0.07
20.00 0.07
21.00 0.07
22.00 0.06
23.00 0.06
24.00 0.04
25.00 0.69
26.00 0.02
27.00 0.13
1 CO 3H2 -> CH4

2523.35 5085.26
17.55 52.65 17.55
2505.80 5032.61 17.55
2 2CO 5H2 -> C2H6

2505.80 5032.61
13.94 34.85 6.97
2491.85 4997.75 6.97
3 2CO 4H2 -> C2H4

2491.85 4997.75
6.94 13.88 3.47
2484.91 4983.87 3.47
4 3CO 7H2 -> C3H8

2484.91 4983.87
24.86 58.00 8.29
2460.06 4925.88 8.29
167
5 3CO 6H2 -> C3H6
2460.06 4925.88
24.60 49.20 8.20
2435.46 4876.68 8.20
6 4CO 9H2 -> C4H10

2435.46 4876.68
141.54 318.47 35.39
2293.91 4558.20 35.39
7 4CO 8H2 -> C4H8

2293.91 4558.20
13.49 26.99 3.37
2280.42 4531.21 3.37
8 5CO 11H2 -> C5H12

2280.42 4531.21
47.66 104.84 9.53
2232.76 4426.37 9.53
9 6CO 13H2 -> C6H14

2232.76 4426.37
22.33 48.38 3.72
2210.44 4377.99 3.72
10 7CO 15H2 -> C7H16

2210.44 4377.99
80.13 171.72 11.45
2130.30 4206.28 11.45
11 6CO 9H2 -> C6H6

2130.30 4206.28
2.13 3.20 0.36
2128.17 4203.08 0.36
12 8CO 17H2 -> C8H18

2128.17 4203.08
294.98 626.83 36.87
1833.19 3576.25 36.87
168
13 9CO 19H2 -> C9H20
1833.19 3576.25
239.52 505.66 26.61
1593.67 3070.59 26.61
14 10CO 21H2 -> C10H22

1593.67 3070.59
57.35 120.44 5.74
1536.32 2950.15 5.74
15 11CO 23H2 -> C11H24

1536.32 2950.15
32.00 66.91 2.91
1504.31 2883.24 2.91
16 12CO 25H2 -> C12H26

1504.31 2883.24
31.26 65.13 2.61
1473.05 2818.10 2.61
17 13CO 27H2 -> C13H28

1473.05 2818.10
1.96 4.07 0.15
1471.09 2814.03 0.15
18 14CO 29H2 -> C14H30

1471.09 2814.03
55.01 113.95 3.93
1416.08 2700.08 3.93
19 15CO 31H2 -> C15H32

1416.08 2700.08
94.95 196.24 6.33
1321.13 2503.84 6.33
20 16CO 33H2 -> C16H34

1321.13 2503.84
85.91 177.19 5.37
1235.21 2326.65 5.37
169
21 17CO 35H2 -> C17H36
1235.21 2326.65
80.34 165.40 4.73
1154.88 2161.25 4.73
22 18CO 37H2 -> C18H38

1154.88 2161.25
69.47 142.81 3.86
1085.40 2018.44 3.86
23 19CO 39H2 -> C19H40

1085.40 2018.44
65.37 134.18 3.44
1020.03 1884.25 3.44
24 20CO 41H2 -> C20H42

1020.03 1884.25
45.61 93.50 2.28
974.42 1790.75 2.28
25 30CO 61H2 -> C30H62

974.42 1790.75
676.95 1376.46 22.56
297.47 414.29 22.56
26 3CO 5H2 -> C3H6O

297.47 414.29
7.13 11.88 2.38
290.34 402.40 2.38
27 3CO 4H2 -> C3H6O2

290.34 402.40
38.00 50.67 12.67
252.34 351.74 12.67
170
(sasol, 2014)
itrial sehingga selektifitas sesuai dengan literatur

data literatur
7.00
24.00
6.00
36.00
12.00
9.00
6.00
100.00
07 dan R-208 sasol

output
55.00
mol/hr massa(kg/hr)
252.34 7065.45
171
351.74 703.47
17.55 280.81
6.97 209.13
3.47 97.14
8.29 364.54
8.20 344.41
3.37 188.93
35.39 2052.39
9.53 686.26
3.72 320.03
0.36 27.69
11.45 1144.78
36.87 4203.44
26.61 3406.58
5.74 814.40
2.91 453.84
2.61 442.90
0.15 27.77
3.93 777.99
6.33 1342.02
5.37 1213.50
4.73 1134.19
3.86 980.36
3.44 922.09
2.28 643.13
22.56 9522.42
2.38 137.85
12.67 937.33
2243.30 40379.37
80824.19
chosen constraint
172
H2O
17.55
17.55
2H2O
13.94
13.94
2H2O
6.94
6.94
3H2O
24.86
24.86
173
3H2O
24.60
24.60
4H2O
141.54
141.54
4H2O
13.49
13.49
5H2O
47.66
47.66
6H2O
22.33
22.33
7H2O
80.13
80.13
6H2O
2.13
2.13
8H2O
294.98
294.98
174
9H2O
239.52
239.52
10H2O
57.35
57.35
11H2O
32.00
32.00
12H2O
31.26
31.26
13H2O
1.96
1.96
14H2O
55.01
55.01
15H2O
94.95
94.95
16H2O
85.91
85.91
175
17H2O
80.34
80.34
18H2O
69.47
69.47
19H2O
65.37
65.37
20H2O
45.61
45.61
30H20
676.95
676.95
2H20
4.75
4.75
H2O
12.67
12.67
176
#REF! #REF!
#REF! #REF!
0.00 #REF!
0.00 #REF!
0.00 #REF!
0.00 #REF!
0.00 #REF!
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177
#REF! #REF!
#REF! #REF!
#REF! #REF!
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#REF! #REF!
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#REF! #REF!
0.00 #REF!
0.00 #REF!
#REF! #REF!
Komposisi Separator
178
179
Detail Reaksi (SASOL ADVANCED SY
180
Detail Reaksi (SASOL ADVANCED SYNTHOL)
181
182
Detail Perhitungan Separator (T-203)
asumsi V 0.2251 25000

Liquid 0.7749
Perhitungan berdasarkan persamaan flash se(vannes, 2003 hal 345)
mol,
Compon mass, kmol/h Liquid,
Psat Ki V y x
ent kg/hr r z,kmol kmol/hr
CO 7065.45 252.34 0.08145 924612 9246.123 0.362 0.3617 4E-05 0.09392
H2 703.471 351.74 0.11353 7.3E+29 7E+27 0.504 0.5044 7E-29 2E-25
CH4 280.809 17.551 0.00566 81989.8 819.8975 0.025 0.0251 3E-05 0.07339
C2H6 209.125 6.9708 0.00225 5669.27 56.6927 0.009 0.0094 0.00017 0.39909
C2H4 97.1445 3.4694 0.00112 9353.61 93.53609 0.005 0.0048 5E-05 0.12317
C3H8 364.543 8.2851 0.00267 1367.08 13.67082 0.009 0.0095 0.00069 1.66674
C3H6 344.408 8.2002 0.00265 1637.54 16.37545 0.01 0.0097 0.00059 1.42453
C3H6O 137.85 2.3767 0.00077 74.8373 0.748373 0.001 0.0006 0.00081 1.95234
C3H6O2 937.328 12.667 0.00409 1.30658 0.013066 7E-05 7E-05 0.00526 12.6187
C4H8 188.925 3.3737 0.00109 455.934 4.559337 0.003 0.0028 0.0006 1.45147
C4H10 2052.39 35.386 0.01142 525.674 5.256745 0.031 0.0307 0.00583 14.0038
C5H12 686.257 9.5313 0.00308 114.717 1.147175 0.003 0.0034 0.00298 7.14918
iC5H12 0 0 0 150.858 1.508577 0 0 0 0
C6H14 320.029 3.7213 0.0012 35.9575 0.359575 0.001 0.0005 0.0014 3.36937
iC6H14 0 0 0 5.397 0.05397 0 0 0 0
C6H6 27.6939 0.3551 0.00011 1.3E-65 1.26E-67 0 2E-71 0.00015 0.35505
C6H12 0 0 0 44.828 0.44828 0 0 0 0
C7H16 1144.78 11.448 0.0037 11.8701 0.118701 0.001 0.0005 0.00461 11.0662
C8H18 4203.44 36.872 0.0119 3.91739 0.039174 0.001 0.0006 0.01519 36.4574
C9H20 3406.58 26.614 0.00859 1.3074 0.013074 0 0.0001 0.01104 26.5132
C10H22 814.398 5.7352 0.00185 0.44265 0.004427 1E-05 1E-05 0.00239 5.72783
C11H24 453.845 2.9093 0.00094 0.15697 0.00157 2E-06 2E-06 0.00121 2.90794
C12H26 442.898 2.6053 0.00084 0.06046 0.000605 7E-07 7E-07 0.00108 2.60482
C13H28 27.7686 0.1509 5E-05 0.01716 0.000172 1E-08 1E-08 6E-05 0.15091
C14H30 777.988 3.9292 0.00127 0.00529 5.29E-05 9E-08 9E-08 0.00164 3.92917
C15H32 1342 6.3303 0.00204 0.00223 2.23E-05 6E-08 6E-08 0.00264 6.33024
C16H34 1213.5 5.3695 0.00173 0.00075 7.53E-06 2E-08 2E-08 0.00224 5.36947
C17H36 1134.19 4.7258 0.00153 0.00021 2.1E-06 4E-09 4E-09 0.00197 4.7258
C18H38 980.363 3.8597 0.00125 6E-05 6E-07 1E-09 1E-09 0.00161 3.8597
C19H40 922.089 3.4406 0.00111 1.8E-05 1.78E-07 3E-10 3E-10 0.00143 3.44063
C20H42 643.127 2.2806 0.00074 1.4E-05 1.41E-07 1E-10 1E-10 0.00095 2.28059
C30H62 9522.42 22.565 0.00728 4.2E-08 4.18E-10 4E-12 4E-12 0.0094 22.565
169
H20 40379 2243 0.72409 7.32563 0.073256 0.067 0.067 0.91494 2196.56
1.031 1.031 0.991
total kmol 3098 3098.09309495
t.mass 80824
170
0.15899
3974.68 m3/hari
3E+06
38000
50.6667
Vapor,
kmol/hr 50 49
252.24 2.62986 7062.8
351.74 3E-25 703.47
17.477 1.17421 279.63
6.5718 11.9726 197.15
3.3463 3.44869 93.696
6.6183 73.3364 291.21
6.7757 59.8304 284.58
0.4244 113.236 24.614
0.0479 933.784 3.5438
1.9222 81.2825 107.64
21.382 812.223 1240.2
2.3822 514.741 171.52
0 0 0
0.3519 289.766 30.264
0 0 0
1E-68 27.6939 1E-66
0 0 0
0.3815 1106.62 38.154
0.4148 4156.15 47.291
0.1007 3393.69 12.887
0.0074 813.352 1.0458
0.0013 453.638 0.2068
0.0005 442.82 0.0778
8E-06 27.7672 0.0014
6E-05 777.976 0.012
4E-05 1342 0.0087
1E-05 1213.5 0.0027
3E-06 1134.19 0.0007
7E-07 980.363 0.0002
2E-07 922.089 5E-05
9E-08 643.127 3E-05
3E-09 9522.42 1E-06
171
46.738 39538 841.29
69393 11431
3098.09309495
80824.1909646
172
Flash Calculation T-208
T, K = 343
P, kpa = 100
vapour, V = 0.5948327 (trial)
(vannes, 2010)
inlet outlet
stream
63 65 64
unit kg/hr kmol/hr kg/hr
Komponen Mr zi
CO 28 0.00 -3.64E-14 -1.0183E-12 -1.656E-17 -2E-16
H2 2 0.00 0 0 0 0
CH4 16 0.00 -3.47E-16 -5.5487E-15 -2.417E-18 -2E-18
C2H6 30 0.00 -5.33E-16 -1.5877E-14 -1.1E-16 -3E-18
C2H4 28 0.00 -4.76E-16 -1.3267E-14 -5.588E-17 -3E-18
C3H4 40 772.26 19.306595 733.951481 38.312319 0.12458
C3H8 44 0.00 0 0 0 0
C3H6 42 1448.36 34.484684 1416.91905 31.4376803 0.22251
C4H8 56 1536.92 27.44492 1434.92281 101.992689 0.17709
C4H10 58 0.00 0 0 0 0
C5H12 72 0.00 0 0 0 0
iC5H12 72 0.00 0 0 0 0
C6H14 86 0.00 0 0 0 0
iC6H14 86 0.00 0 0 0 0
C6H6 78 0.00 0 0 0 0
C6H12 8 0.00 0 0 0 0
C7H16 100 0.00 0 0 0 0
C8H18 114 0.00 0 0 0 0
C9H20 128 59.93 0.4681737 4.88563952 55.0406004 0.00302
C10H22 142 1400.97 9.865958 47.9087868 1353.05726 0.06366
C11H24 156 1454.78 9.3255426 20.7636744 1434.02097 0.06017
C12H26 170 7861.05 46.241485 49.744362 7811.30814 0.29837
C13H28 184 101.28 0.5504092 0.23798857 101.037296 0.00355
C14H30 198 62.47 0.315507 0.05098843 62.4193918 0.00204
C15H32 212 520.63 2.4558184 0.20455215 520.42894 0.01585
C15H30 210 305.17 1.4531846 0.09317998 305.07558 0.00938
C16H34 226 47.64 0.2108073 0.00817634 47.6342634 0.00136
C17H36 240 68.05 0.2835478 0.00458262 68.0468947 0.00183
C18H38 254 78.43 0.3087757 0.00198864 78.4270306 0.00199
C19H40 268 73.77 0.2752505 0.00072449 73.766401 0.00178
170
C20H42 282 51.45 0.1824473 0.00028072 51.449846 0.00118
C30H62 422 761.79 1.8051982 2.8959E-05 761.793622 0.01165
C3H6O 58 0.00 0 0 0 0
C3H6O2 74 0.00 0 0 0 0
H2O 18 790.76 43.931194 247.237043 543.524441 0.28347
Total 17395.71 154.9783 3956.93535 13438.7734 1
Total 17395.7087040252 17395.7087040252
Komponen A B C D E F lnP
CO 40.1655 -1109.88 0 -5.45485 9E-05 2 15.2479
H2 9.1827 -107.929 0 0.164099 6E-04 2 80.6625
CH4 31.35 -1307.52 0 -3.26134 3E-05 2 11.9602
C2H6 44.0103 -2568.82 0 -4.97635 1E-05 2 9.19337
C2H4 48.1101 -2473.65 0 -5.73618 2E-05 2 9.69094
C3H4 11.14 -1.1E+03 -7.7E+01 0 0E+00 2 7.17386
C3H8 52.3785 -3490.55 0 -6.10875 1E-05 2 7.85686
C3H6 58.3524 -3591.08 0 -7.10916 1E-05 2 8.02942
C4H8 65.4218 -4487.6 0 -8.01753 1E-05 2 6.86516
C4H10 58.7845 -4136.68 0 -7.01666 1E-05 2 6.98241
C5H12 63.3315 -5117.78 0 -7.48305 8E-06 2 5.6405
iC5H12 66.7563 -5059.18 0 -8.08935 9E-06 2 5.87178
C6H14 70.4265 -6055.6 0 -8.37865 7E-06 2 4.63783
iC6H14 70.24623 -5928.68 0 -8.76503 8E-06 2 2.69029
C6H6 16.965 -10314.8 0 -23.5895 2E-05 2 -148.35
C6H12 86.1624 -6469.15 0 -10.9125 1E-05 2 4.81547
C7H16 78.3285 -6947 0 -9.44866 6E-06 2 3.67788
C8H18 86.997 -7890.6 0 -10.6255 6E-06 2 2.72524
C9H20 111.977 -9558.5 0 -14.2702 8E-06 2 1.79942
C10H22 123.136 -10635.2 0 -15.8051 9E-06 2 0.88037
C11H24 121.162 -11079.2 0 -15.3772 8E-06 2 -0.0138
C12H26 125.191 -11737 0 -15.8737 7E-06 2 -0.8352
C13H28 14.1201 -3892.9 -98.93 0 0E+00 2 -1.8298
C14H30 143.577 -13893.7 0 -18.2992 7E-06 2 -2.8888
C15H32 152.638 -14762.2 0 -19.5485 8E-06 2 -3.6204
C15H30 217.81 -18359 0 -29.05 1E-05 2 -3.8726
C16H34 225.023 -18736.5 0 -30.231 1E-05 2 -4.4489
C17H36 14.1361 -4294.53 -123 0 0E+00 2 -5.3845
C18H38 14.1069 -4361.79 -129.899 0 0E+00 2 -6.3613
C19H40 14.1381 -4450.43 -135.5 0 0E+00 2 -7.3098
C20H42 196.75 -19441 0 -25.525 9E-06 2 -7.8976
C30H62 188.81 -22404 0 -23.359 4E-18 6 -12.864
C3H6O 80.863 -6506.1 0 -9.8198 7E-06 2 5.36819
171
C3H6O2 86.4985 -8721.62 0 -10.255 6E-06 2 1.8786
H2O 65.9278 -7227.53 0 -7.17695 4E-06 2 3.43346
Component ki y x
CO 41886.89 -3.94E-16 -9.42E-21
H2 1.1E+33 0 0
CH4 1563.985 -3.76E-18 -2.41E-21
C2H6 98.3176 -5.74E-18 -5.84E-20
C2H4 161.7043 -5.14E-18 -3.18E-20
C3H4 13.04874 0.1990406 0.0152536
C3H8 25.83399 0 0
C3H6 30.69969 0.3659569 0.0119205
C4H8 9.582945 0.2779552 0.0290052
C4H10 10.77514 0 0
C5H12 2.816032 0 0
iC5H12 3.548791 0 0
C6H14 1.033202 0 0
iC6H14 0.14736 0 0
C6H6 3.73E-67 0 0
C6H12 1.234045 0 0
C7H16 0.395625 0 0
C8H18 0.1526 0 0
C9H20 0.060461 0.000414 0.0068481
C10H22 0.024118 0.0036598 0.1517479
C11H24 0.009863 0.0014438 0.1463948
C12H26 0.004338 0.0031742 0.7317615
C13H28 0.001604 1.403E-05 0.008745
C14H30 0.000556 2.793E-06 0.0050205
C15H32 0.000268 1.047E-05 0.0390949
C15H30 0.000208 4.813E-06 0.0231357
C16H34 0.000117 3.925E-07 0.0033566
C17H36 4.59E-05 2.071E-07 0.0045154
C18H38 1.73E-05 8.493E-08 0.0049173
C19H40 6.69E-06 2.932E-08 0.0043835
C20H42 3.72E-06 1.08E-08 0.0029056
C30H62 2.59E-08 7.444E-10 0.0287488
C3H6O 2.144745 0 0
C3H6O2 0.065443 0 0
H2O 0.309837 0.1489962 0.4808851
Total 1.0006736 1
172
Perhitungan Flash Separator T-209
T, K 313
P, kpa 100
vapour, V 0.03385 (trial)
inlet outlet
stream
68 72 70
unit kg/hr kmol/hr kg/hr
komponen zi
CO 28 2.63 0.09392 2.6217632375 0.01 0.001
H2 2 0.00 0 0 0 0
CH4 16 1.17 0.07339 1.1347056841 0.039501 0.001
C2H6 30 11.97 0.39909 7.9634396244 4.009185 0.003
C2H4 28 3.45 0.12317 2.6423869596 0.806306 0.001
C3H8 44 73.34 1.66674 23.750400719 49.58599 0.013
C3H6 42 59.83 1.42453 21.812270478 38.01809 0.011
C3H6O 58 113.24 1.95234 2.893203364 110.3427 0.015
C3H6O2 74 933.78 12.6187 0.427269074 933.3566 0.097
C4H8 56 81.28 1.45147 11.195788507 70.08669 0.011
C4H10 58 812.22 14.0038 126.32612884 685.897 0.108
C5H12 72 25.74 0.35746 0.9944702257 24.74257 0.003
C6H14 86 14.49 0.16847 0.1802546868 14.30803 0.001
C6H6 78 27.69 0.35505 1.161905E-67 27.69392 0.003
C6H12 8 0.00 0 0 0 0
C7H16 100 110.66 1.10662 0.4583204155 110.2041 0.009
C8H18 114 415.61 3.64574 0.5696515221 415.0452 0.028
C9H20 128 339.37 2.65132 0.1553814096 339.2134 0.02
C10H22 142 813.35 5.72783 0.126122724 813.226 0.044
C11H24 156 453.64 2.90794 0.0249466997 453.613 0.022
C12H26 170 398.54 2.34434 0.0084420821 398.5298 0.018
C13H28 184 2.78 0.01509 1.669586E-05 2.776708 0
C14H30 198 0.00 0 0 0 0
C15H32 212 0.00 0 0 0 0
C16H34 226 0.00 0 0 0 0
C17H36 240 0.00 0 0 0 0
C18H38 254 0.00 0 0 0 0
C19H40 268 0.00 0 0 0 0
C20H42 282 0.00 0 0 0 0
C30H62 422 0.00 0 0 0 0
173
H2O 18 0.00 0 0 0 0
iC5H12 72 489.00 6.79172 24.54870228 464.455 0.052
iC6H14 86 275.28 3.2009 0.519540799 274.7578 0.025
iC7H16 100 995.96 9.95961 3.749051E-32 995.9614 0.077
iC8H18 114 3741 32.8117 4.222832006 3736.311 0.253
iC9H20 128 3054 23.8619 0 3054.319 0.184
Total 13250 129.713 232.57603804 13017.31
Total 13249.8832518188 13249.8832518188 1
Komponen A B C D E F lnP Psat

CO 40.166 -1109.88 0 -5.45485 8.64E-05 2 13.7371 924612.3
H2 9.1827 -107.929 0 0.164099 0.000602 2 68.768 7.3E+29
CH4 31.35 -1307.52 0 -3.26134 2.94E-05 2 11.3143 81990
C2H6 44.01 -2568.82 0 -4.97635 1.46E-05 2 8.64282 5669.27
C2H4 48.11 -2473.65 0 -5.73618 1.94E-05 2 9.14352 9353.61
C3H8 52.379 -3490.55 0 -6.10875 1.12E-05 2 7.22043 1367.08
C3H6 58.352 -3591.08 0 -7.10916 1.4E-05 2 7.40095 1637.54
C3H6O 80.863 -6506.1 0 -9.8198 6.79E-06 2 4.31532 74.8373
C3H6O2 86.499 -8721.62 0 -10.255 5.72E-06 2 0.26741 1.30658
C4H8 65.422 -4487.6 0 -8.01753 1.13E-05 2 6.12235 455.934
C4H10 58.785 -4136.68 0 -7.01666 1.04E-05 2 6.26468 525.674
C5H12 63.332 -5117.78 0 -7.48305 7.77E-06 2 4.74247 114.717
C6H14 70.427 -6055.6 0 -8.37865 6.62E-06 2 3.58234 35.9575
C6H6 16.965 -10314.8 0 -23.5895 2.09E-05 2 -149.49 1E-65
C6H12 86.162 -6469.15 0 -10.9125 1.04E-05 2 3.80283 44.828
C7H16 78.329 -6947 0 -9.44866 6.47E-06 2 2.47402 11.8701
C8H18 86.997 -7890.6 0 -10.6255 6.47E-06 2 1.36542 3.91739
C9H20 112 -9558.5 0 -14.2702 8.46E-06 2 0.26804 1.3074
C10H22 123.14 -10635.2 0 -15.8051 8.64E-06 2 -0.815 0.44265
C11H24 121.16 -11079.2 0 -15.3772 7.59E-06 2 -1.8517 0.15697
C12H26 125.19 -11737 0 -15.8737 7.3E-06 2 -2.8058 0.06046
C13H28 14.12 -3892.9 -98.93 0 0 2 -4.0651 0.01716
C14H30 143.58 -13894 0 -18.2992 7.36E-06 2 -5.2413 0.00529
C15H32 152.64 -14762 0 -19.5485 7.64E-06 2 -6.1066 0.00223
C16H34 225 -18737 0 -30.231 1.39E-05 2 -7.1909 0.00075
C17H36 14.136 -4295 -123 0 0 2 -8.47 0.00021
C18H38 14.107 -4362 -129.9 0.00 0.00 2.00 -9.71 6E-05
C19H40 14.138 -4450 -135.5 0.00 0.00 2.00 -10.9 2E-05
C20H42 196.75 -19441 0.00 -25.53 0.00 2.00 -11.2 1E-05
C30H62 188.81 -22404 0.00 -23.36 0.00 6.00 -17.0 4E-08
H2O 65.928 -7228 0.00 -7.18 0.00 2.00 1.99 7.32563
iC5H12 66.756 -5059 0.00 -8.09 0.00 2.00 5.02 150.858
iC6H14 70.246 -5929 0.00 -8.77 0.00 2.00 1.69 5.397
174
iC7H16 8.116 -7414 0.00 -9.80 0.00 2.00 -71.3 1E-31
iC8H18 112 -9080 0.00 -14.40 0.00 2.00 1.17 3.22584
iC9H20 6.923 -6100 0.00 -8.21 0.00 2.00 -59.1 2E-26
Komponen ki y x
CO 9246.122628043 0.02133 2.30638E-06
H2 7.33745692E+27 0 0
CH4 819.8975151167 0.01615 1.969966E-05
C2H6 56.6927042327 0.06046 0.0010663686
C2H4 93.5360915064 0.02149 0.0002297811
C3H8 13.6708188063 0.12293 0.0089924665
C3H6 16.3754466358 0.11828 0.0072229319
C3H6O 0.7483725328 0.01136 0.0151805749
C3H6O2 0.0130658136 0.00131 0.1006441116
C4H8 4.5593372154 0.04553 0.0099866547
C4H10 5.2567446689 0.49604 0.0943633611
C5H12 1.1471749294 0.00315 0.0027421091
C6H14 0.3595748775 0.00048 0.0013275591
C6H6 1.197481526E-67 3.4E-70 0.0028331027
C6H12 0.4482803552 0 0
C7H16 0.1187009538 0.00104 0.0087936684
C8H18 0.0391738683 0.00114 0.0290511308
C9H20 0.0130740033 0.00028 0.0211463584
C10H22 0.0044265428 0.0002 0.0456978135
C11H24 0.0015696765 3.6E-05 0.0232024277
C12H26 0.0006046045 1.1E-05 0.018706147
C13H28 0.0001716174 2.1E-08 0.0001204162
C14H30 0.000052934 0 0
C15H32 2.228012564E-05 0 0
C16H34 7.53419976E-06 0 0
C17H36 2.103601547E-06 0 0
C18H38 6.037892135E-07 0 0
C19H40 1.7827915E-07 0 0
C20H42 1.412184161E-07 0 0
C30H62 4.182928716E-10 0 0
H2O 0.0732563091 0 0
iC5H12 1.5085770947 0.07765 0.051473491
iC6H14 0.0539699651 0.00138 0.0254931887
iC7H16 1.07438877E-33 8.5E-35 0.0794721583
iC8H18 0.0322584428 0.00844 0.261523455
iC9H20 0 0 0.261523455
Total 1 1.00025 1
175
Trial nilai ∑Y dengan goolseek hingga mendekati nilai 1
176

Appendiks A

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Appendiks A

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APPENDIX A

PERHITUNGAN NERACA MASSA

A.1 Production Capacity Calculation

Table A.1 Annual Data Demand Supply (ESDM, 2013)

A.2 Principal Component Mass Balance Calculations

Total Feed Inlet 141233.9973884 kg/hr

Volatile gas 0.5067 50095.6989

Stream 5 (Torrified Biomass) =70% x total overall input straw rice

A.2.3 Gasifier (R-102)

Table A.6 molecular weight compounds in the gasification reaction

Comparison of composition H2O: feed ash free = 1.3

steam 94244.0341173 Kg/hr = 5235.779673183

3 Convertion C 0.5000 (Lettner, 2007)

4 Convertion C 0.0300 (Williams, 2015)

5 Convertion C 1 (Lettner, 2007)

6 Convertion C 0.9 (Williams, 2015)

7 Convertion C 0.3 (Lettner, 2007)

8 Convertion CO 1 (Williams, 2015)

Table A.8 composition of gasification outlet

A.2.4 Cyclone (s-201)

Table A.9 Mass Balance Calculation in CYCLONE (s-201)

A.2.5 Entrainment (T-201)

Tabel A.10 Entrainment mass balance calculations(T-201)

A.2.6 Mixer M-201

Tabel A.10 Perhitungan neraca massa pada MIxer (M-201)

Excess H2O 0.1

A.2.6 Steam Reformer R-202

Table A.11 Mass Balance Calculation in Steam Reformer (R-202)

A.2.7 Water Gas Shift (Low Temperature) (R-203)

Table A.12 Mass Balance Calculation in Reactor WGS (R-203)

A.2.8 CO2 Absorber (T-202)

Table A.13. MDEA Calculation

Table A.14 Mass Balance Calculation in Absorber Tower (R-204)

A.2.9 Stripper Column (T-203)

Table A.15 Mass Balance Calculation in Stripper Column (T-202)

A.2.10 Reflux Drum (V-202)

Syngas input H2O 35998.88716115

Table A.16 Mass Balance Calculation in Reflux Drum (V-202)

A.2.11 Fischer Tropsch SAS Reactor (R-204 dan R-205)

A.2.12 Flash Separator (T-204)

Tabel A.18 Mass Balance Calculation Flash Separator (T-204)

A.2.13 Gravity settling (T-206)

densitas air 1000 kg/m3

Tabel A.19 Mass balance calculation in Gravity Settling (T-206)

Komposisi 65 dan 58 ditentukan maka kondisi operasi destilator dapat ditetapkan

Tabel A.20 Mass balance calculation in C-C6 isomerization reactor (T-207)

A.2.15 C7-C12 Isomerization Reactor (R-208)

Tabel A.21 Mass balance calculation in C7-C12 Isomerization (R-208)

catalyst to feed ratio 0.1

A.2.16 Flash Separator T-209

A.2.17 Demetanizer (T-204)

Tabel A.23 Mass balance calculation in Demetanizer (T-205)

Tabel A.24 Mass balance calculation in Fluid Catalytic Cracking (R-208)

Catalyst to Feed ratio 0.04

A.2.19 Separator T-208 T-208

LPG Product Massflow (Kg/hr)

Dry Ice (kg/hr) 54271.1265

s rice straw that is based on production capacity.

mand Supply (ESDM, 2013)

steady state of operating conditions

Mass (kg/hr) Moles

material atau torrified biomass

Stream 3, Rice straw that had been cut