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MECHANICAL PUMPING

The nature of
the mechanical
pulping process
BY D. MCDONALD, K. MILES, AND R. AMIRI

Abstract: Three independent properties must be optimized simultaneously for lightweight


mechanical printing papers: scattering coefficient which is required for opacity, fibre length for
strength, and density for printability. For a given wood species, there is a single relationship
between scattering coefficient and fibre length, from groundwood to refiner pulps to kraft. Greater
development of long fibres with less cutting, as measured by density, can be achieved by lowering
the refining intensity or increasing either the chemical treatment or temperature.

he quality of mechanical pulp has practical approaches have addressed the potential

T improved steadily over the last few


decades. Shortly after the introduc-
tion of thermomechanical pulp
(TMP) it became the preferred fur-
nish for newsprint and in recent years has
to develop high-quality mechanical pulp and to
reduce specific energy consumption [5,18,21,24].
The two key operating factors in refining are
the specific energy and the intensity [18,24],
defined as the specific energy per bar impact.
become a substantial component of supercalen- Manipulating the refining intensity can have an
dered and lightweight coated grades. With fur- effect on both energy consumption and pulp
ther improvement in fibre and pulp quality, by quality [8]. Increasing the refining intensity by
optimizing refiner operation and fractionation either increasing the rotational speed of the
strategies, TMP could conceivably become the refiner [27] or lowering the consistency [5] low-
sole pulp in many high quality mechanical print- ers the energy required to reach a given freeness
ing grades. but often reduces average fibre length and tear
Extensive research has been done to deter- strength. The optimization of refining intensity to
mine parameters influencing mechanical pulp different wood species and wood of varying qual-
properties. Almost 30 years ago, Forgacs suggest- ity could lead to significant improvements in
ed that mechanical pulp could be characterized refiner operation and pulp quality.
by two factors, one related to fibre length and the This report discusses the factors that deter-
other to specific surface [32]. He proposed a mine the energy/quality relationships in mechan-
groundwood control scheme based on on-line ical pulping. This understanding could unlock
measuring of shives, fibre length and freeness. the potential value of each wood species, reduce
However, this control concept predated suitable process variability, and show how to make a
on-line sensors. Since then a significant amount mechanical pulp with optimized properties.
of work has been done to better understand
mechanical pulps and in particular the effect of BACKGROUND
operating parameters such as specific energy, The basic concepts of mechanical pulping are evi-
consistency and raw material on fibre and pulp dent in the evolution of the process. The first
properties [5,6,9,12,17,19,26,33]. mechanical pulp was groundwood, which is char-
The wide particle size distribution in mechan- acterized by low energy but low strength proper-
ical pulps contributes to improved optical and ties, Fig. 1. Groundwood must be mixed with
surface properties [3,7,15,23,30] making them chemical pulp to achieve adequate strength
suitable for low-cost, lightweight papers. Further D. MCDONALD
properties. With the introduction of refiners,
cost saving could be achieved if minimum Paprican
mechanical pulps were stronger, but the addition
strength and opacity specifications could be met Pointe-Claire, QC
of chemical pulp was still necessary for grades
with fewer fibres per unit area of printing surface. e-mail: dmcdonald@paprican.ca
such as newsprint. Increasing the refining tem-
Another opportunity would be to capitalize on perature by operating at higher casing pressure
either the inherent fibre properties of different was expected to reduce energy consumption. In
wood species or employ fractionation strategies to fact, thermomechanical pulp required more
tailor products for specific markets [1,2,11,12]. energy but produced a high-quality pulp that
Even within species, variations offer significant could be used as a single furnish for grades such
options for cost reductions or quality improve- as newsprint. The highest quality mechanical
ment [4]. However, current refiner operating printing papers, lightweight-coated (LWC) and
conditions limit this approach. supercalendered (SC), now contain a large pro-
Mechanical pulping has been studied at Papri- portion of mechanical pulp but still require kraft
can for many years [14,18,24,25,29]. Work on stone for runnability. History suggests making these K. MILES
groundwood, refiner mechanical and thermome- grades entirely from mechanical pulp would be Paprican
chanical pulps has reflected the industry’s adoption the most cost-effective method. However, with Pointe-Claire,
of the processes [8,10]. Both fundamental and current technology, sufficient energy cannot be QC

Pulp & Paper Canada T 181 105:8 (2004) ❘❘❘ 27


MECHANICAL PUMPING

FIG. 1. Better fibre development occurs with processes FIG. 2. Value-added papers need collapsed fibres to give a
that can apply more energy. dense sheet with a uniform printing surface.

FIG. 3. Higher density on handsheets made with long FIG. 4. Density of handsheets made with long fibres
fibres is achieved through higher fibre flexibility. increases with decreasing fibre coarseness.

applied to the fibres to develop pulp properties.


Although there has been significant research effort world-
wide to reduce energy consumption in mechanical pulping,
experience has shown that the key to a longer, more developed
fibre is being able to put more energy into the pulp. This can be
done by softening the fibre by heat or chemicals, or by reducing
the refining intensity. [Fig. 1]
Cross-sections of lightweight coated and supercalendered
sheets provide an illustration of the type of fibres that are
required for high value mechanical printing papers. [Fig. 2] The
individual fibres are collapsed, giving a highly densified struc-
ture which provides a uniform printing surface. Density is a
macroscopic indicator of the fibre characteristics such as flexi-
bility [28], (Fig. 3), coarseness, (Fig. 4), and collapse [16].
Although calendering provides much of the densification, the
pulp must respond to these forces. There must also be sufficient
long fibre to maintain strength under this mechanical action
and with the addition of fillers, which are required for opacity.
Three independent pulp properties need to be optimized for FIG. 5. For lightweight papers, scattering coefficient, fibre
lightweight papers: scattering coefficient, which is required for length, and density must be optimized.
opacity, fibre length for strength, and density for printability,
(Fig. 5). Mechanical pulps are particularly suited for lightweight Pilot Plant Trials
grades because of the inherent scattering by fines. This permits A considerable quantity of such data was obtained when repeat
a reduction in basis weight without compromising opacity and trials were carried out on black spruce and balsam fir as part of
showthrough. To maintain strength, the fibres must be devel- a study of seasonal quality variations. Pulp from each species was
oped without losing length. Flexible, conformable and collapsed produced on Paprican’s Bauer 36 in. double disc atmospheric
fibres, which promote better printability, are characterized by a refiner under the following conditions:
higher density. Examining pulp data plotted on these three axes • RMP (1200 rpm, no chip pre-steaming)
can provide insight into the limits of mechanical pulping and • Low intensity RMP (900 rpm)
the opportunities. • Low intensity ‘TMP’ (900 rpm, 10 min. of chip pre-steaming at 138°C).

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MECHANICAL PUMPING

FIG. 6. Regardless of the refining process, the scattering


coefficient is a well definied function of the fibre length.
At a given fibre length fir always yields higher scattering
than spruce.

FIG. 7. Adding additional data to the plot of Fig. 6 shows


that the relationshop between scattering coeffieicnt and
fibre length extends all the way from stone groundwood
to softwoodkraft.

FIG. 9. For a given species the energy needed for a given scat-
tering coefficient is extremely dependent upon the process.

and chipping was carried out on a whole tree at a time. The


large number of repeat trials done for this study also greatly
enabled any variations to be smoothed by averaging.

Scattering Coefficient and Fibre Length


Averaging of the results over the nine trials produced the rather
striking trend shown in Fig. 6. It is evident that the scattering
FIG. 8. For a given species scattering coefficient depends coefficient is a well-defined function of the fibre length,
on the quantity of fines and is independent of the process. expressed as the ‘L’ factor of the pulp and is completely inde-
pendent of the process used to make it. Equally apparent is that
The wood was carefully selected so that universal relation- the relationship is highly dependent on the species, with fir
ships could be developed. A common problem with many TMP always yielding higher scattering coefficient than spruce at a giv-
studies noted by Corson [4] is that the relationships developed en fibre length.
with small sample sites are overwhelmed by the inherent varia- Adding data from trials for other processes suggests that the
tions in the wood. In this case, trees of equal age were selected link between scattering and fibre length may be of a general

Pulp & Paper Canada T 183 105:8 (2004) ❘❘❘ 29


MECHANICAL PUMPING

FIG. 10. For a given speices the position on the scattering


coefficient/long fibre line is determined by specific energy, FIG. 11. Mixtures of kraft and groundwood lie along the
refining intensity, temperature, and chemical treatment. same scattering coefficient/long fibre line.

FIG. 13. There is a direct correlation between the long fibre


FIG. 12. Processes with higher specific energy require- content at a given freeness and the energy needed to
ments have more long fibre at a given density. reach that freeness.

nature, (Fig. 7). Clearly, a convincing trend between scattering meeting chosen performance targets. In a refiner, changing the
coefficient and fibre length extends all the way from stone specific energy, refining intensity, temperature or chemical treat-
groundwood to kraft. The implication is that the material need- ment will also change the position on the scattering coeffi-
ed to produce scattering is derived from the reduction of long cient/long fibre operating line. But none of these operating
fibre mass and the cutting of fibres during mechanical treat- changes are able to move off this line. Electrical, equipment and
ment. Therefore, a compromise must always be struck between chemical costs will determine the best set of operating parame-
the long fibre content required for strength and the cut materi- ters to achieve the required properties.
al required for optical properties. As the plot of Fig. 8 shows, for
a given species, scattering coefficient is a function of the quan- Sheet Density and Fibre Length
tity of fines and is independent of the process. However, for a A common goal of most mechanical pulping studies has been the
given species, the energy input needed to achieve a certain scat- reduction of specific energy consumption. However, accom-
tering value is extremely dependent upon the process, as evident plishing this without compromising pulp quality has proven to be
in Fig. 9, where the effects are shown for spruce and fir inde- elusive. The challenge is demonstrated in the plot of handsheet
pendently and also in combination. The difference arises density against long fibre content, (Fig. 12). In order to achieve
because both pre-steaming and reduced refining intensity pro- good strength characteristics, the long fibres must be retained as
mote long fibre development with minimal cutting. This extends the sheet surface is improved by increasing density. But, as Fig. 12
the specific energy which must be applied before a given fines shows, this is a process-dependent condition. Moreover, the high-
content is reached. est long fibre content at a given density is associated with the pro-
Four operating parameters determine the position of the cesses having the highest specific energy consumption. Tradi-
scattering coefficient/long fibre line for a specific wood species: tionally, mechanical printing papers were made by combining
specific energy, refining intensity, temperature and chemical groundwood with kraft. Refiner mechanical pulp provides a
treatment, (Fig. 10). The characteristics of the wood and physics longer fibre but increasing the specific energy increases density
dictate the relationship between scattering coefficient and long at the expense of fibre length. Softening the pulp thermally or
fibre but there are many different ways to move along this line. chemically increases the fibre length and increases the potential
For instance, mixtures of kraft and groundwood lie on the same for density development in effect by operating on a different
operating line, (Fig. 11). This was the traditional method of long fibre-density line. This operating line can also be changed

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MECHANICAL PUMPING

FIG. 15. Low-intensity refining can even out the energy


variations to a given freeness for balsam fir by minimizing
FIG. 14. A whole diversity of fibre dimensions exists the fibre cutting encountered at conventional refining
amongst the various wood species. intensity.

by modifying the refining intensity. This suggests that lower refin-


ing intensities, perhaps combined with higher temperatures and
chemical treatment, could produce a high-yield pulp with prop-
erties approaching those of kraft.

IMPLICATIONS
The foregoing observations strongly suggest that the specific
energy needs for mechanical pulp depend to a large degree on
both the quantity of long fibre and the extent to which it is
developed. In fact, additional support for this was obtained
recently in pilot plant trials carried out on a monthly basis using
a Member Company’s wood supply. Each month’s trial included
conventional as well as low-intensity refining and the results were
interpolated to yield both the quantity of long fibre at 100 mL
CSF and the specific energy needed to obtain that freeness. The
plot, (Fig. 13), then shows very clearly the relationship between
long fibre content and specific energy consumption. Moreover,
low-intensity refining does not depart from the trend set by the FIG. 16. Low-intensity refining can improve fibre develop-
conventional process, but merely extends the line towards more ment of more difficult species such as jack pine.
long fibre retention for a given freeness at a correspondingly
higher energy demand. This is in marked contrast to the lower have a niche as a filler pulp in high-quality newsprint, uncoated
energy requirements at lower fibre lengths where the freeness is specialty ground-wood sheets, or as a supplement to coated
easily reached by fibre cutting. wood-free sheets. Some under-utilized species could give pulps
The potential to obtain particular pulp properties is deter- with greater strength assuming the fibres can be developed with-
mined by the intrinsic characteristics of the wood fibres out breakage. If for example, we tailor the refining conditions to
[1,2,5,11]: fibre length, diameter and cell wall thickness. The the characteristics of the wood, species like Douglas fir and
scattering of light by an individual fibre is related to the diame- southern pine probably have greater potential for strength
ter of the lumen and thickness of the cell wall, when the fibre is development than at present. This is something that is not real-
collapsed [20,22,31]. For a given species, mature wood will tend ized under conventional refining conditions. However, a large
to give longer fibres with thicker walls [13]. Juvenile wood, amount of energy would be required to reach this potential
which has thinner cell walls, would be more appropriate for which could make this approach impractical.
papers that require opacity but are not limited by strength. The Of more immediate interest would be balsam fir, which has
age of the tree is an obvious factor, however any tree has a dis- relatively long fibres but thinner cell walls than jack pine and
tribution of both juvenile and mature wood located at specific black spruce. This wood, although traditionally less valued than
locations in the log [13]. For example, saw mill residuals tend to black spruce, has the potential to make a strong opaque pulp
contain a higher proportion of the mature wood. This indicates because of its thin-walled fibres. At the same long fibre content,
that for optimizing the properties of a particular grade it is nec- balsam fir has a higher scattering coefficient than black spruce,
essary to account for the source of material whether it be in the (Fig. 6). This means that under the right refining conditions bal-
form of chips or roundwood or from old or new growth. sam fir could provide a more opaque sheet than black spruce at
Plotting the diverse fibre dimensions of different wood the same strength. Thus, there would be the potential to make
species gives some insights into their best product applications, a sheet of lower basis weight with balsam fir.
(Fig. 14). At one extreme are the short, thin-walled fibres of The quality of pulp made from balsam fir tends to be more
hardwoods such as maple and aspen. At the other extreme we variable than that from black spruce. In the plot of Fig. 15, the
have the pines and western firs with long, thick fibres. specific energy required to reach a freeness of 150 mL is shown
The thin-walled fibres have the greatest potential to make an for a series of pilot plant refining trials over a two-year period.
opaque sheet assuming the fibres can be sufficiently collapsed by The trials with lower energy are not a real energy saving but indi-
either chemical or mechanical action. The short fibres and frag- cate the fibre has been cut leading to poorer strength proper-
ile walls of the hardwoods are best suited to filler grades intend- ties. By lowering the refining intensity it is possible to put more
ed to raise opacity and perhaps brightness. Aspen CTMP might energy into the pulp which can reduce this variation. Although

Pulp & Paper Canada T 185 105:8 (2004) ❘❘❘ 31


MECHANICAL PUMPING
jack pine has a reasonable fibre length the Reduce Energy. Pulp & Paper Canada 98(4):38 (1997). Two-Stage Chip Refining. Tappi J. 74(3):221 (1991).
pulp does not develop well under con- 9. JANG, H.F., AMIRI, R., SETH, R., KARNIS, A. Fibre 22. GURNAGAL, N., PAGE, D.A., SETH, R.S. Dry
Characterization Using Confocal Microscopy - Col- Sheet Properties of Canadian Hardwood Pulps. J. Pulp
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jack pine look like black spruce pulp, 10. SABOURIN, M.J., CORT, J.B., MUSSELMAN, R., TUOMINEN, R. Pressure Groundwood (PGW), Super
(Fig. 16). This demonstrates the potential RYAN, K. Effect of Residence Time, Temperature, and Pressure Groundwood (SPGW) and Thermomechan-
Speed on TMP Properties Produced from Radiata ical (TMP) Pulp in Wood-Containing Papers. Paperi
to make mechanical pulp from wood Pine. 50th Appita General Annual Conference, pp. Puu 72(4):393-400 (1990).
species that have been under-utilized 567-577 (1996). 24. MILES, K.B. Refining Intensity and Pulp Quality in
because of quality considerations. 11. STATIONWALA, M.I., MATHIEU, J., KARNIS, A. High Consistency Chip Refining. Paperi Puu
On the Interaction of Wood and Mechanical Pulping 72(5):508-514 (1990).
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25. MILES, K.B., MAY, W.D. The Flow of Pulp in Chip
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data gathered from various mechanical Chemithermomechanical Pulps from Second Growth Separation and Development in a Disc Refiner. Paperi
pulping trials has identified the following Softwoods. Pulp & Paper Canada 95(12):67 (1994). Puu 71(7):801-814 (1989).
13. MILES, K.B., KARNIS, A. Wood Characteristics 27. SUNDHOLM, J., HEIKKURINEN, A.,
two key features which all of these pulps and Energy Consumption in Refiner Pulp. J. Pulp Pap. MANNSTRÖM, B. The Role of Rate of Rotation in
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20(10):J280-J288 (1994). fibre Flexibility on Sheet Apparent Density. Paper-
length and can only be increased by fibre 15. TUOVINEN, O., LIIMATAINEN, H. Fibres, Fibrils making Raw Materials. Trans. Eighth Fund. Res.
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32. FORGACS, O.L. Groundwood Pulp Evaluation:
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Mix for High Quality Coated Graphic Paper Grades. 71(1):22 (1992). 8(3):232-239 (1969).
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Helsinki, Finland, June (2001). and Mechanical Pulps. Paperi Puu 74(8):650-664 (1992). ture in a Mechanical Pulp as a Key to the Knowledge
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Increased Energy Efficiency in TMP Production Intensity, Energy Consumption and Pulp Quality in 54(1):72 (1953).
through Fractionation in Hydrocyclones. Internation-
al Mechanical Pulping Conference, Helsinki, Finland,
June (2001). Résumé: Trois propriétés indépendantes doivent être optimisées simultanément pour les
3. BRAATAN, K.R. Fibre and Fibril Properties Versus papiers impression mécaniques légers : le coefficient de dispersion pour l’opacité, la longueur des
Light Scattering and Surface Smoothness for Mechan- fibres pour la résistance, et la densité pour l’imprimabilité. Pour une essence de bois donnée, il y
ical Pulps. Pulp & Paper Canada 101(5):27 (2000). a une seule relation entre le coefficient de dispersion et la longueur des fibres, des pâtes
4. CORSON, S.R. Tree and Fibre Selection for Opti- mécaniques aux pâtes raffinées aux pâtes kraft. On peut obtenir un meilleur développement des
mal TMP Quality. Appita 52(5):351 (1999). fibres longues avec moins de coupures, en mesurant la densité, en réduisant l’intensité de raffi-
5. MOHLIN, U.-B. Fibre Development during nage, ou en accroissant le traitement ou chimique ou la température.
Mechanical Pulp Refining. J. Pulp Pap. Sci., 23(1):J28-
J33 (1997).
6. ALAMI, R., BOILEAU, I., HARRIS, G., KARNIS, A.,
LACHANCE, J., MILES, K.B., ROCHE, A. Evaluation Reference: MCDONALD, D., MILES, K., AMIRI, R. The nature of the mechanical pulping
of the Impact of Refining Intensity on Energy Reduc- process. Pulp & Paper Canada 105(8): T181-186 (August 2004). Paper presented at the 2003 Intl.
tion in Commercial Size Refiners, The Effect of Pri- Mechanical Pulping Conference in Quebec City, QC, June 2-4, 2003. Not to be reproduced with-
mary Stage Consistency. Tappi J. 80(1):185-193 (1997). out permission of PAPTAC. Manuscript received September 29, 2003. Revised manuscript
7. MOHLIN, U.-B. Distinguishing Character of TMP approved for publication by the Review Panel on December 19, 2003.
Pulp. Pulp & Paper Canada 78(12):T291-T296 (1997).
8. SABOURIN, M.J., CORT, J.B., WALLER, A., XU, E.,
BOILEAU, I. Optimizing Residence Time, Tempera-
Keywords: MECHANICAL PULPING, LIGHT WEIGHT PAPERS, PRINTING PAPERS, OPAC-
ture and Speed to Improve TMP Pulp Properties and ITY, STRENGTH PROPERTIES, PRINTABILITY, REFINERS, VALUE ADDED PRODUCT

32 ❘❘❘ 105:8 (2004) T 186 Pulp & Paper Canada

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