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1. Calculate or sketch (or both) titration curves for the following (unbalanced)
redox titration reactions at 25 °C. Assume that the analyte is initially present
at a concentration of 0.0100 M and that a 25.0-mL sample is taken for
analysis. The titrant, which is the underlined species in each reaction, is
0.0100 M.
2. What are the equivalence points for the titrations listed in problem 1?
(b) Will a determinate error be introduced into the analysis if the analyst
forgets to add Sn2+ in the step where the iron ore is dissolved?
b. The excess peroxydisulfate, S2O82–, which was used to oxidize the Cr3+
to Cr2O72–, is destroyed by boiling the solution. What would be the
effect on the reported %w/w Cr3+ if some of the S2O82– was not
destroyed during this step?
8. Under basic conditions, MnO4– can be used as a titrant for the analysis of
Mn2+, with both the analyte and the titrant ending up as MnO2. In the
analysis of a mineral sample for manganese, a 0.5165-g sample is dissolved,
and the manganese reduced to Mn2+. The solution is made basic and titrated
with 0.03358 M KMnO4, requiring 34.88 mL to reach the end point.
Calculate the %w/w Mn in the mineral sample.
6
I3- yang dihasilkan dititrasi dengan larutan Na 2S2O3. Jika 50,0 mL sampel
memerlukan 38,56 mL larutan Na2S2O3 0,1986 M untuk mencapai titik ahir
titrasi, hitunglah kadar NaOCl dalam sampel yang dinyatakan dalam %w/v.