$ set Reh weer gu fey ahr UREA ee at ae (20 wre 4 go wo CH aga fwer wes (MCQ) fey ne # Larval sua “AAA aftroan 1s aft set BE 8 35 ove cen one CoH a a6 weet @ gure 83 | af Mala @ whe Sei Bene Rig ory oe ae MEA Be (aE 'A'A 45, War 'B A 95. cwiz er'C@ 25) 8 ata a ot | RTA, Te worm steer Ra Tay | ae Ra aa ty x a ar eed Ye 38 ate SATE AB Err P yes Gy ate WA fet ah A weve ars aPutdes a ah ols 3) yor aca? ar frtet ae tas wh aA wie 1 ge yPloaer Yew wer wel agra. Tare ere Byes 1 a RY my eure fire 1 weaie FiRtae, ar sane eels af) oper ary sett ai.aenore sary vam A Mle ofa, Fae aaltar Wafes Gal Gt ood ais de a ayn gen wl) ae fe oe hecnons. sare sae H fey oy Pal ox GA MIAN sree ae Yan a wed ve SUEY awe at wel w8s A sels Te ax aE, RTA aia; aTve) eIPy, Parl gnu shen so wae A ereigh AD euler &, el edt 21 ar "Aten BX wee we B 2 oie ate mr CM wed ued 4 oleh er € | aT ‘ATT ‘BX sete maa oat wr aeoee Heri: @ 0.60 aie een nr CY @ + of Poa site | soko ver 8 td an Root ere e Lg a das ew Ree A cael sme “aha BH" 81 aio} vols ew at stan also ex game 1 wos wel ay at aryl Ost oT ate oe Ge Ne MEd ara UenRint ar gu ath ora wedl wdisral & Fare seater seeren i won 2 | earl Oh sere ave Voll B alee ae ae gH AT al Ree waft | 9. Baggies m1 yuatn wel A agua ad & vo. Wer eur oy Me fare far ews ee OMR aera at Pasties at Fe_OMR sure vam eto) uesie amy eegl atdrate uiglaft aon wad 7 1118-4 Ma /eeoer Sura H Rani coud ah ee ae sea eh 42. Sat sie Hg aA we FEA are Gey at A UAleT yar aie) a seed a ay A sare ‘5/1 RISEMB—1AH—1A1. A.and B move clockwise around a cirele, starting from a common point 0. A takes 9 minutes to complete a round but re- starts after a delay of | minute. B takes 13 minutes to complete the round but restaris afler a delay of 2 minutes. How ‘many minutes after they began would they ‘meet again at 02 1 30 a. 29 3. 3t A an 2, Fourteen of the students in a class are girls, Bight students in the class wear blue shirts. Two are neither girls nor wear blue shits, Five students who wear blue shirts care girls, How many students are there in the class? 1 3, 19 i1 wang 6 ue wat a agibe ah anit a ghst war @1 ote gas ota rag gar 8? gay bg 1. U6 2 Ua 3.13 4 12 A stick of length L is broken into, two pieces at random. What is the average length of the smaller picce? 16 2 4 23 48 Ar nestle oy feds 0 aie sition ater completing 3th ofthe ttl distance, Aner covering another £00 of the total distance he geis mevicaratd, Another runner joins him 4 km after the Medical-aid station. ‘The second ninner stops + kin before the completion of run, covering} of the total distance. What is the total distance? 1 21km 2. 30km 3. 42 km 4. 50km HOR A at wre es we Art wate ray 21 a! meow) oR @ ahaa ara aur 8?1. 30.42 3 10.43 2. 20.43 4. 2143 Movement of a car with respect to tine is given below: ie A Gs iy x ‘The average speed of the caris 1 3047 2. 20.43 3. 1043 4. 2143 we get Oy wo fit ¥ 150 alt al tisov0 wr Storer daar g1 afk yaa aftr at wr ed oH % 50 aT Short eter aiarel @, al fered aftr 4 oer we fr er wrt or stare ater? 1. 7450 2. 7500 3. 7580 4. 7600 ‘A fuel station sold diesel costing 215000 to 150 persons on a day. IF the lower limit of sale to & person is © 50, what is the ‘maximum amount in rupees for which one person could faye purchased diesel on tht day? 1. 7450 2. 7500 3. 7530 4. 7600 Prgat (or, 2017), (e027, 2027) aN (097, 2017) 8 a) Prgst er dowd & 1. 2017 2, 100 3. Loovid 4. 100Vvz0 ‘The area of the triangle formed by joining the points (2017, 2017), (2027, 2027) and (2037, 2017) is 1 2017 2. 100 3. 100v70 4. 100020" If Sangeeta’s daughter is my daughter's mother, then how am 1 related to Sangeeta? Son is the only possibility Jaw is the only possibility Daughter is the only possibilty Son-in-law or daughiee HR PW My, My Ma MO TE ARATE Fy hy PA Te tee A Four males Mi,MzyMa,My end four females Fy Fy, Fy and Fare siting around a round table facing away from the table as shown in the figure below. [feach one moves three positions to his/her right and ‘then one position to the left then in which direction does Fy face?10, 1" Mm % Ms we FR a Fe is L Bast 2. Nonth-Rast 3. North-West 4. North Bat at Renita wt seen areh_ Ea at ae th 21 ata Prenat ar af sitet we wer SER GT wars Ye ourer |r seat Aye eer err firm ofr ate St 3 ate wenst y SI ge ee ory feel Sioa, gfe emer eer a8 wer area eee fare Pry oe 1, fer 2. ofer 3. eet a. whe ne Prof, Murthy likes: to let her students Strouse who their partners willbe: however, no pair of students may. work together for more than seven class periods ina row. Alice and Bob have worked together for seven class periods in a row. Calvin and Denny have worked together for three class periods in # row, Calvin does not want to work with Alice. Who should be assigned to work with Bob? 1. Calvin 2 Alice 3. Denny 4. None 1 10 2.15 3. ote ae a7 11. In.a group of 44 players, 26 play hockey, 24 play foottall and 24 play cricket. Eight of them play both hockey and football, 12 Play both football and cricket, and 5 play all the three games. How many play both hockey nd cricket? 110 213 3. None 47 12. een aay @. @ Hee ele areal aie a @ fry fase at fe at anefes daa ate y B fee ay)" = GO). a PTF ta wr aftart om a ae? 1 xS0any>0 2 {x< andy 0andy>0} & {eS 0andy <0} or{x 2 0andy> 0) 4. (2 Djorfy > Oj or fez 0andy>0} 12. Iris given that (a) =aifa>o Sy cy aictners Suppose ‘or ovo real numbers x andy, Gy)"= "OY. Then which of the following is necessarily true? 1. x>Oandy>0 2. { Oandy > 0} 3. (x 0andy 20) 4, (20) or fy 2 Oor fx 2 Mand y 20} 18.00 agWor wa ot aactes ate vad veer ArT Pea cell wet 81 ora after age Row are acater ofret ae ah ct oh wearer t?13, Number of times a research paper is: viewed and cited is shown in the plot. In which month was the percentege increase in citation more than the double of the percentage increase in view? 1 February 2 Apyil 3. May 4, June 14. Rew tert Fett a Reed wat adhe @? O.1, 0.25, 0.3, 0.2, 05, 06, 03, 04, 1.0, 1.2 1. 105 2 085 3. 075 4. 0.65, 14, Which of the following options is the best ‘choice for the missing number? 0.1, 025, 03, 02, 05, 06, 03, 4, 1.0,1.2 1, 108 2. 085 3. 075 4. 065 08, 15. Rar 54 Hl ana—t0 Blew fae 1S. Consider a number $4 expressed in a base different from ten. What is the base of this number system if its equivalent value in the decimal system ig 49? 1 a3 3 6 49 so, Ret ert & fed wegen Rar ser N 2.16, Which of the options is appropriate for the blank space? 17. In the diggram, what is the ratio of the total shaded arve (of the cirele and semi- circle) to the total area of the square and the rectangle? 19. 3 Two students are solving the same prablem independently. IF the probability thatthe ist one solves the problem is 2 and the probability that the second solves the problem is % what is the probability ‘that at least one of them solves the19. A ball is dropped ftom » height of 100 m, The ball after each bounce rises vertically by half its previous height (This means at the first bounce it rises by $0 m, by 25 m at the second lsounce and so-on). What is the vertical distance travelled by the bal between the frst and the fifth bounces? as 5 6 1 Sm 2% sr 333, 3 Bn 4, z 2 u 2 ae cis} a8 +8 20. Three sémi-circles are drawn incide « big irsle as shown in the figure. If the radius ‘of the two identical smaller semi-citcles is 7th of that of the big circle and the radius of the bigger semi-circle is twice that of the small semi-circle, what proportion of the big citcie's area is shaded? a 2. en oe pot ae ie i TT\PART B efiyana [ioHnou A et sa ager yy Bl vets ahr & sates & weet z vm th anemata wh RA Saatoher RAL Dinuclear anion [L(ON,O]* has wo bridging oxo groups. The geometry around ‘each iodine is 1, octahedral 2. monocapped octahedral 3. square pyamidal 4, pentagonal bipyramidal we dt ferge & aatertcer Heciaiebhct @ Kcro, & Raat at Baer ea A Mae rar anew at STP, ae 1. Seer site a ager oftafea at ort 1 2. wew-ggtagnet gear after sige aft B 3. aah 2enarés ar en BI 4, att areal a pti gat at waa BI) Using a double beam UV-visible speettophotometer, Beer's law fails for K,Cr,O; solution when 1. intensity of light source is changed 2, detectors not a photomultiplier ube 3,. cuvette of 2 em size is used 4. pHLis not kept same in all measurements Asics Setargs oer ra greta wait ai tite foe 8 hE 2 od ye 4 Le’23. 4, 25, 6 6 26, 27. ‘Trivalent lanthanide ion having isotropic magnetic susceptibility is i ea 3, Yo" 2 Gd 4 Cab, o ean Brae wee 8, ae & 1 afer sates: 2, Riker arefergs, a. Ue Bee 4 Genes ‘The structure of CaB, is close to that of 1. cesium chloride 2. nickel arsenide 3, rook salt 4. zine blende Co omeee meng or et we 1 HyBCO> [MaiCO}pI" > [CCO)| > [cong 2 IMCOM >{euCO] > IMmCO),|"> BCO 3. IMa(Co)eI" > 1h8-Co> [WiCOnT = {cxCO),} 4 ICKCO),]> IV(CO\L > HyBCO> Fxin(©O\" ‘The correct order of C-O bond length is 1. HaB.CO> [Mn(CO}]' > [CX{CO}]> [vcon) 2 [MCON > [enCOn] > [Mn(CO\ > 1B.CO {Mn{CO)]" > HsB-CO > [V(CO),]" > [CxCO}] 4, [CNCO}] > [V(COMT > HsB:CO> [MniCo),]" Zn. Ga, Ge AMT As, aeat % Be rake weer weet Sot aa Fae we 1. As 2 In 3. Ga 4. Ge Among the elements Zn, Ga, Ge-and As, the ‘one with the lowest first ionization energy is 1 AS 2 Zn 3. Ga 4 Ge anenefte safer a co! (sea fea Serer sm Fe TACT Ls By 3. 28 49 27. The total degeneracy of the ground term of ‘Co! (high spin) in octahedral geometry is 1.18 212 3, 28 a) 28, Poafafta wir & Re : Fe, fo, "ea tome | | Sod Se 3 fo) 4, Fe pag? ood Oo 28, For the following reaction 6 «© ro r a 0 eo] Nowy ones Se the structure of the intermediate is. 1] Sy 2:29, 29, 30. 0. M 340g ser M & seq er aga a aeersfta svagitst oy A gene aregt 29 DM. 8, mar ageroie aa 41 BME, at ME 1. Col" 2 Ni 3. Cu! 4. Coll High spin complex of 3¢ metal ion MI has a magnetic moment of 2.9 BM, in octahedeal coordination environment and 4.1 BM. in tetrahedral environment. The M ion is: 1. Colt 2. Nil 3..Cu" 4. Col KiCr0, (A) a8 K.MoO, (B) geagrae Stacat & fee edt deter FAT AE SU hag THA CB BL BRAT LMCTE FMT hug ATTA < BEL SHAT UMTS FAT haa AT A> BBL SHAT MLCTE AMT hau BT A> BB For electronic spectra of K.CrO, (A) and K,MoO, (B) the correct combination is L. transition is d-d and Jing for A B 4. transition is MLCT and Ps foF A> B No # 3 uw gia ® Pere ar attonar dar & A InetagT # NO) a gee 5. EPR eAetis sesh C. HOMOs & geteciet at argchert & 2p aifieet @ ater otearar & fae eat D. HOMOs 3 paagist ar ailevterr & 2p aiffest footer angie & Pree eri wht sent 1. aw A 2 Amr 2. BaD 4. A.BaUTC 10 31, 2 Removal of an electron from NO molecule results in ‘A. an increase in the v(NO) im the IR speetram Ban EPR active species CC. electrons in HOMOs being closer to the oxygen than o nitrogen 2p orbitals D. electrons in HOMOs being closer fo the nitrogen then to oxygen 2p orbitals ‘The correct answer is L Aonly 2. AandC 3. BandD 4. A,B,andC wan 12 Rawat @ 2 ag wef ar mies 4% Ru 1, & Biter Rarest # BT nae FE Re ARIE] TR | ae ER Hw Ret Afar (, ae & fae Rom 520 nm 8) RF Goan) oO | 20 @_ | 500 | a sees ca | | 30 e)= Cit} (a) = Gv) HCE) inde Ce) GED 3. @)-O1@)- Gi} ©) - (ME {)— GH) 4 Ga) Cvk (b) ~C); (e) C43) —G Consider the neture of solvents in column tnd the corresponding Amu for fy in various solvents given in column Ul, (for la vapor Regn is 520 nm). Match Column I with Column tt ‘Column T | Column tt Ging m0) |(@)_[ron-donor i a (6) weak donee Gi) [Strong donee) (@) [x electron donor 1h ‘The correct match is 1. @)—(s(b) ~ Gs ©) - Gd, (@)— Ge) 2 OG) GE Gi)-0 3. @)—O: () Gi: ) = Gv} (6) — Gi) 4. @) (iv) (= Gi: ©) —E(@)—G)3 33, co on ze ama gt omens Rarate tage @ coke ater & fe aft wun sta te (A)CuatT za det aftaraere 8 (0) Far Cog sriganeesn Br (©) An ¥itirataen & ote Cu et Pet eat aferetst ag samy & ofreantta ar ama fl (0) Zo at fat gat eA ry ToT, a aeata er ane El 1 aT) 2 ta ©) 3.886 (0) 4. (BERT ID) For the catalytic activity of Cu and Zn ‘containing enzyme, superoxide dismutase, ‘what is/are the corrcet statement(s)? (A) Cu and Zn both are essential (B) only Cu is essential (C)2n is essential and Cu may be feplaced by any other divalent metal ators (D) Zi may be replaced by any other divalent ‘metal atom 1. (Adoniy 2. (C)only 3. (D) only 4, (B) and (D) em atin & goumne weer A (M2) srert eur Roar 8 st Pe MO Rare ame A681 ue ga Sra EA aI HR, ow 1 gate 2 Fee 3. per 4, ater ‘Mass spectrum of a compound shows an [M2] fon peak that is about 4% of M’. This indicates that the compound has one 1. fuorne 2. sulfur 3. bromine 4. chlorine faves afte a sera gen sere ‘OH tBu. Bu 4: 1GFICN), 2:0, uw 2 SS tafe : i By 0: = = ESS Ce, . « ‘ ee an ‘OH 35 reaction is “ye ue OH = ss aces o> dys ae a ‘The major product formed in the following KaFe(CN), 20, os os Che aa Bu $84, ‘eu tad tei tBu, OH 48 EB a tBu ti mee. 7B Bu36. rafts aimet a ame Ae oa iter & ge Reretwcr a Be we 1 36, eiter gates < afte tte < Wits Casgsss < taitaes tats < Aes tate c>a 2. A>Boc 3.2 BDA 4 C>ASB 43. The correct order of mate of solvolysis in 80% ethanol at 25°C is 8 ae 8 A B ie LB>C>A 2. A> BC 3.C>B>A 4, CH A>B 44 Praia weer | a arene = A Tupac 44 45, 45 1, Beperpeet [1.1.1.0] Seta 2, Gigengeet (1.10.1) ett 3. ORRRRAY (L107) Bele 4. Demet (1.1.1.0) teat . TUPAC nomenclature of following propetlane is A + tieyeloft.1.1.0%}pentane 2 trieyelof1.1.0.1! pentane tricyeloft.1 1° 0'Jpentane = ricyelof.1.1.0"ypentane 1 2 4 feafataa cies & fae me ae e g © 56 |. Agar B aaomtiee é 2. Attia ¢ ar pafeiiiiee ey 3. Asrtthiite & ar pofeedate 81 4. ACE ft cer peat eae Br — species is # G6 A 8 Roth A and Bare aromatic Ais aromatic and B is antiaromatic Ais nonaromatic and B is antiaromadte Ais aromatic and B is homoaromatic Srafatea atte & este a eer ar num ea oda a aiftts freee 2. Ay site afer fee &47, 1, 48. 45 3. Acer B Wane ea a RRR E 4. Aca B Mat aay Hero & . The correct statement about the following compounds is Me Me A B . Aismore stable than B . Bis more stable than A Aaand B are equally stable A and B are both locked conformations sere 0, RR gaaqiae Beran ater %s, 8 & gen war ota cg A dee 1. am rat it eT et 2, Roem y eael ha ger ee 3, wa J Rat ae weE Ha EL 4. Tato Jere ave mae aE ene El In the pure Ramen rotational spectrum of '°O,, whose electronic ground state is “Sy, transitions to/from 1, even / levels are missing 2. odd Fievels are missing 3, all Jlevels appear 4. none of the /levels appear we niin & Re weithe oe se war &) ky AbB a 20 ka 2e%p at c® fae Ret seem aires My aT at srintarer at seag Prat A z 1. (Alfa) & erg 8 1 2. [AP BP & waren 81 3 (apopey 2 & aon 81 4: (ANB) & Fada F1 Elementary steps of a reaction are as follows 49. 49. si. si. If steady state approximation is applicable to C, the tate of product formation in the reaction is 1. proportional to [4] [8] 2. proportional to [A]?[2]? 3. proportional to [A}’/2pay/2 4, independent of {4][B] 6, rere aeeer & fae ae ate F 1 op ery 4% 4, asp ‘The term symbel for the ground state of Bs is 1, 13g 25 Lay As ep ee arsete Rewer ar aired ae £08) = paeee OS | oe Prag Fawr wT 1 3.0 x 2 4. [A Ganssian distribution has the finctional form f(@) = pie -0"/28 The variance of such cistibution is la 2. ab ae we serawle eauisr wa far week & chad gar t 1 ser 2 aR 2 4 aT ‘The change in entropy for a reversible adiabatic process is 1, maximum 3. 210 2, minimum 4. positive52, sf fiFar 58. Zu(s) + Cu (a9) = Fr?*(ay) 4 CuGs) fou aim ta Peet, 61.10. v ore ora #, Moser gah a fear & (F=96500 eoutor mol!) L212 kb mot" 2 4313 1d mot! 3. 212 Ki mol! 4210) mol" . The standard cell potential for the reaction En(s) + Cul*(aq) = Zn?*(aq) + CuCs) ls +1.10 V. The Gibbs free energy change during the reaction is (F=96500 coulomb mot") 1. 21.24) mot! 2. 4212 Kd mot"! 3. -212 KI mol" 4, -212 mot" Ifthe unit of the rate constant of a'reaction is L’mot"s'! the order of the reaction is Ld at 3.3 44 Fe Pr & qe isla! gee feearer & Paw agra aot areca & 17S. 2 1s, 3.45, 4. 45, ‘The lowest energy state of a 15125! electronic configuration, according to Hund? rule, is 1.35 2 18% 3.38; 4 1S, aan teeter 7 eer meatex [ef] ia 2 ih he 4 oe The commutator of & the Hamiltonian A, [z.Alis 16 Ee 2 th 3 4 oh 56.0 Sof at age Raa, 25 ky ator we Fag jax Aer A ge AReraer wr 25 CMe RN Te (tm A) & (At = 2500 J mol! Aa 1. 002 2.0.05 3. bas 4. 6.008 56. A'S g/L polymer solution is prepared with polymer whose molar mass is 25 ke. The “osmotic pressure (in aim) of this solution at 25°Cis (Consider RT = 2500.1 mot") 1. 0.002 2 0.05 3. 0.005 $0. 008 87. af em rece % eet sree atte get at ead od ge, ew aT wat whe aiteper ane aa, a age mer A Brest B a 2. ae 57. IFall the latice points of an FCC structure ae occupied by uniform hard spheres that touch each other, the fraction of volume ‘ovcupled is 2G wi 2 se = ae $8. og aca & Opteron ar se 1. fae sept & arene 2, BaeeRerae sep & ver svete 3, PR we eet ot ye ea 4 Pr ar ees ‘58. Origin of the colligative properties of a dilute solution is + Xolatility of solute molecule interaction of solute-solvent molecules zero enthalpy of mixing - entropy of mixing$9, Aneay ahr gate ar BT Fe TST UG ee te ee Ae = 59, The graph that represents the Langmuir Adsorption Isotherm is “| He ; = = 60. wo Ay SE eoIEH AUT HEH Bat few seh yarat ar wet rarer 8) 17 aTeT\PART C 61. bisly? Ae) Peer gat pr, A safes a mite sqrt & agratetaer # a seme Ak we aie AR gee eect a) agate A ti 24 nil * PR: = eee i Ni PRS . TA eB NADH @| FAB R | Coast 61. One of the products formed in the bist? ally) nickel complex catalyzed eyclo- dimorization of butadiene in the presence ‘of PR; is compound A given below. Identify its precursor. A 60, Correct match for the eoenzymes in Column A with their function in Column Bis 1 ates Column A| | Column] hl Ni Oxidation PRy ‘Acyl group transier | : Reduction. 3, Pails Quit, Rei 4. Pag Qi, Rai SI RISEM8—1AH—2ARIN He a ae ae A afterte fee th area i ae area gh an Brac Ae aT ae @ Who fe TSG, [ono 1B) Mech > (i) HF Nisa No [esc at @ Ae+ Avs |W TSORT AglAursy (Se Fe @ HPO [a aeBi, {peor att Pa 8 4. (a) (ij (b), fo) ~ Gi @)~ Civ), 2, @)-(i:)—Gid; ©) - GV: @-@- 3. (@)~(il), ©) Gs. OO, ~ Go) 4, (=i 6) -O;@)~ Gv) @) ~ 62. The transformation are given in column 1 ‘and reagent in column II, Match the items ‘of column I with those of eoluma IT Column | @ Mao, {mor | (b) MeCH > | (ii) Nain liquid [Mec]! | __NHS (Ag + Au > | GH) SOFT |__AgtAuks) | “¢superacid) | @@ HPO.» |G) Liguid Bet (POOH) | ‘The correct match is, i: (0) = Gid; I= Cs @)— 4 @) fii}; ©): 0), 58, Matearaay a aewraoT & Fae fresfafas saat oy Pra Ae: (A) dat alex ream A orate sraeun 3 ot ay ates eter @) ae eIGer Sa ater et ser EI (©) Siganeaetort ar 0,7 A aqeae a mer 81 (0) sets gratia sen tae ATO HUT jay rae sears et BI ae wet 18 64, L ORTO 2 @)RMO, 2. ALD ATC 4. @, OTTO) Consider the following statements for the oxygenation of hemocyanine: (A) oxidation sate of both copper atoms changes by two (B) iv becomes intense tive fom colouriess (C) dioxygen is reduced to 0,7. (D) the pon?en? bond forms between ‘gl oxy gen and copper atoms, The correct statements L (Abend (©) 2. (B) and (C) 3. (A), B)and (©) 4. @), (Chane (D) . PoaAaa amt (Ap) # cc sree rag THY ot aft TS (PICMG HAT (A), (PUPP)AG HO] B), [PUPP Hye fCAEN)](C), 1 O L ie} fracna® +[corcN),)* Ot Gh) Cobsps)sF*+ feotibipy) E> CoibipyhsT" + [Conbipy i] (iby (esti) FF + (CHELLO ME, 5 [CONH(HO)F + CHHLOEP * Bre" “OH (6) aR & Be EAE ote = ary ett Ei ‘ (8) eer Be eR whe ary eet Bi Be 7 (© eater (gern sa: OH BREET eater arate eat Bl oo) were in Ae 8 sere ee Raview ateatea ear 81 eet 81. The major product formed in the fol i |. The major product formed in the foltowing, LAqaTB: eee oxidation reaction is apap 4. Camp i, Urea-H,0. Comite eens AD mptng tree)? equations 1-Il: () [Fe(CN),]* + [Co(CN).}* > ii, HsO* [Fe(CN)]* + [Co(CN)} () Colbiny)al + {Co*(bipy s} > coat en IMD ( L)oP | = [Cr(H,O),] > [Co(NH,}.(HO)P + [Cr(HLO) FP fs (er) (A) Marcus equation is applicable t0 Fand I, (B) Mareas equation is applicable to only. Bee “OH il, Bro, CCl,a $3, Beaten afte a 4 zee oye aor Amel ones, MeCN Re Nan Gos ee i thienepent NM COL 82, The major product formed in the following reaction is 1, C1CO,Me, Ww i HO osimes sites { { t % | { AR oe 83, The major products A and B formed in the following reaction sequence are CC ee ge mae a ae ee orn ar i In oa 07 “ome a ne AN ae FN . : = ahi oth # nbs84, Roafiter aia at A sear sa See Amer Be) dye i+ ga Oo et ee ee Foe Ogee 84, ‘The major products A and B formed in the 25 me once ort 7 | a rose Be oes = Bone a. SRE 85, Structure of the intermediate A and the final product B in the following reaction sequence are (aba = dibeazylidene acetone) ‘ 1 one tee following reaction sequence are ee CHO prpseneooe CHC HORE hs , Kove va ae 2 “, 5 ee ee ee - ee 4 85. Preafafta aD war At weaadtt A af ier ae sir see Ba (aba = Srpa rates) Lie 0 = rong Rime = OT oS 86, faeafefas eutato état a ot wirataa 8 ae & con Rei eee my er cc 1, com Bo gaecrerefa cer state seer (212) grat diver 2. con wp eRediargfiae aera shatter BASRA [442] Wea eevee26 3. whe gates seat (4:2) erga eam Ade TT eaehettes sheer srpafte [202] areata 86. Mechanism of the following transformation involves 1. A [242] eyeloaddition followed by eon" rotatory elecirocy-lie ring opening 2. A [4+2] cycloaddition followed by “cont rolatory electrocyclic ring opening 3. A [4*2] eycloaddition followed by Cope rearrangement 4. A [242] cycloaddition followed by ‘dis rotatory electrocycli¢ sing opening 87. faeafatea attret ar NeOAcIACOH 3. A reacts faster than B to give ofs-1.2- diacetoxyeyclohexane 4. Brreacts faster than A to give’ cis-1.2- sceloxyeyelohexane 88, feniafaa afer at meradt A é aiewer ar facta caper sere Ei heat Bu, l =e S ae a ferme sme & fe we OTs OTs oc he 1 trans 22a terrtmerStT ae Re 8 ft ora Age ofafrer For 81 2. wean 2-arptcrrdergrattrter 2A Fe A A oer was APATCT ae FI 3. cic a-sretreraatengeateata 2a & Re 8 #1 308 Aas HBB se 1 4, cio 2erpteterethampectiater Sot Fare A ft arte wd aeer weer 1 87. The correct statement about solvolysis using NaQAc/ACOH of following compounds is fat a "OAc B ‘OAC 1, A reacts faster than B to give trans. 1,2-diacetoxycyclohexane B reacts faster than A to: give rans: 1,2-diacetoxyeyciohexane 3 sS an s 88. ‘The structure of the intermediate A and the major product B formed in the following reaction are ay 22g * %2 80.ue athe a fae Rhee ae ‘Preafattr &: SHNMB: 87.9 (d,J = 8 He, 21), 66 (d= 8 Hz, 2H), 43 (g,./= 6 Hz, 2H), 4.0 (br s, 2H, 1,0 faa, 14 (4 J= 6 He, 3H) Mass: mlz 165, 137, 120, 92 tft & eet dew 8) 1 cox Hn ° 5 3. Cc Nie 3 4 ex Ni 89, A compound shows following spectral data: "HNMR: 87.9 (4, J=8 Ha, 21), 6.6 (d, J=8 Hz, 2H), 4.3 (@, J = 6 He, 2H), 4.0 (brs 2H, D,0 exchangeable), 14 (1, = 6 Hz, 3H) Mass: miz 165, 137, 120,92 ‘The correct structure of the compound is 0 L 2 An HN 90, The major allylie eleohol A:end the ester B formed in the following reaction sequence are92. Daag # Menifa aftetel a afer sera ec) 1 aitiede: |, tater Hr (E10), P(O)CH,COsEt, NaH Poe: 3, 91. The major products A and B formed in the following reaction sequence are 92, Reaction of Deplucose with following 2 iuoamusc: , moran reagents produces A ® ¢ wo mores Reagens) 1. Acetone, H's 2. POC, 3, HO (E10), P(O)CH,CO,E!, Nall 0. = Ph- P io PD lessen (eet eo om Ph. i ; 0 % bigs D Be 6 2S h same ee me ° Ve Eto, oe“Oe | | 4 | 93. Rreaforaa arte [2:2] engeat eat wisi So Sere (TS) FHT eno gary Reo & afer & Be ae eet #8 ‘i : ch aaene coe pas LL YStatas Meo ihe ube todas thee tene 93. For the following thermal [2+2} Sasi cee ke eee statement about Transition State (T'S) and preference for endo product formation is. + -O — of ; - ie 2, TS: metas -Bu> i-Pr>Me 3. TS: tata; Me >i-Pr> t-Bu 4. TSimctta: LBU> EPr> Me 94, Paraffin sor Re spr sere ATID Bi GX 10 nore oe * hes #e 00°C — [ee Oko OX sf 4, [Ark one BK Aon 94, ‘The major products A and B formed in the following reaction sequence are Ch res | sent > we “ano * oe woe tact cea [Coe 8 OT Pata per sere HH : : Or ees95. The major produets formed in the following photochemical reaction are 9 bv Celle Coie ou in ee (epee 96, cise 37a crans Reet 8 Pah a at 31d am se Pei ee tore FET 95% cis ARM 79% trans SAAR aT TOT ea Ber & sats 1. one oY area mins Preertr afte Rr ti 2. setore arte oe ci fRerater sre rans Pree on Prat Ti afte & 3. cis FRE rome Reet & FB oT sroean & aieaort fest F1 30 4. cise FAT ans Rete Pr Fee sca srreard Piet sat Eee We eet I 96, Irradiation of either cis- or sris-stilbene at 313 nm results in the formation of a mixture 0f 93% cis and 7% trans olefin because 1, trans-stilbene is more stable than aas-stilbene 2. the extinction coefficient of wrans= stilbene is greater than cir-stilbene ‘at exciting wavelength 3, the transition state structures of efs- and trans-stilbenes are different 4, the triplet excited states of ci3= and trens-stilbenes are at different energy levels 97. Paes amar at Rei qe reer cote ter B) Zz 97. The major heterocyclic compound formed in the following reaction is 1. =—s0,Ph &y heat ce Zt ewe ae Mech1 |G soxn 2 | Qs0m 2 Era a 2 'S0,Ph Boe 4] ON é 'SO.Ph 98, Breen athe war A after eer wesrg acer Bel BH wtipenm BF a, 2.GacO, “= |S +e oe belt ee | % O |= oF oh Beal [oO] 98. The major products A and B formed in the following reaction sequence are 2, sbee NaH OH 1 Tel eawiv) PY & OH — 2 esc, 31 1 NH, eee Nani 1 ort Lt EONE Nog 2 F ort ae EtONa NOs NO; 1 k= he STIG > hy 2. kya AUT? by 3. KP AAMT > hy 4 ka ky BUTE > by 99. The correct order of rates for the following, reactions is 1 NH, hy Nani c NHp a1 et Ld EtONa No, NO. F OE Ki EONS NO NOz k.>keand ky> ke ki? keand ke> ky p> ky and les > ky ky> kyand ky > ky 100. Srafatae witter & senz & fe arom AH feat omy sterit ote arent pw #8 a6 NMR aT ae et far BI Hes Ha alRlor] 1 Pols Qe; Rolls Seiy 2 ii Rie $i 3. Pov Qi Ra a Pi Qi 100. The correct match of protons in Column A with the 'H NMR chemical shifis. in Column B for the product of the following reaction is cai Spee] Sl 32 101, 102, Gteaeaa AR wa mT AREA SoM & See Sere Teena es! & aw sfaa awearetiga ai wen ag 1. Hs 282}-26( 162\HAVA2)) 2 Is 1)25°2}42s()ist2h lal A2}- Biya) 2, ThaC2se}-2510 92H) [a0)A2}+A Hat2)) 4, [1s D252}2CD 12a 2D] Which of these is not. a suitable unnormalized wave function for the excited 1s'2s' electron configuration of the helium atom? 1, (190192502261 LANA) 2, [19(1)2s(2)*29(1)152)]o(1) 80 Avo) 3. (Is(1)262)-25C1) 1521 {a(1A2)+A1)o2)) 4. [19(1)28(2)+2s(1)1s(2)Ila(1)R2)} Me HSS Lh Gta gee A a nat rae Ay argst wT est ar afir (ar zh 2a, Pre oe eat gr Ra ABO, A Wieg TAR De® DH oes et srat 8h 8. (2,57 2,1) Sa eae een area we fi ©. atl sat aR Be ord Bate (2.1) AA HET (12) eee a act ates ea baat st eR we om f 3th (21) Fae A orton (12) een Sot ar ott Bh ot att avert E L Aare 2, amme 3 Bane 4 Amb3 102, ‘Two opposite sides (in the y-direction) ofa 108, CE FT d= oy +3y See AE wet ‘square box of side Z are slighty stretched Consider the following four statement ‘A. The point group changes from Diy 10 Dix B. The (1,2) and (2,1) energy levels remain #0 gy BTR Mea anger Feet § tert Saget are wa: & ger & 8 paerear a ar $ ater sot ti soubly degenerate, ©. Both the eneray levels are lowered and 5 (6.+98,)a0 the energy of the (1.2) level is higher 2. (E,438,) than that of the 2,1) level, D, Both the enengy levels are lowered and the energy of the (1,2) level is lower than that of the (2,1) level ‘The two cortect stalements are: 1, AandB 2, AandC 3, Bande 4. AandD 3. (E498, ia 4. 6,438,)/10 104. A particle is in a state $= iy. 4 3 ys, whore Ww ond ¢ ate eigenfunctions of the Hamiltonian of the particle with eigenvalues #, and 3, respectively. ‘The average energy of the panicle inthe sate 6 103. cH oneth ava fae ua ere 3. > strat ome one dae oe 1 (6, +98, )/t0 weteairada ats ¢, ox ee 2 (6, 438,) AUS He & Taw eet es 3 (B+98,)r4 f= Stra esdedmenle oy*+ 2) 4 (G+38,)/10 Set mao A ea, aw sbvte ares mn By. BRT p, Wer ome Bi ge 5 a * seivatragte wfisnet a Garr a a ae ‘eet £6) ser efit sift sat stent ED & & fav Pewfatta at at aa ai ‘tan one Fhe he 1 qe h itedaie & tena 3, <3 sen & ante, 6) Rete ameter a 2 5 See Hor 8) 103. Consider a model system of five non= 2. ha aor: Se seme. Bi interacting fermions in a ‘single 3. dimensional harmonic oscillator. The Hamiltonian of a single particle is Pepa casts s BWI Pa bne' ees where m is the mass of the particle, @ is the angular frequeney, f,, and p, are the momentum operaiors, The ground state energy of the system of S non-interacting fermions is 3. FQ) at xprere gar areeam t1 4 ED +E eee Pasar oer sat & fe scare aint 105. Which of the following statements on ground state perturbation theory, involving the zeroth order energy £(, fist ordet senigy correction {and second order energy correction EY, is false? Wea 2% 45 1. Bf! is the average value of perturbation 372 oe ‘operator with respect te the ground state ae alae of the zeroth order Hamiltonian, Sho Zhe 2. RiP is necestarily negative, 8/11 RISEM8—1AH—338 3. Eis necessarily negative. the slope and the intercent of the plot 4. BP «Bis an upper bound tothe between {and = are 107s and 10° M's, ‘exact ground state energy, respectively. IP Es-10* M and 2 = 1090, the value of k; will be close to hy units of 06, UR SenaOIT sate a vised ser Ms) [ris the rate of the reaction and Eq aadt set @ after sist & ae is the Initial concentration of the enzyme) Baw o212RT to ow aN we Gf a Lae sue amit gens rsa after & fae Ee ee aoa xii A gear A et ger 81 108, 100 em? & amgrt % 25°C uy efter D: Se a4 Rar & fare area fant 3, & re eerinte are wa am Mae cae A eS (2610s tot" HC) 1 ao! 2 oxo 1, 3.8107 2, saxto* 3. Ito 4, W107 3. 78x10” 4. 98x10" 106. Difference besseen activation energies of 108, Translational partition fimction of «Dy the reverse and forward steps of a molecule confined in a 100 cm* vessel at reversible reaction is 9.212RT. If the pre- 25°Cis exponential factor of the forward reaction Ieee k Wis er Be OTe is double'that of the reverse reaction at the See ae eas et ae 1S) same temperature, the equilibrium constant 1. 3.82107 2, 58x10" for the reaction a that temperature will be 3. Tae 4, 98x10" (ini0= 2.303) b bett 2, 2xi0t 109. dt fiver ant oe Coe sree st orate a ie (ora kya after rar ate 2 at Bi Ler erage ater [ar OT 8 Besaes Mem j__1 25 __| 40 a fg aat st aa co 8 afte axe set (em’) SEAT fetaor ot waar 8, axe meq anes at eet 1. 50 2.109 sear 1 M's Bf Se 190: 20). = 1000, 8 AT ky (Mt ‘afte #) or at faek fone er, ae bh 109, The volume (em') of CO adsorbed on Ce pe eee charcoal 273 K) al two ifeent pressures o : ‘is given below Par area Ft) = 1, bet 2, Ixlot Pe 140 3. bxto* 4, 1x10 Vicm*) 107, For an enzyme-substrate reaction, Assuming Langmuir isoheim, the ky maximum possible volume (ciz') CO that reeees canbe adsorbed is ke 1. 50 2. 100 = 3. 150 4, 200 ESAE+P,110. C0; (ip-1) EPR Stag # eget seen 3 ay 27 49 116. The number of fines in EPR spectrum of COs (o=1is 1 25 37 49 111, Reenter #9 ot aro aaIRR weg A one , ae 8 1. eB 2, tia 1. mages 4, bare TILA symmesic wp molecule, among. the folloving, i 1. ethylene 2, allene 3. butateiene 4 hexatriene 112, wept ay 3 ogre gage va ® REL OR, AEA, 112, The allowed electronic transition in fluorine riclecale is 1.2; +E 3.2, 901, LUE, 43554, IB.eatee aire eer off HeL+D; > Det + HO % Fre co! Ha safertar 81 (fan ange ates, em! A ait enters a eu &) HOT] Be | ap. 2685.) 960"| 1990 | 3627 1. 258 2. 4258 3-139 4, 4129 113, Assuming harmonic approximation, the energy change for the Dy > DCL-+ HO in env frequency data in ens" is given in the table below). Te a (act | 285 | 380 35 1-258 3. 129 1a. wm ear a & FT y= 1 Mp= 0 Fen = 2; My= 0 seaeemat & arem per deer & Ree ee weer airorr argh wore fers eee B, ae 1. [Fees? a¢acoste — ae 2, [fleos? 0(3cos*6 — 1)sinddo 3, [feos @Ceos%9 — 1)sinodo 2. 4288 4. +129 4. fF ens 6(3c0s%0 —1)sintao 114. The transition moment integeal for a rotational trensition beween J = 1: M)= 0. and J = 2; M,= 0 states for a diatomic ‘molecule along the z axis is proportional to 1, feos? @3cos?0 — 140 2. ff cos? 6(3cos?6 — 1)sinodo 3. [feos @(Bcoste —1)sineao 4, cos 6(3c0s%6 ~ 1)sin?an 11S. we sEMATeRga op watt snfdest A wae 1 FP toa, they, ip, oH & 2 Sct BP HB, 8 tet AP 4 do. 480,,, 118. One ofthe correct normalize sp" hybrid orbitals is Se 4 Ve 5154 5% rp bP ap, ’ 4 2 fot Bor, Fog, 2 2 : 3 Ant hes, 4, $0,642,116. stat Pe 300 K, ae ar OT gale ger meat afsaar far 2xtO* KART Se10% ber" #1 320K FAT 1 BRR oe & Faw (Z) ebor 3) eto 124 21g 3. 08 4.120 116. At 300 K, the thermal expansion coefficient and the isothermal compressibility of feuid water are 210K"! and 5x10" bar respectively. @), (in kbar)for water at $20 K and 1 bar will be 124 2 12 3. 06 4. 12.0 17. se Re sree ante & Shere ata ay eats soreness Bi se HeaT eqaeN #1 GRU TE eA A wT ama 8, ae : 1, Bearer ar ae oy et 2, fren a aaa oe araert 3. rare ar ret ae aE 4 frenr ar at we wet 117. In the phase diagram of water, the solid: liquid boundary has a negative slope. The reason for this unusual behaviour can be traced to decrease in 1, density ofthe system on melting 2. volume of the system on melting 3. entropy of the system on melting AL enthalpy of the system on melting 118, aI IH PutalRriagASBADIAGLO) FT ‘awa om are St tor a am aA oitaet #°(Volt) = 001 ~ 1 10-4¢7 298) 2 10°40 — 290)" # sa 8 fhe mr Ren 28k ae SEG cg OK Inol') ae rte Ga mot!) & 1 9.65 arn 3.4 2 380AU-965 3-13. am-768 4 re8zen-183 118. The sundard cell potential of cell, PUH BEB r(aqAgens)Ag(s) was 36 120. 25°C 5 OH Fe measured over a range of temperatures, and the data was fited as E%(Volt) = 0.01 — 1 x 10-*(7 — 298) - 2x 10-*(7 — 298)? ‘The standard reaction entropy (IK ‘inot") and enthalpy (kimot) at 298 K are 1. 9.65 and-3.84 2 384 and 9.65 3, “18.3 and 7.08 4. 168 and-18.3 19. eH arfere toc Seem er jn) ae x FRI (4 = 0.134 nm) ar Bada oe a gar ay & atm Bi few at oat 4410! kg nr? | ore aes ore eat 12 2 3 8k Aw 119, The (002) plane of an elemental FCC crystal diffiacts X-rays (1 = 0.154 nm) at Hsragg angle 90°, ‘The density af the crystal is 410" kg m*. The atomic weight of the elemental sotidis 122 a as 3. 88 4 66 ®& fae ar faseitater SEIU Co" & Reams B Peer wer 3) $0 MeO” FG) BING Pe ara Brome 8, oor sevent tora Bara & ome [V Ajeet wearer: (RTE 8 spare = 0.77V logis 307) 1 0734 aero.77 2. O77 RRR G385 3. OTT eer T3 4. 0385 a2T0.367 120, A solution oF Fe is irate potertiometiay using Ce" solution at 25°C. The emf (in V) of the redox system thus formed when, (3) $0.% of Fe" and (ii) 80% of Fe are titrated, would respectively be Given Bp,o+y924 = 0.77V,logio2 = 0.301 ) 1. 0,734 and 0.77 2. O:7Tand 0.385 3. 0.77 and 0.734 4. 0.385 and 0.367