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PROJECT REPORT
Submitted to Panjab University,Chandigarh
In Partial Fulfilment of the requirements
For the Degree of
B.E.(CHEMICAL WITH MBA)
2018
SUBMITTED BY:
ANKUSH DHADWAL
ROLL NO. : CM14204
Dr. S. S. BHATNAGAR UNIVERSITY INSTITUTE OF CHEMICAL
ENGINEERING & TECHNOLOGY
PANJAB UNIVERSITY
CHANDIGARH- 160014, INDIA
ACKNOWLEDGEMENT
Thanks to all the teachers and staff of Dr. S. S. Bhatnagar University Institute
of Chemical Engineering And Technology for their time to time guidance.
ANKUSH DHADWAL
CERTIFICATE
This is to certify that Mr. Ankush Dhadwal pre-final year student of the
Dr. S. S. Bhatnagar University Institute of chemical Engineering and
Technology, Panjab University, Chandigarh has completed his project
entitled “ PRODUCTION OF AMMONIUM SULPHATE” under my
supervision.
His report of the project may be accepted for the evaluation as a part of
the requirement of B.E. (CHEMICAL WITH MBA) degree.
TEACHER SIGNATURE
TABLE OF CONTENTS
1. INTRODUCTION ……………………………………………………………........................5
3. PROCESS IN DETAIL………………………………………………………….......................12
5 MATERIAL BALANCE..................................................................................……..17
8. COST ESTIMATION..............................................................................................61
9. PLANT LOCATION…………………...…………………………………………………………….69
Fertilizers have been the important horizon for several years past and from all
appearances should continue to a considerable future distance. A subject that has attained
as much importance as the American and soviet space programmes, fertilizers have
projected themselves into an important orbit amid present day complexities. It is but
common knowledge that these chemical combinations are of direct lineage to human
nutrition and with recent spurt in population statistics, have been pressurized into
significance, that even Vietnam crisis can stem.
Up to present Ammonium Sulphate has been the most popular nitrogen fertilizer
among farmers. Urea is also competing with Ammonium Sulphate, where lack of sulphur
is likely to be a problem. But the availability of gypsum has solved the problem to some
extent.
2. FACTS AND FIGURES
The first pioneering effort to produce fertilizers in India was made at Belagula in
Mysore in 1939 and a plant to produce 20 tones of Ammonium sulphate per day was set
up. Since then the fertilizers industry has grown from strength to strength both in private
and public sectors.
Ammonium Sulphate production in India was around 8,50,000 per annum.
Following table gives the individual capacity of the existing Ammonium Sulphate.
3.RAW MATERIALS
The raw materials for the manufacture of Ammonium Sulphate from gypsum are
ammonia, carbon dioxide, gypsum and water.
Ammonia: Ammonia can be made by the famous Haber Bosch process. Synthetic
Ammonia is a landmark in the history of Chemical fertilizers. The nitrogen can be got
abundantly from air. The manufacture of semi water gas from Coke, the purification of
the gas and oxidation of carbon monoxide content to carbon dioxide and finally the
7
removal of carbon dioxide from this either by scrubbing with water under pressure or
with ethanol amine solution and then synthesizing to ammonia. In Sindri large producers
are filled with coke and air is passed through. Producer gas it got with carbon, carbon
dioxide and nitrogen as products. In the next cycle steam is blown through the producers,
which produces carbon monoxide and Hydrogen. The gases in the two cycles are mixed
which thus contains carbon monoxide, nitrogen and Hydrogen. This raw gas is passed
through sulphide boxes to catch the Hydrogen Sulphide. Carbon monoxide in the raw gas
in oxidized to carbon dioxide by the steam process using iron catalyst in the converters.
C + Air → CO + N2
C + H2O → CO + H2
CO + H2O → CO2 + H2
Gases pass through exchangers to have maximum thermal efficiency. The gases
are sent to Ammonia plant in Stoichimetric ration where they are compressed to 17 atm
and carbon dioxide is scrubbed using water. The Nitrogen and Hydrogen go to the
Ammonia converter, while carbon dioxide is released from water, and sent to the sulphate
plant. At about 122.5 atm carbon monoxide and oxygen picked up from scrubbing water
and the residual carbon dioxide are eliminated by scrubbing the gases with a complex
solution of mixed salt of ammoniacal cuprous, cupric formate and
8
plant. Ammonia is stored in two large Horton Spheres each capable of holding 690 tones.
This also goes to the carbonization tower.
The Alwaye wood is used as the raw material. As they come off the barges the
logs are slashed to 40.64 cms. Lengths and conveyed to the world’s largest wood
producer gas plant at the rate of 207 tones a day. Wood is charged continuously into a
battery of gas producers to obtain 0.51 million cu.meter per day of producer gas
containing approximately 22 percent carbon monoxide and 11 percent Hydrogen. This
section includes few producers, one a spare, and 5660 cu.meter gas holder. Some of this
producer gas is used to reduce the iron oxide content mass packed in the steam cross
generation, two of which are spares. The rest of producer gas is burnt at the rate of 19,250
cubic meter per day to generate superheated steam. In the next operation the steam acts
on the reduced iron oxide mass to liberate 8.5 x 104 cu.meter per day of Hydrogen. The
burnt spent gases from the boiler are passed through a Gerbitol unit to yield 28,300
cu.meter per day of pure nitrogen and 5,660 cu.meter of carbon dioxide. A 15 percent
solution of monoethanol amine is the absorbing liquid used in the carbon dioxide
absorption tower.
Gypsum: At present our conservative estimate of know reverses, in the more important
deposits capable of being worked today is as below:
Rajasthan
Reserves in million tones
a. Bikaner 45.5
b. Jodhpur 16.3
Madras:
a. Tiruchirapalli 15.3
b. Sulurpet 0.6
9
Himalchal Pradesh 1.8
Saurashtra 4.0
Kutch 2.0
Total 85.5
As the total amount mined in Bikaner is going to Sindri and due to heavy
transportation cost, Tiruchirapalli, Gypsum can become our mainstay. It covers over
and area of 22 sq.miles, occurring up-to a few cms. Deep, frequently ferruginous.
Water Supply: The question of water supply, which is so great, deserves a paragraph.
The Requirement at Sindri is 12 million gallons per day. So this plant, which is about
one seventh of that capacity, will require about 1.5 million of gallons per day for which
a suitable riverside should be chosen.
Power Supply: There is every need for a separate station as the power requires is
enormous. The factory needs lot of process steam. The steam generated can be
first supplied to the turbine and then used for process work.
10
PROPERTIES OF AMMONIUM SULPHATE
THRESHOLD
COEFF.
11
4. PROCESS IN DETAIL
An end rock kippler and conveyor systems are used to handle incoming
gypsum. This is designed to deliver gypsum direct to crushing mills or to stock piles as
may be required gypsum stock pile is housed under cover top keep it dry, for wet
grinding gives rise to lot of difficulties. The building walls are clothed with steel
framed asbestos cement sheet.
Slurry Preparation:
Slurry tank is a ordinary open cylindrical vessel of 1.7 M diameter and height
about 2.3 meter. Gypsum and water fed into it in calculated proportion. An agitator
(paddle type) is employed which is run at about 50 – 70 r.p.m. After necessary mixing
slurry is fed to the Reactors.
Carbonation Section:
almost pure CO2 enters primary at bottom and passes up counter currently to the
carbonate solution trickling down the tower, which is packed with 2-by 2-in stone wire
12
rings. The un absorbed CO2 from the top section of which condensate is sprayed. As the
amount of liquor is re circulated in each of the towers in order that the packing may be
effectively wetted. A part of liquor is bled off into a tank from it is sent to the reaction
section.
Reactor section:
Gypsum in slurry form is fed into the first or second vessel of 8 vessel chain,
along with the carbonate solution. The normal practice is to use 240 gallons of carbonate
solution pr ton of gypsum fed to the reactor vessels, which are cylindrical, provided with
stirrer to keep the magma agitated, and arranged for gravity flow. The reaction vessels are
made of mild steel, but the gravity lines are of cast iron and the open type impellor pumps
and associated piping are stainless steel of type 18/ 8
The reaction in the reactor section is exothermic, hence the reaction vessels are provided
with cooling coils. The chemical reaction taking place inside the reactor is as fallows:
13
the primary filter cake. The liquor from the first is stored in a liquid tank of
diameter 1.75 meter and height 3.86 meter, from which its is fed to Dorr-Oliver type
settler.
Filtered liquor from the primary filter contains about 3030 ppm. of suspended
calcium carbonate. The settler reduces this to 300ppm. Settler is made up of stainless
steel and height of 1.23 meter (conical bottom) and diameter 3.2 meter. The settled liquor
contains about 0.386 gm. (NH4)2CO3 per 100 cc. Together with some dissolved CO2 and
air.
Ammonium carbonate decomposes to give Ammonia and carbon dioxide when
o
heated over 109 C
(NH4) 2 CO3 → 2NH3 + CO2 + H2O
Crystallizing Section:
The decomposed liquor flows by gravity from storage tanks continuously into
Olso type ‘Krystal’ evaporator. This is a modern form of evaporation crystallizer. This
unit is particularly well adapted to the production of large sized, uniform crystals usually
somewhat rounded. It consists essentially of a forced circulation evaporator with an
external heater containing a combination salt filter and particle – size classifier on the
bottom of the evaporator body. The unique feature of this crystalliser is that a slightly
super-saturated solution is passed upward through a bed of crystals, depositing on them
the excess solute above saturation and simultaneously classifying them so that only larger
ones settle against the stream. Fine crystals and saturated solution leave the top of the bed
and are recycled.
14
Drying; Cooling Section:
Crystals from centrifuge are fed to a counter current rotary dryer wherein hot air
at 150C is used as drying medium.
Internal flights lift the solid and control its cascade through the air stream. The
dryer is tilted so that the solids gradually work their way from feed end to the discharge
ammonium sulphate crystals which leave at 90C are cooled in a cooler using fresh air.
Fresh air enters at150C and leaves at 92. C. Ammonium sulphate crystals
leaving from the cooler will be also at 80C. These crystals are conveyed to the bagging
house.
15
PROCESS FLOW DIAGRAM
16
5. MATERIAL BALANCE
Chemical reactions:
Molecular weights:
NH3 -------------- 17
H2O ---------- 18
NH4OH ---------- 35
CO2 --------------- 44
(NH4)2CO3 -------------- 96
17
Raw materials required for the process:
For the process considered, assuming that conversion in reaction (1) & (2) is
complete conversion and for reaction (3) conversion is 96%
Gypsum required:
18
136 kg of gypsum requires 96 kg of ammonium carbonate
Ammonia required:
Hence,
35 kg of Aq ammonia requires 17 kg of ammonia
3588.25 kg of Aq. Ammonia would require:
19
From reaction (3),
100 kg of ammonium carbonate requires 44 kg of carbon dioxide
9842 kg of ammonium carbonate would require:
Water required:
Amount
Raw materials (kg per hour)
Gypsum 13279
Ammonia 1743
20
Material balance across all equipments:
Input output
Gypsum lumps 13279 13279
SLURRY TANK
Input Output
16640.0 16640.0
21
ABSORBER SECTION
Input Output
Water - 1665.2
11507.2 11507.2
REACTOR
Input Output
27082 27082
22
FILTERS
22788 22788
23
DECOMPOSER
Input Output
Ammonium sulphate 10417 10417
Calcium carbonate 30 30
Water 657.5 557.5
Water evaporated - 100
Ammonium carbonate 843.5
Decomposition of - 843.5
Ammonium carbonate to
atmosphere
11948 11948
CRYSTALLIZER
Input Output
Calcium carbonate 30 30
11004.5 11004.5
24
CENTRIFUGE
Input Output
Ammonium sulphate 10417 10417
Water 212.5 212.5
Calcium carbonate 30
Calcium carbonate 30
centrifuged
10659.5 10659.5
ROTARY DRYER
Input Output
Ammonium sulphate 10417 10417
Water 212.5 105.25
Water dried 107.25
Air 16743.9 16743.9
27373.2 27373.2
Product: 10417 kg/hr of ammonium sulphate crystals with 1% (dry basis) moisture
25
6. HEAT BALANCE
Since all the reactions in absorber and even formation of aq.ammonia, which is
sent to absorber are exothermic reaction the heat of reaction should be removed off from
absorber section, to maintain it at a low temperature of 20 0c. This task is achieved by
installing a shell and tube heat exchanger to the stream that is being sent to the absorber
section a part of bottoms of absorber is recycled to achieve the good conversion.
F
F1
water
HE
ABSORBER
water
R ( R+F)
F
26
∴ R = 0.50 R+ F
0.5R = 0.5F (∴F1 = R+F)
X = ( F + RX) x (1 – 0.15)
F+R
X = (1+X) x 0.85
2
X = 1/ 1.35 = 0.74
X = 0. 74
27
3
Stream sent to the heat exchanges is 376.2 x 10 g mol or14353 kg/hr. In reality it is
mixture of Ag. Ammonia and ammonium carbonate but concentration of ammonium
carbonate is too small that the entire stream can be considered as containing of only Aq.
Ammonia.
Heat liberated
0
Tr = 20 c
o 3
Cp of NH4OH = 90 J /g.mo c
9 3
∴ 2.60 x 10 = 376.1 x 10 x 90 T - 20
0
∴ T = 96.81 ∼ 97 c
0
or T = 97 c
28
2. REACTOR SECTION
o
(NH4)2 CO3 + CaSO4 (NH4)2SO4 + CaCO3 + 3.9 k cal/ g. mol C
= 383. 84 KJ
the outlet stream contains ammonium sulphate , ammonium carbonate and calcium
carbonate.
Rise in temperature
29
The total heat in the reactor exit stream Q,
3
Q = 383.84 × 10 = [79.69x 215.1 + 97 x 120.5 + 8. 78 x 298] x ( T – 30)
∴T = 42 oC
3
Hence cooling water requirement = m = (383. 84× 10 )/ (4.184x ( 42- 30))
= 1.835kg/ hour
DECOMPOSER SECTION.
30
Qd = ( mas cp1+ mwater cp2 + mac cp ) ( 109- 30)
Qd = [ 109417x 1.63 + 657.7 x 4.184 + 843.5 x 3.10 ] (109- 30) = 843.5 x 1300
Qd = 2861 KJ
Steam requirement.
It is assumed that saturated steam is supplied and the exhaust stream would be of
saturated liquid
Amount of steam required for decomposition of ammonium carbonate,
mh mh = 2861/ 1.80 ( 100- 0)= 15.69 kg / hour
4. KRYSTAL EVAPORATIOR.
In this section evaporative crystllisation takes place.
Amount of water to be evaporated = 345 kg.
Assuming the steam side is at higher pressure, i.e. 2 atmospheres.
Amount of heat required for evaporation = m 1
= 345 x 2256.9
3
= 778.63 x 10 KJ/ kg
2198.18 KJ/ kg
$W DWPRVSKHULF SUHVVXUH ODWHQW KHDW RI VWHP 2 =
3
Amount of steam required= 778.63 x 10 / ( 2198.18)
= 354.18 kg / Hr
31
7. PROCESS EQUIPMENT DESIGN
1. ROTARY DRIER
Feed
(NH4)2SO4 +H20 Hot air
Spent air
Product
Moist (NH4)2SO4
32
Heat balance
Cp of (NH4)2SO4 =1.63 kJ/kg ºC
Cp of water = 4.187 kJ/kg ºC
Temperature detail
Feed Air
Inlet 30 ºC 150 ºC
Outlet 80 ºC 85 ºC
=
ûWm [(150 –30) – (85-80)]
Ln[( 150-30)÷(85-30)]
The minimum velocity of air is set based on the particle size. Air flow rate of
100 lb/hr .ft3 is sufficient for 420 microns. Hence this will be used in application. The
minimum velocity is used since it gives the smallest possible size of drier.
33
Amount of air required:
M = (Qt / Cp ûW
= 989412/ (150- 85)
= 15221.72 kg / hr
The maximum amount of water present in this amount water is 60% i.e.
9133.03 kg / hr
An extra amount of 10% of this quantity to account the heat losses.
1.1 x 15221.72 = 16743.89 kg / hr.
If the velocity of air is 1000lb/ hr.ft = 4880 kg / hr. m3
= 2.09 m.
Diameter of dryer = 2.09 m.
Length of transfer unit has been related to mass velocity and diameter by following
relation, Ltu = 0.0064 xCp x (G) 0.84 x2.04
= 7.36 m.
Length of the drier = Ltu x NTU
= 7.36 x 1.5
=11.05 m.
Following dimensions for the drier are chosen.
L = 12m ; D= 2m
L/D = 12/2
=6
L/D should range in between 4 – 10. Hence the design is safe.
34
2. SHELL AND TUBE HEAT EXCHANGER
0
20 C
1) Temperature detail:
water in
0
Cold fluid Hot fluid 15 c
0 0
In let 15 c 97 c
Waterout
Outlet 350c 200
97O C
2. Heat load
35
Cold fluid : (Water)
Qc = MC x Cp x. ût
Where MC = to be determined.
Cp = Sp heat of water.
Mass of cold water required to remove the heat associated = 9.548 kg/sec.
Correction factor Fr
R = (T 1– T 2 ) S = (t 2 - t 1 )
(t2 - t 1) (T1 – t1)
36
th.
From perry 6 cd. page 10.27
Considering 2-shell pass, 4 table pass i.e., 2.4 exchanger.
FT = 0.8
3) Rounting of fluid:
Reference perry, page (10-44)Ud for water in shell side, inorganic solvent in tube side is
ranging between(100-250) BTU/ (F.Ft2.hr)
37
Heat transfer area of over tube = 0.04968 x 4.8768
2
= 0.2431 m
Tube
∴No of tube = 73.57 = 302
0.2431
Nearest tube count from perry, page 11-13 is 274. and corresponding shell diameter
(inner) = 438 mm.
∴Shell ID = 438mm.
Corrected heat transfer area = 274 x 0.243
= 66.60m2
3
corrected Ud = 799 x 10
66.60 x 18.1
2.
= 662.0 W/m °k
Number of passes = 4
Available flow area = π x di 2 x NT
4 NP
2
= π x (0.01257) x 274
4 4
2
at = 0.0085m
∴ Velocity of fluid in the tube Vt = Mt
38
f x dt
Vt = 3.98 x 1 x 1
832 0.0085
Vt = 0.563 m/s
shell I D , Ds = 438mm
Lc baffle cut = 0.25 x Ds
Ls , baffle spacing = 0.5 Ds = 0.219m
Sm = ( p1 – Do)Ls x Ds
p1
Sm = Gross sectional area at centre of shell
Nb = No of baffles , L = length of tube
p1 = 13 inches square pitch = 0.0206m
16
= 0.4284 m/s
No. of baffles
Nb + 1 = Total length of tube
39
Baffle spacing
= 4.8768/ 0.2
= 22.26 ∼ 23
∴Nb = 22
a) Tube side
0
At 55 c
S = 832 kg / m3
Cp = 2.57 KJ/ kg0 k
M = 1.26 mNs / m2 = 1.26 x 10 –3 NS
K = 0.219 w/m0 k m2
NRC = fVtD
M
= 832 x 0.563 x 0.01257
1.26 x 10–3
= 4673
NPr = MCp
K
–3 –3
= 2.57 x 10 x 1.26 x 10
14.78
40
= 14.78
From perry page (10-29) jH = 0.02
∴ NNh = jH x NRC x (NPr )• NNh
= 0.02 x 4673 x 14.78 •
k
∴hi = 229.35 x 0.219
0.01257
= 3995.83 w/m2 0k
hi = 3995.83 w/m2 0k
(b) Shell
side at 250c
C = 995.045 kg / m3
Cp = 4.184 kj / kg 0 k
-3
M = 0.95 x 10 poise
k = 1.42 w / m k
NPr = M x Cp
K
41
=
0.95 x 10–3 x 4.18 x 103
1.42
=
2.8
From perry, page (10-29) , jH = 1 x 10–3
= 10.74
but, hodo = NNh
k
2
∴ ho = 10.74 x 1.42 = 960 w / m k
0.01587
2
ho = 960 w / m k
Uo = 243.096 w / m2 0 k
42
7) Pressure drop calculation :
a) Tube side
2
û PL = 4fLV x f x g
2gDi
but, f = 0.079 x Rc –0.25
=
0.079 x (4673 )–0.25
= 0.0095
2
û PL =4 x 0.0095 x 4.8768 x (0.563 ) x 832
2 x 0.01257
û PL = 1.943a Kpa
2
∴ û Pt = 2.5 (f x Vt )
2
2
û Pt = 2.5 ( 832 x ( 0.563) ) = 0.3796 KPa
2
û Ptotal 1S [ û PL + û Pt )
= 4 x 1.9439 + 0.3796
b) shell side
Shell side pressure drop is calculated using bell ‘s method
43
From figure 10.25 (a) page 10-31 friction factor fk
fk = 0.19
f . f2m
-3
b= 2 x 10
w = 9.54 kg/s
Sm = 0.02235m2
Nc = Ds x 1 – 2(Lc / Ds) / Pp
Where Ds = shell 1D = 0.438m
Lc = 0.1095
Pp = pitch parallel (cross )flow = 13 in = 0.0206m
16
Nc = 0.438 1 – 2 (0.1096/0.438)
0.0206
Nc = 16
∴ û Pc = 2 x 10-3 x 0.19 x 9.542x 16 1 0.4
997.04 x 0.02235
= 0.0252 KPa
44
(ii) End zone pressure drop û3c
û3c û PL 1 + ( N cw / N c)
Ncw = 0.8lc
Pp= 0.8 x 0.1095
0.0206
=4
∴ ûPc = 0.0252 x 1+ 4 16
2
û Pw = b x w 2+0.6 klcw
fm x Sw x f
b = 5 x 10-4
Sm = 0.02235 m2
N cw = 4
w = 9.84 kg / s
2
S = 997.045 kg /m
Area for flow though window Sw = Swg – Swt
Swg , from fig (10-18) , page (10-29), perry hand book.
Swg = 0.029
45
Swt = NT ( 1-Fc ) Do
8
= 2
274 x (1 - 0.68) x (0.0158)
8
Swt = 0.0085
∴∴∴∴
Sw = 0.0205 m2
Pressure drop at window zone û Pw
Total pressure drop at shell side is less than 70 Kpa hence, shell & heat exchanger design
is satisfactory.
465
8. MECHANICAL DESIGN OF PROCESS EQUIPMENTS
1. Flight design:
Number of flights = 3 x D.
= 3 x2.09
=6.27 ≈ 7 flights are required using lip angle of 45°.
Radial height is taken as 1/8 of diameter,
Radial height = 2.09/8
= 0.2615m.
2. Thickness of dryer:
Let x be the thickness of drier.
Mild steel can be used since it can withstand temperature up to 200°C.
Density = 7688.86kg/m3.
D2 – D1 = 2x.
Volume of mild steel =(πD22/4 - πD12/4) x L
=(π(D1+2x)2/4 - πD12/4) x L
= πDLx.
476
2
= π x2 x12. x0.2
4
= 7.53 m3.
4 4
Z = π x(D2 – D1 ) / 32D2.
= 0.785x3 + 12.59x2 + 67.31x.
f = 1800psi.
Take factor of safety = 5.
f = 3.6 x105lb/ft3.
= 1.75767 x104kg/m2.
Thus M = f xZ on simplification becomes,
1.38 x106x3 + 22.13 x106 x2 + 113.264 x106x – 0.819 = 0
x = 15 mm
487
3. Diameter of the feed pipe:
2
Cross-section of feed chute = 7.53/ 150 = 0.050 m
Diameter of feed chute = √ (C.S.A. x4 /π) = √ (0.050 x 4 /π)
= 0.252 m
4. BHP to drive the drier:
HP of blower:
0
Temperature of atmospheric = 30 C
3
Humidity in air= 16743. 89 kg/ min = 915. 5 ft /min
Volume of this air , Q = 279.05 / 29 x 22. 4 x 303/ 298
= 219.9 m3/min
= 718.9 ft3 /min
498
HP of blower = 0.000157 x Q x (head developed by water)
= 0.000157 x718.9 x10
=1.2 hp
5. HP of exhaust fan
0
At inlet conditions of 150 C and humidity of 0.002
the volume of air handled = 219.2 x 423 / 303
3 3
=306 m /min or 5.1 m /sec.
5049
2. MECHANICAL DESIGN OF HEAT EXCHANGER
510
SHELL SIDE
1.Shell thickness
ts= PD/(2fJ+P)
= 0.11 x438/(2 x95 x0.85+0.11)
= 0.31
2.Head thickness.
Shallow dished and torispherical
w = 1/ 4 x ( 3 + ¥ 5c / R K )
= 1/ 4 x ( 3 + ¥ 5c / .06 Rc )
= 1.77
t = PRcW/2fJ
= 0.11 x305 x1.77/(2 x95 x0.85)
= 0.528 mm.
minimum shell thickness should be 10mm including corrosion allowance.
3.Transverse Baffles
521
number of baffles,
Nb+1=L/LS=4.88/0.350=14
Nb =13
Thickness of baffles, tb=6mm
5.Flanges
532
Assume a gasket thickness of 10 mm
2
y = minimum design yield seating stress = 25.5 MN/m
543
=0.0241 MN.
Am=Ag=Wg/Sg
=
0.862 /138
= -3 2
6.246×10 m
Calculation of optimum bolt size
Bolt size,M18 X 2
Actual number of bolts =20
Radial clearance from bolt circle to point of connection of hub or nozzle and back of
flange = R = 0.027 m
C =ID + 2(1.415g + R)
=325 +2[1.41 x0.008+0.027]
= 0.726m
Bolt circle diameter = 0.40163 m.
Using bolt spacing Bs = 45mm
C = n Bs / 3.14 =44 x 0.045 / 3.14 = 0.63
Hence C = 0 .726
Calculation of flange outside diameter
Let bolt diameter = 18 mm.
A= C+ bolt diameter +0.02
=0.716 +0.018+0.02
554
= 0.764m.
56
(b) For bolting condition
Mg=Wa3
W=(Am+Ab) xSg/2
2
t = M CF Y / (B SF), SF is the allowable stress for the flange
material K =A/B = 0.764/0.446 = 1.71
For K = 1.71 Y = 4.4
Assuming CF =1
t2 = 0.125 x 1 x4.4/ (0.446 x 100)
t= 0.11m
576
Actual flange thickness = CF xt
= 0.11 x0.772
= 0.085 m
= 85mm.
12.Channel and channel Cover
th=Gc(KP/f)
= 0.446 x(0.25 x0.11/95)
= 0.00767m =7.67mm
th= 8mm including corrosion allowance
587
Weight of shell = π D x 0.008 x 7600 x L
= 83.67 x 4.88
= 408.30 kg
-03 -03
Weight of tube = π ( 19.05 ×10 - 12.27 ×10 ) x 4.88 x 7600 x 274
= 1480 kg
2
weight of water = π 0.01224 x 4.88 995 x 274
= 626.19 kg
weight of vessel and contents W = 2215.69 kg
M1 = QA[1-(1-A/L+(R2-H2)/(2AL))/(1+4H/(3L))]
Q = W/2(L+4H/3)
= 2215.6/2 x(4.88 +4 x0.07586/3)
= 5518kg m
M1 = 598.05 kg-m kg-m
2 2
M2 = QL/4[(1+2(R -H )/L)/(1+4H/(3L))-4A/L]
M2 =6014. 4 kg-m
17.Stresses in shell at the saddle
(a) At the topmost fibre of the cross section
2
f1 =M1/(k1π R t) k1=k2=1
2
=598.06 / (3.14 x0..219 x0.01)
2
= 35.22 kg/cm
The stresses are well within the permissible values.
Stress in the shell at mid point
f2 =M2/(k2π R2 t) = 6014.4 / (1 x π 0.2192 0.01)
598
2
= 399.07 kg/cm
5960
9. COST ESTIMATION
The capital investment for the 250TPD ammonium sulphate plant was found to be
Rs310.30 crores in the year of .1993-94.
Chemical Engineering Plant Cost Index:
Cost index in 1994 = 368.1
Cost index in 2018 = 520
Thus, Present cost of Plant = (original cost) × (present cost index)/(past cost index)
7 7
= 310.3× 10 (520/368.1) = 338.8× 10
7
i.e., Fixed Capital Cost (FCI) = Rs 438.8× 10
1. Direct Costs:
Material and labour involved in actual installation of complete facility (70-85% of
fixedcapital investment)
610
3. Instrumentation and controls, installed: (6-30% of
Purchased equipment cost.)
621
Thus, Direct cost =
7
(109.6+43.8+16.44+43.8+27.4+43.8+54.8+14.3+4.38)*10^7=358.32×10
II. Indirect costs: Expenses, which are not directly involved with material and labour of
actual installation of complete facility (15-30% of Fixed-capital investment)
7
Thus, Indirect Costs = Rs.250×10
632
Fixed capital investment = Direct costs + Indirect costs
7 7
= (Rs.358.32×10 ) + (250.7×10 )
= 7
Rs 609.02×10
7
Fixed capital investment = Rs. 609.02×10
643
ii. Local Taxes: (1-4% of fixed capital investment)
Consider the local taxes of 3% of fixed capital investment
7 7
i.e. Local Taxes = 0.03×438.34×10 = Rs. 13.15×10
654
7
= Rs.20.63×10
iii. Direct Supervisory and Clerical Labour (DS & CL): (10-25% of OL)
Consider the cost for Direct supervisory and clerical labour = 12% of OL
7
Direct supervisory and clerical labour cost = 0.12× 61.84×10
7
Direct supervisory and clerical labour cost = Rs.7.42× 10
665
C. Plant overhead Costs (50-70% of Operating labour, supervision, and maintenance or
5-15% of total product cost); includes for the following: general plant upkeep and overhead,
payroll overhead, packaging, medical services, safety and protection, restaurants,
recreation, salvage, laboratories, and storage facilities.
Consider the plant overhead cost = 60% of OL, DS & CL, and M & R
7 7 7
Plant overhead cost = 0.60 × ((61.84×10 ) + (7.42 × 10 ) + (21.092×10 ))
7
Plant overhead cost = Rs. 54.7×10
Thus, Manufacture cost = Direct production cost + Fixed charges + Plant overhead costs.
7 7 7
Manufacture cost = (300.7×10 ) + (59.7 x 10 ) + (61.84×10 )
7
Manufacture cost = Rs. 417.23×10
A. Distribution and Selling costs: (2-20% of total product cost); includes costs for
sales offices, salesmen, shipping, and advertising.
Consider the Distribution and selling costs = 10% of total product cost
7
Distribution and selling costs = 0.10 × 412.26×10
7
=41.26×10
7
Distribution and Selling costs = Rs. 41.26×10
C. Research and Development costs: (about 3% of total product cost)
Consider the Research and development costs = 3% of total product cost
7
Research and development costs = 0.03 × 412.26×10
7
Research and Development costs = Rs. 12.36×10
67
7
Thus General Expenses = 56.71×10
V. Gross Earnings/Income:
Wholesale Selling price of ammonium sulphate per kg = Rs 115.50
687
10. PLANT LOCATION AND LAY OUT.
When it has been decided to start a factory it is most important to select a suitable
site or location to house the factory. This is not an easy problem, because of the site
selected may not be proper, then all the money expanded on factory building, equipments
and layout etc. will go in waste. Therefore while selecting a site, owner must consider
technical, commercial and financial aspects and then to select a site that will produce a
maximum advantage.
This problem can be divided into two main parts:
(a) General location of the factory.
(b) The selection of particular site.
(a) For the general location of the factory following factors must be considered: -
1) The raw materials should be easily available at comparatively low cost
and at low freight charges.
2) The market should be near the factory for the quick service to the
customers and easy transportation.
3) There should be good transport facilities for bringing raw material and
sending finished product.
4) Skilled and cheap laborers should be available near the plant site.
5) Availability of power and fuel were very influencing in olden days to day
it has no much effect on plant site.
6) Climatic and atmospheric conditions are governing factor to several
chemical industries. However, air conditioning systems have changed the
situation.
7) All factories need soft and pure water especially in large quantities.
8) Availability of capital.
9) Social and recreational facilities: can be created near the factory site.
698
10) Banking facilities are necessary for the factories, which requires constant
feeding of the working capital.
11) Existence of related factories sometimes play very important role in
selection of site.
12) The factors like local byelaws, Taxes, Fire protection facilities, post and
telegraph facilities should also be considered.
(b) Selection of Actual site: -The most important factors in this respect are: -
1) Availability of cheap land to build and expand the plant.
2) The cost of leveling the land and providing foundations, subsoil conditions
for foundations and drainage.
3) The cost of bricks, sand, cement, limes, steel and other materials required
for construction.
4) Facilities for the upkeep and general maintenance.
5) Facilities for transport in getting and sending materials.
6) Facilities for housing the workers and if necessary their transport from
their place of residence to work sites.
7) Cost of laying the water supply and providing sewage and disposal work.
8) Cost of installation of electricity, gas and other facilities, etc.
9) Any restrictions placed by the planning department or local bye-laws be
well studied.
7069
The economic construction and efficient operation of a process unit will depend on how
well the plant and equipment specified on the process flow sheet is laid out. The principal
factors are considered are:
Process requirements
An example of the need to take into account process consideration is the need to elevate
the base of columns to provide the necessary net positive suction head to a pump or the
operating head for a thermosyphon reboiler.
Operations
Equipment that needs to have frequent attention should be located convenient to the
control room. Valves, sample points, and instruments should be located at convenient
positions and heights. Sufficient working space and headroom must be provided to allow
easy access to equipment.
Maintenance
Heat exchangers need to be sited so that the tube bundles can be easily withdrawn for
cleaning and tube replacement. Vessels that require frequent replacement of catalyst or
packing should be located on the out side of buildings. Equipment that requires
Dismantling for maintenance, such as compressors and large pumps, should be places
under cover.
710
Safety
Blast walls may be needed to isolate potentially hazardous equipment, and confine the
effects of an explosion.
At least two escape routes for operators must be provided from each level in process
buildings.
Plant expansion
Equipment should be located so that it can be conveniently tied in with any future
expansion of the process.
Space should be left on pipe alleys for future needs, and service pipes over-sized to allow
for future requirements.
Modular construction
In recent years there has been a move to assemble sections of plant at the plant
manufacturer’s site. These modules will include the equipment, structural steel, piping
and instrumentation. The modules are then transported to the plant site, by road or sea.
The advantages of modular construction are:
721
The Plant Layout key words
732
PID DIAGRAMS
74
REFERENCES
nd
Joshi M. V., “Process Equipment Design”, 2 Ed., McMillan India Ltd,
Max S. Peters and Klaus Timmerhaus, “Process Plant Design and Economics
rd
For Chemical Engineers”, 3 Ed., McGraw Hill Book Company, Page No:
207-208, 484-485.
L.E. Brownell and E.H. Young, “Process Equipment Design”, John Wiley
& Sons Inc. New York, page no.219-248
www. Fertilizerworks.com
www. fert.in.co.
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