H2+ CO2 ↔ H2O CO

Inicial 1 1 0 0
Final 0 0 1 1

v= 0
n0= 2 ε= YH2= YCO2= YH2O= YCO= teste
Pela Equação 13.5 0.406978 0.296511 0.296511 0.203489 0.203489 -4.88E-08
�_𝑖 (𝑛_𝑖0+𝑣_𝑖 𝜀)/(𝑛_0+𝑣𝜀) Ge
1 Err:502
0.9 -2.04952
0.8 -2.06566
0.7 -2.07641
0.6 -2.08314
0.5 -2.08638
0.4 -2.08627
T= 1000K 0.406978 -2.08639
∆G,CO2 -395790 0.3 -2.08267
∆G,H2O -192420 0.2 -2.07505
∆G,CO -200240 0.1 -2.06204

Pela equação (A) fornecida na questão

∆G=0 logo
0
-2.03
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

-2.04

-2.05

-2.06

-2.07

-2.08

-2.09
A) A12=0,59 A21=1,42 P1sat=82,37 P2sat=37,31
X Gama 1 Gama 2 Pbolha y1
0.25 1.759997696 1.010997533 64.53299103 0.56161588
0.5 1.426180654 1.158933285 80.35715068 0.730952376
0.75 1.121522907 1.759997696 85.70125989 0.808446474

B) Deu ruim Foi pro Matlab

X Delta 1 Delta2 Gama 1 Gama 2 P Y1 Y1 teste Teste
0.25 55013409.37 0.055200883 1.759997696 1.010997533 34.122 0.47821 1.93E-08 430.9033371
0.5 3203.738211 1.352688E-08 1.426180654 1.158933285 56.87 0.5 0.000322 0.009166402
0.75 3203.738211 1.352688E-08 1.121522907 1.759997696 56.87 0.5 0.00038 0.010812687
 3.15E-07
-2.99286
Delta teste
6824304 913365878
 X1α X2α X1β X2β
0.1 0.9 0.9 0.1
A21 A12
0 0
Gama1α 1 Teste 01 Teste 02
Gama1β 1 0.111111 0.111111
Gama2α 1 1 1
Gama2β 1 -0.88889 -0.88889