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Electronic Devices

Lecture 2
05-08-2014

BITS Pilani, K K Birla Goa Campus


BITS Pilani, K K Birla Goa Campus
Periodic Table

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Semiconductor materials

• If we look at the periodic table, the element


semiconductors, such as silicon (Si) or germanium
(Ge), can be found in column IV of the table.

• In the early 1950s, Ge was the most important


semiconductor material, but, since the early 1960s,
Si has played a major role and virtually displaced
Ge as the main material for semiconductor material

BITS Pilani, K K Birla Goa Campus


Semiconductor materials
• The reasons of that are:
– Better properties at room temperature
– High-quality silicon dioxide (SiO2) can be
grown thermally.
– Si is second only to oxygen in great quantity.
– Devices made from Si cost less than any other
semiconductor material
– Silicon technology is by far the most advanced
among all semiconductor technologies.

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Significance of Si

1. Easily oxidized to form SiO2, a high quality electrical


insulator

2. Oxide layer provides an excellent barrier layer for the


selective diffusion steps needed in integrated-circuit
fabrication

3. Abundant element in nature, providing the possibility of a


low-cost starting material

4. Wider bandgap than Ge and operate at higher


temperature than Ge
BITS Pilani, K K Birla Goa Campus
BITS Pilani, K K Birla Goa Campus
BITS Pilani, K K Birla Goa Campus
Crystal structures

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Unit cell

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Cubic unit cell

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FCC structure

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Miller Indices

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BITS Pilani, K K Birla Goa Campus
BITS Pilani, K K Birla Goa Campus
Crystallographic Notation

Miller Indices Notation Interpretation


(hkl) crystal plane
{hkl} equivalent planes
[hkl] crystal direction
<hkl> equivalent directions
h: inverse x-intercept of plane
k: inverse y-intercept of plane
l: inverse z-intercept of plane
(h, k and l are reduced to 3 integers
having the same ratio.)

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Crystallographic Planes

_
(632) plane (001) plane (221) plane

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Crystallographic Planes

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Crystal Growth CZ Method

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Crystal Growth Until Device Fabrication

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Metallurgical grade silicon - MGS
Electronic Grade Silicon - EGS

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Crystallographic Planes of Si Wafers

 Silicon wafers are usually cut along a {100} plane with a flat or notch to orient the
wafer during integrated-circuit fabrication.
 The facing surface is polished and etched yielding mirror-like finish.

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Crystallographic Planes of Si

Unit cell:

View in <111> direction

View in <100> direction View in <110> direction

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