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CODE 5 [P2155 | (5) Paren-2 Time : 3 Hours Maximum Marks : 240 READ THE INSTRUCTIONS CAREFULLY GENERAL : 1. This sealed booklet is your Question Paper. Do not break the seal till you are told to do so. 2. The question paper CODE is printed on the left hand top comer of this sheet and the right hand top comer of the back cover of this booklet. 3. Use the Optical Response Sheet (ORS) provided separately for answering the questions. 4, The ORS CODE is printed on its left part as well as the right part. Ensure that both theso codes are identical and samo as that gn the question paper booklet. If not, contact the invigilator. 5. Blank spaces are provided within this booklet for rough work. 6. Write your name and roll number in the space provided on the back cover of this booklet. 7. After breaking the seal of the booklet, verify that the booklet contains 32 pages and that all the 60 questions along with the options are legible, QUESTION PAPER FORMAT AND MARKING SCHEME 8. The question paper has three parts: Physiés, Chemistry and Mathematics. Each part has three sections. 9. Carefully read the instructions given at the beginning of each section. 10. Section 1 contains 8 questions. The answer to each question is a single digit integer ranging from 0 to 9 (both inclusive). Marking scheme: +4 for correct answer and 0 in all other cases. 11. Section 2 contains 8 multiple choice questions with one or more than one correct option. Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases. 12. Section 3 contains 2 “paragraph” type questions. Each paragraph describes an experiment, a situation or a problem. Two multiple choice quostions will be ask con this paragraph. One or more than one option can be correct. Marking schome: +4 for'corréat answer, UTnof attompted and -2 in all other cases. OPTICAL RESPONSE SHEET : 13. The ORS consists of an original (top sheet) and its carbon-less copy (bottom sheet). 14. Darken the appropriate bubbles on the original by applying sufficient pressure. This will leave an impression at the corresponding place on the carbon-less copy. 15, The original is machine-gradable and will be collected by the inviglator at the end of the examination, 16. You will be allowed to take away the carbon-less copy at the end of the examination. 17. Do not tamper with or mutilata the ORS. 18. Write your name, roll number and the name of the examination center and sign with pen in the space provided for this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble under each digit of your roll number. DO NOT BREAK THE [EAM WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR Sane SPACE FOR ROUGH WORK 5 2182 SECTION 1 (Maximum Marks: 32) ‘This section contains EIGHT questions The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive For each question, darken the bubble corresponding to the correct integer in the ORS ‘Marking scheme: +4 Ifthe bubble corresponding to the answer is darkened 0 Inallother cases Qi Q2 Qs ‘The densities of two solid spheres A and B of the same radii R vary with radial distance r s palr)=k| Z| and pg(r)=k| |, respectively, where k is a constant. The moments of AR, se R inertia of the individual spheres about axes passing through their centres are Ix and Is, respectively. If 42.=-, the value of nis I, 10 Four harmonic waves of equal frequencies and equal intensities Jo have phase angles 0, 2/3, 2n/3 and x. When they are superposed, the intensity of the resulfing wave is no. The value of nis For a radioactive material, its activity A and rate of change of its activity R are defined as A= ox and (R= where N(}) is the number of nuclei at time ¢. Two radioactive sources oP (mean ys ‘and Q (mean life 2x) have the same activity at t= 0. Their rates of change of activities at (= 2x are Rp and Rg, respectively. If pa =, then the value of n is 8B ‘Space for rough w 3/32 Q4 A monochromatic beam of light is incident at 60° on one face of an equilateral prism of refractive index n and emerges from the opposite face making an angle (7) with the normal -1* i“ ae the value of 6 és 60% and <* =m /The value of m is = dn (see the figure). For n: Q5 In the following circuit, the current through the resistor R (= 20) is Amperes. The value 4» of Fis — RE2Q) 5 yy =. 29 ee 6.5V 42 a. ‘Space for rough work +B 4/32 Qe Qi Qs 5 PHYSICS An electron in an excited state of Lit ion has angular momentum (3h/22. The de Broglie wavelength of the electron in this state is_px@y (where gy is the Bohr radius). The value 8 A large spherical mass M is fixed at one position and two identical point_masses m are kept on a line passing through the centre of M (see figure). The point masses are connected by a rigid massless rod of length | and this assembly is free to move along the line connecting them. All three masses ract only throug] mutual gravitational interaction. When the point mass nearer to(M is at a distance(r = 31 from M, the tension in the rod is zero for (#). The value of kis 288. ‘The energy of a system as a function of time ¢ is given as E(t)= A*exp(-at), where @=0.28", The measurement of A has an error of 1.25%. If the error in the measurement of timé is 1.50%, the percentage error in the value of E( at ¢= sis ‘Spa for rough work 5/82 PHYSICS SECTION 2 (Maximum Marks : 32) + This section contains EIGHT questions + Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct. ‘© Foreach question, darken the bubble(s) corresponding to all the correct option(s) in the ORS © Marking scheme : +4 Ifonly the bubble(s) corresponding to all the correct option(s) is(are) darkened 0 Ifnone of the bubbles is darkened -2 Inall other cases Q9 parallel plate capacitor having plates of area $ and plate separation d, has capacitance C, in air. When two dielectrics of diffrent relative permittivities (e,=2 and e,=4) ate introduced between the two plates as shown in the figure, the capacitance becomes C;. ‘The C, ratio =2 is 1 (A) 65 ®) 53 © wm * oi 13 ‘Space for rough work PHYSICS Q.10 An ideal monoatomic gas is confined in a horizontal eylinder by a spring loaded piston {as shown in the figure). Initially the gas is at temperature 7), pressure P, and volume V, and the spring is in its relaxed state. The gas is then heated very slowly fo temperature 7, pressure P, and volume V;, During this process the piston moves out by a distance x, Ignoring the friction between the piston and the cylinder, the correct statement(s) is(are) TOOT If V,=2V, and T; = 37, then the energy stored in the spring is tay, S& If V, = 2V, and 1, = 37,, then the change in internal energy is 8P,V, (© IfV,=8V, and 7; =47;, then the work done by the gas is fay, (D) IfV,=3V, and 7; = 47, then the heat supplied to the gas is Lay, Space for rough work 5 132. PHYSICS: 40 Ql A fission reaction is given by "SU — {Xe + {Sr+xy) where x and y are two particles. Considering *33U to be at rest, the kinetic energies of the products are denoted by Ky, Kon. K, (2 MeV) and K, (2 MeV), respectively. Let the binding energies per nucleon of *33U, ‘sXe and “Sr be 7.5 MeV, 8.5 MeV and 8.5 MeV, respectively. Considering different conservation laws, the correct option(s) is(are) (A) x=n,y=n, Ke, = 129 MeV, Ky, = 86 MeV (B) x=p,y =e", Kg, = 129 MeV, Kx, = 86 MeV (©) x=p,y=n, Ky = 129 MeV, Kx, = 86 MeV (D) x=n, y=, Ko, = 86 MCV, Kx, ‘Space for rough work 8/32, PHYSICS Q.12 Two spheres P and @ of equal radii have densities p, and pp, respectively. The spheres are connected by a massless string and placed in liquids L, and L, of densities o, and 0) and viscosities 7, and 7, , respectively. They float in equilibrium with the sphere P in L, and sphere @ in L, and the string being taut (see figure). If sphere P alone in L, has terminal velocity Vp and Q alone in L, has terminal velocity Ve , then wy Wel + D) Vp-Vg <0 Wal ™ Q.13. In terms of potential difference V, electric current I, permittivity ¢, permeability jp and speed of light c, the dimensionally correct equation(s) is(are) a (A) wel? = eV? (B) oP = HV () L=eeV @) wel=eV ‘Space for rough work ee 5 9782. PHYSICS Q.14 Consider a uniform spherical charge distribution of radius R, centred at the origin O. In this distribution, a spherical cavity of radius f, centred at P with’ distance R,~R, (see figure) is made. If the electric field inside the cavity at position 7 is oP E(@), then the correct statement(s) is(are) @ (A) _E is uniform, its magnitude is independent of R, but its direction depends on? is uniform, its magnitude depends on R, and its direction depends on 7 7 (©) E is uniform, its magnitude is independent of a but its direction depends on @ (BY B is uniform and both its magnitude and direction depend on @ ‘Space for rough work 10/82, +5 Q.15 In plotting stress versus strain curves for two materials P and Q, a student by mistake puts strain on the y-axis and stress on the x-axis as shown in the figure. Then the correct statement(s) is(are) Strain Stress JAF Phas more tensile strength than Q \@Y Pis more ductile than @ - (©) Pis more brittle than Q + (D) The Young's modulus of Pie more than that of Q Q.16 A spherical body of radius R consists of a fluid of constant density and is in equilibrium under its own gravity. If P(r) is the pressure at r(r < R), then the correct option(s) iS (Gre) ne P(r=3R/4)_ 63 (A) P(r=0)=0 ® Fe carp)" 80 Plr=3R/5)_16 Plr=R/2)_ 20 © P(r=2R/5) 21 Pr=R/3) 27 ‘Space for rough work +5 11/82 PHYSICS SECTION 3 (Maximum Marks : 16) This section contains TWO paragraphs Based on each paragraph, there will be TWO questions Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS Marking scheme +4 Ifonly the bubble(s) corresponding to all the correct option(s) is(are) darkened 0 Ifnone of the bubbles is darkened -2_Inall other cases ‘Space for rough work 12/32 PHYSICS PARAGRAPH 1 Ina thin rectangular metallic strip a constant current I flows along the positive x-direction, as shown in the figure. The length, width and thickness of the strip are J, w and d, respectively. A.uniform magnetic field B is applied on the strip along the positive y-direction. Due to this, the charge carriers experience a net deflection along the z-direction. This results in accumulation of charge carriers on the surface PQRS and appearance of equal and opposite charges on the face opposite to PQRS. A potential difference along the z-direction is thus developed. Charge accumulation continues until the magnetic force is balanced by the electric force. The current is assumed to be,uniformly distributed on the cross section of the strip and carried by electrons. Q.17 Consider two different metallic strips (1 and 2) of the same material. Their lengths are the same, widths are w, and w, and thicknesses are d, and d,, respectively. Two points K and M are symmetrically located on the opposite faces parallel to the x-y plane (see figure). V, and V, are the potential differences between K and M in strips 1 and 2, respectively. Then, for a given current J flowing through them in a given magnetic field strength B, the correct statement(s) is(are) (A) Tfw,=w, and d, ®) Ifw,=w, and d, = 2d,, then V, = V; (©) Ifw,=2w, and d, = d,, then V, = 2V, ) Ifw,=2w, and d, = d,, then V, = V, Q.18 Consider two different metallic strips (1 and 2) of same dimensions (length 1, width w and thickness d) with carrier densities n, and nz, respectively. Strip 1 is placed in magnetic field B, and strip 2 is placed in magnetic field B,, both along positive y-directions. Then V, and V, are the potential differences developed between K and M in strips 1 and 2, respectively. Assuming that the current J is the same for both the strips, the correct option(s) is(are) (A) fB,=B, and n,=2n,, then V,=2V; (B) 1fB,=B, and n, =2n,, then V,=V; (© 1B, =2B, and n, =n,, thon V;=0.5V, ) 1B, =2B, and n,=n,, then V;=V, ‘Space for rough work 5 13/32 PHYSICS Light guidance in an optical fiber can be understood by considering a structure comprising of thin solid glass cylinder of refractive index n, surrounded by a medium of lower refractive index ny ‘The light guidance in the structure takes place due to successive total internal reflections at the interface of the media n, and n, as shown in the figure. All rays with the angle of incidence i less than a particular value i,, are confined in the medium of refractive index n,. The numerical aperture (NA) of the structure is defined as sin i, . PARAGRAPH 2 Q.19 For two structures namely S,with n,=045/4 and n,=38/2, and S, with n,=8/5 and ng = 7/5 and taking the refractive index of water to be 4/3 and that of air to be 1, the correct option(s) is(are) GH NAof S, immersed in water is the same as that of S, immersed ina liquid of refractive 16 index v5 4B) NA of S, immersed in liquid of refractive index K is the same as that of S, immersed in water yna of S, placed in air is the same as that of S, immersed in liquid of refractive index 4 ‘15, WD) _NAof S, placed in air is the same as that of S, placed in water Q.20 If two structures of same cross-sectional area, but different numerical apertures NA, and NA, (NA, Add © , @) HC 2 oh Hye’ Z Q.33 The major product U in the following reactions is Chi H.C, Ht radical initiator, O2 QO : ’ high pressure, heat 4 oe HG CHy CH; 0. 4 9? CH, CHa KOrg-H © @) . ‘Space for rough work 5 18/32 [EMISTRY Q.34 In the following reactions, the major Profucg is LN co NaNOz, HCI a 0°c (C) Q = fei (@) OO yr a” Q.35. The correct statement(s) regarding, (i) HCIO, (ii) HCIO,, (ii) HCIO, and (iv) HClO, is(are) (A) The number of Cl=O bonds in (ii) and (iii) together is two LY The number of lone pairs of eléctrons on Cl in (ii) and (ii) together is three SF The hybridization of C1 in Gv) is . sp (D) Amongst (i to dv), the strongest acid is (i) Q.36 The pair(s) of ions where BOTH the ions are precipitated upon passing H,S gas in presence of dilute HCl, is(are) (A) Ba®\Zn* = (B)_-Bi**, Fe* SOF Cu", Pb™ Dy He, Bi* — ECE See ‘Space for rough work 19/32 CHEMISTRY SECTION 3 (Maximum Marks: 16) «This section contains TWO paragraphs * Based on each paragraph, there will be TWO questions + Each question has FOUR options (A), (B), (C) and (D), ONE OR MORE THAN ONE of these four option(s) is(are) correct * For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS © Marking scheme: +4 Ifonly the bubble(e) corresponding to all the correct option(s) is(are) darkened © Ifnone of the bubbles is darkened =2 _Inall other cases ae PARAGRAPH 1 4a In the following reactions Ker pa.Bas0, 1. ByHg Cele CoHy x - H; te i, H2Oz, NaOH, HzO Le 2 ois i. HyOa, by t H,0 HgS0,, HaSOq i, EtMgBr, H20 CaHgO Y ji, HY, heat Q.37 Compound X is Oo OH » Com wc OH + © o~ ®) cre Q.38 The major compound ¥ is i felstehse 7 on CH, ( CH3 oO »o (ee ‘Space for rough work CHEMISTRY PARAGRAPH 2 When 100 mL of 1.0 M HCl was mixed with 100 mL, of 1.0 M NaOH in an insulated beaker at constant pressure, a temperature increase of 5.7°C was measured for the beaker and its contents (Expt. 1). Because the enthalpy of neutralization of a strong acid with a strong base is a constant (-57.0 kJ mol”), this experiment could be used to measure the calorimeter constant. In a second experiment (Expt. 2), 100 mL of 2.0 M acetic acid (K, =2.0%10°°) was mixed with 100 mL of 1.0 M NaOH (under identical conditions to Expt. 1) where a temperature rise of 5.6 °C was measured, (Consider heat capacity of all solutions as 4.2 J g" K~ and density of all solutions as 1.0 g mL*) Q.39 Enthalpy of dissociation (in kJ mol *) of acetic acid obtained from the Expt. 2 is @ 10 @®) 10.0 (© 245 @) 514 Q.40 The pH of the solution after Expt. 2 is a) 28 @ 47 oF 5.0 @ 70 END OF PART II: CHEMISTRY +5, ‘ 21/32 _ EET SECTION 1 (Maximum Marks: 32) “This section contains EIGHT questions = «The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, bot) inclusive + For each question, darken the bubble corresponding to the correct integer in the ORS © Marking scheme: +4 Ifthe bubble corresponding to the answer is darkened 0 Inallother cases Ql The coefficient of x" in the expansion of (1+x)(1+x7)(1+x*)...+2™) is we 2 Q.42 Suppose that the foci of the ellipse a are (f,, 0) and (fz, 0) where f, >0 and f, <0. Let P, and P, be two parabolas with a common vertex at (0, 0) and with foci at (f, 0) and (2f,, 0), respectively. Let T, be a tangent to P, which passes through (2f;,0) and 7; be a tangent to P, which passes through (j,,0). If m, is the slope of T, and m, is the slope of Tp, thon-the value of @ nt) is WG-43, Let m and n be two positive integers greater than 1. If m then the value of = is n {-2. Ht Sot Q.44 Q.45 Q.46 MATHEMATICS It ~ ee Jeo “sy (2: =) a ° a where tan'x takes only principal values, then the value of ( ee. nze|-£) is ° o Let {:R +R be a continuous odd function, which vanishes exactly at one point and ¢ 4 f= i . Suppose that F(x) f(t) dt for all xe[-1, 2) and G(x)= fl fcfay|ae for all ra 1 2 fi 2 re[-12) If ine pr then the value of (5) Suppose that 2, Gand # are three non-coplanar vectors in R’. Let the components df a vector $ along B, G and 7 be 4, 3 and 6, respectively. If the components of this vector & along (-B+G +7), (B-G+7) and (—B~ G+?) are x, y and z, respectively, then the value of 2x+y+z is 3 igh work 23/82 Q4AT Q48 MATHEMATICS For any integer b, let x, en) -isin( AE , where i= V~1. The value of the expression 2 7 Dees - a! iret Bo i Yeas -au2 a Suppose that all the terms of an arithmetic progression (A.P.) are natural numbers. If the ratio of the sum of the first seven terms to the sum of the first eleven terms is 6: 11 and the séventh term lies in between 130 and 140, then the common difference of this AP. is Oe 24/32 MATHEMATICS SECTION 2 (Maximum Marks: 32) This section contains EIGHT questions Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS Marking scheme: +4 Ifonly the bubble(s) corresponding to all the correct option(s) is(are) darkened 0 Ifnone of the bubbles is darkened 2 Inallother cases Q49 Q.50 +5 Let f,g:[-1,2] > RB be continuous functions which are twice differentiable on the interval (1, 2). Let the values of f and g at the points -1, 0 and 2 be as given in the following table: x=-1 | x=0 | x=2 0 -1 fx) 3 a) 0 slo In each of the intervals (-1, 0) and (0,2) the function (f-8g)" never vanishes. Then the correct statement(s) is(are) (A) f'(2)-3¢'(x)=0 has exactly three solutions in (-1, 0) U (0, 2) B) _f'(z)-3g'(x)=0 has exactly one solution in (-1, 0) © f(x)-8e'(x) (D) /'(e)-3¢'(e)=0 has exactly two solutions in (-1, 0) and exactly two solutions in (0, 2) 0 has exactly one solution in (0, 2) Let f(x)=Ttan’x+Ttan®x-Stan*x—3tan*x for all se(-2.2) ‘Then the correct expression(s) is(are) a6 7 as @ [xforae-a @) Jfepdr=o a on © fxfede-b ©) ffede=1 > ° ‘Space for rough work 25/32, Q51 Q5z MATHEMATICS 92x r 1 = for all xe R with (Z)-0 If ms | f(x)dx 0 (B) sinf<0 (©) cos(a+f)>0 (D) cosa<0 Let E, and B, be two ellipses whose centers are at the origin. The major axes of , and E, lie along the x-axis and the y-axis, respectively. Let S_be the circle x* +(y—1) =2. The straight line r+y=8 touches the curves S, BE, and E, at P,Q and R, respectively. 22 Suppose that PQ=PR= "57. If ¢ and e, are the eccentricities of H, and Ey, respectively, then the correct expression(s) is(are) 2 48 v7 2 @ Gre BD aa-se © lee ‘Space for rough work 27/32, MATHEMATICS Q.55 Consider the hyperbola H:x*—y?=1 and a circle S with center N(2,0). Suppose that Q.56 Hand S touch each other at a point P(x,,9,) with x, >1 and y, >0. The common tangent to Hand S at Pintersects the x-axis at point M. If (J, m) is the centroid of the triangle APMN, then the correct expression(s) is(are) dm a) for x >1 eo * for x >1 2 Te dl 1 dm_1 © deity raed @ Ferg nro ‘The option(s) with the values of a and L that satisfy the following equation is(are) € (sin® at + c08" at) dt 4? e'(sin® at + cos at)dt | we 5 28/32 MATHEMATICS SECTION 3 (Maximum Marks : 16) This section contains TWO paragraphs Based on each paragraph, there will be TWO questions Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS Marking scheme : +4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened 0 Ifnone of the bubbles is darkened -2 Inallother cases Let n, and n, be the number of red and black balls, respectively, in box I. Let_n, and n, be the number of red and black balls, respectively, in box II. PARAGRAPH 1 QaT, One of the two boxes, box I and box II, was.gelected at random and a ball was drawn randomly gut of this box. a ball was found to teed If the probability that this red ball was drawn “trom box I is B then the correct option(s) with the possible values of 7m, Mang and. n, “is(are) WA 23, r= 8, my =5, my =15 WO mn =3, m= \O %=8, m=6, m5, my = 20 @) 1 =6, m=12, ny +g =10, n =50 14 =20 Q.58 A ball is drawn at random from box I and ar mesiiee to box I. Ifthe probability of drawing a red ball from box I, after this transfer, is i, then the correct option(s) with the pos possible values of m and n, is(are) a (A) n=4 and n,=6 (B) n,=2 and n,=3 (OY n,=10 and n, =20 _ OY m=8 and n,=6 29/32 MATHEMATICS: )=0, FG PARAGRAPH 2 Let F:R->R be a thrice differentiable function. Suppose that F() F(x) O for all xe (1/2 ,3). Let f(x) = xF(@) for all xe R. and Q.59_ The correct statement(s) is(are) @ fa

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