AMITY INSTITUTE FOR COMPETITIVE EXAMINATIONS

DELHI CENTRES: • E-26, Defence Colony New Delhi - 110024. Ph.: 24336143, 24336144.
• B-1/632, Main Nazafgarh Road, Janakpuri, New Delhi - 110058. Ph.: 011-25573111/12/13/14.
NOIDA CENTRE: Amity Campus, Sector-44, Noida - 201303. Ph.: 95120-2431839, 2431842

P ET - -1
SAPER 1
SYNCHRO XI STUDYING
UNIT TEST-05 (CHEMISTRY) CODE-A
Time : 1 hr. 15 min. M.M. : 60
Date : 12/12/2011 COP

TOPIC COVERED : (Chemical and Ionic Equilibrium)

ANSWERS
Section-A
1. (b) 2. (d) 3. (d) 4. (b) 5. (d) 6. (a)
7. (d) 8. (a) 9. (a) 10. (b) 11. (d)

AMITY
Section-B and C

12. (c) 13. (b) 14. (a) 15. (b) 16. (d) 17. (b)

Section-D

1. A-(s); B-(p); C-(p); D-(q)

InstituteINSTITUTE
AMITY for Competitive Examinations
FOR COMPETITIVE EXAMINATIONS
DELHI CENTRES: • E-26, Defence Colony New Delhi - 110024. Ph.: 24336143, 24336144.
• B-1/632, Main Nazafgarh Road, Janakpuri, New Delhi - 110058. Ph.: 011-25573111/12/13/14.
NOIDA CENTRE: Amity Campus, Sector-44, Noida - 201303. Ph.: 95120-2431839, 2431842
P ET - -1
SAPER 1
SYNCHRO XI STUDYING
UNIT TEST-05 (CHEMISTRY) CODE-B
Time : 1 hr. 15 min. M.M. : 60
Date : 12/12/2011 COP

TOPIC COVERED : (Chemical and Ionic Equilibrium)

ANSWERS
Section-A
1. (d) 2. (a) 3. (a) 4. (b) 5. (d) 6. (b)
7. (d) 8. (d) 9. (b) 10. (d) 11. (a)

Section-B and C

12. (a) 13. (c) 14. (b) 15. (b) 16. (d) 17. (b)

Section-D

1. A-(s); B-(p); C-(p); D-(q)

[5] Unit Test-05 (Syncyro XI Studying) (12-12-11)

 UNIT TEST-05 (CHEMISTRY) SOLUTIONS
Section-A
Choose the correct answer :

1. To a 50 ml of 0.1 M HCl solution, 10 ml of 0.1 M NaOH is added and the resulting solution is diluted to 100 ml.
What is change in pH of the HCl solution?
(a) 4.398 (b) 0.398 (b) 0.1M (d) none of these.
Sol.: (b) Before adding HCl solution
pH = 1 [ [HCl] = [H3O]+ = 10–1 M]
nHCl (initially) = MV = 0.1 M  0.05 L = 5  10–3 mol
nNaOH added = MV = 0.1 M  0.01 L = 1  10–3 mol
HCl + NaOH  NaCl + H2O
t=0 5  10–3 mol 1  10–3 mol 0
–3
4  10 mol 0
Vfinal  = 100 ml = 0.1 L
n 4 10 –3 mol
[HCl] =  = 4  10–2 M
V 0.1L

AMITY
pH = – log [H3O+] = 2 – log4 = 2 – 2 log2 = 2 – 2  0.301= 2 – 0.602 = 1.398
Increase in pH = (1.398 – 1) = 0.398

2. What amount of solid sodium acetate be added into 1 litre of the 0.1 M CH3COOH solution so that the resulting
solution has pH almost equal to pKa (CH3COOH) = 4.7
(a) 12gm (b) 5 gm (b) 16 gm (d) 16.4 gm.
Sol.: (d) Since the resulting solution be acidic buffer, one may use Henderson equation.
Institute for
pH = pK  log
[CH Competitive
COO ] Examinations
3
–

a
[CH3COOH]
Let n mol of CH3COONa be added to do so
n mol
or, pH = 4.70 + log
vL
0.1 mol
vL
n
or, 5 = 4.70 + log
0.1
n
or, log = 0.3
0.1
n
or, = antilog 0.20 = 0.2
0.1
 n = 0.2 mol
Amount of sodium acetate = 0.2  82 gm = 16.4 gm

3. A weak base (BOH) with Kb = 10–5 is titrated with a strong acid, HCl. At 3/4th of the equivalent point, pH of the
solution is:
(a) 5 + log3 (b) 5 – log3 (c) 14 – 5 + log3 (d) 8.523.
Sol.: (d) Let the initial equivalent of BOH be x
BOH + HCl ? BCl + H2O
Initial equivalent x 3/4x 0 0
3x x 3 3
At 3/4th eqv. pt. x   0 x x
4 4 4 4
[6] Unit Test-05 (Syncyro XI Studying) (12-12-11)
 [salt] 3x  4
pOH = pK b  log  5  log
[Base] 4 x
pH = 14 – 5 – log 3 = 8.523

4. A reaction mixture containing H2, N2 and NH3 has partial pressures 2 atm, 1 atm and 3 atm respectively at 725 K.
 2NH is 4.28  10–5 atm–2 at 725 K, in which direction
If the value of Kp for the reaction, N2(g) + 3H2(g)  3(g)

the net reaction will go?

(a) Forward (b) Backward
(c) No net reaction (d) Direction of reaction cannot be predicted.
2

Sol.: (b) Qp =
P  NH 3

(3) 2 9
 atm 2 = 1.125 atm–2.
3 3
P  P 
N2 H2
(1)(2) 8

Since value of Qp is larger than Kp (4.28  10–5 atm–2), it indicates net reaction will proceed in backward
direction.

5. 2.0 mol of PCl5 were introduced in a vessel of 5.0 L capacity at a particular temperature. At equilibrium, PCl5 was

AMITY
found to be 35% dissociated into PCl3 and Cl2. The value of Kc for the reaction is
(a) 1.89 (b) 0.377 (c) 0.75 (d) 0.075.
2  35
Sol.: (d) Moles of PCl5 dissociated = = 0.7
100
Moles of PCl5 left undissociated = 2 – 0.7 = 1.3 mol
1.3 0.7 0.7
Institute
[PCl ] =
5 for Competitive
M, [PCl ] =
5
5
M, [Cl ] =
5
M Examinations
3 2

 0.7  0.7 
[PCl3 ][Cl2 ]  5  
 5   0.75
K 
[PCl5 ]  1.3  = 0.075
 
 5 

6.  2AB(g) + B2(g) with

At temperature T, a compound AB2(g) dissociates according to the reaction 2AB2(g) 
degree of dissociation , which is small compared with unity. The expression for Kp, in terms of  and the total
pressure, PT is

PT  3 PT  2 PT 3 PT  2
(a) (b) (c) (d) .
2 3 3 2
Sol.: (a) For the given equilibrium, the equilibrium concentration are
 2AB(g) + B2(g)
2AB2(g) 
c
Equilib. conc. c (1 – ) c
2
c
(PB2 )(PAB ) 2  (c) 2  PT 3  PT
KP   2 K P 
 (PAB2 )2  ;  
2
[c(1 – )] [c(1  )] 2(1– )2 1  
2  2

[7] Unit Test-05 (Syncyro XI Studying) (12-12-11)

 
Since,  is small compared to unity, so 1 –   1 and 1 +  1.
2
3  PT
 KP 
2

7. The equilibrium constant for equilibria, SO2(g) + 12 O2(g) SO3(g) and 2SO3(g) 2SO2(g) + O2(g)
are K1 and K2 respectively. Then
(a) K2 = K1 (b) K2 = K12 (c) K2 = 1/K1 (d) K2 = 1/K21
Sol.: (d) Factual

8. If different quantities of ethanol and acetic acid are used in the following reversible reaction,
CH3COOH + C2H5OH CH3COOC2H5 + H2O the equilibrium constant will have values which will be:
(a) same in all cases
(b) Different in all cases
(c) Higher in cases where higher concentration of ethanol is used
(d) Higher in cases where concentration of acetic acid is used.

AMITY
Sol.: (a) Equilibrium constant is constant at constant temperature, do not depends on initial amount of reactant
9. If 1.0 mole of I2 is introduced into 1.0 litre flask at 1000 K, at equilibrium (Kc = 10–6), which one is correct:

(a) [I2(g)] > [I–(g)] (b) [I2(g)] < [I–(g)] (c) [I2(g)] = [I–(g)] (d) [I2(g)] = 12 [I–(g)]
Sol.: (a) Since KC < 10–3, therefore reactant predominats over product.
10. Oxidation of SO2 by O2 to SO3 is an exothermic reaction. The yield of SO3 will be maximum if:
Institute for Competitive Examinations
(a) Temperature is increased and pressure is kept constant
(b) Temperature is reduced and pressure is increased
(c) Both temperature and pressure are increased
(d) Both temperature and pressure are reduced
Sol.: (b) Factual

11. The pKa of acetylsalicylic acid (aspirin) is 3.5. The pH of gastric juice in human stomach is about 2-3 and the
pH in the small intestine is about 8. Aspirin will be
(a) unionised in the small intestine and in the stomach
(b) completely ionised in the small intestine and the stomach
(c) ionised in the stomach and almost unionised in the small intestine.
(d) ionised in the small intestine and almost unionised in the stomach
Sol.: (d) Factual

Section-B
Read the following questions and choose
A. Both Statement-1 and Statement-2 are true and Statement-2 is correct explanation of Statement-1.
B. Both Statement-1 and Statement-2 are true but Statement-2 is not a correct explanation of Statement-1.
C. Statement-1 is true and Statement-2 is false.
D. Statement-1 is false and Statement-2 is true.

[8] Unit Test-05 (Syncyro XI Studying) (12-12-11)

12. Statement-1: An aqueous solution made by adding CH3COOH and CH3COO–Na+ to water in molar ratio
n1 : n2 where n2 >> n1, the solution can take more acid than base without getting pH changed
substantially.
Statement-2: A good buffer is made when concentration of acid and base differs substantially in a buffer
solution.
(a) A (b) B (c) C (d) D
Sol.: (c) To make a good buffer solution the concentration of ratio of weak acid and their conjugate base should be
1:1

13. Statement-1: Degree of ionization of a weak electrolyte decreases with increase in concentration
Statement-2: In presence of common ion the degree of ionization of a weak electrolyte is suppressed.
(a) A (b) B (c) C (d) D
Sol.: (b) Common ion effect.

14. Statement-1: The equilibrium (given below) attained in a closed vessel remains unaltered by the addition of
CaCO3(s). CaCO3 (s) CaO(s) + CO 2

AMITY
Statement-2:
(a) A

Comprehension
Institute for
 A4
2 A2 
The active mass of a solid is a constant independent of its mass and is always taken to be unity.

.....(i)

 A2C2
A2 + C2 
K =
(b) B

Competitive
2 atm Examinations

.....(ii)
(c) C

Section-C

p1
81
–1
(d) D

 2AC
A2C2  .....(iii)
A2 and C are taken in 3 : 1 mole ratio in a closed container of a certain volume at a fixed temperature and above
three equilibriums are established simultaneously. K p1 for the first reaction is 2/81 atm–1. At equilibrium partial
pressure of A4(g) and AC(g) are found to be 1/2 atm each and the total pressure at equilibrium is found to be
27
atm. Then
4

15. The partical pressure of A2C2 at equilibrium is

(a) 1/2 (b) 1/4 (c) 3/4 (d) 1
9
Sol.: (c) 3P –x – y =
2
1 9
6– –y=
2 2
y = 1 atm

16. The mole ratio of gases A2 and AC at equilibrium is

(a) 9/2 (b) 7/2 (c) 8 (d) 9

[9] Unit Test-05 (Syncyro XI Studying) (12-12-11)

 n A2 PA2 3P  x  y 9 / 2
Sol.: (d) =   9
n AC PAC 2z 1/ 2

17.  A2C2 is

Equilibrium constant Kp for the reaction, 2AC 

(a) 3/4 (b) 3 (c) 4 (d) 1/3

PA2 C2 3/ 4
Sol.: (b) Kp = P 2  (1 / 2)2  3
AC

Section-D
Match the following

1. For CH3COOH (Ka = 10–5)

Column I Column II
A. 0.1 M 200 ml CH3COOH + 0.1 M 100 ml NaOH (p) pH = 5 – log 3

AMITY
B. 0.1 M 200 ml CH3COOH + 0.1 M 100 ml NaOH +0.1 M 50 ml HCl (q) pH = 5 + log 3
C. 0.1 M 200 ml CH3COOH + 0.1 M 50 ml NaOH (r) pH = 6
D. 0.1 M 200 ml CH3COOH + 0.1 M 150 ml NaOH (s) pH = 5
A-(s), B-(p), C-(p), D-(q)


Institute for Competitive Examinations

[10] Unit Test-05 (Syncyro XI Studying) (12-12-11)