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V1 175.6140 cm3/mol
T 340 K
x1 0 x2 1
P1 sat 53.00926 kPa
P x1 * g 1 P1* x 2 * g 2 P
P2 sat 27.16336 kPa
R 1.987 cal/molK
a12 384.9 cal/mol
a21 2449.12 cal/mol
A12 0.19636
A21 0.076755 x1g 1 P1*
g1 y1
12.82058 P
g2 1
P 27.16336 kPa
y1 0 y2 1
Sacar A21
V2 a 12
Sacar g1 A12 exp
V1 RT
Sacar g2
V1 a 21
Sacar P A 21 exp
Sacar y1
V2 RT
y2=1-y1
x2 * g 2 P
1
ln g ln x x A
1 2 12
x
A
12
2 x x A
x
1 2 12 2
2
ln g ln x x A
2 1 21
x A
12
1 x x A
x
1 2 12 2
A
12
x
A
12
2 x x A
A
21
x x A
1 2 12 2 1 21
A
21
x
A
12
1 x x A
A
21
x x A
1 2 12 2 1 21
1) El sistema binario acetonitrilo(1)/nitrometano(2) se conforma bien a la
ley de Raoult. Las presiones de vapor para las especies puras se dan
mediante las siguientes ecuaciones de Antoine: La P en kPa y T en ºc
CONSTANTES
PROPIEDADES CRITICAS PROPIEDADES DE SATURACIÓN
ACETONITRILO
Masa Molar 41,053 A 7.0735
w 0.338 B 1279.2
Tc (k) 545.5 C 224.01
Pc (Bar) 48.30 T(min) -13
Zc 0.184 T(max) 117
Vc (cm^3/m 173. T(ºC) 95
Tn (k) 354.8 Pvap (kPa) 154.31
P (Kpas) 80.00
T(Sat) 73.81
NITROMETANO
Masa Molar 61,040 A 7.044
w 0.348 B 1291
Tc (k) 588.2 C 209.01
Pc (Bar) 63.10 T(min) 5
Zc 0.223 T(max) 136
Vc (cm^3/m 173. T(ºC) 95
Tn (k) 374.4 Pvap (Kpas) 83.59
P (Kpas) 80.00
T(Sat) 93.64
155.00
150.00
145.00
140.00
135.00
130.00
125.00
P (Kpas)
120.00
Burbuja
115.00 Rocio
110.00
105.00
100.00
95.00
90.00
85.00
80.00
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1
XY
94.00
93.00
92.00
91.00
90.00
89.00
88.00
87.00
86.00
85.00
84.00
Temp (ºC)
83.00 Burbuja
82.00 puntos de rocío.
81.00
80.00
79.00
78.00
77.00
76.00
75.00
74.00
73.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00
XY
2) Para el sistema 2-propanol(1)/agua(2), los valores siguientes de
parámetros son recomendados para la ecuación de Wilson:
V2 18.07 cm3/mol
V1 76.92 cm3/mol
T 363.15 K
x1 0.35 x2 0.65
P1 sat 137.09 kPa
P x1 * g 1 P1* x 2 * g 2 P
P2 sat 70.12 kPa
R 1.987 cal/molK
a12 437.98 cal/mol
a21 1238 cal/mol
A12 0.12803
A21 0.76554 x1g 1 P1*
g1 y1
1.62664 P
g2 1.31532
P 138 kPa
y1 0.566 y2 0.434
Sacar g2
1
ln g ln x x A
1 2 12
x
A
12
2 x x A
x
Sacar P 1 2 12 2
Sacar y1
2
ln g ln x x A
2 1 21
x
A
12
1 x x A
x
y2=1-y1 1 2 12 2
A
12
x
A
12
2 x x A
A
21
x x A
1 2 12 2 1 21
A
21
x
A
12
1 x x A
A
21
x x A
1 2 12 2 1 21
Presión de Rocío
R 1.987 cal/molK
V1 76.92 cm3/mol
V2 18.07 cm3/mol
T 363.15 K
y1 0.7 y2 0.3
P1 sat 137.089 kPa
P2 sat 70.1206 kPa
a12 438 cal/mol
a21 1238 cal/mol
A12 0.128
A21 0.7655
P 106.56 kPa
x1 0.544 X2 0.456
g1 1.2259
g2 1.6458
P x1 x2 A12 A21 gama1
147.82 0.616 0.384 0.1280 0.7655 1.1483
146.57 0.6518 0.3482 0.1280 0.7655 1.1177
146.29 0.6683 0.3317 0.1280 0.7655 1.1052
146.23 0.6756 0.3244 0.1280 0.7655 1.1000
146.22 0.6787 0.3213 0.1280 0.7655 1.0978
146.22 0.6801 0.3199 0.1280 0.7655 1.0969
146.22 0.6806 0.3194 0.1280 0.7655 1.0965
146.22 0.6809 0.3191 0.1280 0.7655 1.0964
146.22 0.6810 0.3190 0.1280 0.7655 1.0963
146.22 0.6810 0.3190 0.1280 0.7655 1.0963
146.22 0.6810 0.3190 0.1280 0.7655 1.0962
146.22 0.6811 0.3189 0.1280 0.7655 1.0962
146.22 0.6811 0.3189 0.1280 0.7655 1.0962
146.22 0.6811 0.3189 0.1280 0.7655 1.0962
146.22 0.6811 0.3189 0.1280 0.7655 1.0962
146.22 0.6811 0.3189 0.1280 0.7655 1.0962
146.22 0.6811 0.3189 0.1280 0.7655 1.0962
146.22 0.6811 0.3189 0.1280 0.7655 1.0962
146.22 0.6811 0.3189 0.1280 0.7655 1.0962
146.22 0.6811 0.3189 0.1280 0.7655 1.0962
146.22 0.6811 0.3189 0.1280 0.7655 1.0962
146.22 0.6811 0.3189 0.1280 0.7655 1.0962
146.22 0.6811 0.3189 0.1280 0.7655 1.0962
146.22 0.6811 0.3189 0.1280 0.7655 1.0962
146.22 0.6811 0.3189 0.1280 0.7655 1.0962
Sacar P1sat y P2sat
1
P
y1 y2
P1 sat P 2sat
y1P
x1
P1 sat
x 2 1 x1
V2 a 12
A 12 exp
V1 RT
V1 a 21
A 21 exp
V2 RT
A12 A21
ln g 1 ln x1 x2 A12 x2
x1 x2 A12 x2 x1 A21
A12 A21
ln g 2 ln x2 x1 A21 x1
gama2 x1 x2 A12 x2 x1 A21
1.8008
1.8870
1
1.9285 P
1.9472 y1 y2
1.9553 g 1 P1 sat
g 2 P2sat
1.9588
1.9603
1.9609
y1 P
1.9612 El cambio de P es muy
x1
1.9613
1.9613
pequeño
g 1 P1 sat
1.9613
1.9614
1.9614
1.9614
1.9614
1.9614
1.9614
1.9614
1.9614
1.9614
1.9614
1.9614
1.9614
1.9614
A21
x1 A21
A21
x1 A21
Temperatura de Burbuja
V2 18.07 cm3/mol
V1 76.92 cm3/mol
P 101.33 kPa
x1 0.65 x2 0.35
R 1.987
B 3640.2 3816.44
A 16.678 16.2887 Datos de Antoine
C 53.54 46.13
T1 355.390 °K
T2 373.151 °K
T 361.607 °K
P1 sat 129.247 KpA P2 sat 66.11
a12 437.98 cal/mol
a21 1238 cal/mol
A12 0.1277
A21 0.7600
l ln gama1 0.1135 gama1 1.1201
ln gama 2 0.6354 gama2 1.8879
P1 sat 95.0498 kPa
Kpa
ln g 1 ln x1 x 2 A12
ln g 2 ln x 2 x1 A21
gama 1 gama 2 y1 y1
1.1258 1.9151 0.686 0.314
1.1260 1.9158 0.681 0.319
1.1260 1.9158 0.681 0.319
1.1260 1.9158 0.681 0.319
1.1260 1.9158 0.681 0.319
1.1260 1.9158 0.681 0.319
1.1260 1.9158 0.681 0.319
1.1260 1.9158 0.681 0.319
1.1260 1.9158 0.681 0.319
1.126 1.916 0.681 0.319
puede sacar y
Bi
Ti sat
Ci
Ai ln P
T xiTi sat
3640.20 3816.44
780 ln P2sat 16.28870
T 53.54 T 46.13
V2 a12
A12 exp
V1 RT
V1 a 21
A21 exp
V2 RT
A12 A21
n g 1 ln x1 x 2 A12 x 2
x1 x 2 A12 x 2 x1 A21
A12 A21
n g 2 ln x 2 x1 A21 x1
x1 x 2 A12 x 2 x1 A21
P
P1sat
P2sat
x1g 1 x2g 2 sat
P1
P
P1sat
P2sat
x1g 1 x2g 2 sat
P1
Bi
T Ci
Ai ln P1sat
DT son pequeñas
x1g 1 P1*
y1
P
T de Rocío
Pi sat P
i g i Pi sat
x1
y1P Bi
P1 sat T Ci
x 2 1 x1
Ai ln P1sat
3816.44
ln P2sat 16.28870
T 46.13
T sea pequeña. V2 a
A12 exp 12
x2 g1 g2 V1 RT
0.615 1.5201 1.3648
V1 a 21
0.640 1.6191 1.3347 A21 exp
0.660 1.6851 1.3067 V2 RT
0.673 1.7353 1.2876
0.683 1.7733 1.2744
0.690 1.8019 1.2652 y1 P
0.695 1.8233 1.2585 x1
0.699 1.8392
1.8510
1.2538
1.2503
g 1 P1 sat
0.701
0.703 1.8597 1.2478
0.704 1.8662 1.2460 A12 A21
0.705 1.8710 1.2447 ln g 1 ln x1 x2 A12 x2
0.706 1.8745 1.2437 x x
1 2 12A x 2 x A
1 21
0.707 1.8771 1.2430
A12 A21
0.707 1.8790 1.2425 ln g 2 ln x2 x1 A21 x1
0.707 1.8804 1.2421 x x
1 2 12A x 2 x A
1 21
ln g 1 ln x1 x2 A12 x2
x x
1 2 12 A x 2 x A
1 21
A12 A21
ln g 2 ln x2 x1 A21 x1
x1 x2 A12 x2 x1 A21
0.708 1.8815 1.2418
0.708 1.8823 1.2416
0.708 1.8828 1.2414
0.708 1.8832 1.2413
0.708 1.8835 1.2412
0.7082 1.8838 1.2412
3816.44
n P2sat 16.28870
T 46.13
3816.44
T 46.13
A12 A21
x2 A12 x2 x1 A21
A12 A21
x2 A12 x2 x1 A21
x2 A12 x2 x1 A21
A12 A21
x2 A12 x2 x1 A21
e) Paz, la presión azeotrópica, y xa; = yaz, la composición azeotrópica, para T = 363.15 K.
v1= 76.92 cm3/mol A12 0.1280
v2= 18.07 cm3/mol A21 0.7655
T= 363.15 K P1 sat 137.09
R= 1.987 cal/mol P2 sat 70.12
a12= 437.98 cal/mol γ1∞ 9.877 α12 19.310
a21= 1238 cal/mol γ2∞ 3.124 α12 0.626
P 101.33
x1 0.3 x2 0.4
y1 0.3 y2 0.4
V1 74.05 V2 18.07
a12 291.27 a21 1448.01
R 1.987
Coeficientes de Antoine
A B C
Acetona 4.2184 1197.01 228.06
Agua 16.3872 3885.7 230.17
Tsat1 -3220.72
Tsat2 99.99911
T -926.215
P1 191.6025 P2 191.6025
A12 0.285869 A21 9.000525
ln gama1 -0.00428 gama1 0.99573
ln gama 2 -0.4675 gama2 0.626594
P1 sat 184.4521 kPa
P 100.33 x1 0.25 x2
T 90
componente A B C Tsati
Acetona 4.2184 1197.01 228.06 -3296.806896472
Metanol 5.20277 1580.08 239.5 2419.2010762735
Agua 16.3872 3885.7 230.17 99.7211061753
n con la ley de Raoult, haga los cálculos siguientes:
0.4
Psati
1.5168817649
1.4991459819
3.8324243217