Académique Documents
Professionnel Documents
Culture Documents
The reaction rate is the speed with which a certain amount of moles of a chemical species
is consumed to form another chemical species.
Individual species involved in a particular reaction are known as reactive (if disappear) or
product (if formed) with a given speed.
The rate of disappearance of one species (A), is the number of molecules that lose their
chemical identity (react) per unit time per unit volume due to rupture and subsequent
chemical bonding during the course of the reaction.
The types of chemical reactions that can be found, in general, are classif ied as:
decomposition (reactive smaller molecules, atoms or fragments atoms break),
combination of two or more molecules or isomerization (implies a change in conf iguration)
.
UNIT 1. BASICS IN CHEMICAL REACTOR
DESIGN.
Decomposition reaction. A→B + C
Composition reaction. A + B →C
A + 2B → C + D
mol
−r A = 4
lt∗sec The reacton rate r, is the number of
moles that react per unit tme and
unit volume. Its units are (mol s-1 lt-1)
UNIT 1. BASICS IN CHEMICAL REACTOR
DESIGN.
Nomenclatura y signos para definir la velocidad de reacción.
A + 2B → C + D
k (T )=k 0 exp ( )
−E a
RT
Fi0 Fi
Gi
Si las propiedades del sistema son uniformes: T, P, Cj, ..., uniformes en todo
el volumen de control
Gi [ ] [ ]
gmol
s
=ri
gmol
s∗L
V [ L]
V
M →∞ G i =∫ r i dV
ΔV →0
UNIT 1. BASICS IN CHEMICAL REACTOR
DESIGN.
1.2 Balances molares.
V
dN i
F io − F i + ∫ r i dV =
dt
( )
k (T )=k 0 exp
−E a
RT
UNIT 1. BASICS IN CHEMICAL REACTOR
DESIGN.
1.4 Efectos de la temperatura sobre al velocidad de reacción.
Separations.
UNIT 1. BASICS IN CHEMICAL REACTOR
DESIGN.
Reaction Engineering
UNIT 1. BASICS IN CHEMICAL REACTOR
DESIGN.
UNIT 1. BASICS IN CHEMICAL REACTOR
DESIGN.
UNIT 1. BASICS IN CHEMICAL REACTOR
DESIGN.