PHY. + INO.

CHEMISTRY

DPP NO.

TARGET : JEE (Main + Advanced) 2016

01
Course : VIJETA (JP) Date : 02-04-2015 DAILY PRACTICE PROBLEMS

T E S T I N FO R M AT I O N
DATE : 19.04.2015 SCHOLARSHIP TEST

Syllabus : Complete IX Syllabus

This DPP is to be discussed in the week (02-04-2015 to 04-04-2015)

DPP No. # 01 (JEE-MAIN)
Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60,40]

1. In the reaction A(s) + B(g) + Heat 2C(s) + 2D(g) equilibrium is established. The pressure of B is
doubled to re-established the equilibrium. The factor by which D is changed is
vfHkfØ;k esa A(s) + B(g) + Heat 2C(s) + 2D(g) esa] lkE; LFkkfir gksrk gSA B dk nkc lkE; dks iqu% LFkkfir djus
ds fy, nqxquk fd;k tkrk gS D fdl dkjd ls ifjofrZr gksxkA)
(A) 2 (B) 3 (C*) 2 (D) 3

PD2
Sol. Kp   PD final  2 PD initial
PB

2. The e/m ratio for cathode rays

dSFkksM fdj.k ds fy, e/m vuqikr
(A*) is constant
(B) varies as the atomic number of the element forming the cathode in the discharge tube changes
(C) varies as the atomic number of the gas in the discharge tube varies
(D) has the smallest value when the discharge tube is filled with hydrogen.
(A*) fu;r gksrk gSa
(B) ifjofrZr gksrh gSa tSls gh foltZd ufydk esa cuk;s x;s dSFkksM es mifLFkr rRo dk ijek.kq Øekad ifjofrZr gksrk gSA
(C) ifjofrZr gksrk gS tSls gh foltZu ufydk esa xSl dk ijek.kq Øekad ifjofrZr gksrk gSA
(D) lcls de eku gksrk gSa tc folZtu ufydk dks gkbMªkstu ds lkFk Hkjk tkrk gSA

3. The time taken for a certain volume of a gas 'X' to diffuse through a small hole is 2 minutes. It takes 5.65
minutes for oxygen to diffuse under the similar conditions. The molecular weight of 'X' is.
,d xSl 'X' ds fuf'pr vk;ru dks ,d lw{e fNnz }kjk folfjr gksus esa yxk le; 2 feuV gSA leku ifjfLFkfr;kssa esa vkWDlhtu
xSl ds folj.k esa yxk le; 5.65 feuV gSA rc 'X' dk eksyj nzO;eku gSA .
(A) 8 (B*) 4 (C) 16 (D) 32

rX MO 2
Sol. rO 2 = MX

/2 32 5.65 32
 / 5.65 = MX , 2 = MX , MX = 4

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4. The Bohr orbit radius for the H–atom (Z = 1) is approximately 0.53 Å. The redius for the first excited state orbit is:
H–ijek.kq (Z = 1) ds fy, cksgj d{kk fd f=kT;k yxHkx 0.53 Å gSA rc izFke mRrsftr d{kk voLFkk ds fy, f=kT;k gksxhA
(A) 0.13 Å (B) 1.06 Å (C) 4.77 Å (D*) 2.12 Å
Sol. 1st excited state means n = 2
1st mRrsftr voLFkk dk vFkZ gS n = 2
 r = r0 x 22 = 0.53 x 4 = 2.12 Å

5. The number of H+ in 1 cc of a solution of pH = 13 is ?

pH = 13 ds 1cc foy;u esa H+ vk;uksa fd la[;k D;k gS \
(A*) 6.023 x 107 (B) 1 x 10–13 (C) 6.023 x 1013 (D) 1 x 1016
Sol. pH = 13 means [H+] = 10–13 mol L–1
pH = 13 dk vFkZ [H+] = 10–13 mol L–1
or 10–13 x 6.023 x 1023/ 1000 H+ ions/c.c. = 6.023 x 107

6. Given that : Gf° (CuO)= –30.4 kcal/mole

Gf° (Cu2O) = –34.98 kca/mole T = 298 K
Now on the basis of above data which of the following predictions will be most appropriate under the standard
conditions and reversible reaction.
fn;k gS % Gf° (CuO)= –30.4 kcal/mole
Gf° (Cu2O) = –34.98 kca/mole T = 298 K
vc mijksDr vkWdMksa ds vk/kkj ij fuEu esa ls dkSulk vuqeku] ekud ifjfLFkfr;ksa o mRØe.kh; vfHkfØ;k esa lcls mi;qDr
jgsxkA
(A) Finely divided form of CuO kept in excess O2 would be completely converted to Cu2O
(B*) Finely divided form of Cu2O kept in excess O 2 would be completely converted to CuO
(C) Finely divided form of CuO kept in excess O 2 would be converted to a mixture of CuO and Cu2O (having
more of CuO)
(D) Finely divided form of CuO kept in excess O2 would be converted to a mixture of CuO and Cu2O (having
more of Cu2O)
(A) O2 ds vkf/kD; esa j[kk eghu pwf.kZr CuO iw.kZr% Cu2O esa ifjofrZr gks tk,xkA
(B*) O2 dsvkf/kD; esa j[kk eghu pwf.kZr Cu2O iw.kZr% CuO esa ifjofrZr gks tk,xkA
(C) O2 ds vkf/kD; esa j[kk eghu pwf.kZr CuO, Cu2O o CuO ds feJ.k esa ifjofrZr gksxk (vf/kd CuO ;qDr)
(D) O2 ds vkf/kD; esa j[kk eghu pwf.kZr CuO, Cu2O o CuO ds feJ.k esa ifjofrZr gksxk (vf/kd Cu2O ;qDr)
1
Sol. (B) Cu2O(s) + O (g) 2CuO (s)
2 2
G0reaction = [2 × (–30.4)] – [–34.98] = – 25.82 kcal
and – 25.82 × 103 = 2.303 × 2 × 298 logK
 K  1019, a very high value, hence reaction will be almost complete with a trace of Cu2O.

7. Consider two slightly soluble salts, calcium carbonate and calcium sulphate. On addition of HCl to above
salts solution The correct statement for above solution will be : -
nks vYi foys;h yo.k dsfY'k;e dkcksZusV rFkk dsfY'k;e lYQsV dk voyksdu fdft,A mijksDr yo.k foy;u esa HCl feykus
ij mijksDr foy;u ds fy, ;gh dFku gksxk %
(A) The solubility remains same after addition of HCl
(B*) The solubility of calcium carbonate increases while that of calcium sulphate is almost unaffected.
(C) The solubility of calcium sulphate increases while that of calcium carbonate decreases .
(D) The solubility of both salts decreases due to addition of HCl.
(A) HCl ds feykus ds i'pkr~ foys;rk leku jgrh gS
(B*) The solubility of calcium carbonate increases while that of calcium sulphate is almost unaffected.
dsfY'k;e dkcksZusV dh foys;rk c<rh gS tcfd dsfY'k;e lYQsV dh foys;rk ges'kk vizHkkfor jgrh gSA
(C) The solubility of calcium sulphate increases while that of calcium carbonate decreases.
dsfY'k;e lYQsV dh foys;rk c<rh gS tcfd dsfY'k;e dkcksZusV dh foys;rk ?kVrh gSA
(D) The solubility of both salts decreases due to addition of HCl.
HCl ds feykus ij nksuks yo.kksa dh foys;rk ?kVrh gSA

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Sol. HSO4– is a stronger acid than HCO3– so the calcium carbonate is much more soluble in acidic solution where
CaSO4 is slightly affected. SO
HSO4– , HCO3– dh vis{kk ,d izcy vEy gS blfy, dsfY'k;e dkcksZusV vEyh; foy;u esa vf/kd foys;h gS tcfd dsfY'k;e
lYQsV esa FkksMk izHkkfor gksrk gSA

8. A pre-weighed vessel was filled with oxygen at NTP and weighed. It was then evacuated, filled with SO3 at the
same temperature and pressure and again weighed. The weight of oxygen will be–
(A) Same as that of SO3 (B) 4 times that of SO3
(C) 2.5 times that of SO 3 (D) 0.25 times that of SO3
igys ,d [kkyh ik=k dk Hkkj eki dj NTP ij mls vkDlhtu ls Hkjdj Hkkj ekirs gSA vc bl ik=k dks fuokZfrr djds mlh
leku rki vkSj nkc ij SO3 ls Hkjdj nksckjk Hkkj ekirs gSA vkDlhtu dk Hkkj gksxk
(A) SO3 ds leku (B*) SO3 dk 4 xquk
(C) SO3 dk 2.5 xquk (D) SO3 dk 0.25 xquk
Sol. Since T & P are same & vessel is also same so at constant P, V, & T no of males in both the cases will be
same
tc dh rki vkSj nkc leku vkSj ik=k Hkh leku gS blfy, fu;r P, V, & T ij eksyks dh la[;k Hkh leku gksxh
WSO3 WO 2 2
= ; WO2 = WSO 3 = 0.4 WSO3
80 32 5

9. At which temperature the, reaction will be spontaneous if H = – 176 kJ, S = – 284.5 JK–1
H = – 176 kJ, S = – 284.5 JK–1 gS rks fdl rki ij vfHkfØ;k Lor% gksxh
(A) 380 K (B) 480 K (C) 580 k (D) 680 K
Ans. (D) The minimum temperature above which the reaction will be spontaneous is given by
H 176  1000J
G = 0  T = = = 619 K
S  284.5JK 1
Hence at 680 K, G < O
(D) mijksDr og U;wuRe rki gS ftl ij vfHkfØ;k Lor% gksxh
H 176  1000J
G = 0  T = = = 619 K
S  284.5JK 1
blfy, 680 K ij G < O

10. A 0.1 A sodium acetate solution was prepared. The Kh = 5.6 × 10 –10 . The correct statement is
(A) Degree a hydrolysis is 7.48 × 10–4 (B) [OH –] = 7.48 × 10–5
– –6
(C*) [OH ] = 7.48 × 10 M (D) pH is approximately 7
,d 0.1 A dk lksfM;e ,flVsM dk foy;u cuk;k tkrk gSA ftldh Kh = 5.6 × 10–10 gSA
(A) ty vi?kVu dh ek=kk 7.48 × 10–4 gS (B) [OH –] = 7.48 × 10–5 gSA
(C*) [OH–] = 7.48 × 10–6 M gSA (D) pH yxHkx 7 ds cjkcj gSA
Ans. (C)
Sol. CH3COO– + H2O CH3COOH + H–
0.1 (1 – h) 0.1 h 0.1 h

0.1 h2
Kh =  5.6 × 10–10; 0.1 h2  h = 7.48 × 10–5
1 h
 [OH–] 0.1 × 7.48 × 10–5 = 7.48 × 10–6 M

11. If pKb for fluoride ion at 25º C is 10, the ionisation constant of hydrofluoric acid in water at this temperature is:
;fn 25ºC ij ¶yksjkbM vk;u ds fy, pKb dk eku 10 gS] rks bl rki ij ty esa gkbMªks¶yksfjd vEy dk vk;uu fLFkjkad
gksxk&
(A) 105 (B) 103 (C*) 104 (D) 102
Sol. Pk a  Pk b  14  Pk a  4  K a  10 –4

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12. For the reaction, Fe2O3(s) + 3 CO(g)  3 CO2(g) + 2 Fe() which of the following is correct
vfHkfØ;k Fe2O3(s) + 3 CO(g)  3 CO2(g) + 2 Fe() ds fy,] fuEu esa ls dkSulk lR; gS&
(A) Hº = Eº + 3 RT (B) Hº = Eº + RT
(C*) Hº = Eº (D) Hº = Eº  RT
Sol.  H = E + ng RT since for the above reaction ng = 0  Hº = Eº
Sol.  H = E + ng RT vr% mijksDr vfHkfØ;k ds fy, ng = 0  Hº = Eº

13. In which of the following cases, entropy decreases :

(A) Solid changing to liquid (B) Expansion of a gas
(C) Crystal dissolves in water (D*) Polymerisation (E) Homolytic fission of H 2
fuEu esa ls fdl izØe esa ,UVªkWih esa deh vkrh gS %
(A) Bksl dk nzo esa ifjorZu (B) ,d
xSl dk izlkj
(C) fØLVy dk ty esa foys; gksuk (D*) cgqyhdj.k (E) H 2 dk leka'k fo[k.Mu
Sol. Polymerisation leads to more ordered structure. ¼cgqyhdj.k esa vf/kd O;ofLFkr lajpuk;sa curh gSA½

14. As a 0.1 M solution of CuSO4 is maintained saturated with H2S (0.1 M) given that K1 = 10–7, K2 = 10–14 for
H2S, Ksp of CuS = 10–44, which of the following is INCORRECT ?
(A) CuS precipitates out
(B*) pH = 4 at final equilibrium
(C) [Cu2+] in solution decreases due to precipitation
(D) [H2S] remains constant at 0.1 M
(E) None of these
tc 0.1 M CuSO4 ds foy;u dks H2S (0.1 M) ls lar`Ir j[kk tkrk gS] vkSj fn;k x;k gS H2S ds fy, K1 = 10–7, K2 =
10–14 CuS dk Ksp = 10–44 rks fuEu esa ls dkSulk dFku xyr gS ?
(A) CuS vo{ksfir gksrk gS (B*) vfUre lkE; ij pH = 4 gS
(C) vo{ksi.k ds dkj.k foy;u esa [Cu2+] esa deh vkrh gSA (D) 0.1 M ij [H2S] fu;r jgrk gSA
(E) buesa ls dksbZ ugha
Sol. CuSO4 + H2S  CuS  + H2SO4.
The solution becomes strongly acidic due to H2SO4
H2SO4 ds dkj.k foy;u izcy :i ls vEyh; gks tkrk gSA

15. The first three successive ionisation energies of an element Z are 900, 1757 and 14850 kJ mol–1 respectively.
The element Z belongs to
,d rRo Z dh izFke rhu Øekxr vk;uu ÅtkZ;s Øe'k% 900, 1757 rFkk 14850 kJ mol–1 gSA rRo Z lEcfU/kr gS %
(A) group-1 ( B*) group-2 (C) group-15 (D) group-17
(A) oxZ- 1 ls (B*) oxZ-2 ls (C) oxZ-15 ls (D) oxZ-17 ls
Sol. As .E1 is not very high, element Z cannot belong to group-15 or group-17. As successive .E. increases
therefore element belong to group-.
tSlk dh iz'u ds vuqlkj .E1 cgqr vf/kd ugha gS] vr% rRo Z, oxZ-15 vFkok oxZ-17 ls lacaf/kr ugha gks ldrk gSA tSls fd
Øekxr :i ls .E. esa o`f) gksrh tkrh gS] oSls gh rRo oxZ -2 ls lEcfU/kr gks tkrk gSA
16. (i) Br2 + 2NaOH [cold BaMk]  NaBr + (X) + H2O

(ii) 2Br2 + 6NaOH [hot xeZ]  NaBr + (Y) + H2O

What is the oxidation number of Br in (X) and (Y) respectively
X rFkk Y esa Br dk vkWDlhdj.k vad Øe'k% gS \
(A) +1, +7 (B*) +1 , +5 (C) +4, +5 (D) +3, +5
1
cold
Sol. (i) Br2 + 2NaOH  NaOBr + H2O
(X)
5
hot
(ii) 2Br2 + 6NaOH  5NaBr + Na BrO 3 + 3H2O [hot]
(Y)

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17. A solution of sodium metal in liquid ammonia is strongly reducing due to the presence of
(A) sodium atoms (B) sodium hydride (C) sodium amide (D*) solvated electrons
fuEu esa ls fdldh mifLFkfr ds dkj.k] lksfM;e /kkrq dk nzo veksfu;k esa foy;u] çcy vipk;d gksrk gS %
(A) lksfM;e ijek.kq (B) lksfM;e gkbMªkbM (C) lksfM;e ,ekbM (D*) foyk;fdr bysDVªkWu
Sol. (D) The free ammoniated electrons make the solution of Na in liquid NH 3 is a very powerful reducing agent.
The ammonical solution of an alkali metal is rather favoured as a reducing agent than its aqueous solution
because in aqueous the alkali metal being highly electropositive quite stable, provided no catalyst (transition
metal) is present.
gy- (D) eqDr veksfu;ke; bysDVªkWu] nzo NH3 esa Na foy;u dks çcy vipk;d cuk nsrs gSA {kkj /kkrq dk veksfu;ke; foy;u
blds tyh; foy;u dh vis{kk vipk;d dh rjg O;ogkj djrk gSA D;ksafd tyh; foy;u esa {kkj /kkrq mPp fo?kqr /kukRed
gksrh gS blds dkj.k ;g vf/kd LFkk;h gksrh gSA bl vfHkfØ;k esa dksbZ Hkh mRçsjd ¼laØe.k /kkrq½ ç;qDr ugha gksrs gSaA

18. Match List – I with List – II and select the correct answer using the codes given below the lists :
lkj.kh – I dks lkj.kh – II ls lqesfyr fdft;s rFkk fn;s gq;s dksM dk mi;ksx djrs gq, lgh mRrj p;fur fdft;s A
List – I List – II
lkj.kh – I lkj.kh – II
A. (SiH3)3N 1. 3 centre-2 electron bond f=kdsUnzh; nks bysDVªkWu ca/k
3 3
B. BF3 2. sp - hybridization sp - ladj.k
C. SiO2 3. p – p bond p – p ca/k
D. B2H6 4. p – d bond p – d ca/k

A B C D A B C D
(A) 4 2 1 2 (B) 2 3 2 1
(C) 1 2 3 4 (D*) 4 3 2 1
Sol. (SiH3)3N has p–d back bonding, BF3 has p – p back bonding, in SIO 2 each Si is sp3 – hybridized and in
B2H6 there are two 3c – 2e bonds present called banana bond.
(SiH3)3N , p–d i'p ca/ku j[krk gSA BF3 , p – p i'p ca/ku j[krk gSA SIO2 esa izR;sd Si , sp3 – ladj.k j[krk gS
rFkk B2H6 esa nks f=kdsUnzh; nks bysDVªkWu ca/ku mifLFkr gksrs gSA fTUgs cukuk ca/k dgrs gSaA

19. An aqueous solution of borax is

(A) Neutral (B) Amphoteric (C*) Basic (D) Acidic
cksjsDl dk ,d tyh; foy;u gS %
(A) mnklhu (B) mHk;/kehZ (C*) {kkjh; (D) vEyh;

20. The oxide which is not a reducing agent is :

og vkWDlkbM tks fd vipk;d ugha gS] fuEu gS %
(A*) CO2 (B) CO (C) SO2 (D) Both (A) & (C) nksuks (A) rFkk (C)
Sol. CO2 can not act as reducing agent because carbon is in its highest oxidation state, i.e., +4.
gy- CO2 vipk;d ds :i esa dk;Z ugha djrk gS D;ksafd dkcZu bldh mPpre vkWDlhdj.k voLFkk +4 esa gSaA

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