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  • Department of Mining, Metallurgical and Materials Engineering Mrspoblete Mate 101

    Transféré par

    Claudine Allyson Dungo
    13 vues34 pages
    This document contains lecture notes from MatE 101 on thermodynamics. It discusses concepts such as work, the work-energy theorem, enthalpy, heat transfer, and the first law of thermodynamics. Equations presented include definitions of work, heat, internal energy change, and the first law. Examples are provided to calculate work done during gas expansions using the integral form of the work equation and the ideal gas law.

    Description originale:

    Law of thermodynamics

    Titre original

    Lecture 02 - First Law of Thermodynamics

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    This document contains lecture notes from MatE 101 on thermodynamics. It discusses concepts such as work, the work-energy theorem, enthalpy, heat transfer, and the first law of thermodynamics. Equations presented include definitions of work, heat, internal energy change, and the first law. Examples are provided to calculate work done during gas expansions using the integral form of the work equation and the ideal gas law.

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    © All Rights Reserved
    Téléchargez comme PDF, TXT ou lisez en ligne sur Scribd
    Signaler comme contenu inapproprié
    13 vues34 pages

    Department of Mining, Metallurgical and Materials Engineering Mrspoblete Mate 101

    Transféré par

    Claudine Allyson Dungo
    This document contains lecture notes from MatE 101 on thermodynamics. It discusses concepts such as work, the work-energy theorem, enthalpy, heat transfer, and the first law of thermodynamics. Equations presented include definitions of work, heat, internal energy change, and the first law. Examples are provided to calculate work done during gas expansions using the integral form of the work equation and the ideal gas law.

    Droits d'auteur :

    © All Rights Reserved
    Téléchargez comme PDF, TXT ou lisez en ligne sur Scribd
    Signaler comme contenu inapproprié
    sur 34

    MatE 101  Department of Mining, Metallurgical and Materials Engineering

    Lecture 02 MRSPoblete

    MatE 101  Department of Mining, Metallurgical and Materials Engineering


    Lecture 02 MRSPoblete
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete

    MatE 101  Department of Mining, Metallurgical and Materials Engineering


    Lecture 02 MRSPoblete
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete


    MatE 101  Department of Mining, Metallurgical and Materials Engineering


    Lecture 02 MRSPoblete
    −𝑤 = ∆𝑈
    −𝑤 = 𝑈𝑓 − 𝑈𝑖

    MatE 101  Department of Mining, Metallurgical and Materials Engineering


    Lecture 02 MRSPoblete
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    𝑉2
    ∆𝑤 = 𝑃𝑑𝑉
    𝑉1

    MatE 101  Department of Mining, Metallurgical and Materials Engineering


    Lecture 02 MRSPoblete


    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete

    MatE 101  Department of Mining, Metallurgical and Materials Engineering


    Lecture 02 MRSPoblete
    𝑞 = 𝐶∆𝑇
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    𝑞 = ∆𝑈
    𝑞 = 𝑈𝑓 − 𝑈𝑖
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    ∆𝑈 = 𝑞 − 𝑤

    MatE 101  Department of Mining, Metallurgical and Materials Engineering


    Lecture 02 MRSPoblete

    MatE 101  Department of Mining, Metallurgical and Materials Engineering


    Lecture 02 MRSPoblete
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    ∆𝑈 = 𝑞 − 𝑤

    𝑑𝑈 = 𝛿𝑞 − 𝛿𝑤

    MatE 101  Department of Mining, Metallurgical and Materials Engineering


    Lecture 02 MRSPoblete
    MatE 101 1 𝐿 ∙ 𝑎𝑡𝑚 = 101.325 𝐽
     Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    W   PdV
    V2

    V1

    W  Aabcd  Adefg  Aghij


    solving for the different volumes :
    RT 0.082057 L  atm * 298K
    V1  
    P1 100 atm  mol
    V1  0.244658 L

    V2  V1 P1 / P2  2.45 x10  4 * 2
    V2  0.489316 L

    V3  V1 P1 / P3  2.45 x10  4 * 5
    V3  1.22329 L

    V4  V1 P1 / P4  2.45 x10  4 *10


    V4  2.44658 L
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete
    Solving for work :
    V2
    W   PdV
    V1

    W  Aabcd  Adefg  Aghij


    W  50 0.489316  0.244658 
    20 1.22329  0.489316 
    10 2.44658  1.22329
    W  39.14528 L  atm
    W  3.972 kJ

    MatE 101  Department of Mining, Metallurgical and Materials Engineering


    Lecture 02 MRSPoblete
    Solving for work :
    V2
    W   PdV
    V1

    1 V4
    W  RT  dV
    V1 V

    W  RT lnV4   lnV1 
    V4
    W  RT ln
    V1
    Note that V4  V1 *10
    W  8.3144 J / mol  K * 298 K * ln10
    MatE 101 W  5.705
     Department kJ Metallurgical and Materials Engineering
    of Mining,
    Lecture 02 MRSPoblete
    MatE 101  Department of Mining, Metallurgical and Materials Engineering
    Lecture 02 MRSPoblete

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