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Leader & Enthusiast Course/Score(Advanced)/25-04-2018/Paper-1

HAVE CONTROL ¾® HAVE PATIENCE ¾® HAVE CONFIDENCE Þ 100% SUCCESS


BEWARE OF NEGATIVE MARKING
PART-1 : MATHEMATICS
SECTION–1 : (Maximum Marks : 30)
˜ This section contains TEN questions.
˜ Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of
these four option(s) is (are) correct.
˜ For each question, darken the bubble(s) corresponding to all the correct option(s) in the
ORS
˜ For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble(s) corresponding to all the correct option(s) is (are)
darkened.
Zero Marks : 0 In all other cases.
1. If the complex numbers z1, z2, z3 and z4 satisfy 5z1 - 6z2 + 3z3 - 2z4 = 0 and 5|z1 - z4|2 = 9|z2-z3|2
then which of the following is/are correct.
(A) z1, z2, z3 and z4 are vertices of a rectangle.
(B) The line segment joining z1 and z3 divides the line segment joining z2 and z4 in the ratio 1 : 3.
(C) The line segment joining z2 and z4 divides the line segment joining z1 and z3 in the ratio 3 : 5.
(D) z1, z2, z3 and z4 are concyclic.

2. Let N = 2
200
( 200
C0 )( 200
)
C100 - 2198 ( 200
C1 )( 199
)
C99 + 2196 ( 200
C2 )( 198
)
C98 - ....... + ( 200
C100 )( 100
C0 )
then
(A) N is equal to the coefficient of x100 in (1 - x)200
(B) The number of zeroes at the end of N is only one.
(C) N = 3101 ´ k where k is an integer.
(D) N is equal to the number of ways of distributing 200 different objects among 2 persons
equally.
Space for Rough Work

1001CJA102117099 E-3/28
Target : JEE (Main + Advanced) 2018/25-04-2018/Paper-1
3. If A and B are two matrices such that AB = A and BA = B, then

( ) = (A ) ( )
5 3 3
(A) A 3 - B 3 5
- B5 (B) A4 - B4 = A12 - B12

(C) (A - B) is idempotent (
10
(D) A - B
10
) is nilpotent
1 1

ò x .ln x dx and J (m ) = ò x . ( ln x ) dx , where m Î N, then


m m 2
4. If I(m) =
0 0

(A) I(1) + J(1) = 0 (B) 2I(2) + 3J(2) = 0


(C) I(3) + 2J(3) = 0 (D) 2I(4) + 5J(4) = 0
¥
e - ax - e -bx
5. If I(a, b) = ò dx , where a,b > 0 , then
0
x

(A) I(2, 4) - I(4, 8) = 0 (B) I(3, 6) - I(6, 12) = 0

I ( 4,16 ) I ( 9,81)
(C) =1 (D) =2
I ( 2,4 ) I ( 3,9 )

p
1 - cos nx
6. If I n = ò
0
1 - cosx
dx , where n Î N then

(A) I1010 + I1008 = 2018p (B) I1010 + I1009 = 2019p

(C) I1010 - I1008 = 2p (D) I1010 - I1009 = 2p

Space for Rough Work

E-4/28 1001CJA102117099
Leader & Enthusiast Course/Score(Advanced)/25-04-2018/Paper-1

æ x 3 + 2 - 2 x 3 + 1 + x 3 + 10 - 6 x 3 + 1 ö dx = 2x + C ,
7. If ò çè ÷
ø
when x Î [m, n ] where m and n is

least and greatest possible values of x respectively then


(A) n + m = 2 (B) n - m = 2 (C) mn = n (D) nm = n
8. Let f(x) be the function defined by

ì æ é sin x ù ö
2n

ï ç1 + ê
ç ú ÷ {x}
ï è ë x û ø÷ p
ïlim 2n
; 0<x<
ï
n ®¥
é x ù 2
ï 1+ ê ú
f(x) = í ë tan x û
ï
{x} - 3 {x}
3
ï
ï ; -2 < x £ 0
4 - [x ]
ï
ïî x 3 - 27x - 46 ; x £ -2
(where [.] represents greatest integer function and {.} represents fractional part function)
then which of the following options is/are true

æ pö
(A) there exist exactly 2 points of local minima of f(x) in the interval ç –4 , ÷
è 2ø
(B) The sum of abscissa of all of its point of local maxima is -4
(C) The sum of abscissa of all of its point of local minima is 1

(D) f(x) is not differentiable in the interval ( – ¥ , –1 )

Space for Rough Work

1001CJA102117099 E-5/28
Target : JEE (Main + Advanced) 2018/25-04-2018/Paper-1

9. ( ) ( )
Let f : ( -4 , 4 ) ® R defined by f ( x ) = [a ] - 3 [a] + 2 x 2 + 2 {a} - 3 {a} + 1 x . Let f(x) is an odd
2 2

function "x Î ( –2 , 2 ) and is an even function " ( –4 , – 2] È [2 , 4 ) , (where [.] represents


greatest integer function & {.} represents fractional part function). If a Î (1 , 3) then which of
the following options is true
a

ò (sin px ) dx is an odd integer.


4
(A) If f(x) is continuous at x = 2 then 16
0
(B) f(x) is differentiable function in its domain only for two values of ‘a’
(C) If f(x) is continuous function in its domain then its range consists of only one integer
(D) If f(x) is continuous function in its domain then sum of all possible values of ‘a’ is an odd
integer
ì ax 3 + bx 2 + cx + d
ï "x ¹ 0
10. Let f ( x ) = í x is a continuous function where a, b, c, d are in
ï 2 x=0
î
Arithmetic progression. If x = p be the point of local minimum of f(x) then,
(where [.] represents greatest integer function and {.} represents fractional part function)
2
(A) [ p] = –1 (B) {p} =
3
4 1
(C) minimum value of f(x) is (D) {p} =
3 3

Space for Rough Work

E-6/28 1001CJA102117099
Leader & Enthusiast Course/Score(Advanced)/25-04-2018/Paper-1
SECTION–2 : (Maximum Marks : 30)
˜ This section contains TEN questions.
˜ The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
˜ For each question, darken the bubble corresponding to the correct integer in the ORS.
˜ For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : 0 In all other cases.

x2 y2
1. Consider the ellipse + = 1 and the parabola y2 = 2x. They intersect at P and Q in the first
9 4
and fourth quadrant respectively. Tangent to the ellipse at P and Q intersect the x-axis at R and
tangent to parabola at P and Q intersect the x-axis at S. If the area of quadrilateral PRQS is A
æ 2 ö
then determine the value of ç A÷
è5 3 ø ex + e- x
e x + e- x
2. The number of positive integral value of 'p' for which the equation p.2 -8 . 2 2
+ p=0
has at least one solution, is

3. Let (x, y) be a variable point on the curve x + 4y -4x+ 8y + 4 = 0. Then


2 2
(
max x 2 + y2 + 4 x + 2 y + 5 )
min ( x 2
+y 2
+ 4x + 2 y + 5)
is

Space for Rough Work

1001CJA102117099 E-7/28
Target : JEE (Main + Advanced) 2018/25-04-2018/Paper-1

4. Let tangents be drawn to the curve y2 - 4 (x + y) = 3 sin q + 4 cos q - 15, q Î R from the origin

where the vertex of the curve is at maximum distance from the origin. If slopes of these tangents
1
are m1 and m2, then find the value of
m1m2 .

5. If a, b, c Î R+ and a2bc + 4abc + 4bc = 81 such that (2a + b + c + 4) assumes its least value, then
the value of (a + b + c) is

6. Number of solution of the equation sin


-1
( ) ( ) (
x + 2 + 1 = cos-1 -x 2 - 4 x - 5 - cos -1 x 2 + 4 x + 4 is )
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Leader & Enthusiast Course/Score(Advanced)/25-04-2018/Paper-1
7. Tangents are drawn from point A to a circle with centre O, which touches at P and Q. Another
tangent is drawn at a point R on circle, such that circle is outside the triangle formed by tangents.
Perimeter of triangle is 30 cm and angle between tangents at A is 60º. If radius of circle is r then
[r] equals

(where [.] represent greatest integer function)

8. For l, m, n Î R , p and q are the value of l and m respectively such that equation
l(13 + 11n) + m(19 + 17n) - 4 (8 + 7n) = 0 is satisfied " n Î R then (p + q) equals
9. Let a point P(x, y) moving in x-y plane such that it always satisfies x2 + y2 -8|x| -8|y|+31= 0

and ((1 + x ) - 1) ((1 + y ) - 1) < 0 . If a line passing through L(–5, 6) intersect the locus of P
2
y
2
x

at A, B, C & D in order and LA . LB . LC . LD = l then l/120 equals


10. The value of k (k > 0) such that the length of the longest interval in which the function
p
f ( x ) = sin -1 sin kx + cos-1 ( cos kx ) is constant is will be
4
Space for Rough Work

1001CJA102117099 E-9/28
Target : JEE (Main + Advanced) 2018/25-04-2018/Paper-1

PART-2 : PHYSICS
SECTION–1 : (Maximum Marks : 30)
˜ This section contains TEN questions.
˜ Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is (are) correct.
˜ For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
˜ For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble(s) corresponding to all the correct option(s) is (are)
darkened.
Zero Marks : 0 In all other cases.
1. The pitch of screw gauge is 0.75 mm & there are 50 divisions on the circular scale. When nothing
is put between the studs it shows the following where zero of mains scale is not visible.

35
30
25

Now thickness of a metal plate is measured. And when the plate is put between the studs it
shows.

0 1 2 3 15
10
mm 5

What is the thickness of metal plate ?


(A) 4.20 mm (B) 3.90 mm (C) 3.65 mm (D) 3.75 mm
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Leader & Enthusiast Course/Score(Advanced)/25-04-2018/Paper-1
2. Which of the following combinations have the dimension of energy per unit volume

YDl rRT 1 V2 F2
(A) (B) (C) e0 2 (D)
l M 2 l 2m 0 I 2l 2
When Y ® Young’s modulus, l ® length, r ® density, M ® molar mass, R ® gas constant,
T ® absolute temperature, e0 ® permittivity of free space, V ® potential, F ® force,
m 0 ® permeability of the vaccum, I ® current.
3. Consider two satellites A and B of equal mass m, moving in same circular orbit about earth, but
in opposite sense as shown in figure. The orbital radius is r. The satellites undergoes a collision
which is perfectly inelastic. For this situation, mark out the correct statement(s). [Take mass of
earth as M] (Assuming no interaction between satellites)

(A) The total mechanical energy of the two satellites plus earth system just before collision
GMm
is -
r
(B) The total mechanical energy of the two satellites plus earth system just after collision
-2GMm
is
r
-GMm
(C) The total mechanical energy of two satellites plus earth system just after collision is
2r
(D) The combined mass (two satellites) will fall towards the earth just after collision.

Space for Rough Work

1001CJA102117099 E-11/28
Target : JEE (Main + Advanced) 2018/25-04-2018/Paper-1
4. Two parallel plate capacitors are arranged perpendicular to the common axis. The separation d
between the capacitors is much larger than the separation l between the plates and their size.
The capacitors are charged to q 1 and q2 respectively. Tick the incorrect options for the force F of
interaction between the capacitors.
q1 q2
l l

3q1q 2l2 4q1q 2 l2 q1q 2 l2 q1q 2 l2


(A) (B) (C) (D)
2p ε 0d 4 3p ε 0d 4 2p ε0 d 4 3p ε 0d 4
5. The minimum strength of a uniform electric field which can tear a conducting uncharged hollow
thin-walled sphere into two parts is known to be E0. Tick the incorrect option for the minimum
electric field strength E1 required to tear the sphere of twice as large radius if the thickness of
its walls is the same as in the former case.
E0 E0 E0 E0
(A) (B) (C) (D)
3 2 2 3
6. Three small identical neutral metal balls are at the vertices of an equilateral triangle. The balls
are connected to an isolated large conducting sphere (one by one individually) whose centre is on
the perpendicular erected from the plane of the triangle and passing through its centre. As a
result, the first and second balls have acquired charges q1 and q2 respectively. Determine the
charge q3 of the third ball.

q12 q22 q22 2q22


(A) (B) (C) (D)
q2 q1 2q1 q1

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E-12/28 1001CJA102117099
Leader & Enthusiast Course/Score(Advanced)/25-04-2018/Paper-1
7. A particle P1 moves with a constant velocity v along x-axis, starting from origin. Another particle
P2 chases particle P1 with constant speed v, starting from the point (0, d). Both motion begin
simultaneously. Select the correct alternative.
n2
(A) initial acceleration of P2 is
2d

d
(B) Ultimate separation between P1 and P2 is .
2
(C) In the reference frame attached to P1, P2 does not follow a hyperbolic path
(D) In the reference frame attached to P1, P2 follows a hyperbolic path
8. Given mA = 30 kg, m B = 10 kg, m C = 20 kg. Between A and B µ 1 = 0.3, between B and C µ 2 = 0.2
and between C and ground µ 3 = 0.1. (g = 10 m/s2)

A F
B
C

(A) Limiting friction between A & B = 90 N


(B) Limiting friction between B & C = 80 N
(C) Limiting friction between C & ground = 60 N
(D) The least horizontal force F to start the motion of any part of the system is 60 N
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Target : JEE (Main + Advanced) 2018/25-04-2018/Paper-1
9. A particle of mass m is constrained to move in circle of radius r in x–y plane with center at

r
origin. It is released from rest at (r, 0) and it is accelerated by a force F = 2
(
-yiˆ + xjˆ )
. Select the
(x + y2 )
correct alternative.
(A) As the particle completes one circle, work done by the given force is zero.
(B) The given force is a non-conservative force.

p
(C) The speed acquired by the particle as it completes one circle is 2
m
(D) The speed acquired by the particle as it completes one circle is zero.
10. A small sphere of mass m suspended by a thread is first taken aside and released when the
string becomes horizontal. Select the correct alternative.

(A) The acceleration of the sphere when string makes angle q with vertical is g 1 + 3 cos 2 q

(B) Thread tension as a function of q is T = 3 mg cos q


(C) When the tension is mg, the vertical component of velocity of sphere is maximum
(D) The tension has a maximum value 3mg.

Space for Rough Work

E-14/28 1001CJA102117099
Leader & Enthusiast Course/Score(Advanced)/25-04-2018/Paper-1
SECTION–2 : (Maximum Marks : 30)
˜ This section contains TEN questions.
˜ The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
˜ For each question, darken the bubble corresponding to the correct integer in the ORS.
˜ For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : 0 In all other cases.
1. A positive ion of kinetic energy T0 collides with a stationary molecule of same mass and forms a
single excited composite molecule. Assuming that the initial internal energies of the ion and
neutral molecule were zero, calculate the ratio of T0 to final internal energy of the molecule.
2. Let the radius of ground state H-atom (as per Bohr's atomic model) be r0 and its ionisation
energy be E0. A hydrogen like system of e+ – e– (electron-positron) is called positronium. If the
rE0
radius of ground state positronium is r and ionisation energy is E, then find the value of .
r0 E
3. A uniform wooden box of base area 10 cm2, height 10 cm and specific gravity 0.6 floats in water
while a coin of mass 20g and specific gravity 2 lies above it. The area of the base of container is
100 cm2. Now, the coin is picked up from the block and put directly into the container. Find the
change in level of water in the container in mm.

Space for Rough Work

1001CJA102117099 E-15/28
Target : JEE (Main + Advanced) 2018/25-04-2018/Paper-1
4. A spool with dimensions shown in figure has an inextensible thread wrapped over it, such that
the free end is connected to a block. As the block goes down the spool rolls without slipping.
Consider the free part of thread that is the length of the thread which is not wound over the
x
spool. When the block goes down by x, the length of free part changes by . Find the value of n.
n

2R
R

Block

5. An electron is confined within a thin layer of semiconductor. If the layer can be treated as a
deep-one dimensional well, calculate its thickness in nm (rounded off to nearest integer) if the
difference in energy between the first and second level is 0.05 eV.
6. A concave mirror of radius of curvature 50 cm lies at origin of the coordinate system such that
its axis coincides with x axis. A small straight object lies on the x-axis along the line
5y + 4x – 25 = 0 Assuming mirror formula to be valid for the image formation of this object,
calculate the value of 5m where m is slope of the line along which the image lies.

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Leader & Enthusiast Course/Score(Advanced)/25-04-2018/Paper-1
7. Two cohorent sources S 1 and S2 separated by a distance 5l are placed as shown and the
interference is observed on a very long screen inclined at Ð53° with the perpendicular bisector
of S1. S2. What is the total number of maxima obtained on the screen.

Screen

S1
53°
5l

S2

8. A particle of mass 1 mg and charge 1mC is projected with speed 50 m/s towards a region containing
a uniform magnetic field 10 T. What should be the minimum thickness (d) of this region (in m)
so that the particle returns back to left side.

x x

x x

37°
x x
d

Space for Rough Work

1001CJA102117099 E-17/28
Target : JEE (Main + Advanced) 2018/25-04-2018/Paper-1
9. A conducting square loop of uniform wire as shown in figure is being moved away from the long
straight wire with a constant speed. At the moment shown, the distance of AB from wire is equal
to the edge length of the loop and the motional emf in the wire AB is 24 volt. What is the
potential difference between points A and D at this moment.

A D

B C

10. In a series LCR circuit, half power frequencies (frequency at which power disspited is half the
maximum power disspited in the circuit)are found to be 90 rad/s and 40 rad/s. Find the value
w0
of , where w0 is the resonance frequency.
10

Space for Rough Work

E-18/28 1001CJA102117099
Leader & Enthusiast Course/Score(Advanced)/25-04-2018/Paper-1

PART-3 : CHEMISTRY
SECTION–1 : (Maximum Marks : 30)
˜ This section contains TEN questions.
˜ Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of
these four option(s) is (are) correct.
˜ For each question, darken the bubble(s) corresponding to all the correct option(s) in the
ORS
˜ For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble(s) corresponding to all the correct option(s) is (are)
darkened.
Zero Marks : 0 In all other cases.
1. Select the correct options :
(A) The osmotic pressure associated with the fluid inside the blood cells equivalent to that of
0.9% (mass/ volume) NaCl solution.
(B) Normal boiling point of 0.1 M aq. NaHSO4 (Ka (HSO4– ) = 0.05) is 100.13°C
(Use : Kb (H2O) = 0.52 K kg mol–1 and molarity = molality)
(C) Desalination of sea water is based on reverse osmosis.
(D) Water movement from soil into plant roots and subsequently into upper portion of the
plant is partly due to osmosis.
2. Select the correct statement about ABAB........ type two dimensional arrangement
(two dimensional hexagonal unit cell)
(A) C.N. of arrangement is 6.
(B) There are some voids (empty spaces) and they are called triangular void.

p
(C) Packing effeciency of the arrangement is ' '
3 2

(D) Maximum radius of foreign atom that can be placed in two dimensional void generated in
above arrangement without disturbing the crystal, will be 0.155 R (R = radius of host atom)

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1001CJA102117099 E-19/28
Target : JEE (Main + Advanced) 2018/25-04-2018/Paper-1

3. Select the correct statements.


(A) Resistance of conductivity cell is measured by high frequency A.C. (550 to 5000 cycles/sec.)

(B) For concentration cell, E°cell = 0 , therefore we can't obtain electricity as a useful work.

(C) Lead storage cell is a primary cell and cannot be recharged.


(D) In mercury cell, cell potential practically remain constant during its life as the overall reaction
does not involves any ion in solution.
4. Select the correct options :
(A) Zero order reaction are relatively uncommon but they occur under special conditions.
(B) Decomposition of gaseous NH3 on hot platinum surface is a zero order reaction at high
pressure.
(C) On increasing number of nucleons, B.E. (Binding energy) increases.
(D) For exoergic nuclear reactions, Q-value of the reaction is negative.
5. Identify the correct reaction for major product :

O O
COOMe 1. HS
N2 SH
(A) MeOH ®
¾¾¾¾¾ (B)
2. H2 / Ni

OH
OH
NaBH4
(C) Br (D) ¾¾¾
TsCl
®
CH2 OH CH2 OTs

Space for Rough Work

E-20/28 1001CJA102117099
Leader & Enthusiast Course/Score(Advanced)/25-04-2018/Paper-1

6. Identify the reactions that gives aromatic products.

CHO
(NH4 )2 CO3 NH2NH2
(A) ¾¾¾¾¾¾
® (B) ¾¾¾¾¾
+
®
D H ,D
CHO
O O

O
Conc. H2SO4 D
(C) ¾¾¾¾¾¾
D
® (D) 2HC º CH + NH3 ¾¾®

O y
1. O / DCM
7. ¾¾¾¾¾¾
3
® A ¾¾¾¾¾
dil. O H
® Products
2. Me S2 D

In the above sequence the final products of the reaction is/are :

O
O CHO
O CHO
CHO
(A) (B) (C) (D)
CHO
8. A mixture containing soluble salts of copper (II), silver (I), mercury (I), mercury (II) and
zinc (II) is treated with dil. HCl to get ppt 'A' and filtrate 'B'. Filtrate 'B' on passing H2S
gives ppt 'C' and filtrate 'D'. Identify true statements :
(A) Precipitate 'A' is fairly soluble in NH4OH leaving behind no residue.
(B) Filtrate 'B' contains three types of metal ions while filtrate 'D' contains only one type of
metal ion.
(C) Precipitate 'C' is black and is completely soluble in conc. HNO3.
(D) Precipitate 'A' and 'C' each has two types of metal ions.

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1001CJA102117099 E-21/28
Target : JEE (Main + Advanced) 2018/25-04-2018/Paper-1
9. Which of the following does / do not characterise DIBORANE ?
(A) Hydrolysis product is a weak monobasic Lewis acid
(B) Involves homolysis when treated with ammonia at room temperature.
(C) Readily reacts with electron deficient molecules.
(D) It is an endothermic compound (DHf° = +ve)
10. What is/are true for SF4 ?

(A) Hybridisation of 'S' involves d z2 orbital.

(B) Angle distortion between two axial bonds is less than that between two equatorial bonds.
(C) None of the bond angle is 90°.
(D) The molecules in its sample undergo deflection in a nonuniform electrostatic field.

Space for Rough Work

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Leader & Enthusiast Course/Score(Advanced)/25-04-2018/Paper-1
SECTION–2 : (Maximum Marks : 30)
˜ This section contains TEN questions.
˜ The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
˜ For each question, darken the bubble corresponding to the correct integer in the ORS.
˜ For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : 0 In all other cases.
-1 6 -1
1. k1 = 100 sec
A ¾¾¾¾¾¾ k 2 = 10 sec
® B ¾¾¾¾¾¾ ®C
If reaction starts with pure A having concentration 8M then conc. of C (in M) after
3ln(2)
t= sec will be (approx.) :
100
2. For the reaction : 2HI(g) H2(g) + I2(g) , DG° = 0 at 127°C. If reaction starts with 128 gm of
pure HI, then value of '9a' will be (where a = degree of dissociation of HI)
(Given that : Atomic mass of I = 127 gm/mole)
3. Ratio of Cp,m and Cv,m of a gas 'X' (molecules are linear) is 1.28. The number of atoms in 'X'
present in 11.2L of this gas at 2 atm and 273°C are given as ' y × 1023 ' . Then value of 'y' will be :
(assuming all degree of freedoms are active, and ideal behaviour for the gas and NA= 6×1023)
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Target : JEE (Main + Advanced) 2018/25-04-2018/Paper-1
4. Identify the total number of carbohydrates which can undergoes mutarotation
HO OMe
OH
H CH2OH O
HO H O H H
O
HO
O O
H OH HO
H OH H OH
OH OH
H OH
CH2OH H OH OH

CH2OH
HO
O H
CH 2OH H OH
O H H
H H OH OH
O H
H H OH H O
H H OH
OH
H O OMe
OH OMe O
H OH H H OH HOH 2C
O
H OH H OH
CH 2OH
H OH H CH2OH
H OAc OH H
O H
HO H
H OH CH2 OH
H O OH
O CH2OH
H H OH CH2OH
H H O H
H OH O H
CH2OH H
H OH H H
H OH
H OH OH
O
HO H OH
CH2OH H OH

Space for Rough Work

E-24/28 1001CJA102117099
Leader & Enthusiast Course/Score(Advanced)/25-04-2018/Paper-1
5. Identify the total number of compounds that gives positive iodoform test

O O
, , Ph , Lactic acid, Ethanol, Chloral,
OH O

O
|| , , CH3 – NO2
Ph - C - CH 2 I
O
6. Identify total number of 'b' elimination reactions.
OH POCl 1. TsCl
(i) ¾¾¾¾
3
® (ii) OH ¾¾¾¾ ®
Pyridine 2. LiAlH4

Me
Cl
D Cl
(iii) H D NaI/ acetone (iv) Zn, D
¾¾¾¾¾¾ ® ¾¾¾®
Cl
Me

Br
Cl
(v) ¾¾¾¾
® Mg / DE (vi) KOH/ DMSO
¾¾¾¾¾¾ ®
Cl

Me OH
|Å y Conc. H PO
(vii) Me - N - Et D
OH ¾¾ ® (viii) ¾¾¾¾¾¾
3 4
®
D
|
Me

OH
+
KMnO4 , H
(ix) ¾¾¾¾¾¾ ®
D

Space for Rough Work

1001CJA102117099 E-25/28
Target : JEE (Main + Advanced) 2018/25-04-2018/Paper-1
7. The complex [Zn (acac)2]0 has a spiral structure with Zn atom at the center. What will be the
number of carbon atom(s) in the spirocyclic arrangement of the molecule ?

C
8. S + A B H2O D + E
SO2Cl2 ¾¾¾ ®

In the above sequence of the chemical changes, out of A, B, C, D, E identify the number(s)
of substances that are gases in pure form at room temperature.
9. Consider given molecular orbitals of O2 and find total number of electrons in given molecular
orbitals of O2 in ground state configuration?

+ – + – +
s2s s2pz
p2px p*
2px s*
2s
s*
2p
z

Consider the number of geometrical isomers = x for the formula [Co (dien)2 ]
3+
10. . What is
the value x ?

Space for Rough Work

E-26/28 1001CJA102117099
Paper Code : 1 001CJA10 2117099

CLASSROOM CONTACT PROGRAMME


(Academic Session : 2017 - 2018)

JEE (Main + Advanced) : LEADER & ENTHUSIAST COURSE


SCORE(ADVANCED)
ANSWER KEY : PAPER-1 TEST DATE : 25-04-2018
Test Type : FULL SYLLABUS Test Pattern : JEE-Advanced
PART-1 : MATHEMATICS
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-1
A. B,C,D B,C A,D A,B,C,D A,B,C A,B,C, A,B B,C,D A,B,C A,B,C
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-2
A. 3 3 9 4 7 1 8 2 6 4
PART-2 : PHYSICS
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-1
A. A A,B,C,D A,B,D B,C,D A,B,D B B,C A,B,C,D B,C A,B,D
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-2
A. 2 4 1 1 5 3 9 1 3 6
PART-3 : CHEMISTRY
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-1
A. A, B, C, D A, B, D A, D A, B, C A, D A, B, C, D A, C B, D B, C A, B, C, D
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-2
A. 7 6 6 4 6 6 6 4 9 3

Paper Code : 1001CJA10 2117100

CLASSROOM CONTACT PROGRAMME


(Academic Session : 2017 - 2018)

JEE (Main + Advanced) : LEADER & ENTHUSIAST COURSE


SCORE(ADVANCED)
ANSWER KEY : PAPER-2 TEST DATE : 25-04-2018
Test Type : FULL SYLLABUS Test Pattern : JEE-Advanced
PART-1 : MATHEMATICS
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-1
A. A A A C D C A B B D
Q. 1 2 3 4 5 6
SECTION-2
A. C C D A B D
Q. 1 2 3 4
SECTION-3
A. D C D B

PART-2 : PHYSICS
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-1
A. A C A A B B A A A B
Q. 1 2 3 4 5 6
SECTION-2
A. A A B C A A
Q. 1 2 3 4
SECTION-3
A. C A D A
PART-3 : CHEMISTRY
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-1
A. A A A D C C D C B B
Q. 1 2 3 4 5 6
SECTION-2
A. B B B C A D
Q. 1 2 3 4
SECTION-3
A. B D B A

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