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On examination,two samples of clay from Aprbs examen de deux 6&autillons d’argile des
Keuper marls have been found to contain a chloritic marues Keuper on a trouvb qu’ils contiennent un
mineral showing a limited c-axis expansion on minCral chloritique qui montre une dilatation
glycerol treatment. One of these samples gives the limit& de I’axe c apres traitement par le glycerol.
same (001) spacing as montmorillonoids when Un de ces Chantillons donne le m&me espacement
treated with glycerol, and a heating test is necemary (001) que les montmorillonoides aprbs traitement
to make the distinction. par le glycPro1, et un essai par le chauffage e#
n5xssaire pour faire la distinction.
The observed spacing of 17.8 Angstriim units is probably due to one layer of glycerol molecules
between the chlorite layers of about 14 &@riim units thickness, whereas the similar spacing
in glycerol-montmorillonoid is due to two layers of molecules between pyrophyllite-like layers
of about 9.4 Angstrom units thickness. The Blithe valley material thus appears to be a
new mineral, with properties different from those of either normal chlorites or montmorillo-
noids. In order to differentiate it from these two mineral types, it is necessary to take X-ray
photographs both after glycerol treatment and after heating to 500” C., and it is desirable also
to take a photograph of a dry aggregate without treatment. Table 1 indicates the basal
reflexions given by the three mineral types discussed above, and indicates how they may be
distinguished.
Without treatment ..
Glycerol-saturated .. 1: 1:
Heated to 599” C. .. .. ..
l The symbol /ta indicates a sequence of sharp higher orders. The heated chlorite muy show such a
sequence. The spacings are approximate, no account being taken of possible small shifts.
This mineral and the related mineral mentioned first were found in Keuper-marl deposits
(where they occurred in admixture with mica), and a number of similar chloritic clay minerals
have since been found in other deposits of the same age, both by the Authors and by Dr Aruja
and Mr Honeyborne 1 of the Building Research Station. Such minerals appear, therefore,
to be characteristic of these deposits, although presumably not uniquely so. It is of note
that, starting from montmorillonite, an artificial chlorite-like material that shows certain
similarities to those described above has been produced in the laboratory (Caill6re and Henin,
1949).
REFERENCES
CAILL~&S, S., and H~NIN, S., 1949. Experimental formation of chlorites from montmorillonite.
Mineralogical Magazine. 28 : 612-620.
MACEWAN, D. M. C., 1944. Identification of the montmorillonite group of minerals by X-rays. Notwe.
154 : 577-578.
i Honeyborne, D. B. The clay minerals in the Keuper Marl. Read before the Mineralogical Society (Clay
Minerals Group), London, 11 November, 1949. Nol published.