No :

Nama : Lupita Churry Aini

NPM : 260110160107

(1) Nama Senyawa

Vetiver oil
Khusimol
6-Methanoazulene-3-methanol, octahydro-7,7-dimethyl-8-methylene

National Center for Biotechnology Information. 2018. PubChem Compound Database;

CID=167519. Tersedia online di https://pubchem.ncbi.nlm.nih.gov/compound/167519
(Accessed July 1, 2018).

(2) Struktur Senyawa

National Center for Biotechnology Information. 2018. PubChem Compound Database;

CID=167519. Tersedia online di https://pubchem.ncbi.nlm.nih.gov/compound/167519
(Accessed July 1, 2018).

(3) Bobot Molekul

220.356 g/mol
 National Center for Biotechnology Information. 2018. PubChem Compound Database;
CID=167519. Tersedia online di https://pubchem.ncbi.nlm.nih.gov/compound/167519
(Accessed July 1, 2018).

(4) Sumber
Smyrnium cordifolium khusimol Akar
Smyrnium cordifolium khusimol Batang
Vetiveria zizanoides khusimol Akar
Lantana fucata khusimol Daun

Tersedia online di http://nipgr.res.in/cgi-

bin/disc/essoildb/search_2.cgi?txtCompoundName=khusimol

(5) Analisis Kromatografi Lapis Tipis (KLT)

 Fase gerak : Eluen1 P-eluen2 P-eluen3 P (0:0:0)
 Fase diam : Silika gel 60 F254
 Larutan uji : 00% dalam pelarut P
 Larutan pembanding : Pembanding 0,1% dalam pelarut P
 Volume penotolan : Totolkan 00 µL Larutan uji dan 0 µL Larutan pembanding
 Deteksi : Pereaksi LP, panaskan lempeng pada suhu 100°C selama 3
menit dan UV254/UV366

Gambar KLT

S P
 Keterangan: S = Sampel; B = Pembanding

(6) Analisis Spektroskopi UV

Gambar Spektrum UV Senyawa

Keterangan : …….

(7) Analisis Spektroskopi IR

 Keterangan:
The IR spectra of Vetiver oil contain bands in the range of 3473 -3158 cm-1 and these
correspond to ʋN-H and in cases where the oil contains solvent molecules, ʋO-H.
Bands are also observed between 1610 and 1568 cm -1 and these are due to ʋC-N
and ʋC-C respectively. The absorption at 1633 cm-1 was principally associated with
absorbed water, since the hemicelluloses usually have a strong affinity for water, and
in the solid state these macromolecules may have disordered structures which can
easily be hydrated.
The band at 1388 and 1169 cm-1 attribute to C–H deformation and C–O–C vibration
in hemicelluloses, respectively. The prominent band at 1043 cm-1 was attributed to
the C–O, C–C stretching or C–OH bending in terpenes. The sharp band at 897 cm-1
corresponding to the C-1 group frequency or ring frequency, was characteristic of
vetivone.

(8) Analisis Spektroskopi Massa

Keterangan:
 Interpretation of mass spectra is limited by the interpreter’s knowledge of chemistry and ability
to understand fragmentation patterns. The majority of the organic compounds have
vibrational energy between 10-20 eV (1 eV=96.49 KJ/mol = 23.06 Kcal/mol). The common
energy of the electrons generated in the ion source is typically 70 eV. After receiving this
energy in excess, the organic molecules release one electron and fragment. During
ionization, the molecule loses one electron from the orbital and typically produces a molecular
ion (M+), which has excess energy, and will fragment into a neutral fragment and an ion
fragment (A+), which will continue producing neutral fragments and fragment ions having
smaller energy each time. The pattern of the mass spectrum gives an impression of the
successive degradation of the target compound with the series of peaks corresponding to the
various fragments. Their intensity gives an idea of stability of fragments. The fragments
appears at 825/875/913/929 (100%m/z) and 540(45% m/z) corresponds to [C36H57N3O24]+
and [C19H32NO16]+ respectively, which could be the result of degradation of the compound.
The compound after degradation, finally forms [C13H24N2O10], 465/307(20% m/z). The
extra stability of m/z values at 594 and 643 may be because of intermolecular hydrogen
bonding.

Tersedia online di
http://shodhganga.inflibnet.ac.in/bitstream/10603/135475/12/12_chapter7.pdf

(9) Analisis 1H-NMR

 Keterangan:
The H NMR spectra of the compound show well-resolved signals appeared. The
compound shows the resonance with integrated intensities. The chemical shift of the
compound appeared at 3.38---3.64(8H, m) for OH-alcohol, 2.0 (3H, m) for methoxy,
3.09-5.03, (9H, m) for CH, 7.27-7.30 (5H, m) for CH of benzene, 3.39 and 1.18 (9H,
d) for CH3.

(10) Analisis 13C-NMR

Gambar Spektrum 13C-NMR Senyawa

Keterangan : …….