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Atoms Molecules
1. (S) If we consider that 1/6 in place of 1/12, mass of carbon 5. (S) If 1021 molecules are removed from 200mg of CO2, then
atom is taken to be the relative atomic mass unit, the the number of moles of CO2 left are
mass of one mole of a substance will
(a) 2.85 × 10–3 (b) 28.8 × 10–3
(a) decrease twice
(c) 0.288 × 10–3 (d) 1.68 × 10–2
(b) increase two fold
6. (S) A gaseous mixture contains oxygen and nitrogen in
(c) remain unchanged the ratio of 1 : 4 by weight. Therefore, the ratio of
(d) be a function of the molecular mass of the substance their number of molecules is
(a) 1 : 4 (b) 1 : 8
2. (A) Assertion : Both 138 g of K2CO3 and 12 g of carbon
have same number of carbon atoms. (c) 7 : 32 (d) 3 : 16
Reason : Both contains 1 g atom of carbon which 7. (S) A compound possesses 8% sulphur by mass. The least
contains 6.022 × 1023 carbon atoms. molecular mass is
(a) 200 (b) 400
(a) A (b) B
(c) 155 (d) 355
(c) C (d) D
8. (M) 8 g O2 has same number of molecules as that in :
3. (A) Assertion : 1 Avogram is equal to 1 amu.
(a) 14 g CO (b) 7 g CO
Reason : Avogram is reciprocal of Avogadro’s number.
(c) 11 g CO2 (d) 22 g CO2
(a) A (b) B
9. (M) Which of the following have same number of atoms ?
(c) C (d) D
(a) 6.4 g of O2 (b) 0.1 mol of NH
4. (X) Column I Column II (c) 4.0 g of He (d) 22.4 L of Cl2 at STP
(A) 5.4 g of Al (P) 0.5 NA electrons 10. (A) Assertion : Number of molecules present in SO2 is
twice the number of molecules present in O 2.
(B) 1.2 g of Mg2+ (Q) 15.9994 amu
Reason : Molecular mass of SO2 is double to that of
(C) Exact atomic weight of (R) 0.2 mole atoms mixture
O2.
of oxygen isotopes (a) A (b) B
(D) 0.9 ml of H2O (S) 0.05 moles (c) C (d) D
SOME BASIC CONCEPTS OF CHEMISTRY
Stoichiometric Calculations
Or KClO {2Al.
11. (S) P and Q are two elements which forms P 2Q3 and PQ2.
If 0.15 mole of P 2Q3 weights 15.9g and 0.15 mole of I : CaO + 3C o CaC2 + CO
PQ 2 weights 9.3g, the atomic weight of P and Q is
(respectively) : II : CaC2 + 2H2O o Ca(OH)2 + C2H2
(a) 18, 26 (b) 26,18 CaC2 (calcium carbide) is prepared in step I. It is used to
(c) 13, 9 (d) None of these
prepare acetylene (C2H2) in step II. Suppose we want to
12. (S) 1 mole of oxalic acid is treated with conc. H2SO4. The
resultant gaseous mixture is passed through a solution determine amount of CaO that can give enough CaC2 to
of KOH. The mass of KOH consumed will be (where converted required amount of C2H2. Amount of CaO is
KOH absorbs CO2.)
determined in step I and then amount of C2H2 in step II.
(COOH)2 CO + CO2 + H2O
We can relate CaO and C2H2 stoichiometrically by writing
2 KOH + CO2 K2CO3 + H2O
net reaction which is
(a) 28 g (b) 56 g
CaO + 3C + 2H2 O o Ca(OH)2 + C2H2 + CO
(c) 84 g (d) 112 g
13. (M) 0.2 mole of K3PO4 and 0.3 mole of BaCl2 are mixed in 1 L of Thus, CaO { C2H2
solution. Which of these is/are correct ?
14. (C) NX is produced by the following step of reactions
(a) 0.2 mole of Ba3(PO4)2 will be formed
M + X2 o M X2
(b) 0.1 mole of Ba3(PO4)2 will be formed
MX2 + X2 o M3X8
(c) 0.6 mole of KCl will be formed
M3X8 + N2CO3 o N X + CO2 + M3O4
(d) 0.3 mole of KCl will be formed
How much M (metal) is consumed to produce 206 gm of
Comprehension
NX. (Take At. wt of M = 56, N=23, X = 80)
Often more than one reaction is required to change
starting materials into the desired product. This is true (a) 42 gm (b) 56 gm
for many reaction that we carry out in the laboratory and
for many industrial process. These are called sequential 14 7
(c) gm (d) gm
reactions. The amount of desired product from each 4
reaction is taken as the starting material for the next
15. (C) The following process has been used to obtain iodine
reaction.
from oil-field brines in California.
I : 2KClO3 o 2KCl + 3O2
NaI + AgNO o AgI + NaNO
II : 4Al + 3O2 o 2Al2 O
AgI + Fe o FeI2 + Ag
KClO3 decomposes in step I to give O2, which in turn, is
used by Al to form Al2O3 in step II. First we determine FeI2 + Cl2 o FeCl3 + I2
O2 formed in step I and then Al used by this O2 in step II. If 381 kg of iodine is produced per hour then mass of
Both reactions can be added to determine amount of
AgNO required per hour will be
KClO3 that can give required amount of O2 needed for
Al. [atomic mass Ag– 108, I– 127, Fe–56, N–14, Cl–35.5]
Net : 2KClO3 + 4Al o 2KCl + 2Al2O (a) 170 kg (b) 340 kg
Thus, 2KClO {4Al (c) 255 kg (d) 510 kg
SOME BASIC CONCEPTS OF CHEMISTRY
16. (C) 120 gm Mg was burnt in air to give a mixture of MgO and 18. (S) If 7.0 moles of Y is placed in a container and allowed to
react with X until equilibrium is reched according to the
Mg3N2. The mixture is now dissolved in HCl to form reaction :
MgCl2 and NH4Cl, if 107 grams NH4Cl is produced. The
2X + Y o 2Z
reaction are follows
It is found that the equilibrium mixture contains 8.0 moles
1 of X and 5.0 moles of Y. How many moles of X were
I. Mg + O2 o MgO ,
2 present in the original container ?
II. 3Mg N2 o Mg 3 N2 (a) 10 (b) 12
23. (I) A 0.01 moles of sample of KClO was heated under such
conditions that a part of it decomposed according to the
(s) Second reactant is the equation :
limiting reactant. (a) 2KClO3 o 2KCl + 3O2 and the remaining undergoes
p q r s change according to the equation :
(d) C A B C
SOME BASIC CONCEPTS OF CHEMISTRY
24. (M) Three metals of alkaline earth metal group (A, B, and C) 27. (M) Which of the following statements is/are correct ?
when reacted with a fixed volume of liquid Br2 separately The following reaction occurs :
gave a product (metal bromides) whose mass is plotted
'
against the mass of metals taken as shown in the figure. 2Al 3MnO o CCl4 S2Cl 2
H 2SO 4 C (OH) 2
o C SO 4 H 2O
(d) The weight percent of Ca in the original mixture is (c) 116.66 kg (d) 120 kg
20% Ca.
SOME BASIC CONCEPTS OF CHEMISTRY
30. (S) NH3 is formed in the following steps : 36. (C) Volume of acid that contains 63g pure acid is.
III. CaCN2 + 3H2O o 2NH3 + CaCO3 50% yield 37. (C) Volume of water required to make 1N solution from 2 mL
conc. HNO3.
To obtain 2 mol NH3, calcium required is :
(a) 1 mol (b) 2 mol (a) 29.56 mL (b) 30.56 mL
(a) A (b) B
(c) C (d) D
SOME BASIC CONCEPTS OF CHEMISTRY
52. (I) 50 mL of 1 M HCl, 100 mL of 0.5 M HNO3, and x mL of 5 (d) 100 mL of 2.0 M HCl (s) [Ca2+] = 1.2 M
M H2SO4 are mixed together and the total volume is
made upto 1.0 L with water. 100 mL of this solution exactly +200 mL of 1.0 M NaOH [Na ] = 0.4 M
neutralises 10 mL of M/3 Al2(CO3)3. Calculate the value
of x. +150 mL of 4.0 M CaCl2 [Cl 4 ] = 2.8 M
53. (I) How many mL of a solution of concentration 100 mg
+50 mL of H2O
Co2+ per mL of a solution of concentration 20 mg Co2+
per mL. 58. (S) 100 mL of mixture of NaOH and Na2SO4 is neutralised
54. (I) A solution contains 75 mg NaCl per mL. To what extent by 10 mL of 0.5 M H2SO4. Hence, NaOH in 100 mL
must it be diluted to give a solution of concentration 15 solution is
mg NaCl per mL of solution.
(a) 0.2 g (b) 0.4 g
Strength : Stoichiometric Calculations
(c) 0.6 g (d) None
55. (S) How much NaNO3 must be weighed out to make 50 ml of
an aqueous solution containing 70 mg of Na+ per ml? 59. (S) BrO34 5Br 4 o Br2 3H2 O
(a) 12.394 g (b) 1.29 g
1f 50 mL 0.1 M BrO34 is mixed with 30 mL of 0.5 M Br 4
(c) 10.934 g (d) 12.934 g
solution that contains excess of H ions, the moles of
56. (S) 11.4 gm of a mixture of butene, C4H8 and butane C4H10,
was burned in excess oxygen. 35.2 gm of CO2 and 16.2 Br2 formed are
gm of H2O were obtained. Calculate the percentage by (a) 6.0 × 10–4 (b) 1.2 × 10–4
mass of butane in original mixture.
(a) 50.87% (b) 49.13% (c) 9.0 × 10–3 (d) 1.8 × 10–3
(c) 50% (d) None of these Molar Volume of Gas based Calculations
57. (X) Match the solution mixtures given in column I with the 60. (S) 1 g alloy of Cu and Zn reacted with excess of dil. H2SO4
concentrations given in column II.
to give H 2 gas which occupies 60 ml at STP. The
Column I Column II percentage of Zn in the alloy (Given only Zn reacts with
H2SO4)
(a) 11.1 g CaCl2 and 29.25g (p) [Ca2+] = 0.8 M
(a) 17% (b) 34%
of NaCl are diluted [Na ] = 1.2 M
(c) 83% (d) 40%
with water to 100 mL [Cl 4 ] = 2.8 M 61. (S) A solution of NaOH is prepared by dissolving 4.0 g of
NaOH in 1 L of water. Calculate the volume of the HCl
(b) 3.0 L of 4.0 M NaCl and (q) [Ca2+] = 0.001 M gas at STP that will neutralize 50 mL of this solution.
(a) 224 mL (b) 56 mL
4.0 L of 2.0 M CaCl2 are [Na ] = 0.005 M
(c) 112 mL (d) 448 mL
combined and diluted [Cl4 ] = 0.007 M 62. (M) 11.2 L of a gas at STP weighs 14 g. The gas could be :
to 10.0 L (a) N2 (b) CO
(c) 3.0 L of 3.0 M NaCl (r) [Ca2+] = 1.6 M (c) NO2 (d) N2O
Principle of Atom Conservation 80. (A) Assertion : 1mole of H2SO4 is neutralised by 2 moles of
74. (S) 2.76 g of silver carbonate on being strongly heated yields NaOH but 1 equivalent of H2SO4 is neutralised by 1
a residue weighing equivalent of NaOH.
(a) 2.16 g (b) 2.48 g Reason : Equivalent weight of H2SO4 is half of its
(c) 2.32 g (d) 2.64 g molecular weight while equivalent weight of NaOH is 40.
75. (I) Igniting MnO2 in air converts it quantitatively to Mn3O4. (a) A (b) B
A sample of pyrolusite is of the following composition :
(c) C (d) D
MnO2 = 80%, SiO2 and other inert constituents = 15%,
and rest bearing H2O. The sample is ignited to constant 81. (A) Assertion : Equivalent volume of H2 is 11.2 L at 1 atm
weight. What is the percent of Mn in the ignited sample ? and 273 K.
76. (S) How many moles of ferric alum Reason : 1/2 mole H2 has produced when 1 mole of H+(aq)
accepted 1 mole of e–.
(NH 4 )2 SO 4 Fe 2 (SO 4 )3 . 24H 2O can be made from the
(a) A (b) B
sample of Fe containing 0.0056 g of it ?
(c) C (d) D
(a) 10–4 mol (b) 0.5 × 10–4 mol
82. (A) Assertion (A) : The equivalent mass of an element is
(c) 0.33 × 10–4 mol (d) 2 × 10–4 mol variable.
77. (I) A sample of a mixture of CaCl2 and NaCl weighing 4.22g Reason (R) : It depends on the valency of the element.
was treated to precipitate all the Ca as CaCO3, which (a) A (b) B
was then heated and quantitatively converted to 0.959g (c) C (d) D
of CaO. Calculate the percentage of CaCl2 in the mixture.
83. (S) N2 + 3H2 o 2NH3
(Ca = 40, O = 16, C = 12 and Cl = 35.5)
Molecular weight of NH 3 and N 2 are x 1 and x 2 ,
Equivalent Concept respectively. Their equivalent weights are y1 and y2,
respectively. Then (y1 – y2) is
78. (S) A metal oxide has the formula Z2O3. It can be reduced by
hydrogen to give free metal and water. 0.16 gm of the
§ 2x1 x 2 ·
metal oxide requires 6 mg of hydrogen for complete (a) ¨ ¸ (b) (x1 – x2)
reduction. The atomic weight of the metal is : © 6 ¹
(a) 27.9 (b) 159.6 (c) (3x1 – x2) (d) (x1 – 3x2)
(c) 79.8 (d) 55.8 84. (S) The vapour density of a chloride of an element is 39.5.
The Ew of the elements is 3.82. The atomic weight of the
79. (M) For the reaction element is
H3PO4 + Ca(OH)2 o CaHPO4 + 2 H2O (a) 15.28 (b) 7.64
(d) 1 mol of H3PO4 is completely neutralized by 1.5 mol (c) 1 mole of AxBy contains x moles of A and y moles of B
of Ca(OH)2 (d) equivalent weight of AxBy = equivalent weight of B
SOME BASIC CONCEPTS OF CHEMISTRY
86. (M) Which of the statements are true ? 92. (X) Match the items given in column I with those in column
II.
(a) The equivalent weight of Ca3(PO4)2 is Mw/6.
Column I Column II
(b) The equivalent weight of Na3PO4. 12H2O is Mw/3. (a) 9.8% H2SO4 by weight (p) 3.6 N
–1
(c) The equivalent weight of K2SO4 is Mw/2. (density = 1.8g mL )
(d) The equivalent weight of potash alum (b) 9.8 % H3PO4 by weight (q) 1.2 M
K2SO4Al2(SO4)3. 24H2O is Mw/8. (density = 1.2g mL–1)
Normality (c) 1.8 NA molecules of (r) 1.8 Equivalents
87. (S) 10 mL of N/2 HCl, 20 mL of N/2 H2SO4 and 30 mL N/3 HCl is 500 mL
HNO 3 are mixed together and solution made to one (d) 250 mL of 4N NaOH (s) 1.10 m
litre. The normality of the resulting solution is + 250 mL of 1.6 M Ca(OH)2
(a) 0.20 N (b) 0.10 N 93. (S) 10 mL of 0.2 N HCl and 30 mL of 0.1 N HCl together
exactly neutralises 40 mL of solution of NaOH, which is
(c) 0.50 N (d) 0.025 N also exactly neutralised by a solution in water of 0.61 g
of an organic acid.What is the equivalent weight of the
88. (S) 0.115 g of pure sodium metal was dissolved in 500 ml organic acid ?
distilled water. The normality of the above solution,
(a) 61 (b) 91.5
whose resulting volume is 400 mL, would be
(c) 122 (d) 183
(a) 0.010 N (b) 0.0115 N
94. (M) 1 gm Mg sample is treated with 125 ml 0.1 N HCl and the
(c) 0.0125 N (d) 0.046 N excess of HCl is neutralised by 50 ml 0.5 N NaOH
completely. The correct statement is/are :
89. (S) 50 ml of 10 N H2SO4, 25 ml of 12 N HCl and 40 ml of 5N
(a) Mass of Mg present in the sample is 0.12 gm
HNO 3 were mixed together and the volume of the
(b) Mass of Mg sample unreacted is 0.88 gm
mixture was made 1000 ml by adding water. The
normality of the resulting solution will be (c) % of Mg present in the sample is 12%
(d) Mass of impurities present in the sample is 0.88 gm.
(a) 1 N (b) 2 N
95. (X) Match the Column
(c) 3 N (d) 4 N Column Column
–1
90. (S) Which of the following 1 g L solution has the highest (a) 20 ml (N) HCl reacts (p) No. of molecules of HCl
normality ? N
with 50 mL NaOH. left = 0
5
(a) NaOH (b) H2SO4
N
(c) HCl (d) HNO3 (b) 10 ml HCl reacts (q) No. of molecules of HCl
2
91. (A) Assertion :- 0.1 M H3PO3 (aq) solution has normality N
with 50 ml NaOH. left = 6.02 × 1021
equal to 0.3N when completely reacted with NaOH. 10
N
Reason : H3PO3 is dibasic acid. (c) 50 ml HCl reacts (r) No. of molecules of HCl
10
(a) A (b) B N
with 100 ml NaOH. left = 2.71 × 1022
(c) C (d) D 50
N
(d) 100 ml HCl reacts (s) No. of molecules of HCl
2
N
with 50 ml NaOH. left = 1.8 × 1021
10
SOME BASIC CONCEPTS OF CHEMISTRY
1. Dissolving 120g of urea (mol. wt. 60) in 1000g of water 6. 6.3g of oxalic acid dihydrate have been dissolved in
gave a solution of density 1.15 g/mL. The molarity of water to obtain a 250 mL solution. How much volume of
0.1 N NaOH would be required to neutralise 10 mL of
the solution is (2011)
this solutions ? (2001)
(a) 1.78 M (b) 2.00 M
(a) 40 mL (b) 20 mL
(c) 2.05 M (d) 2.22 M (c) 10 mL (d) 4 mL
5. How many moles of electron weighs one kilogram ? (a) 0.7 (b) 0.5
ANSWER KEY
Advanced Objective Questions
1. (c) 2. (a) 3. (c) 4. (A) o (R) (B) o (P, S), (C) o (Q), (D) o (P),(S) 5. (a)
6. (c) 7. (b) 8. (bc) 9. (ab) 10. (d) 11. (b) 12. (d) 13. (bc)
14. (a) 15. (d) 16. (c) 17. (c) 18. (b) 19. (c) 20. (0080) 21. (0059)
22. (0014) 23. (0060) 24. (a,b) 25. (0008) 26. (abd) 27. (ac) 28. (b) 29. (a)
30. (d) 31. (c) 32. (b) 33. (a) 34. (a,c,d) 35. (b) 36. (c) 37. (a)
38. (c) 39. (d) 40. (a,b) 41. (a) 42. (b) 43. (a) 44. (a) 45. (abcd)
46. (abc) 47. (abd) 48. (a,b,c,d) 49. (d) 50. (a) 51. (d) 52. (0010) 53. (0002)
57. (a o q), (b o p), (c o r), (d o s) 58. (b) 59. (c) 60. (a) 61. (c) 62. (ab)
63. (bc) 64. (c) 65. (d) 66. (b) 67. (a) 68. (a) 69. (b) 70. (c)
71. (b) 72. (a) 73. (d) 74. (a) 75. 59.36% 76. (b) 77. 45.04% 78. (d)
79. (abcd) 80. (b) 81. (a) 82. (a) 83. (a) 84. (b) 85. (b,c,d) 86. (abcd)
87. (d) 88. (c) 89. (a) 90. (c) 91. (d)
9. (c) 10. (d) 11. (c) 12. (8) 13. (2) 14. 5 × 10–19 m2 15. 55.55M
Dream on !!
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