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t
o
potential
r
n
t
re
r
current
u
0
r
c
c
r
1
Icorr
r lu
r
Icorr I corr
r
g o l0
g o l0
o
o
t gn e or
Ec
Ec
Ec
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potential
potential
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potential
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Icorr
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ul0
Ec
potential
increase [H+] increase increase
ge
increase β (a)
n
increase decrease
t
increase β(a)
3-8. [a] Plot the appropriate polarization curves for the following half-cell
reactions and determine the corrosion potential and corrosion rate
[current density] assuming activation control of both the anodic and
cathodic processes. [b] Same as [a], but assume the limiting current
density for the reduction reaction is 10-5 A/cm2. Again, determine the
corrosion potential and corrosion rate [current] from your plot.
reaction ENernst jo β
M = M+ + 1e- -0.70 v 10-8 A/cm2 βa = +0.1
2H+ + 2e- = H2 +0.10 v 10-6 A/cm2 βc = -0.1
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0
log current, log(10) amperes
-2
I corr [AC]
-4
I corr [DL]
-6
-8
0.0
-1.0
-2.0
log current, log I
-3.0
icorr = 10^(-2.97)
-4.0 = 1.07x10^(-3)
-5.0
Only 5/6 data points to do a Tafel extrapolation - where you lay the
line is subjective and subject to error. Data points might have been
generated using either galvanostatic or potentiostatic polarization
methods. Jcorr = 1.07x10-3 A/1.13 cm2 = 9.47x10-4 A/cm2.