Ct 0.1 Ka1 1.995262E-12 B1 5.

01187E+11
Ka2 1.258925E-07 B2 3.98107E+18
Ka3 0.01 B3 3.98107E+20

log[OH-] log[H+] pH [PO4 3-] log[PO4 3-] [HPPO4 2-] log[HPPO4 2-

-14 0 0 2.487016E-22 -21.604321 1.246461E-10 -9.9043214
-13.9 -0.1 0.1 4.949561E-22 -21.305433 1.970456E-10 -9.7054333
-13.8 -0.2 0.2 9.843983E-22 -21.006829 3.112941E-10 -9.5068291
-13.7 -0.3 0.3 1.95623E-21 -20.70858 4.913829E-10 -9.30858
-13.6 -0.4 0.4 3.883522E-21 -20.410774 7.748645E-10 -9.1107742
-13.5 -0.5 0.5 7.699793E-21 -20.113521 1.220335E-09 -8.9135209
-13.4 -0.6 0.6 1.524213E-20 -19.816954 1.918871E-09 -8.7169543
-13.3 -0.7 0.7 3.011352E-20 -19.521238 0.000000003 -8.5212384
-13.2 -0.8 0.8 5.935094E-20 -19.226572 4.714413E-09 -8.3265724
-13.1 -0.9 0.9 1.166284E-19 -18.933196 7.358755E-09 -8.1331957
-13 -1 1 2.283533E-19 -18.641393 1.144478E-08 -7.9413927
-12.9 -1.1 1.1 4.451465E-19 -18.351497 1.77216E-08 -7.751497
-12.8 -1.2 1.2 8.631929E-19 -18.063892 2.729656E-08 -7.5638922
-12.7 -1.3 1.3 1.663375E-18 -17.77901 4.178208E-08 -7.3790099
-12.6 -1.4 1.4 3.18183E-18 -17.497323 6.348585E-08 -7.1973231
-12.5 -1.5 1.5 6.034879E-18 -17.219331 9.564638E-08 -7.0193315
-12.4 -1.6 1.6 1.133598E-17 -16.945541 1.427115E-07 -6.8455411
-12.3 -1.7 1.7 2.106513E-17 -16.676436 2.106513E-07 -6.6764358
-12.2 -1.8 1.8 3.86862E-17 -16.412444 3.072954E-07 -6.5124439
-12.1 -1.9 1.9 7.016107E-17 -16.153904 4.426864E-07 -6.3539038
-12 -2 2 1.255935E-16 -15.901033 6.294587E-07 -6.2010327
-11.9 -2.1 2.1 2.218678E-16 -15.653906 8.832716E-07 -6.0539057
-11.8 -2.2 2.2 3.868584E-16 -15.412448 1.223354E-06 -5.9124479
-11.7 -2.3 2.3 6.661283E-16 -15.176442 1.673239E-06 -5.7764421
-11.6 -2.4 2.4 1.133574E-15 -14.94555 2.261777E-06 -5.6455503
-11.5 -2.5 2.5 1.90834E-15 -14.719344 3.024516E-06 -5.5193442
-11.4 -2.6 2.6 3.181704E-15 -14.49734 4.005528E-06 -5.3973402
-11.3 -2.7 2.7 5.259778E-15 -14.279033 5.259778E-06 -5.2790326
-11.2 -2.8 2.8 8.631339E-15 -14.063922 6.856117E-06 -5.1639218
-11.1 -2.9 2.9 1.407552E-14 -13.851536 8.881054E-06 -5.0515355
-11 -3 3 2.283272E-14 -13.641442 1.144347E-05 -4.9414424
-10.9 -3.1 3.1 3.687573E-14 -13.433259 1.468049E-05 -4.8332594
-10.8 -3.2 3.2 5.933981E-14 -13.226654 1.876489E-05 -4.7266539
-10.7 -3.3 3.3 9.520455E-14 -13.021342 2.39143E-05 -4.6213423
-10.6 -3.4 3.4 1.52375E-13 -12.817086 3.04028E-05 -4.5170863
-10.5 -3.5 3.5 2.433949E-13 -12.613688 3.85755E-05 -4.4136885
-10.4 -3.6 3.6 3.881624E-13 -12.410987 4.886675E-05 -4.3109865
-10.3 -3.7 3.7 6.182319E-13 -12.208849 6.182319E-05 -4.2088486
-10.2 -3.8 3.8 9.836292E-13 -12.007169 7.813244E-05 -4.1071686
-10.1 -3.9 3.9 1.563644E-12 -11.805862 9.865929E-05 -4.005862
-10 -4 4 2.48392E-12 -11.604862 0.000124491 -3.9048624
-9.9 -4.1 4.1 3.943497E-12 -11.404118 0.000156993 -3.8041184
-9.8 -4.2 4.2 6.257605E-12 -11.203592 0.000197883 -3.7035919
-9.7 -4.3 4.3 9.925324E-12 -11.003255 0.000249313 -3.6032553
-9.6 -4.4 4.4 1.573652E-11 -10.803091 0.000313985 -3.5030913
-9.5 -4.5 4.5 2.49407E-11 -10.603091 0.000395284 -3.4030913
-9.4 -4.6 4.6 3.951343E-11 -10.403255 0.000497445 -3.3032553
-9.3 -4.7 4.7 6.257605E-11 -10.203592 0.000625761 -3.2035919
-9.2 -4.8 4.8 9.905618E-11 -10.004118 0.000786831 -3.1041184
-9.1 -4.9 4.9 1.567248E-10 -9.8048624 0.000988866 -3.0048624
-9 -5 5 2.478209E-10 -9.605862 0.001242047 -2.905862
-8.9 -5.1 5.1 3.915898E-10 -9.4071686 0.001558947 -2.8071686
-8.8 -5.2 5.2 6.182319E-10 -9.2088486 0.001955021 -2.7088486
-8.7 -5.3 5.3 0.000000001 -9.0109865 0.002449139 -2.6109865
-8.6 -5.4 5.4 1.535718E-09 -8.8136885 0.00306416 -2.5136885
-8.5 -5.5 5.5 2.414981E-09 -8.6170864 0.003827486 -2.4170864
-8.4 -5.6 5.6 3.790161E-09 -8.4213423 0.004771531 -2.3213423
-8.3 -5.7 5.7 5.93398E-09 -8.2266539 0.00593398 -2.2266539
-8.2 -5.8 5.8 9.262764E-09 -8.0332594 0.007357675 -2.1332594
-8.1 -5.9 5.9 1.440647E-08 -7.8414424 0.009089867 -2.0414424
-8 -6 6 2.230819E-08 -7.6515356 0.011180581 -1.9515356
-7.9 -6.1 6.1 3.436197E-08 -7.463922 0.013679746 -1.863922
-7.8 -6.2 6.2 5.259775E-08 -7.2790328 0.016632869 -1.7790328
-7.7 -6.3 6.3 7.992073E-08 -7.0973405 0.020075181 -1.6973405
-7.6 -6.4 6.4 1.20408E-07 -6.9193447 0.024024552 -1.6193447
-7.5 -6.5 6.5 1.79659E-07 -6.7455511 0.02847403 -1.5455511
-7.4 -6.6 6.6 2.651897E-07 -6.5764433 0.03338541 -1.4764433
-7.3 -6.7 6.7 3.86857E-07 -6.4124496 0.038685695 -1.4124496
-7.2 -6.8 6.8 5.573036E-07 -6.2539081 0.044268199 -1.3539081
-7.1 -6.9 6.9 7.924353E-07 -6.1010362 0.049999289 -1.3010362
-7 -7 7 0.000001112 -5.9539086 0.055730297 -1.2539086
-6.9 -7.1 7.1 1.540102E-06 -5.8124506 0.061312549 -1.2124506
-6.8 -7.2 7.2 2.106469E-06 -5.6764449 0.066612399 -1.1764449
-6.7 -7.3 7.3 2.847387E-06 -5.5455534 0.071523136 -1.1455534
-6.6 -7.4 7.4 3.807606E-06 -5.419348 0.075971727 -1.119348
-6.5 -7.5 7.5 5.042606E-06 -5.297345 0.079919918 -1.097345
-6.4 -7.6 7.6 6.621575E-06 -5.1790387 0.083360692 -1.0790387
-6.3 -7.7 7.7 8.631184E-06 -5.0639296 0.086311837 -1.0639296
-6.2 -7.8 7.8 1.118032E-05 -4.9515456 0.088808477 -1.0515456
-6.1 -7.9 7.9 0.000014406 -4.8414553 0.090895984 -1.0414553
-6 -8 8 1.848094E-05 -4.7332759 0.092624117 -1.0332759
-5.9 -8.1 8.1 2.362245E-05 -4.626675 0.094042681 -1.026675
-5.8 -8.2 8.2 3.010446E-05 -4.5213692 0.095198657 -1.0213692
-5.7 -8.3 8.3 3.827185E-05 -4.4171205 0.096134541 -1.0171205
-5.6 -8.4 8.4 4.855882E-05 -4.3137319 0.096887585 -1.0137319
-5.5 -8.5 8.5 6.151182E-05 -4.2110415 0.097489658 -1.0110415
-5.4 -8.6 8.6 7.781833E-05 -4.1089181 0.097967473 -1.0089181
-5.3 -8.7 8.7 0.000098343 -4.0072564 0.098343025 -1.0072564
-5.2 -8.8 8.8 0.000124173 -3.9059729 0.098634097 -1.0059729
-5.1 -8.9 8.9 0.000156674 -3.8050023 0.098854778 -1.0050023
 -5 -9 9 0.000197563 -3.7042949 0.099015926 -1.0042949
-4.9 -9.1 9.1 0.000248992 -3.6038143 0.099125568 -1.0038143
-4.8 -9.2 9.2 0.000313664 -3.5035356 0.099189212 -1.0035356
-4.7 -9.3 9.3 0.000394962 -3.4034442 0.099210075 -1.0034442
-4.6 -9.4 9.4 0.000497124 -3.3035356 0.099189212 -1.0035356
-4.5 -9.5 9.5 0.00062544 -3.2038143 0.099125568 -1.0038143
-4.4 -9.6 9.6 0.000786511 -3.1042949 0.099015926 -1.0042949
-4.3 -9.7 9.7 0.000988548 -3.0050023 0.098854778 -1.0050023
-4.2 -9.8 9.8 0.00124173 -2.9059729 0.098634097 -1.0059729
-4.1 -9.9 9.9 0.001558632 -2.8072564 0.098343025 -1.0072564
-4 -10 10 0.001954708 -2.7089181 0.097967474 -1.0089181
-3.9 -10.1 10.1 0.00244883 -2.6110415 0.097489659 -1.0110415
-3.8 -10.2 10.2 0.003063855 -2.5137319 0.096887587 -1.0137319
-3.7 -10.3 10.3 0.003827185 -2.4171205 0.096134543 -1.0171205
-3.6 -10.4 10.4 0.004771235 -2.3213692 0.09519866 -1.0213692
-3.5 -10.5 10.5 0.005933692 -2.226675 0.094042685 -1.026675
-3.4 -10.6 10.6 0.007357396 -2.1332759 0.092624123 -1.0332759
-3.3 -10.7 10.7 0.009089599 -2.0414553 0.090895995 -1.0414553
-3.2 -10.8 10.8 0.011180327 -1.9515455 0.088808493 -1.0515455
-3.1 -10.9 10.9 0.013679508 -1.8639295 0.086311861 -1.0639295
-3 -11 11 0.016632652 -1.7790385 0.083360727 -1.0790385
-2.9 -11.1 11.1 0.020074989 -1.6973447 0.079919969 -1.0973447
-2.8 -11.2 11.2 0.024024393 -1.6193476 0.0759718 -1.1193476
-2.7 -11.3 11.3 0.028473914 -1.5455528 0.071523239 -1.1455528
-2.6 -11.4 11.4 0.033385354 -1.476444 0.066612539 -1.176444
-2.5 -11.5 11.5 0.038685722 -1.4124493 0.061312738 -1.2124493
-2.4 -11.6 11.6 0.044268344 -1.3539067 0.055730544 -1.2539067
-2.3 -11.7 11.7 0.049999604 -1.3010334 0.049999604 -1.3010334
-2.2 -11.8 11.8 0.055730853 -1.2539043 0.04426859 -1.3539043
-2.1 -11.9 11.9 0.061313445 -1.2124443 0.038686168 -1.4124443
-2 -12 12 0.066613766 -1.176436 0.033385969 -1.476436
-1.9 -12.1 12.1 0.071525147 -1.1455412 0.028474674 -1.5455412
-1.8 -12.2 12.2 0.075974601 -1.1193316 0.024025278 -1.6193316
-1.7 -12.3 12.3 0.079923935 -1.0973231 0.020075985 -1.6973231
-1.6 -12.4 12.4 0.083366203 -1.07901 0.016633744 -1.77901
-1.5 -12.5 12.5 0.086319281 -1.0638922 0.013680684 -1.8638922
-1.4 -12.6 12.6 0.088818403 -1.051497 0.011181574 -1.951497
-1.3 -12.7 12.7 0.090909078 -1.0413927 0.009090908 -2.0413927
-1.2 -12.8 12.8 0.092641236 -1.0331957 0.007358755 -2.1331957
-1.1 -12.9 12.9 0.0940649 -1.0265724 0.005935094 -2.2265724
-1 -13 13 0.095227324 -1.0212384 0.004772672 -2.3212384
-0.9 -13.1 13.1 0.096171347 -1.0169543 0.00382865 -2.4169543
-0.8 -13.2 13.2 0.096934656 -1.0135209 0.003065343 -2.5135209
-0.7 -13.3 13.3 0.097549662 -1.0107742 0.002450337 -2.6107742
-0.6 -13.4 13.4 0.098043769 -1.00858 0.00195623 -2.70858
-0.5 -13.5 13.5 0.098439833 -1.0068291 0.001560166 -2.8068291
-0.4 -13.6 13.6 0.098756726 -1.0054333 0.001243274 -2.9054333
-0.3 -13.7 13.7 0.099009901 -1.0043214 0.000990099 -3.0043214
-0.2 -13.8 13.8 0.099211932 -1.0034361 0.000788068 -3.1034361
-0.1 -13.9 13.9 0.099372999 -1.0027316 0.000627001 -3.2027316
0 -14 14 0.099501312 -1.0021712 0.000498688 -3.3021712
[H2PO4 -] log[H2PO4 -] [H3PO4] log[H3PO4]
0.000990099 -3.00432137 0.0990099009 -1.00432137 log[PO4 3]- vs pH
0.001243274 -2.90543332 0.0987567263 -1.00543332 0
0 2 4 6 8 10 1
0.001560166 -2.80682913 0.0984398335 -1.00682913
0.00195623 -2.70858 0.0980437691 -1.00858 -5
0.002450337 -2.61077423 0.0975496625 -1.01077423

log[PO4 3-]
0.003065343 -2.51352093 0.0969346558 -1.01352093 -10

0.00382865 -2.4169543 0.0961713478 -1.0169543

-15
0.004772672 -2.32123841 0.095227325 -1.02123841
0.005935094 -2.2265724 0.0940649013 -1.0265724
-20
0.007358755 -2.13319565 0.0926412376 -1.03319565
0.009090908 -2.04139273 0.0909090805 -1.04139273 -25
0.011181575 -1.95149702 0.0888184073 -1.05149702
pH
0.013680685 -1.86389215 0.0863192876 -1.06389215
0.016633746 -1.77900993 0.0833662121 -1.07900993
0.020075988 -1.69732307 0.0799239484 -1.09732307
0.024025284 -1.61933146 0.07597462 -1.11933146
log[H2PO4 -] vs pH
0.028474684 -1.54554108 0.071525173 -1.14554108
0
0.033385987 -1.47643578 0.0666138021 -1.17643578 0 2 4 6 8 10
0.038686199 -1.41244394 0.0613134936 -1.21244394 -2
0.044268641 -1.35390381 0.0557309167 -1.25390381
0.049999685 -1.30103273 0.0499996853 -1.30103273 -4
log[H2PO4 -]

0.055730671 -1.25390573 0.0442684456 -1.35390573 -6

0.061312932 -1.21244792 0.0386858447 -1.41244792
0.066612828 -1.17644213 0.0333854989 -1.47644213 -8
0.071523657 -1.14555029 0.0284740809 -1.54555029 -10
0.075972395 -1.11934418 0.0240245807 -1.61934418
0.079920798 -1.09734019 0.0200751967 -1.69734019 -12
0.083361862 -1.07903259 0.0166328782 -1.77903259 pH
0.086313393 -1.06392181 0.0136797509 -1.86392181
0.088810535 -1.05153551 0.0111805839 -1.95153551
0.090898688 -1.04144239 0.0090898688 -2.04144239
0.092627644 -1.03325938 0.0073576753 -2.13325938 0
0.094047255 -1.02665388 0.0059339806 -2.22665388 0 1 2 3 4
0.095204555 -1.02134227 0.0047715308 -2.32134227
0.096142111 -1.01708635 0.0038274864 -2.41708635 -2

0.096897264 -1.01368849 0.0030641605 -2.51368849

0.097501994 -1.0109865 0.0024491394 -2.6109865 -4
0.097983156 -1.00884858 0.001955021 -2.70884858
0.09836292 -1.00716859 0.0015589472 -2.80716859
-6
0.098659294 -1.005862 0.0012420469 -2.905862
0.098886643 -1.00486237 0.0009888664 -3.00486237
0.099056175 -1.00411844 0.0007868312 -3.10411844 -8
e Especies

-10
 -6

-8
0.099176357 -1.00359185 0.0006257605 -3.20359185
0.099253243 -1.0032553 0.0004974446 -3.3032553

Variación de Especies
-10
0.099290732 -1.00309129 0.0003952835 -3.40309129
0.099290732 -1.00309129 0.0003139849 -3.50309129
0.099253243 -1.0032553 0.0002493129 -3.6032553 -12
0.099176357 -1.00359185 0.0001978828 -3.70359185
0.099056175 -1.00411844 0.0001569935 -3.80411844
-14
0.098886643 -1.00486237 0.0001244909 -3.90486237
0.098659294 -1.005862 9.86592935E-05 -4.005862
0.09836292 -1.00716859 7.81324446E-05 -4.10716859 -16
0.097983155 -1.00884858 6.18231914E-05 -4.20884858
0.097501993 -1.01098651 4.88667541E-05 -4.31098651 -18
0.096897262 -1.01368849 3.8575495E-05 -4.41368849
0.096142109 -1.01708636 3.04028042E-05 -4.51708636
0.095204551 -1.02134229 2.39143021E-05 -4.62134229 -20

0.094047249 -1.0266539 1.87648932E-05 -4.7266539

0.092627636 -1.03325942 1.46804909E-05 -4.83325942 -22
0.090898675 -1.04144245 1.14434651E-05 -4.94144245
0.088810515 -1.05153561 8.88105152E-06 -5.05153561
-24
0.086313363 -1.06392196 6.85611415E-06 -5.16392196
0.083361818 -1.07903282 5.25977514E-06 -5.27903282
0.079920734 -1.09734054 4.00552515E-06 -5.39734054
0.075972303 -1.11934471 3.02451187E-06 -5.51934471
0.071523529 -1.14555107 2.26177258E-06 -5.64555107
0.066612651 -1.17644328 1.67323415E-06 -5.77644328
0.061312695 -1.2124496 1.22334909E-06 -5.9124496
0.055730361 -1.25390815 8.8326669E-07 -6.05390815
0.049999289 -1.30103617 6.29453756E-07 -6.20103617
0.044268148 -1.35390864 4.42681484E-07 -6.35390864
0.038685603 -1.41245063 3.0729067E-07 -6.51245063
0.033385284 -1.47644493 2.10646901E-07 -6.67644493
0.028473873 -1.54555345 1.42707419E-07 -6.84555345
0.02402437 -1.619348 9.56427379E-08 -7.019348
0.020074976 -1.69734497 6.34826475E-08 -7.19734497
0.016632645 -1.77903869 4.17793146E-08 -7.37903869
0.013679504 -1.86392964 2.72941995E-08 -7.56392964
0.011180325 -1.95154558 1.77196208E-08 -7.75154558
0.009089598 -2.0414553 1.14431264E-08 -7.9414553
0.007357395 -2.13327592 7.3573951E-09 -8.13327592
0.005933692 -2.226675 4.7132991E-09 -8.326675
0.004771235 -2.32136918 0.000000003 -8.52136918
0.003827185 -2.41712054 1.91813627E-09 -8.71712054
0.003063854 -2.51373187 1.21974243E-09 -8.91373187
0.002448829 -2.61104145 7.74387879E-10 -9.11104145
0.001954708 -2.70891809 4.91000468E-10 -9.30891809
0.001558632 -2.80725644 3.1098795E-10 -9.50725644
0.00124173 -2.90597293 1.96800897E-10 -9.70597293
0.000988548 -3.00500234 1.24450792E-10 -9.90500234
 0.000786511 -3.10429495 7.86511455E-11 -10.1042949
0.00062544 -3.20381431 4.96804691E-11 -10.3038143
0.000497124 -3.30353556 3.13663831E-11 -10.5035356
0.000394962 -3.40344422 1.97950124E-11 -10.7034442
0.000313664 -3.50353556 1.2487182E-11 -10.9035356
0.000248992 -3.60381431 7.87382373E-12 -11.1038143
0.000197563 -3.70429495 4.96255179E-12 -11.3042949
0.000156674 -3.80500234 3.12606256E-12 -11.5050023
0.000124173 -3.90597293 1.96800897E-12 -11.7059729
0.000098343 -4.00725644 1.23806533E-12 -11.9072564
7.781833E-05 -4.10891809 7.78183304E-13 -12.1089181
6.151182E-05 -4.21104145 4.88605723E-13 -12.3110415
4.855882E-05 -4.31373186 3.06385451E-13 -12.5137319
3.827185E-05 -4.41712053 1.91813631E-13 -12.7171205
3.010446E-05 -4.52136916 1.19848013E-13 -12.9213692
2.362245E-05 -4.62667498 7.47007602E-14 -13.126675
1.848094E-05 -4.73327589 4.64220282E-14 -13.3332759
0.000014406 -4.84145525 2.87438373E-14 -13.5414553
1.118033E-05 -4.9515455 1.77196239E-14 -13.7515455
8.631186E-06 -5.06392952 1.08660195E-14 -13.9639295
6.621578E-06 -5.17903851 6.62157789E-15 -14.1790385
5.042609E-06 -5.29734469 4.00548681E-15 -14.3973447
3.80761E-06 -5.41934758 2.40243925E-15 -14.6193476
2.847391E-06 -5.54555283 1.42707622E-15 -14.8455528
2.106473E-06 -5.67644401 8.38602184E-16 -15.076444
1.540106E-06 -5.81244929 4.87024387E-16 -15.3124493
0.000001112 -5.95390672 2.7931437E-16 -15.5539067
7.924403E-07 -6.10103344 1.5811263E-16 -15.8010334
5.573085E-07 -6.25390431 8.83274492E-17 -16.0539043
3.868617E-07 -6.41244428 4.87030004E-17 -16.3124443
2.651942E-07 -6.57643601 2.65194178E-17 -16.576436
1.79663E-07 -6.74554124 1.4271143E-17 -16.8455412
1.204116E-07 -6.91933157 7.59746012E-18 -17.1193316
7.992394E-08 -7.09732314 4.0056856E-18 -17.3973231
5.260052E-08 -7.27900998 2.09406434E-18 -17.67901
3.436432E-08 -7.46389218 1.08669537E-18 -17.9638922
2.231017E-08 -7.65149704 5.60406238E-19 -18.251497
1.440812E-08 -7.84139275 2.87479746E-19 -18.5413927
9.264124E-09 -8.03319566 1.46826464E-19 -18.8331957
5.935094E-09 -8.2265724 7.47184061E-20 -19.1265724
3.791068E-09 -8.42123842 3.79106806E-20 -19.4212384
2.415715E-09 -8.6169543 1.91887065E-20 -19.7169543
1.536311E-09 -8.81352093 9.69346555E-21 -20.0135209
0.000000001 -9.01077423 4.88906454E-21 -20.3107742
6.186144E-10 -9.20858 2.46274813E-21 -20.60858
3.91896E-10 -9.40682913 1.23928408E-21 -20.9068291
2.480657E-10 -9.60543332 6.23112817E-22 -21.2054333
1.569201E-10 -9.80432137 3.13096798E-22 -21.5043214
9.921193E-11 -10.0034361 1.57240315E-22 -21.8034361
6.270012E-11 -10.2027316 7.89347786E-23 -22.1027316
3.961219E-11 -10.4021712 3.96121858E-23 -22.4021712
 log[PO4 3]- vs pH log[HPPO4 2-] vs pH
4 6 8 10 12 14 16 0
0 2 4 6 8 10 12 14 16
-2

-4

log[HPPO4 2-]
-6

-8

-10

-12
pH pH

log[H2PO4 -] vs pH log[H3PO4] vs pH
4 6 8 10 12 14 16 0
0 2 4 6 8 10 12 14 16

-5
log[H3PO4]

-10

-15

-20

-25
pH pH

1 2 3 4 5 6 7 8 9 10 11 12 13 14
pH
 pH φ(PO4 3-) φ(HPO4 2-) φ(H2PO4 -)
pH 0 2.5E-21 1.2E-09 0.01
0.1 4.9E-21 2.0E-09 0.01
10 12 14 16 0.2 9.8E-21 3.1E-09 0.02
0.3 2.0E-20 4.9E-09 0.02
0.4 3.9E-20 7.7E-09 0.02
0.5 7.7E-20 1.2E-08 0.03
0.6 1.5E-19 1.9E-08 0.04
0.7 3.0E-19 3.0E-08 0.05
0.8 5.9E-19 4.7E-08 0.06
0.9 1.2E-18 7.4E-08 0.07
1 2.3E-18 1.1E-07 0.09
1.1 4.5E-18 1.8E-07 0.11
1.2 8.6E-18 2.7E-07 0.14
1.3 1.7E-17 4.2E-07 0.17
1.4 3.2E-17 6.3E-07 0.20
1.5 6.0E-17 9.6E-07 0.24
pH 1.6 1.1E-16 1.4E-06 0.28
1.7 2.1E-16 2.1E-06 0.33
10 12 14 16
1.8 3.9E-16 3.1E-06 0.39
1.9 7.0E-16 4.4E-06 0.44
2 1.3E-15 6.3E-06 0.50
2.1 2.2E-15 8.8E-06 0.56
2.2 3.9E-15 1.2E-05 0.61
2.3 6.7E-15 1.7E-05 0.67
2.4 1.1E-14 2.3E-05 0.72
2.5 1.9E-14 3.0E-05 0.76
2.6 3.2E-14 4.0E-05 0.80
2.7 5.3E-14 5.3E-05 0.83
2.8 8.6E-14 6.9E-05 0.86
2.9 1.4E-13 8.9E-05 0.89
3 2.3E-13 1.1E-04 0.91
3.1 3.7E-13 1.5E-04 0.93
12 13 14 15 3.2 5.9E-13 1.9E-04 0.94
3.3 9.5E-13 2.4E-04 0.95
3.4 1.5E-12 3.0E-04 0.96
3.5 2.4E-12 3.9E-04 0.97
3.6 3.9E-12 4.9E-04 0.98
3.7 6.2E-12 6.2E-04 0.98
3.8 9.8E-12 7.8E-04 0.98
3.9 1.6E-11 9.9E-04 0.99
4 2.5E-11 1.2E-03 0.99
4.1 3.9E-11 1.6E-03 0.99

[PO4 3-]
[HPO4 2-]
 4.2 6.3E-11 2.0E-03 0.99
4.3 9.9E-11 2.5E-03 0.99
4.4 1.6E-10 3.1E-03 0.99
[PO4 3-] 4.5 2.5E-10 4.0E-03 0.99
[HPO4 2-]
4.6 4.0E-10 5.0E-03 0.99
[H2PO4 -]
4.7 6.3E-10 6.3E-03 0.99
[H3PO4]
log[H+] 4.8 9.9E-10 7.9E-03 0.99
log[OH-] 4.9 1.6E-09 9.9E-03 0.99
5 2.5E-09 1.2E-02 0.99
5.1 3.9E-09 1.6E-02 0.98
5.2 6.2E-09 2.0E-02 0.98
5.3 9.8E-09 2.4E-02 0.98
5.4 1.5E-08 3.1E-02 0.97
5.5 2.4E-08 3.8E-02 0.96
5.6 3.8E-08 4.8E-02 0.95
5.7 5.9E-08 5.9E-02 0.94
5.8 9.3E-08 7.4E-02 0.93
5.9 1.4E-07 9.1E-02 0.91
6 2.2E-07 1.1E-01 0.89
6.1 3.4E-07 1.4E-01 0.86
6.2 5.3E-07 1.7E-01 0.83
6.3 8.0E-07 2.0E-01 0.80
6.4 1.2E-06 2.4E-01 0.76
6.5 1.8E-06 2.8E-01 0.72
6.6 2.7E-06 3.3E-01 0.67
6.7 3.9E-06 3.9E-01 0.61
6.8 5.6E-06 4.4E-01 0.56
6.9 7.9E-06 5.0E-01 0.50
7 1.1E-05 5.6E-01 0.44
7.1 1.5E-05 6.1E-01 0.39
7.2 2.1E-05 6.7E-01 0.33
7.3 2.8E-05 7.2E-01 0.28
7.4 3.8E-05 7.6E-01 0.24
7.5 5.0E-05 8.0E-01 0.20
7.6 6.6E-05 8.3E-01 0.17
7.7 8.6E-05 8.6E-01 0.14
7.8 1.1E-04 8.9E-01 0.11
7.9 1.4E-04 9.1E-01 0.09
8 1.8E-04 9.3E-01 0.07
8.1 2.4E-04 9.4E-01 0.06
8.2 3.0E-04 9.5E-01 0.05
8.3 3.8E-04 9.6E-01 0.04
8.4 4.9E-04 9.7E-01 0.03
8.5 6.2E-04 9.7E-01 0.02
8.6 7.8E-04 9.8E-01 0.02
8.7 9.8E-04 9.8E-01 0.02
8.8 1.2E-03 9.9E-01 0.01
8.9 1.6E-03 9.9E-01 0.01
 9 2.0E-03 9.9E-01 0.01
9.1 2.5E-03 9.9E-01 0.01
9.2 3.1E-03 9.9E-01 0.00
9.3 3.9E-03 9.9E-01 0.00
9.4 5.0E-03 9.9E-01 0.00
9.5 6.3E-03 9.9E-01 0.00
9.6 7.9E-03 9.9E-01 0.00
9.7 9.9E-03 9.9E-01 0.00
9.8 1.2E-02 9.9E-01 0.00
9.9 1.6E-02 9.8E-01 0.00
10 2.0E-02 9.8E-01 0.00
10.1 2.4E-02 9.7E-01 0.00
10.2 3.1E-02 9.7E-01 0.00
10.3 3.8E-02 9.6E-01 0.00
10.4 4.8E-02 9.5E-01 0.00
10.5 5.9E-02 9.4E-01 0.00
10.6 7.4E-02 9.3E-01 0.00
10.7 9.1E-02 9.1E-01 0.00
10.8 1.1E-01 8.9E-01 0.00
10.9 1.4E-01 8.6E-01 0.00
11 1.7E-01 8.3E-01 0.00
11.1 2.0E-01 8.0E-01 0.00
11.2 2.4E-01 7.6E-01 0.00
11.3 2.8E-01 7.2E-01 0.00
11.4 3.3E-01 6.7E-01 0.00
11.5 3.9E-01 6.1E-01 0.00
11.6 4.4E-01 5.6E-01 0.00
11.7 5.0E-01 5.0E-01 0.00
11.8 5.6E-01 4.4E-01 0.00
11.9 6.1E-01 3.9E-01 0.00
12 6.7E-01 3.3E-01 0.00
12.1 7.2E-01 2.8E-01 0.00
12.2 7.6E-01 2.4E-01 0.00
12.3 8.0E-01 2.0E-01 0.00
12.4 8.3E-01 1.7E-01 0.00
12.5 8.6E-01 1.4E-01 0.00
12.6 8.9E-01 1.1E-01 0.00
12.7 9.1E-01 9.1E-02 0.00
12.8 9.3E-01 7.4E-02 0.00
12.9 9.4E-01 5.9E-02 0.00
13 9.5E-01 4.8E-02 0.00
13.1 9.6E-01 3.8E-02 0.00
13.2 9.7E-01 3.1E-02 0.00
13.3 9.8E-01 2.5E-02 0.00
13.4 9.8E-01 2.0E-02 0.00
13.5 9.8E-01 1.6E-02 0.00
13.6 9.9E-01 1.2E-02 0.00
13.7 9.9E-01 9.9E-03 0.00
13.8 9.9E-01 7.9E-03 0.00
13.9 9.9E-01 6.3E-03 0.00
14 1.0E+00 5.0E-03 0.00
 1.2E+00

1.0E+00
φ(H3PO4)
0.99
0.99
0.98 8.0E-01
0.98
0.98
0.97
0.96 6.0E-01
φcI

0.95
0.94
0.93
0.91 4.0E-01
0.89
0.86
0.83
0.80
2.0E-01
0.76
0.72
0.67
0.61
0.0E+00
0.56 0 2 4 6 8 10 12
0.50 pH
0.44
0.39
0.33
0.28
0.24
0.20
0.17
0.14
0.11
0.09
0.07
0.06
0.05
0.04
0.03
0.02
0.02
0.02
0.01
0.01
0.01
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
 Ct K2 K1 B1
0.1 6.3095734E-05 3.1622777E-12 316227766017

pH Log[L 2-] Log[HL-]

0 -16.700027401 -5.2000274013
0.1 -16.500034496 -5.1000344959
0.2 -16.300043427 -5.0000434273
0.3 -16.100054671 -4.900054671
0.4 -15.900068826 -4.8000688256
0.5 -15.700086644 -4.7000866445
0.6 -15.500109076 -4.6001090761
PO4 3- 0.7 -15.300137314 -4.5001373143
HPO4 2- 0.8 -15.100172861 -4.4001728613
H2PO4 - 0.9 -14.900217608 -4.3002176083
H3PO4
1 -14.700273935 -4.2002739349
1.1 -14.500344835 -4.1003448354
1.2 -14.300434077 -4.0004340775
1.3 -14.1005464 -3.9005464005
1.4 -13.900687765 -3.8006877655
1.5 -13.700865668 -3.7008656681
1.6 -13.501089531 -3.6010895306
1.7 -13.301371193 -3.5013711928
1.8 -13.101725525 -3.401725525
1.9 -12.902171192 -3.3021711922
10 12 14 16 2 -12.702731604 -3.2027316043
2.1 -12.503436095 -3.1034360948
2.2 -12.304321374 -3.0043213738
2.3 -12.105433314 -2.9054333142
2.4 -11.906829128 -2.8068291283
2.5 -11.708579999 -2.7085799992
2.6 -11.510774226 -2.6107742255
2.7 -11.313520922 -2.5135209221
2.8 -11.116954289 -2.4169542893
2.9 -10.921238402 -2.321238402
3 -10.726572376 -2.2265723757
3.1 -10.53319562 -2.1331956201
3.2 -10.341392685 -2.0413926854
3.3 -10.151496942 -1.9514969423
3.4 -9.9638920346 -1.8638920346
3.5 -9.7790097504 -1.7790097504
3.6 -9.5973227948 -1.6973227948
3.7 -9.4193310497 -1.6193310497
3.8 -9.2455404656 -1.5455404656
3.9 -9.0764348661 -1.4764348661
4 -8.9124426081 -1.4124426081
4.1 -8.7539018987 -1.3539018987
4.2 -8.6010300065 -1.3010300065
4.3 -8.4539019063 -1.2539019063
4.4 -8.3124426239 -1.2124426239
4.5 -8.1764348914 -1.1764348914
4.6 -8.0455405022 -1.1455405022
4.7 -7.9193311004 -1.1193311004
4.8 -7.797322863 -1.097322863
4.9 -7.6790098406 -1.0790098406
5 -7.5638921527 -1.0638921527
5.1 -7.4514970956 -1.0514970956
5.2 -7.341392883 -1.041392883
5.3 -7.2331958738 -1.0331958738
5.4 -7.1265727001 -1.0265727001
5.5 -7.0212388155 -1.0212388155
5.6 -6.9169548151 -1.0169548151
5.7 -6.8135215893 -1.0135215893
5.8 -6.7107750708 -1.0107750708
5.9 -6.6085810688 -1.0085810688
6 -6.5068304802 -1.0068304802
6.1 -6.4054350217 -1.0054350217
6.2 -6.3043235289 -1.0043235289
6.3 -6.2034388134 -1.0034388134
6.4 -6.1027350324 -1.0027350324
6.5 -6.0021755134 -1.0021755134
6.6 -5.9017309708 -1.0017309708
6.7 -5.8013780542 -1.0013780542
6.8 -5.7010981741 -1.0010981741
6.9 -5.6008765552 -1.0008765552
7 -5.5007014771 -1.0007014771
7.1 -5.400563668 -1.000563668
7.2 -5.3004558215 -1.0004558215
7.3 -5.2003722149 -1.0003722149
7.4 -5.100308409 -1.000308409
7.5 -5.0002610138 -1.0002610138
7.6 -4.9002275106 -1.0002275106
7.7 -4.8002061181 -1.0002061181
7.8 -4.7001956989 -1.0001956989
7.9 -4.6001956989 -1.0001956989
8 -4.5002061181 -1.0002061181
8.1 -4.4002275106 -1.0002275106
8.2 -4.3002610138 -1.0002610138
8.3 -4.200308409 -1.000308409
8.4 -4.1003722149 -1.0003722149
8.5 -4.0004558215 -1.0004558215
8.6 -3.900563668 -1.000563668
8.7 -3.8007014771 -1.0007014771
8.8 -3.7008765552 -1.0008765552
8.9 -3.6010981741 -1.0010981741
9 -3.5013780542 -1.0013780542
 9.1 -3.4017309708 -1.0017309708
9.2 -3.3021755134 -1.0021755134
9.3 -3.2027350324 -1.0027350324
9.4 -3.1034388134 -1.0034388134
9.5 -3.0043235289 -1.0043235289
9.6 -2.9054350217 -1.0054350217
9.7 -2.8068304802 -1.0068304802
9.8 -2.7085810688 -1.0085810688
9.9 -2.6107750708 -1.0107750708
10 -2.5135215893 -1.0135215893
10.1 -2.4169548151 -1.0169548151
10.2 -2.3212388155 -1.0212388155
10.3 -2.2265727001 -1.0265727001
10.4 -2.1331958738 -1.0331958738
10.5 -2.041392883 -1.041392883
10.6 -1.9514970956 -1.0514970956
10.7 -1.8638921527 -1.0638921527
10.8 -1.7790098406 -1.0790098406
10.9 -1.697322863 -1.097322863
11 -1.6193311004 -1.1193311004
11.1 -1.5455405022 -1.1455405022
11.2 -1.4764348914 -1.1764348914
11.3 -1.4124426239 -1.2124426239
11.4 -1.3539019063 -1.2539019063
11.5 -1.3010300065 -1.3010300065
11.6 -1.2539018987 -1.3539018987
11.7 -1.2124426081 -1.4124426081
11.8 -1.1764348661 -1.4764348661
11.9 -1.1455404656 -1.5455404656
12 -1.1193310497 -1.6193310497
12.1 -1.0973227948 -1.6973227948
12.2 -1.0790097504 -1.7790097504
12.3 -1.0638920346 -1.8638920346
12.4 -1.0514969423 -1.9514969423
12.5 -1.0413926854 -2.0413926854
12.6 -1.0331956201 -2.1331956201
12.7 -1.0265723757 -2.2265723757
12.8 -1.021238402 -2.321238402
12.9 -1.0169542893 -2.4169542893
13 -1.0135209221 -2.5135209221
13.1 -1.0107742255 -2.6107742255
13.2 -1.0085799992 -2.7085799992
13.3 -1.0068291283 -2.8068291283
13.4 -1.0054333142 -2.9054333142
13.5 -1.0043213738 -3.0043213738
13.6 -1.0034360948 -3.1034360948
13.7 -1.0027316043 -3.2027316043
13.8 -1.0021711922 -3.3021711922
13.9 -1.001725525 -3.401725525
14 -1.0013711928 -3.5013711928
B2
5.0118723E+15 0
0 2 4 6

Log[H2L]
-2
-1.0000274013
-1.0000344959
-1.0000434273
-4
-1.000054671
-1.0000688256
-1.0000866445
-6
-1.0001090761
-1.0001373143
-1.0001728613
-1.0002176083 -8

-1.0002739349
-1.0003448354
-1.0004340775 -10
-1.0005464005
-1.0006877655
-1.0008656681 -12
-1.0010895306
-1.0013711928
-1.001725525 -14
-1.0021711922
-1.0027316043
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-5.9017309708
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-12.702731604
-12.902171192
-13.101725525
-13.301371193
6 8 10 12 14

pH
14 16

l og[L 2-]
l og[HL -]
LOG[H2L]
LOG[OH-]
LOG[H+]