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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

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ANSWERS, HINTS & SOLUTIONS


CRT– I
(Paper-1)
ALL INDIA TEST SERIES

Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. A, B D A, B, C, D

2. C, D A, B, C A, B, C

3. A, B, D A, C C, D

4. A, C B, C A, B, C, D

5. A, B A, C A, B

6. A, D B A, B, C, D

7. C, D B B, D

8. A, C A, D A, D

9. A, D B, D A, B, C

10. B, D A, B A, D

1. 2 3 0

2. 0 3 1

3. 2 4 3

4. 3 3 3
5. 4 7 1
6.
3 8 1
7. 2 9 4
8. 5 3 2
9. 0 0 4
10. 3 2 2

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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

Physics PART – I

SECTION – A
1. Using concept of relative velocity we can
solve v 
vA

v B(d, )
(0, 0)

vB  vjˆ
R min

3. Use v 2  u2  2as
And impulse = change in momentum

2gh
4. Use v 

I
where,   1 
Mr 2

5. Use work energy theorem

6. Buoyant force FB = Vegeff


If lift accelerates
geff = g + a

 v  v0 
7. Use,  app   v  
 v  vs 
v = speed of sound

8. for isothermal process, PV = constant


For adiabatic process, PV = constant

9. Electric field at centre = 0 R


So, charge q will produce same electric
field as induced charge on sphere at centre d q
so A & D

10. Using conservation linear moment and conservation mechanical energy.

SECTION – C
1. For translation position of A will be 2.

2. formula for rod and are both are


k k
 sin   sin   ˆi   cos   cos   ˆj
d d
 
So, E  0 and b = 0

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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

3
6. work done = P0 V0
2
P V  P1V1
U  2 2
 1
3
Q  P0 V0
2
k=3

7. f1 = f 30 m/s 30 m/s
C 330 O
fw  f  1000 Hz S
C  30 300
C  v0 360 330
f2  fw    1000  1200 Hz
C 330 300
Frequency Band width = f2  f1 = 200 Hz

8. Fnet  Fpseudo  FBuoyant  V  2  10  v  10  v  10


Fnet v  10
a   5 m/s
n v  2

100
9. IL   2 A
50 2
100
IC   2
50 2
Isource  IL  IC  0

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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

Chemistry PART – II

SECTION – A
1. Dacron is a copolymer of ethylene glycol and terephthalic acid

A  A 4  A 4  A 4
2. ZA 
 B 
 C 
 D
Z 2 Z 1 Z
 - emission gives isodiapher.

3. From kinetic theory of gases


K. E.  T

WB  1000 WB  1000
MNa2CO3  MH2 C2O4 .2H2O 
mB  V mB  V
4.
5.3  1000 6.3  1000
  0.5   0.5
106  100 126  100
W  1000 N  1000
NNa2CO3  B NH2C2O4 .2H2O  B
EB  V EB  V
5.3  1000 6.3  1000
 1  1
53  100 63  100
n-factor =2 n-faction = 2

o
5. Eredox change will be negative for non-spontaneous reaction

Ni2  aq  Cu  s   Ni  s   Cu2  aq 


Eo  EoNi2  / Ni  ECu
o
2
/ Cu
 0.25  0.34  0.59V   ve, non  spon tan eous 

Cu  s   2H  aq  Cu2   aq  H2  g


Eo  EHo  /H  ECu
o
2
/Cu
 0  0.34  0.34V  ve, non  spon taneous 
2

6.

H Ring H
 
Exp
  
H O
2

OH OH OH OH
O

7. H
 i CH3MgBr H SO /  HBO
 CH3  CH  CH2  CH3  CH2  CH2  OH
CH3 CHO  
 H3C C CH3 
2 4
ii H2O B  C 
OH
B 
2
8. Compounds have all ‘c’ atom sp hybridised are coplanar.

9. B. O. of NO = 2.5, paramagnetic
NO+ = 3.0, diamagnetic

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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

10. Cr 3  , d3 configuration shows same number paired e– and EAN but strength of all ligands are
different so does not slow same colour and splitting.

SECTION –C

1. [Mabcd] type square planar complex has 3 G. I.

2. NO2  HCl  HNO2  Cl

3HNO2  HNO3  2NO  H2 O

2NO  O2  2NO2 


SO23   HCl  H2O  2Cl  SO2 
HCO3  HCl  H2O  CO2  Cl

3. H Cl Cl Cl

H Cl H H H H H H Br Br H H

Br Br Br Br Br H H Br

meso Enatiomers

5. Aromatic compounds

, graphite
N , , , , , N N
N
A layer of graphite (graphene) contains infinite lattice of fused aromatic rings. All the valencies
are satisfied (except at the edges) and no bonds are needed between layers. (Planar layered
structure of fused aromatic rings).

6. 5 mol H2 SO 4  5  98  490 gm of H2 SO 4
5M
1000 ml of solution  1000  1.115  1115 gm solution
 wt. of solvent = 1115 – 490 = 625 gm
moles of solute 5
m   8 mol / kg
wt. of solvent  in kg  625  103

2
7. 15 P  1s ,2s2 ,2p6 ,3s2 3p3
For ‘s’  = 0, m = 0, e– = 6
-1
For ‘p’,  = 1, m = +1
0

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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

-1 0  1 0 1

 2e  1e
Total e– = 6 + 2 + 1 = 9

8. 

PCl5 
 PCl3  Cl2
a 0 0
a ax a a  0.50

 2P Kp 0.5  0.5
Kp  2
 
1  P 0.75
P
 3
KP
 P = 3  KP

9. O O
S

O O

O O
S S
O O O

3
10. Mn  CN 
 6
x + 6(–1) = –3
 x = +3
Mn3    Ar  3d4 4S0

t 2g eg
As CN– is strong ligand hence due to splitting it will from low spin complex.

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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

Mathematics PART – III

SECTION – A
1 x
1. 4  x1  2 1
x2 x2
1 x
1  x2  2 2
x3 x3
1 x
4  x3  2 3
x4 x4
1 x  1  1  1  1 4
1  x4   2 4  16   x1    x2    x3   x 4    2
x1 x1  x 2  x 3  x 4  x1

 2
2. Any point on xy = 2 is P  2t, 
 t 

 2 2
Normal at P is  y    t x  2t
t 
 

3.  ABC  BPC   APC C


1 1
 ar  br
2 2
2 A B
r P
ab
A B C s s  a s  s  b s s  c  s
cos cos cos    
2 2 2 bc ac ab abc

1 2
4. P(A1  A2) = , P(A1) =
4 4
1
P(A2) = . Thus P(A1  A2) = P(A1) P(A2)
2

z4 z4 2 2
5.   0 which is a circle x + y – 4x – 2y = 0
z  2i z  2i
xx1 + yy1 – 2(x + x1) – (y + y1) = x12  y12  4x1  2y1
2 2
It passes through (0, 0), so, the locus of (x1, y1) is x + y – 2x – y = 0.
So, z1 = x1 + iy1, lies on this circle for which the points (2, 0) and (0, 1) are extremities of a
diameter. Also (0, 0) and (2, 1) represent extremities of another diameter

 
6. I e

x
dx   cos x ln  x 

1  x 2 dx 
3
 e  e  
2
3 2
7. f(t) = t – t + t + 1
f(t) > 0
 max.{f(t): 0  t  x} = f(x)

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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

8. Put 2
 2 sin 2
x  3 sin x 1t

n n n–2 n n–4
9. En = 3 + C2·3 + C4·3 + …..
On = nC1·3n–1 + nC3·3n–3 + …..
Adding and subtracting, we get En + On = (3 + 1)n = 4n, En – On = (3 – 1)2 = 2n
4n  2n
Adding and subtracting again, we get 2En = 4n + 2n  En 
2
n n
n n 4  2
2On = 4 – 2  On 
2

dx
10.  x 2 y 3  xy
dy
dx
 xy  x 2 y 3
dy
1 dx y
    y3
x 2 dy x
1
Put t
x
SECTION – C

3 x c3
1. cos  
4 1 1 1
3 3  M
 x  AB  A B p 7
4 2 x
7 3 3
p  4 2  3 2  7 and c 3M 
4 
c1 C c2
7 3 7
 CM  7   3 3
4 4

2. x2 + 1 = (x + i)(x – i)
b = 1, a = c
Number of ways of choosing a, b, c = 10 = 10  1
k=1
 
3. Unit vector  n̂  perpendicular to OA and CB
 
CB  OA  3  7  ˆi  4ˆj   5    kˆ
n̂    
CB  OA  3  7 2  16   5   2
ˆi ˆj kˆ
    7  3   4  2     2  5   
As CB  OA  1   3 1 = BA  nˆ 
1 2 3  3  7 2  16   5   2
 
Shortest distance = BA  n
1  1   1 2
4. Replacing x by , we obtain f   f 1    2x 
1  x   1 x   x x
1
Again, replacing x by 1 
x

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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

5. We have a =

x x6  1 
2
x 1
 x 2  1
 x6 + 1 = a    2a
 x 
 2a – x6  1
2 2 2
6.  (x – 1) = –3{1 + cos(ax + bx + c)} solution exists when L.H.S. = R.H. S. = 0
 x = 1 and cos(ax2 + bx + c) = –1
When x = 1, x = –1
 a + b + c = 3, a – b + c = 
 b =  and a + c = 2

100
i101 i 
7. f  x     x  i
i 1
100
ln  f  x     i 101  i  ln  x  i 
i 1

1 
100 i 101  i
 f ' x  


f x i 1  x  i 

8. For any quadrilateral,


a + b + c > d.
Now, (a  b)2 + (b  c)2 + (c  a)2  0
 a2 + b2 + c2  (ab + bc + ca)
 3 (a2 + b2 + c2)  3 (ab + bc + ca)
 3 (a2 + b2 + c2)  a2 + b2 + c2 + 2 (ab + bc + ca)
 3 (a2 + b2 + c2)  (a + b + c)2
 3 (a2 + b2 + c2) > d2
(a2  b2  c 2 ) 1
  .
d2 3
 a2  b2  c 2  1
 The minimum value of   is
 d2  3

2 –1 1  1
9. As P(, (1 +  ) ) lie on y   2, 
1 x2  5
1  1 
 On solving y  with L1, we get 5,
2
x 1 P2  26 
P1
 1
 2, 5  ….. (1)
 
 1 
and with line L2, we get P2  5,  ….. (2)
 26  y+2=0
 Equation (1) and (2), we get 2    5 L1 = 0 L2 = 0

10. f(x) = cos x – 2a cos 2x – cos 3x + 2a  0  x  R


 2 sin2 x (cos x + a)  0
 a  – cos x  1

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