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Confirmatory test
1)A little of salt mixed with equal
volume of freshly prepared ferrous A brown ring is formed at the
sulphate solution and shaken well junction of the two Presence of nitrate is confirmed
con.H2so4 is then added to this
mixture along the walls of the test
tube
2)A little of the salt solution heated A colorless pungent smelling gas
with zinc dust and NaoH is evolved which solution gives
Presence of nitrate is confirmed
dense white fumes when a glass
rod is dipped in con.HCL is shown
at the mouth of test tube
Confirmatory Test
A little of the salt solution is treated a)No precipitate Presence of alkali metal
with sodium carbonate solution
b)A precipitate Presence of group metal
Confirmatory Test
To about 1 ml of neslurs reagent two A brown precipitate is obtained
drops of salt solution and two drops Presence of ammonium is
of NaoH is added confirmed
Confirmatory test
A little of the above precipitate is The precipitate dissolves
Presence of lead is confirmed
boiled with water in excess
To one portion of the above hot A yellow precipitate is obtained Presence of lead is again confirmed
solution potassium chromate solution
is added
GROUP II Cadmium(cd2-1)
A little of the salt solution is treated
with dil.Hcl and then H2S is passed A yellow precipitate is formed which is Presence of Cadmium
soluble in hot water
Confirmatory test
1)A little of the salt solution is treated White precipitate which dissolves in Presence of Cadmium confirmed
with NH4OH solution drop by drop in excess of NH4OH is obtained
excess
Confirmatory Test
1)NaoH solution is added drop by
drop in excess to little of the salt Presence of Aluminium is confirmed
A white precipitate which dissolves in
solution excess of NaoH solution
A little of the salt solution is boiled
with a few drops of con.HNO3 and
Blue ash is Obtained Presence of Al3+ is
cobalt nitrate solution is added. A
piece of filter paper dipped in it is
turned in to ash by burning
A little of the salt solution is boiled A white precipitate is formed which Presence of Zn2+ is confirmed
with con.HNO3 and few drops of dissolves in excess of NaoH
Cobalt Nitrate solution. A piece of Presence of Zn2+ is again confirmed
filter paper is dipped in it and turned Green Ash is Obtained
into ash
Group 5( Ba2+,Sr2+,Ca2+)
NH4cl, NH4OH,(NH4)2CO3 solutions
are added to a little of salt solution A white precipitate is obtained Presence of Ba2+,Sr2+
Analysis of group 5
A little of the salt solution is treated Absence of Ba2+
with acetic acid &potassium chromate No characteristic precipitate
solution
Absence of Sr2+
A little of the salt solution is treated
No characteristic precipitate
with dil.H2SO4
Confirmatory Test(ca2+)
A little of the salt solution is made
into a paste with Con.Hcl and a small Presence of Ca2+ is confirmed
portion of the paste is shown into the Brisk red color is seen in the color of
flame
non luminous flame by charid spender
Group 6(Mg2+)
Presence of Mg2+ confirmed
NH4Cl,NH4OH,di sodium hydrogen
phosphate solution are added to a A white precipitate is obtained
Confirmatory Test
NaoH solution is added 10 drop to
Presence of Mg2+ is confirmed
excess of salt solution A white precipitate solution of NH4Cl is
obtained