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Liburdi Turbine Services Inc
1
Liburdi Group of Companies
• Liburdi Engineering Ltd
• Liburdi Turbine Services Inc.
• Liburdi Automation Inc.
• Liburdi Dimetrics Corp
5
GT Component Repairs – Why ?
• Maintenance, after fuel, is the main operating cost over the life cycle of a
gas turbine engine
• Spare part replacements and repairs of hot section components
represent the major cost portion of all Maintenance
• Typically a component repair will cost 10% - 30% of the replacement new
part cost
• Therefore, repairs represent the main cost savings opportunity for the
operator
• Repair is ecologically favourable; less resources and energy required
6
Why are they referred to as Superalloys?
7
Overview of why Superalloys
are used in Gas Turbines
• Excellent mechanical properties in the service range that gas
turbine materials operate in, even after prolonged service
• Excellent creep strength
• Useful mechanical strength
• Good fatigue and thermal fatigue properties
• Adequate ductility and toughness (low crack growth rates)
• Useful thermal expansion characteristics
• Excellent resistance to oxidation and corrosion
• Alloy additions form self-healing protective scales
• Fabricability (forging, casting, welding, machining, coating)
8
Superalloy elements - and Why?
• Alloy “Solvent” must be stable throughout the intended operating
temperature range and be able to dissolve large amounts of
“Solute”. Usually a mixture of nickel and cobalt
• Protective scale formers added for oxidation protection; provided
by aluminum & chromium,
• Heavy “refractory” elements added for solution hardening,
molybdenum, niobium, rhenium, tantalum, tungsten
• Precipitation forming elements added for strengthening
aluminum, titanium, niobium
• Grain boundaries are strengthened (or controlled) carbon,
hafnium, zirconium, boron
• Deleterious “tramp” elements are rigorously limited - sulphur,
lead, silver
9
Compositions and Properties
Nickel Based Alloys
•Sheet alloys like solid-solution HasteloyX, Nimonic263, IN617
have low aluminum + titanium content have excellent
formability, used for combustor section fabrications and
lightly loaded combustion liner segments.
´ effective for
strengthening to
Al 2000oF (1090oC).
˝ only effective
for strengthening to
Ni 1200oF (650oC).
Cuboidal primary
´ phase
Spherical
secondary ´
phase
13
Casting Technologies
Equiaxed (EQ)
Conventionally Cast (CC) Directionally Solidified (DS) Single Crystal (SC or SX)
[polycrystalline - random] [polycrystalline - textured] [monocrystalline]
14
Equiaxed Grain Structure
Directional Solidified Grain Structure
Single Crystal Structure
MarM002
15
Cast Nickel Based Alloy Compositions
Alloy Ni Cr Co Mo W Ta Nb Al Ti Fe Mn Hf C B Zr Others
Alloy 713C 74 12.5 0.0 4.2 0.0 0.0 2.0 6.1 0.8 0.0 0.0 0.0 0.12 0.012 0.10
B-1900 64 8.0 10.0 6.0 0.0 4.0 0.0 6.0 1.0 0.0 0.0 0.0 0.10 0.015 0.10
C-1023 58 15.5 10.0 8.5 0.0 0.0 0.0 4.2 3.6 0.0 0.0 0.0 0.16 0.006 0.00
GTD-111 60 14.0 9.5 1.5 3.8 2.8 0.0 3.0 4.9 0.0 0.0 0.0 0.10 0.01 0.03
GTD-222 51 22.5 19.0 0.0 2.0 1.0 0.8 1.2 2.3 0..0 0.0 0.0 0.10 0.010 0.01
IN-100 60 10.0 15.0 3.0 0.0 0.0 0.0 5.5 4.7 0.0 0.0 0.0 0.18 0.014 0.06 1.0 V
IN-738LC 61 16.0 8.5 1.7 2.6 1.7 0.9 3.4 3.4 0.0 0.0 0.0 0.11 0.010 0.05
IN-939 48 22.5 19.9 0.0 2.0 1.4 1.0 1.9 3.7 0.0 0.0 0.0 0.15 0.009 0.09
IN-792 61 12.4 9.0 1.9 3.8 3.9 0.0 3.1 4.5 0.0 0.0 0.0 0.12 0.020 0.10
MarM-002 61 9.0 10.0 0.0 10 2.5 0.0 5.5 1.5 0.0 0.0 1.5 0.14 0.015 0.05
MarM-247 60 8.3 10.0 0.7 10 3.0 0.0 5.5 1.0 0.0 0.0 1.5 0.10 0.015 0.05
CMSX- 2 66 8.0 4.6 0.6 7.9 5.8 0.0 5.6 0.9 0.0 0.0 0.0 0.00 0.000 0.00
PWA-1483 61 12.8 9.0 1.9 3.8 4.0 0.0 3.6 4.0 0.0 0.0 0.0 0.07 0.0 0.0
Rene-N5 62 7.0 8.0 2.0 5.0 7.0 0.0 6.2 0.0 0.0 0.0 0.2 0.0 0.0 0.0 3.0 Re
CMSX-10 62 3.0 6.0 1.0 6.0 8.5 0.3 6.0 0.8 0.0 0.0 0.1 0.0 0.0 0.0 6.0 Re
16
Cast Nickel Based Alloy Compositions
Alloy Ni Cr Co Mo W Ta Nb Al Ti Fe Mn Hf C B Zr Others
Alloy 713C 74 12.5 0.0 4.2 0.0 0.0 2.0 6.1 0.8 0.0 0.0 0.0 0.12 0.012 0.10
B-1900 64 8.0 10.0 6.0 0.0 4.0 0.0 6.0 1.0 0.0 0.0 0.0 0.10 0.015 0.10
C-1023 58 15.5 10.0 8.5 0.0 0.0 0.0 4.2 3.6 0.0 0.0 0.0 0.16 0.006 0.00
GTD-111 60 14.0 9.5 1.5 3.8 2.8 0.0 3.0 4.9 0.0 0.0 0.0 0.10 0.01 0.03
GTD-222 51 22.5 19.0 0.0 2.0 1.0 0.8 1.2 2.3 0..0 0.0 0.0 0.10 0.010 0.01
IN-100 60 10.0 15.0 3.0 0.0 0.0 0.0 5.5 4.7 0.0 0.0 0.0 0.18 0.014 0.06 1.0 V
IN-738LC 61 16.0 8.5 1.7 2.6 1.7 0.9 3.4 3.4 0.0 0.0 0.0 0.11 0.010 0.05
IN-939 48 22.5 19.9 0.0 2.0 1.4 1.0 1.9 3.7 0.0 0.0 0.0 0.15 0.009 0.09
IN-792 61 12.4 9.0 1.9 3.8 3.9 0.0 3.1 4.5 0.0 0.0 0.0 0.12 0.020 0.10
MarM-002 61 9.0 10.0 0.0 10 2.5 0.0 5.5 1.5 0.0 0.0 1.5 0.14 0.015 0.05
MarM-247 60 8.3 10.0 0.7 10 3.0 0.0 5.5 1.0 0.0 0.0 1.5 0.10 0.015 0.05
CMSX- 2 66 8.0 4.6 0.6 7.9 5.8 0.0 5.6 0.9 0.0 0.0 0.0 0.00 0.000 0.00
PWA-1483 61 12.8 9.0 1.9 3.8 4.0 0.0 3.6 4.0 0.0 0.0 0.0 0.07 0.0 0.0
Rene-N5 62 7.0 8.0 2.0 5.0 7.0 0.0 6.2 0.0 0.0 0.0 0.2 0.0 0.0 0.0 3.0 Re
CMSX-10 62 3.0 6.0 1.0 6.0 8.5 0.3 6.0 0.8 0.0 0.0 0.1 0.0 0.0 0.0 6.0 Re
17
Hot Section Coating Requirements
COATING SELECTION COATING PROCESSES
18
Cyclic Oxidation Mechanism
• Aluminum oxide scale formed on surface of nickel base alloys – the
scale is a barrier to additional oxidation and is protective
• During thermal cycling, the difference in thermal expansion coefficients
(metal>>oxide) between the oxide and metal leads to stresses at the
interface
• Spalling will result – therefore scale adhesion is necessary for good
oxidation performance
20
Nickel Aluminide Diffusion Coatings
Compositions & Microstructures
Silicon Aluminide Platinum Aluminide
22
MCrAlY Overlay Coatings
• Overlay coatings are applied by thermal spray which results in minimal
reaction with the substrate
• This allows greater freedom to tailor coating composition than in diffusion
coatings
Typical thickness
0.005 to 0.010”
• Dense and uniform coatings are preferred for MCrAlY coatings as they
better isolate the base metal from gas infiltration
• Except as bond-coatings under TBC’s, in these applications the
porosity and defects allow differential thermal expansion
• Clean and rough interfaces promote better adhesion.
26
Comparative Oxidation and
Corrosion Performance
PtAl
Silicon Al
27
Thermal Barrier Coatings (TBC)
• Thermal Barrier Coatings are applied over an MCrAlY bond coating. Bond
coating provides oxidation/corrosion resistance; TBC provides thermal
insulation layer
• Repair surface must be clean of oxides/contamination to ensure good bond
and adhesion of MCrAlY bond coat. The bond coat is usually applied with a
rough surface to assist in the bonding of the TBC top coat.
• TBC is applied by Air Plasma Spray (APS) on large and loss-critical
hardware like combustor components and vanes.
• TBC is applied as Electron Beam Physical Vapour Deposition (EBPVD) in
a low pressure chamber on small and critical components like blades.
28
Comparison: EBPVD and Thermal Spray;
Two Different TBC Microstructures
30
Thermal Mechanical
Fatigue (TMF) Damage
• Transient thermal strains during start-up and shutdown cycles
combined with the steady state thermal and centrifugal loads
generate a complex low cycle fatigue load on turbine parts –
thus TMF life is a function of start/stop cycles
31
Thermal Mechanical
Fatigue (TMF) Damage
32
Thermal Mechanical
Fatigue (TMF) Damage
33
High Cycle Fatigue (HCF)
• High cycle fatigue in turbines is most frequently excited by
an engine order fatigue load
• It should be recognized that, at these frequencies, millions
of cycles can be accumulated in a few hours
• As such, turbine components are not designed with a HCF
life – they should have infinite life under normal operating
conditions
• Conversely HCF damage can be accumulated very rapidly
under non-design conditions
34
High Cycle Fatigue (HCF)
35
High Cycle Fatigue (HCF) (Cont.)
• High cycle fatigue fractures typically show the cyclic growth of
the crack with each cycle by the formation of fatigue striations
on the crack surface
• Beach marks may be formed by episodic
crack growth
36
Microstructure - ´ Aging
• The metal temperatures in the hot section are high enough
that growth of ´ particles takes place by diffusion to
minimize the interfacial energy
• The particle growth takes place at constant volume fraction
(ie. there are fewer larger particles)
38
Creep Damage (Cont.)
39
Environmental Attack: Oxidation
40
Environmental Attack Hot Corrosion
41
Environmental Attack - Hot
Corrosion (Cont.)
• Distinctive scale morphologies associated with each
temperature range have been identified, but attack with
features of both scales is commonly identified
42
Environmental Attack - Hot Corrosion (Cont.)
Dependent
rate hot corrosion takes place
Sulphur most rapidly at
Independent approximately 700˚C
(1300˚F) and only in high
Sulphur environments
Na2SO4
Dewpoint • High temperature (Type I)
hot corrosion occurs at
700 800 900 approximately 875˚C
Temperature [°C] (1600˚F)
43
43
Coating Degradation - Depletion
44
Coating Degradation - Cracking
46
Metallurgical Sectioning Plan
47
47
Mechanical Testing
• Stress-Rupture, Creep, Tensile Test Bars
• Compare to new material specifications
• Compare to minimum serviceability limits
48
48
Common Repair and Refurbishment
Operations
• Strip remaining coating
49
Chemical Stripping of Coating
• The repair of coated components requires that old spent
coating be removed from the parts
50
Chemical Stripping: Metallurgical Effects
51
Chemical Stripping: Control
• Non-destructive testing
52
How Compositions Affect Weld Repair
- Nickel based Alloys
• Solid-solution superalloys, HastX, Haynes230, IN617 IN625 (zero to low
aluminium+titanium) are weldable
• Superalloys with high gamma-prime (´) content (high
aluminium+titanium) are difficult to weld because of cracking
• In many cases there is no matching filler metal in wire form, so you may
have to resort to powder as filler metal. This limits available welding
techniques.
• IN625 solid solution alloy has been an industry choice to weld some of
the cast, high gamma prime (´) content superalloys. However it is
relatively weak which limits welding to low stress areas of low to
intermediate temperatures
53
53
Welding Challenges
Welding of gamma prime
(´) strengthened
superalloys is difficult
compared to welding of
cobalt base alloys or
stainless steel alloys.
• Fusion Zone cracking
MM002
• HAZ cracking
(microfissuring)
• Post weld heat treat
cracking (strain age
cracking)
54
Gas Tungsten Arc Welding
(GTAW) or “TIG”
• Arc established between the non consumable
tungsten electrode and the work piece.
• The process uses shielding gas (typically Argon
or Helium) and filler metal.
• Most common method for manual welds
• Process advantages include:
– Producing superior quality welds, free of
defects.
–.
GTAW (TIG) welding using DCEN (Direct
Current, Electrode Negative)
55
Laser Beam Welding (LBW)
• LASER (light amplification by stimulated
emission of radiation)
• Heat is generated by a concentrated
beam of coherent, monochromatic light.
• The laser beam is directed by fibre-optic
cables or mirrors and then focused to a
spot using lenses.
• High energy density welding
• Low total heat input gives small fusion
zone for clean welds
57
New Advanced Repairs for
SGT-A35 Industrial RB211 Components
Time Line of Advanced Repairs Introduced by Liburdi
1995 – RB211-24C HPT Blades
1997 – RB211-24C/G IPT Blades
2002 – Rolls-Royce (now Siemens) Authorizes Liburdi Advanced Repairs
2003 – RB211-24C HPT NGV
2003 – RB211-24G HPT NGV
2003 – RB211-24C/G IPT NGV
2004 – RB211-24G HPT Seal Segments
2004 – RB211-24C HPT Seal Segments
2005 – RB211-24C/G IPT Seal Segments
2008 – RB211 Compressor Vane Repair/Upgrades
– RB211 Stage 5 Stage 6 OGV Repairs in development
– RB211 DLE Combustor Repair in development
– RB211-24GT Blade Repairs in development
58
LTS SGT-A35 RB211 Applications
59
RB211 HPT and IPT Blades
Advanced Weld Repair
Advanced Weld Repair
after 24,000 hours service
• no shroud metal loss
• L3667 Weld Alloy
Sets now achieve 24,000 hours intervals
and service intervals through to 120,000+ hours
New Blades 24,000 hrs service Conventional CM64 Weld after 13,000 hrs
• - metal loss leads to weld repair extensive metal loss
60
FSR® Full Solution Rejuvenation
for RB211 Blades Alloys MarM002, MarM002DS
• Full Solution rejuvenation heat treat – not partial
• Proprietary vacuum heat treatments
• Restore MicroStructure and Properties (creep strength)
61
RB211 HPT NGV Reconstruction Repair
Original braze joint •Incoming damage –
requires burned leading and
repair/restoration trailing edges , thin
airfoils, burned outer
shroud surfaces, shroud
braze joints deteriorated
Severely burned
trailing edges
62
RB211 HPT NGV Reconstruction Repair
65
RB211 IPT NGV
Reconstruction by LPM®
• Airfoil thickness restoration in 2007 by LPM® process
• NGV ran in engine 179-822 for 24,281 service hours
• After service, NGV stripped and inspected – LPM reconstruction alloy is
etched to be visible – entire trailing portion of airfoil had been
reconstructed and ready for a second service interval
66
RB211 HPT Seal Segment Reconstruction
• Reconstructed backing
plate – dimensions
checked and new
honeycomb being
applied
68
RB211 IPT Seal Segment Reconstruction
• Incoming seal segs distorted (out
of round), seal slots misaligned,
backing plates thin due to oxidation
– parts were previously declared
scrap and replaced with new
70
Power Turbine Applications
71
Power Turbine Applications
RT45, RT48, RT56, RT62 Power Turbine Repairs
• Liburdi has introduced a full menu of repairs for the Siemens
(RR) Power Turbines as follows:
72
Advanced Weld Repairs for
PT Cases, Diffusers, Rings
RT – 48 RT – 56 RT – 62
(LT-1391, LT-1460, LT-1470, LT-1504) (LT-1531, LT-1462, LT-1458) (LT-1459, LT-1476)
73
Advanced Weld Repairs for PT
Cases, Diffusers, Rings
74
PT Stationary Component Repair
Comprehensive Inspection and repairs of assembly
including – example
Inner Nozzle and Diffuser Assembly
Stage 2 Blade Casing
Downstream Retaining Ring
Stage 2 Nozzle Casing
Outer Inlet Diffuser Casing
Diffuser Casing
Inner Inlet Diffuser
Inspect for service damage
Test for alloy and coating composition
Recommend most cost-effective repair
Replace missing metal to restore strength
Bolt holes repaired, dowels replaced
Correct dimensional variations, distortions, restore flatness
Correct fit-up for smooth assembly
Heat-treatment to re-strengthen alloy
Re-coat to protect component
Inspect for release and issue certificate
75
Comprehensive Repair of
Complete Assembly
• Initial disassemble, clean, and incoming inspections,
• Report of damage and repair requirements
• Repair and final inspections
• Re-assemble
• Certificate of Conformance, pack and ship
76
Stage 1 and 2 Power Turbine Vane Repairs
77
Stage 1 and 2 Power Turbine Blade Repairs
78
RB211 On-Condition Maintenance
79
RB211 On-Condition Maintenance
80
ETN Conference Issues
81