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Nuclear Energy
Atomic structure
Atom consists of a relatively heavy, positively charged
nucleus and a number of much lighter negatively charged
electrons. Electron exist in various orbits around the nucleus.
The nucleus consists of two sub-particles known as nucleons.
Atom = positively charged nucleus (nucleaons) + negatively
charged electrons.
Power Plant Engineering (Nuclear power plant) Dr. Bodius Salam
Department of Mechanical Engineering, CUET 2
electron
proton
neutron
H2 Heavy Helium
hydrogen
(deuterium)
Nuclear symbols
Z XA
Binding energy: The nuclear force acts only when the nucleons
are very close to each other and binds them into a compact
stable structure. The energy associated with this force is
known as binding energy.
To disrupt a nucleus and separate it into its component
nucleons, energy must be supplied from outside.
Let
M = mass of an atom (mass of nucleus + electrons)
mn = mass of neutron
mH = mass of proton + electron
N = neutron number (A – Z)
Then binding energy, B = Nmn + ZmH – M amu
Valence electrons: Electrons that orbit in the outermost shell of
an atom are known as valence electrons. The outermost shell
is called valence shell.
Isotope: Isotopes of the same element have the same atomic
number (Z) but differ in mass number (A).
Uranium isotopes
Atomic number, Z = 92
Mass numbers, A = 227 – 240 (14)
Natural uranium is composed of
99.282 % 92 U 238
Radioactive decay
All isotopes of heavier elements starting from atomic number
Z = 84 posses weak binding energy/nucleon and have the
tendency to emit radiation until a more stable nucleus is formed.
This new nucleus is called daughter and the original nucleus is
called parent. This is a spontaneous disintegration process,
known as radioactive decay.
Radioactive isotopes are known as radioisotopes.
Radioactivity means a radioisotope continuously undergoes
spontaneous disintegration, usually with the emission of one
or more smaller particles from the parent nucleus, changing it
into another, or daughter nucleus. The daughter may or may not
be stable, and several successive decays may occur until a stable
isotope is formed.
Radioactivity is characterized by either decrease in mass or
liberation of energy (in the form of KE) accompanied by
electromagnetic radiation.
0
0
Gamma ray () 0
0
0
Neutrino () 0
4. Electron capture
A nucleus captures an orbital electron from the orbit or shell
nearest to the nucleus. Electron capture is accompanied by x-
ray emission from the atom.
84Po
200
+ -1e0 83Bi
200
+ 0
0
5. Gamma decay
Gamma decay is the emission of electromagnetic radiation from
an unstable nucleus. Gamma decay does not alter atomic or
mass number.
92U
235
92U
235
+ 00
Unit of radioactivity
The original unit for measuring the amount of radioactivity
was the Curie (Ci). It was defined corresponding to
measurement of the activity of 1 gm of Radium-226.
1 Ci = 3.615105 radioactive decays per second (dis/s)
In SI system Curie is replaced by Becquerel (Bq) and is defined
as 1 radioactive decay per second.
1 Bq = 1 dis/s = 2.70310-11 Ci
Z1 K A1 Z 2 LA 2 Z 3 M A 3 Z 4 N A 4
A1 + A2 = A3 + A4
Z1 + Z2 = Z3 + Z4
Nuclear fusion and fission
In fusion, two or more light nuclei fuse to form a heavier
nucleus.
In fission, a heavy nucleus is split into two or more lighter
nuclei.
In both, there is decrease in mass resulting in exothermic
energy.
Fusion
Energy is produced in the sun and stars by continuous fusion
reactions.
41 H1 2 He 4 2 1 e 0 Positron
(+vely charged electron)
Fission
Unlike fusion, which involves nuclei of similar electric charge
and therefore requires high kinetic energies, fission can be
caused by the neutron, which, being electrically neutral, can
strike and fission the positively charged nucleus at high,
moderate, or low speeds without being repulsed. Fission can
be caused by other particles, but neutrons are the only
practical ones that result in a sustained reaction because two
or three neutrons are usually released for each one absorbed in
fission. These keep the reactions going.
Fissionable isotopes
235 239 233
92U , 94Pu , and 92U are fissionable by neutrons of all
energies.
238 232 240
92U , 90Th , and 94Pu are fissionable by high-energy
neutrons only.
92 U 235 0 n1 54 Xe140 38 Sr 2 0 n1
94
Xe (Xenon)
Sr (Strontium)
Xenon
nucleus
Neutron lost by escape
or consumed in
nonfission reaction
neutron
235
92U
Strontium
nucleus
Neutron energies
Kinetic energy of a neutron,
1
KE n m n V 2 V = speed of neutron
2
Fertile material
The material which absorbs neutrons and undergoes
spontaneous changes which lead to the formation of
fissionable material. 92U238 and 90Th232 are fertile materials,
they absorb neutrons and produce fissionable materials 94Pu239
and 92U233 respectively.
Breeding
The process of producing fissionable material from a fertile
material by neutron absorption.
92U
238
+ 0n1 92U239 + radiation
92U
239
93Np239 (Neptunium) + -1e0
93Np
239
94Pu239 + -1e0
90Th
232
+ 0n1 90Th233 + radiation
90Th
233
91Pa233 (Protactinium) + -1e0
91Pa
233
92U233 + -1e0
= 7.95×1010 W.s ◄
= 7.95×104 MW.s ◄
= 1325.3 MW.min ◄
= 22.09 MW.hr ◄
= 0.92 MW.day. ◄
Fig.: Reactor
Reactor control
Reactor control To start power
To increase
To decrease
To turn off
Methods:
(i) Use of control rods: Control rods provide the ability to
change the amount of neutron absorption. The control rods are
operated by control-rod drives that can move them in and out of
the core around a power equilibrium position which is usually
a partially inserted position.
(ii) Use of chemical shim in addition to control rods:
Radiation hazards
(i) Ionization: radiations ionize tissues into which they
penetrate, resulting in complete damage of tissue.
(ii) Displacement: atom in the tissue is displaced by
neutron and -radiation.
Power Plant Engineering (Nuclear power plant) Dr. Bodius Salam
Department of Mechanical Engineering, CUET 18
18
Waste disposal
One of the major problems in the nuclear power plants is the
disposal of waste products that are highly radioactive. They
emit large quantities of rays and these high-energy rays
destroy all living matter through which they pass. The
radioactive products of 400 MW power station would be
equivalent to 100 tons of radium daily and the radioactive
effect of these plant products if exposed to atmosphere would
kill all the living organisms within an area about 100 square
miles.
Wastes require strong control to ensure that radioactivity is
not released into the atmosphere to avoid atmospheric
pollution.
Wastes form: (i) Liquid
(ii) Gas
(iii) Solid
Liquid wastes:
Ways of disposal
(i) Dilution: Liquid wastes are diluted with large
quantities of water and then released into the ground. This
method suffers from the drawback that there is a chance of
contamination of underground water if the dilution factor is
not adequate.
(ii) Concentration to small volumes and storage:
When the dilution of radioactive liquid wastes is not desirable
due to amount or nature of isotopes, the liquid wastes are
Pressurizer
In PWR primary loops, the coolant is maintained at a pressure
around 155 bar greater than the saturation pressure
corresponding to the maximum coolant temperature in the
reactor. This avoids bulk boiling of the coolant and keeps it in
the liquid phase throughout the loop. Because liquids are
practically incompressible, small changes of volume caused
by changes in coolant temperatures because of normal load
changes cause severe or oscillatory pressure changes. These
may be quite unsafe when the pressures increase. They cause
flashing into steam and consequent disruption of the reactor
nuclear characteristics and possible burnout of the reactor fuel
elements. They cause cavitation when the pressures decrease.
For these reasons it is necessary to provide a surge chamber that
will accommodate coolant (also moderator) volume changes
while maintaining pressure within acceptable limits. Such a
chamber is called a pressurizer.
Vapor pressurizer
Gas pressurizer
Vapor pressurizer
A small boiler
Liquid in the pressurizer is the same as the primary
coolant.
It is maintained by controlled electrical heating at a
constant temperature and consequently a constant vapor
pressure above its full surface.
The pressure in the pressurizer is same as that of the
primary coolant at the junction between the pressurizer and
the hot leg of the primary loop.
The pressurizer temperature is higher than the primary
coolant temperature.
Gas pressurizer
A large volume of gas situated above the primary coolant
at the junction between the pressurizer and the hot leg of
the primary loop.
The gas not miscible with the coolant.
Limited to use in low-pressure systems.
Power Plant Engineering (Nuclear power plant) Dr. Bodius Salam
Department of Mechanical Engineering, CUET 26
26
Re circulation liquid
Re circulating ratio, R
Saturated vapor
g m
m
xe = d
i m
m i
m m
f m
m 1
R= = i g = i 1= 1
g
m g
m g
m xe
x e 10-14
% R 6-10
Energy balance
m i hi = m d hd
f hf + m
im
= (m d )hf + m
d hd
d
m
hi = 1
m
h f d h d
i
m i
m
=(1 x e )hf + x e hd
Power Plant Engineering (Nuclear power plant) Dr. Bodius Salam
Department of Mechanical Engineering, CUET 29
h f h i
29
xe ◄
h f hd
Advantages
Gases easy to handle
Low macroscopic neutron cross section
Plentiful and cheap (except helium)
May be operated at high temperatures without high
pressurization.
Disadvantages
Lower heat-transfer and heat-transport characteristics of
gases, which require large contact surfaces and flow
passages within the reactor and heat exchanger.
High pumping requirements.
Fast-Breeder Reactor
Liquid metal fast breeder reactor (LMFBR)
Fast reactors are those whose neutrons are not slowed down
by a moderator.
Because sodium and other liquid metals suffer from high
induced radioactivities, and are generally chemically active,
intermediate coolant loops are used between the primary
radioactive coolant and the steam cycle. The intermediate
coolant is usually also a liquid metal, often Na or NaK. The
intermediate loop guards against reactions between the
radioactive primary coolant and water.
References
M. M. El-Wakil, Powerplant Technology, McGraw-Hill Book Co., Singapore, 1984.
R. K. Hegde, Power Plant Engineering, Pearson, Delhi, 2015.
W. J. Kearton, Steam Turbine Theory and Practice, CBS Publishers & Distributors, India, 1988.
Web: http://www.world-nuclear.org/ (18/12/2016)