Vous êtes sur la page 1sur 2

Ci Ce qe 1/Ce 1/qe LOG (Ce) LOG(qe)

150 21 32.25 0.047619 0.031008 1.322219 1.50853

200 57.6 35.6 0.017361 0.02809 1.760422 1.55145
1.64
246 96.5 37.375 0.010363 0.026756 1.984527 1.572581
1.62
299 149 37.5 0.006711 0.026667 2.173186 1.574031 1.6
354 189.2 41.2 0.005285 0.024272 2.276921 1.614897 1.58
400 229.4 42.65 0.004359 0.023447 2.360593 1.629919 1.56

LOG (qe)
446 289.7 39.075 0.003452 0.025592 2.461948 1.591899 1.54
493 341.2 37.95 0.002931 0.02635 2.533009 1.579212 1.52
1.5
1.48
Plot of Langmuir Isotherm 1.46

0.035 1.44
1.2
0.03 f(x) = 0.1356245438x + 0.0248598336
0.025 R² = 0.7664386647

0.02
1/qe

0.015
0.01
0.005
0
0 0.01 0.02 0.03 0.04 0.05
1/ce

For Langmuir Isotherm, 1/qe = (1/qm* KL)*Ce + 1/qm

So, 1/qm = 0.0249
Then, qm = 40.1606 and (1/qm*KL) =0.1356
KL = 0.1836

Therefore, the value of Langmuir Isotherm constant, KL = 0.1836

Plot of Freundlich Isotherm
1.64
1.62
1.6 f(x) = 0.0769987312x + 1.4154166126
1.58 R² = 0.6973975555
1.56
LOG (qe)

1.54
1.52
1.5
1.48
1.46
1.44
1.2 1.4 1.6 1.8 2 2.2 2.4 2.6
LOG (Ce)

For Freundlich Isotherm, LOG (qe) = (1/n)* LOG (Ce) + LOG (KF)
So, LOG (KF) = 1.4154 and (1/n) = 0.077
Therefore, KF = 10^(1.4154) = 26.0256
So, the value of Freundlich Isotherm constant, KF = 26.0256

For Langmuir Isotherm regression coefficient value is 0.7664 and

for Freundlich Isotherm it is 0.6974. Therefore, the value of
regression coefficient of Langmuir Isotherm is more close to 1.
So, for the given values of Ci and Ce Langmuir Isotherm is more accurate.