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Blanko 0.2
15 minute 0.4
30 minute 0.8
45 minute 1
60 minute 1.32
120 minute 1.95
1.86 gr
= 8.6
t = 30 minutes
a = 0.8 ml
b = 0.2 ml
Peroxide number = (0.8 -0.2)ml x 0.1 x 100 x 8
1.86 gr
= 25.808
t = 45 minutes
a = 1.0 ml
b = 0.2 ml
Peroxide number = (1.0 -0.2)ml x 0.1 x 1000
1.86 gr
= 34.408
t = 60 minutes
a = 1.32 ml
b = 0.2 ml
Peroxide number = (1.32 -0.2)ml x 0.1 x 100 x 8
1.86 gr
= 48.176
t = 120 minutes
a = 1.95 ml
b = 0.2 ml
Peroxide number = (1.95 -0.2)ml x 0.1 x 100 x 8
1.86 gr
= 75.272
y = 0.0101x + 5.6374
60
R² = 0.9637
50
40
30
20
10
0
0 2000 4000 6000 8000
t (second)
Determine order of reaction
𝑎
With this equation 𝑘 𝑡 = ln (𝑎−𝑥)
1 𝑎
𝑘= ln
𝑡 (𝑎 − 𝑥)
t (second) x Calculation k
900 0,02 1 7,27 3,05 x 10-6
𝑘= ln
900 (7,27 − 0,02)
1800 0,04 1 7,27 3,048 x 10-6
𝑘= ln
1800 (7,27 − 0,04)
2700 0,05 1 7,27 2,547 x 10-6
𝑘= ln
2700 (7,27 − 0,05)
3600 0,066 1 7,27 2,516 x 10-6
𝑘= ln
3600 (7,27 − 0,066)
7200 0,0975 1 7,27 1,862 x 10-6
𝑘= ln
7200 (7,27 − 0,0975)
𝑥
With this equation 𝑘 𝑡 = 𝑎(𝑎−𝑥)
1 𝑥
𝑘 =
𝑡 𝑎(𝑎 − 𝑥)
t (second) x Calculation k
900 0,02 1 0,02 4,216 x 10-7
𝑘 =
900 7,27(7,27 − 0,02)
1800 0,04 1 0,04 4,228 x 10-7
𝑘 =
1800 7,27(7,27 − 0,04)
2700 0,05 1 0,05 3,528 x 10-7
𝑘 =
2700 7,27(7,27 − 0,05)
3600 0,066 1 0,066 3.500 x 10-7
𝑘 =
3600 7,27(7,27 − 0,066)
7200 0,0975 1 0,0975 2,597 x 10-7
𝑘 =
7200 7,27(7,27 − 0,0975)
1 1
With this equation 𝑘 𝑡 = 2(𝑎−𝑥)2 − 2𝑎2
1 1 1
𝑘 = 2
− 2
𝑡 2(𝑎 − 𝑥) 2𝑎
t (second) x Calculation k
900 0,02 1 1 1 9,514 x 10-6
𝑘 = −
900 2(7,27 − 0,02)2 2(7,27)2
1800 0,04 1 1 1 4,788 x 10-6
𝑘 = 2
−
1800 2(7,27 − 0,04) 2(7,27)2
2700 0,05 1 1 1 3,202 x 10-6
𝑘 = −
2700 2(7,27 − 0,05)2 2(7,27)2
3600 0,066 1 1 1 2,413 x 10-6
𝑘 = 2
−
3600 2(7,27 − 0,066) 2(7,27)2
7200 0,0975 1 1 1 1,218 x 10-6
𝑘 = 2
−
7200 2(7,27 − 0,0975) 2(7,27)2
First order
1.9760000 R² = 0.9659
1.9740000
1.9720000
1.9700000
1.9680000
0 2000 4000 6000 8000
t (second)
Second order
0.1388 R² = 0.9648
0.1386
0.1384
0.1382
0.138
0.1378
0 2000 4000 6000 8000
t (second)
Third order
0.019500
Graphic of third order
0.019450
0.019400
0.019350
0.019300
1/(a-x)2
0.019250
y = 6E-08x + 0.019
0.019200 R² = 0.9644
0.019150
0.019100
0.019050
0.019000
0 2000 4000 6000 8000
t (second)