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University

of Texas El Paso
Department of Chemistry
Chem 1407
Fall 2017
Andrew Pardo, Ph.D.

1. Which number is smaller?


A) 5.5 x 10 -9 kg
B) 4.5 x 10 -1 kg
C) 3.2 x 10 -3 kg
D) 7.0 x 10 -6 kg
E) 6.3 x 10 -4 kg
Answer: A

2. Carrots are $0.79 per pound. What is the cost of 1.20 kg of carrots?
A) $2.10
B) $0.43
C) $1.45
D) $0.79
E) $0.95
Answer: A

3. In a candy factory, nutty chocolate bars contain 22.0% by mass pecans. If 5.0 kg of pecans
were used for candy last Tuesday, how many pounds of nutty chocolate bars were made?
A) 10. lb
B) 1.4 lb
C) 48. lb
D) 50. lb
E) 32. lb
Answer: D

4. If a recycling center collects 1298 aluminum cans and there are 22 aluminum cans in 1 lb,
what volume, in liters, of aluminum was collected? (density of aluminum = 2.70 g/mL)
A) 4.82 L
B) 1.34 L
C) 9.93 L
D) 11.0 L
E) 7.45 L
Answer: C

5. What is the density (g/mL) of a cube of butter that weighs 0.250 lb and has a volume of
130. mL?
A) 1.03 g/mL
B) 0.873 g/mL
C) 0.263 g/mL
D) 0.122 g/mL
E) 0.014 g/mL
Answer: B

1
6. What is the mass of 53 mL of ethanol, which has a density of 0.79 g/mL?
A) 67.1 g
B) 41.9 g
C) 42 g
D) 67 g
E) 53 g
Answer: C

7. What will be the cost of gasoline for a 3,700-mile trip in a car that gets 23 miles per gallon if
the average price of gas is $3.90 per gallon?
A) $329
B) $630
C) $500
D) $101
E) $913
Answer: B

8. Which of the following numbers contains the designated CORRECT number of significant
figures?
A) 0.04300 5 significant figures
B) 0.00302 2 significant figures
C) 156 000 3 significant figures
D) 1.04 2 significant figures
E) 3.0650 4 significant figures
Answer: C

9. On a hot day, the thermometer read 95 °F. What is the temperature in degrees Celsius?
A) 77 °C
B) 113 °C
C) 35 °C
D) 63 °C
E) 178 °C
Answer: C

10. How many calories are required to raise the temperature of a 35.0 g sample of iron from 25
°C to 35 °C? Iron has a specific heat of 0.108 cal/g °C.
A) 38 cal
B) 1.1 cal
C) 3.8 cal
D) 93 cal
E) 130 cal
Answer: A

2
11. A 5.3 g sample of french fries is placed in a calorimeter with 250.0 g of water at an initial
temperature of 25 °C. After combustion of the french fries, the water has a temperature of
57 °C. What is the caloric value (kcal/g) of the french fries?
A) 14 kcal/g
B) 11 kcal/g
C) 1.5 kcal/g
D) 3.0 kcal/g
E) 5.4 kcal/g
Answer: C

12. Consider a neutral atom with 30 protons and 34 neutrons. The atomic number of the
element is
A) 30.
B) 32.
C) 34.
D) 64.
E) 94.
Answer: A

13. What is the electron configuration for aluminum?
A) 1 s22s22 p63s23p1
B) 1 s22s22p63s23p3
C) 1 s22s22p63s23p5
D) 1 s22s22p63s23p6
E) 1 s22 22p63s23p8
Answer: A

14. Which of the following is the correct electron-dot structure for carbon?
A)

B)

C)

D)

E)
Answer: C

15. What is the element with the abbreviated electron configuration [Kr]5s24d8?
A) Ni
B) Pd
C) Pt
D) Kr
E) Xe
Answer: B

3
16. What is proper electron configuration for Cr?
A) [Ar]4s24d7
B) [Kr]5s24d8
C) [K]4s14d5
D) [Ar] 4s24d4
E) [Ar] 4s13d5
Answer: E

17. Select the correct orbital diagram for Sulfur?
1s 2s 2p

A)

2s 2p

B)

1s 2s 2p 3s 3p

C)

1s 2s 2p 3s 3p

D)

1s 2s 2p 3s 3p

E)

Answer: D

18. Calculate the specific heat (J/g C) for a 4.07 x 10-2 lb sample of tin that absorbs 183 J when
temperature increases from 308 K to 351.6 K.
A) 0.547 J/g oC
B) 0.190 J/g oC
C) 0.368 J/g oC
D) 0.712 J/g oC
E) 0.227 J/g oC
Answer: E

19) Air is a(n)
A) compound.
B) heterogeneous mixture.
C) element.
D) homogeneous mixture.
E) None of the above.
Answer: D

4
20) 3.25 kcal is the same amount of energy as
A) 3.25 J
B) 0.777 J
C) 777 J
D) 13600 J
E) 13.6 J
Answer: D

21. Calculate the energy in kilojoules lost when 20.00 g of ethanol cools from 58.5 C to -
42.0 C.
A) 4.079 kJ
B) 2.333 kJ
C) 4.940 kJ
D) 3.434 kJ
E) 5.990 kJ
Answer: C

22. The grams of carbohydrate in one apple if the apple has no fat and no protein and
provides 72000 cal of energy.
A) 18 g
B) 31 g
C) 11 g
D) 45 g
E) 93 g
Answer: A

23. What is the mass of 5.6 x 10-2 qt of ethanol, which has a density of 0.79 g/mL?
A) 67.1 g
B) 45.9 g
C) 42 g
D) 67 g
E) 53 g
Answer: C

24. 650. J is the same amount of energy as
A) 155 cal
B) 2720 cal
C) 650 cal
D) 1550 cal
E) 2.72 cal
Answer: A

5
25. How many liters of soft drink are there in 5.25 qt?
A) 4950 L
B) 55.7 L
C) 4.95 L
D) 5.57 L
E) 5.0 L
Answer: C

26) The measurement 0.000 0043 m, expressed correctly using scientific notation, is
A) 4.3 × 10-7 m.
B) 4.3 × 10-6 m.
C) 4.3 × 106 m.
D) 0.43 × 10-5 m.
E) 4.3 m.
Answer: B

6


1000 cal = 1 kcal

1000 J = 1 kJ

TF = 1.8(TC) + 32

TC = (TF – 32) /1.8

TK = TC - 273

heat = mass x DT x specific heat

specific = heat/(mass x DT)

4.184 J = 1 cal

8
Exam II Chapter 5-7
Chem 1407
Andrew Pardo, Ph.D.
University of Texas at El Paso, Department of Chemistry

1) What is the symbol for the ion with 19 protons and 18 electrons?
A) F+
B) F-
C) Ar+
D) K-
E) K+
Answer: E

2) The correct formula for a compound formed from the elements Al and O is
A) AlO.
B) Al2O.
C) Al3O2.
D) AlO3 .
E) Al2O3 .
Answer: E

3) The compound MgCl2 is named
A) magnesium chlorine.
B) magnesium dichloride.
C) magnesium (II) chloride.
D) magnesium chloride.
E) dimagnesium chloride.
Answer: D

4) The name of Al2(SO4)3 is
A) aluminum(III) sulfate.
B) dialuminum trisulfate.
C) dialuminum sulfate.
D) dialuminum trisulfide.
E) aluminum sulfate.
Answer: E

5) Choose the best electron-dot structure for OCl2.
A)
B)
C)
D)
E)
Answer: E

6) What is the formula of carbon tetraiodide?
A) CI
B) CI4
C) C4I
D) CI3
E) C2I4
Answer: B

7) When calcium carbonate is heated it decomposes to yield calcium oxide and carbon dioxide. Choose the correct
balanced chemical equation.
A) CO2 (g) + CaO2 (s) à CaCO3 (s)
B) 2CO2 (g) + 2CaO (s) à CaCO3 (s)
C) 2CaCO3 (s) à 2CO2 (g) + 2CaO (s)
D) CaCO3 (s) à CO2 (g) + CaO (s)
E) 2CO2 (g) + 2CaO (s) à 5CaCO3 (s)
Ansrew: D

8) If you react 2.50 moles of calcium carbonate how many carbon atoms are being produced as carbon dioxide?
(use balance chemical equation from question 7)
A) 5.00 x 1024 C atoms
B) 3.20 x 1024 C atoms
C) 1.51 x 1024 C atoms
D) 2.51 x 1023 C atoms
E) 6.03 x 1024 C atoms
Answer: C

9) How many grams of barium sulfate can be produced from 20.8 g of barium chloride?
BaCl2 + Na2SO4 àBaSO4 + 2NaCl
A) 1.37 g
B) 23.3 g
C) 233 g
D) 137 g
E) 323 g
Answer: B

10) How many L of O2 gas at STP, are needed to react with 15.0 g of Na?
4Na (s) + O2(g) à 2Na2O(s)
A) 3.65 L
B) 14.6 L
C) 32.0 L
D) 22.4 L
E) 7.30 L
Answer: A

11) Cyclopropane, C3H6, is a general anesthetic. A 5.0 L sample has a pressure of 5.0 atm. What is the volume of the
anesthetic given to a patient at a pressure of 1.0 atm with no change in temperature and amount of gas?
A) 32 L
B) 42 L
C) 65 L
D) 25 L
E) 50. L
Answer: D
12) An aerosol can has a pressure of 1.40 atm at 12 C. What is the final pressure in the aerosol can if it is used in a
room where the temperature is 40 C? (assume that n and V remain constant)
A) 2.53 atm
B) 1.54 atm
C) 1.40 atm
D) 4.20 atm
E) 1.00 atm
Answer: B

13) Aluminum oxide can be formed from its elements. How many grams of Al will react with 10.0 L O2 at STP?
4Al(s)+3O2(g)→2Al2O3(s)
A) 54.3 g
B) 22.4 g
C) 32.0 g
D) 43.1 g
E) 16.1 g
Answer: E

14) Calculate the pressure, in atmospheres, of 2.60 moles helium gas in a 20.0 L container at 18 C.
A) 3.11 atm
B) 2.31 atm
C) 4.32 atm
D) 0.12 atm
E) 1.33 atm
Answer: A

15) How many hydrogen atoms are present in 75.0 of g H2O?


A) 75.0 atoms
B) 4.17 atoms
C) 7.53 × 1024 atoms
D) 2.51 × 1024 atoms
E) 5.02 × 1024 atoms
Answer: E

16) When 85.0 g of CH4 are mixed with 160. g of O2 the limiting reactant is __________.
CH4 + 2O2 → CO2 + 2H2O
A) CH4
B) O2
C) CO2
D) H2O
Answer: B

17) When 10.0 g of NH3 reacts, the actual yield of N2 is 8.50 g. What is the percent yield?
4NH3 (g) + 6NO(g) → 5N2 (g) + 6H2O(l)
A) 85.0%
B) 51.5%
C) 20.6%
D) 41.3%
E) 8.5%
Answer: D
18) Zn(s) + 2 HCl(aq) → H2(g) + ZnCl2(aq)
When 25.0 g of Zn reacts, how many L of H2 gas are formed at 25 °C and a pressure of 854 mmHg?
A) 8.56 L
B) 0.120 L
C) 8.32 L
D) 22.4 L
E) 0.382 L
Answer: C

19) Which of the reaction is undergoing oxidation?


A) Na+(aq) + e- à Na(s)
B) Cr3+(aq) + 3e- à Cr(s)
C) 2H+(aq) + 2e- à H2(g)
D) Fe3+(aq) + e- à Fe2+(aq)
E) Ni(s) à Ni2+(aq) + e-
Answer: E

20) How many kilojoules are released when 2.00 g of Fe reacts in the follow equation?
4Fe(s) + 3O2(g) à Fe2O3(s) DH = -1.7 x 103 kJ
A) -15.2 kJ
B) 15.2 kJ
C) 20.3 kJ
D) -20.3 kJ
E) -100. kJ
Answer: A
Helpful Formulas:

P 1V 1 = P 2V 2 1 atm = 760 mmHg

V1/T1 = V2/T2 1 atm = 760 torr

P1/T1 = P2/T2 TF = 1.8(TC) + 32

(P1V1)/T1 = (P2V2)/T2 TC = (TF – 32) /1.8

V1/n1 = V2/n2 TK = TC + 273

PV = nRT

0.0821 (L*atm)/(mole*K)

62.4 (L*mmHg)/(mole*K)

P T = P 1 + P 2 + P 3…

1 mol of gas = 22.4 L of gas (at STP)


University of Texas El Paso
Department of Chemistry
Chem 1407 Exam III (Chapter 8 &9)
Fall 2017
Andrew Pardo, Ph.D.
1) How many equivalents are present in 5.0 moles of Al3+?
A) 15 Eq
B) 1.3 Eq
C) 5.0 Eq
D) 0.67 Eq
E) 3.0 Eq
Answer: A

2) Calculate the amount of solute, in grams, needed to prepare 35.0 mL of a


8.0 % (m/v) KCl solution.
A) 3.0 g
B 1.5 g
C) 7.4 g
D) 4.5 g
E) 2.8 g
Answer: E

3) The equilibrium constant, Kc, for the reaction of H2 and N2 is 1.7×102 at 225 C.
3H2(g)+N2(g) 2NH3(g)
If the system at equilibrium contains 0.16 M H2 and 0.020 M N2, what is the concentration of NH3?
A) 0.19 M
B) 0.12 M
C) 1.20 M
D) 2.31 M
E) 3.21 M
Answer: B

Consider the following reaction for question 4 and 6.


PCl5(g) PCl3(g) + Cl2(g)
4) Choose the correct equilibrium constant for the reaction:
[PCl5]
A) Kc =
[PCl3][Cl2]

[PCl3][Cl2]
B) Kc =
[PCl5]

[PCl3]
C) Kc =
[PCl5]
2 3
D) Kc = [PCl3] [Cl2]
[PCl5]
1
E) Kc =
[PCl3][Cl2]
Answer: B
1
5) Initially 0.58 mole of PCl5 is placed in a 1.00 L flask. At equilibrium, there is 0.16 mole of PCl3 in the
flask. What is the equilibrium concentration of the PCl5?
A) 1.23 M
B) 2.40 M
C) 0.24 M
D) 0.78 M
E) 0.42 M
Answer: E

6) What is the equilibrium concentration of the Cl2?


A) 0.16 M
B) 1.20 M
C) 0.52 M
D) 0.42 M
E) 2.34 M
Answer: A

7) The solubility of KI is 50 g in 100 g of H2O at 20 °C. If 110 grams of KI are added to 200 grams of
H2O,
A) all of the KI will dissolve.
B) the solution will freeze.
C) the solution will start boiling.
D) a saturated solution will form.
E) the solution will be unsaturated.
Answer: D

8) A catalyst is
A) a reactant in a chemical reaction.
B) a product in a chemical reaction.
C) a substance that speeds up a reaction without being consumed in the reaction.
D) a substance that increases the energy of the products.
E) a substance that decreases the energy of the products.
Answer: C

9) For the reaction of carbon with carbon dioxide to make carbon monoxide, one set of conditions
produced a Kc = 1.2 × 10-1. At equilibrium at a certain temperature, the concentration of product
was 0.60 M. What was the concentration of carbon dioxide at that temperature?
C(s) + CO2(g) 2CO(g)
A) 3.0 M
B) 0.60 M
C) 0.36 M
D) 3.33 M
E) 5.0 M
Answer: A

2
10) The calcium carbonate in limestone reacts with HCl to produce a calcium chloride solution and
carbon dioxide gas: CaCO3(s)+2HCl(aq)→CaCl2(aq)+H2O(l)+CO2(g)
How many milliliters of 0.200 M HCl can react with 7.25 g CaCO3?
A) 850 mL
B) 724 mL
C) 234 mL
D) 182 mL
E) 187 mL
Answer: B

11) How many milliliters of a 6.00 M HCl solution are required to react with 27.0 g magnesium?
Mg(s)+2HCl(aq)→MgCl2(aq)+H2(g)
A) 450 mL
B) 233 mL
C) 101 mL
D) 370 mL
E) 420 mL
Answer: D

12) What volume of 0.10 M NaOH can be prepared from 250. mL of 0.30 M NaOH?
A) 0.075 L
B) 0.25 L
C) 0.75 L
D) 0.083 L
E) 750 L
Answer: C

13) What is the molarity of a solution that contains 17 g of NH3 in 0.50 L of solution?
A) 34 M
B) 2.0 M
C) 0.50 M
D) 0.029 M
E) 1.0 M
Answer: B

14) If 34.0 g of KCl is soluble in 100 g of water at 20oC, then 21.0 g of KCl in 100 g of water at 20oC
considered to be________.
A) saturated solution
B) unsaturated solution
C) too salty
D) super saturated solution
E) none of the above
Answer: B

15) Which of the ionic compounds are NOT soluble in water?


A) LiCl
B) K2O
C) Fe(NO3)3
D) BaCO3
E) Na3N
Answer: D

3
16) Use the reaction: 2AgNO3(aq) + H2SO4(aq) → Ag2SO4(s) + 2H2O(l)
What volume of 0.123 M AgNO3(aq) is needed to form 0.657 g of Ag2SO4(s)?
A) 34.2 L
B) 17.1 mL
C) 34.2 mL
D) 10.7 mL
E) 53.4 mL
Answer: C

17) What is the molarity of a KCl solution made by diluting 75.0 mL of a 0.200 M solution to a final
volume of 100. mL?
A) 0.267 M
B) 0.150 M
C) 0.200 M
D) 6.67 M
E) 0.100 M
Answer: B

18) The reaction for the decomposition of PCl5 to chlorine and PCl3 is shown below.
PCl5(g) PCl3(g) + Cl2(g)
If the equilibrium concentrations are [PCl5] = 1.0 M, [PCl3] = 0.10 M, [Cl2] = 0.10 M, what is the
value of the equilibrium constant?
A) 1.0 × 102
B) 1.0 × 10-4
C) 10 × 10-2
D) 1.0 × 10-2
E) 2.0 × 10-2
Answer: D

19) The equilibrium constant, Kc for the reaction of H2 and I2 is 54 at 425 C.


H2(g)+I2(g) 2HI(g)
If the equilibrium mixture contains 0.016 M I2 and 0.025 M HI, what is the concentration of H2?
A) 8.2 x 10-4 M
B) 1.2 x 104 M
C) 4.5 x 10-4 M
D) 7.2 x 10-4 M
E) 3.2 x 10-4 M
Answer: D

4
Indicate any changes that 20-22 will cause for the following reaction initially at equilibrium:
C2H4(g) + Cl2(g) C2H4Cl2(g) + heat
20) Raise the temperature of the reaction
A) The system shifts in the direction of the reactants.
B) The system shifts in the direction of products.
C) The equilibrium does not change.
Answer: A

21) Decrease the volume of the reaction container


A) The system shifts in the direction of the reactants.
B) The system shifts in the direction of products.
C) The equilibrium does not change.
Answer: B

22) Add a catalyst


A) The system shifts in the direction of the reactants.
B) The system shifts in the direction of products.
C) The equilibrium does not change.
Answer: C

5
Helpful Formulas:

C 1V 1 = C 2V 2
g/mL (% m/v)
g/g (%m/m)
mol/L (M)

6
7
University of Texas El Paso
Department of Chemistry
Chem 1407 Exam IV (Chapter 10)
Fall 2017
Andrew Pardo, Ph.D.

1) The conjugate acid of HSO4- is


A) SO42-.
B) HSO4.
C) H2SO4.
D) H2SO4-.
E) HSO3-.
Answer: C

2) In which of the following are the pH values arranged from the most acidic to the most basic?
A) 1, 3, 6, 8, 11, 14
B) 2, 5, 7, 9, 10, 1.1
C) 14, 10, 7, 4, 3, 1
D) 14, 10, 7, 1, 3, 5
E) 7, 10, 14, 4, 3, 1
Answer: A

3) Which of the following is a neutralization reaction?


A) KCl + NaNO3 → KNO3 + NaCl
B) HNO3 + KOH → H2O + KNO3
C) H2O + SO3 → H2SO4
D) 4Na + O2 → 2Na2O
E) 2NO2 → 2NO + O2
Answer: B

4) Which of the following is a buffer system?


A) NaCl and NaNO3
B) HCl and NaOH
C) H2CO3 and KHCO3
D) NaCl and NaOH
E) H2O and HCl
Answer: C
5) How many milliliters of 0.100 M Ba(OH)2 are required to neutralize 20.0 mL of 0.250 M
HCl?
A) 100. mL
B) 50.0 mL
C) 25.0 mL
D) 0.250 mL
E) 0.50 mL
Answer: C

6) According to the Arrhenius concept, if HNO3were dissolved in water, it would act as


A) a base.
B) an acid.
C) a source of hydroxide ions.
D) a source of H- ions.
E) a proton acceptor.
Answer: B

7) The name given to an aqueous solution of HNO3 is


A) nitric acid.
B) nitrous acid.
C) hydrogen nitrate.
D) hydronitrogen acid.
E) hyponitric acid.
Answer: A

8) Which of the following is the strongest acid?


A) HF ( Ka for HF is 7.2 × 10-4)
B) HCN (Ka for HCN is 4.9 × 10-10)
C) HCNO (Ka for HCNO is 2 × 10-10)
D) H3BO3 (Ka for H3BO3 is 5.4 × 10-10)
Answer: A

9) What is the [OH-] in a solution that has a [H3O+] = 1 × 10-6 M?


A) 1 × 10-2 M
B) 1 × 10-6 M
C) 1 × 10-8 M
D) 1 × 10-10 M
E) 1 × 10-12 M
Answer: C
10) What is the [OH-] in a solution that has a [H3O+] = 2.0 × 10-4 M?
A) 2.0 × 10-10 M
B) 5.0 × 10-10 M
C) 1.0 × 10-10 M
D) 2.0 × 10-4 M
E) 5.0 × 10-11 M
Answer: E

11) What is the pH of a solution with [H3O+] = 1 × 10-9 M?


A) 1.0 × 10-5 M
B) -9.0
C) 5.0
D) -5.0
E) 9.0
Answer: E

12) What is the pH of a solution with [OH-] = 1 × 10-4 M?


A) 10.0
B) -10.0
C) 4.0
D) -4.0
E) 1.0 × 10-10
Answer: A

13) How many moles of H2O are produced when 1 mole of Mg(OH)2 reacts with 1 mole of
H2SO4?
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: B

14) The [H3O+] of a solution with pH = 2 is


A) 10 M.
B) -10 M.
C) 1 × 102 M.
D) 1 × 10-2 M.
E) 1 × 10-12 M.
Answer: D
15) In a sulfuric acid solution, where the [H3O+] is 0.01 M, what is the pH?
A) pH = 12.0
B) pH = 2.0
C) pH = 3.0
D) pH = 11.0
E) pH = 5.0
Answer: B

16) The neutralization reaction between Al(OH)3 and HNO3 produces the salt with the formula
A) H2O.
B) AlNO3.
C) AlH2.
D) Al(NO3)3.
E) NO3OH.
Answer: D

17) 25.0 mL of 0.212 M NaOH is neutralized by 13.6 mL of an HCl solution. The molarity of
the NaOH solution is
A) 0.212 M
B) 0.115 M
C) 0.500 M
D) 0.390 M
E) 0.137 M
Answer: D

18) A 25.0 mL sample of H3PO4 requires 50.0 mL of 1.50 M NaOH for complete neutralization.
What is the molarity of the acid?

H3PO4 + 3NaOH → Na3PO4 + 3H2O

A) 0.333 M
B) 3.00 M
C) 1.50 M
D) 1.00 M
E) 0.750 M
Answer: D
19) A 10.0 mL of 0.121 M H2SO4 is neutralized by 17.1 mL of KOH solution. The molarity of
the KOH solution is
A) 0.207 M
B) 0.4141 M
C) 0.0708 M
D) 0.428 M
E) 0.142 M
Answer: E

20) What is the pH of a solution with [OH-] = 2.0 × 10-10 M?


A) 9.70
B) -9.70
C) 4.30
D) -4.30
E) 2.0 × 10-10
Answer: C

For the problem) that follow, consider the reaction in which magnesium reacts with an HCl
solution .
Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)
21) If 2.00 g of Mg reacts completely with 50.0 mL of HCl solution, what is the molarity of the
HCl solution?
A) 1.65 M
B) 80.0 M
C) 8.00 M
D) 0.823 M
E) 3.29 M
Answer: E

22) In a neutralization reaction, how many moles of HClO4 react with 1 mole of Al(OH)3?
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: C
Helpful Formulas:

M = mol/L

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