Presentation Dangerous Goods 2019

1
Dangerous Goods Regulations Amendments 2019
„Orange Book“ 1920th edition 20152017

UN ECOSOC SCETDG Meetings working informal
documents documents
47th 22.06.-26.06.2015 28 58
th
48 30.11.-09.12.2015 57 63
49th 27.06.-06.07.2016 48 78
50th 28.11.-06.12.2016 35 61
∏ 168 260
∏ 428
EASA: 8th General Assembly 30th April and 1st May 2018 Brugge
Dangerous Goods Regulations Amendments 2019 (draft, status 28 March 2018)
norbert.mueller@dbschenker.com
2
Result:
regulation effective
voluntary mandatory
(except not specific transitional period)
ADR (Road Europe) 2019 2019-01-01 2019-07-01
RID (Rail Europe) 2019 2019-01-01 2019-07-01
ADN (Inland Navigation Vessel Europe) 2019 2019-01-01 2019-07-01
IMDG Code (Sea) Amendment 39-18 2019-01-01 2020-01-01
IATA DGR (Air) 60th Edition 2019 - 2019-01-01
3
ADR/RID/ADN: Amendments 2019:
1.1.3.1 Exemptions, related to the nature (b) The carriage of machinery or equipment not specified
of the transport operation in Annex A and which happen to contain dangerous
goods in their internal or operational equipment(deleted)
Note:
- see amended UN 3363 and new UN 3537-3548
- for transitional period see 1.6.1.46
1.1.3.6.3 Exemptions, related to quantities transport category Substances or articles
carried per CTU … UN No.
0 4.3: …, 3132
4 …, 3537-3548
[1.1.4.7 Applicability of other regulations: Notwithstanding sub-sections 6.2.3.4, 6.2.3.5, 6.2.3.6 and
pressure receptacles with DOT 6.2.3.9 gases and liquids listed in the tables of 4.1.4.1 P200
approval, but without ADR and P208 imported in accordance with 1.1.4.2 in refillable
pressure receptacles approved by the US DOT may be
approval carried from the location of the temporary storage to the end-
user under the following conditions:
a) When imported from a non-ADR contracting party, the
conformity of the pressure receptacles to this sub-section
shall be verified and recorded by the consignor. The
verification record shall be kept for five years to allow for
inspection by the competent authority and shall include the
identification of the pressure receptacles, the name of the
person making the verification and the date.
b) The pressure receptacles shall be marked and labelled in
accordance with chapter 5.2.
4
c) All relevant requirements of ADR with regard to filling ratios

and periodic testing frequency shall be fulfilled.
d) When the pressure receptacles are empty or when the
end-user has no further use for the gas or liquid, the pressure
receptacles shall not be refilled and shall be returned to the
country from which they were imported.
e) Empty imported pressure receptacles approved by the US
DOT may be filled with gases and liquids in the tables of
4.1.4.1 P200 provided they are exported to countries which
are not ADR contracting parties. All relevant requirements of
ADR with regard to filling ratios and periodic testing frequency
shall be fulfilled. The pressure receptacles shall be marked
and labelled in accordance with chapter 5.2.
f) The consignor for the ADR journey shall include the
following entry in the transport document: “CARRIAGE IN
ACCORDANCE WITH 1.1.4.7”.
Notes:
- = M299 († 01.06.2019)
- 49 CFR §171.23(a)(3), §173.302(a) and §173.304(a)(3) will be amended to legalize import of pressure
receptacles with ADR approval in the U.S.A.]
5
1.2.1 Definitions Amendment to an existing definition:

“hermetically closed tank”
New definitions:
- “diameter” (of tanks) (inner)
- „protective lining“ (of tanks)
- “over-moulded cylinder” (= cylinder is overmoulded
with a protective case made from plastics)
1.4.2.2.2 Obligations: carrier … In the case of 1.4.2.2.1 (c) (e.g. load securing)
he may rely on what is certified in the “container/
vehicle packing certificate” provided in
accordance with 5.4.2.
Note: relevant for pre-carriage of container from point
of loading of the container to the harbor, with regard
to the securing of the load.
6
1.6.1.1 Transitional measures: general ADR/RID/ADN 20152017 applicable until

30.06.20172019
Transitional measures: specific: training certificates for
1.6.1.21 driver: model † 31.12.2018
Transitional measures: specific: size of “UN XXXX” on gas
1.6.1.25 cylinders † 30.06.2018
+ M294
Transitional measures: specific: label: layout
1.6.1.30 † 30.06.2019
Notes:
- applies to label with line inside of only 1 mm instead of 2 mm
- IMDG Code & IATA DGR 2 mm since 1st January 2017
- BUT: provision will be deleted! ( 5.2.2.2.1.1.2)
Transitional measures: specific: instructions in writing
1.6.1.35 † 30.06.2017
Transitional measures: specific: training certificates for
1.6.1.38 DGSA: model † 31.12.2018
Transitional measures: specific: mark according to SP 188
1.6.1.39 (f) † 31.12.2018
Transitional measures: specific: subsidiary risk 6.1
1.6.1.40 † 31.12.2018
Transitional measures: specific: label 9 instead of 9A
1.6.1.42 † 31.12.2018
Transitional measures: specific: vehicles
1.6.1.43 Update of Special Provisions
Transitional measures: specific: DGSA for consignor
1.6.1.44 As from 01.01.2023
Transitional measures: specific: training certificate for
1.6.1.45 DGSA Continue use
Transitional measures: specific: dangerous goods in
1.6.1.46 machinery and apparatus > LQ 1.1.3.1 (b) applicable until 31.12.2022
Transitional measures: specific: lithium cells and batteries
1.6.1.47 Without test summary: until 31.12.2019
Transitional measures: specific: fixed tanks (tank-vehicles),
1.6.3.47 demountable tanks, battery-vehicles, tank-wagons, tank- Applies to amended 6.8.3.2.9
= 1.6.4.49 container, portable tanks
1.6.3.48 Applies to new special provision TU42: applicable for

= 1.6.4.50 existing tanks as from 1st January 2023
7
1.6.3.49 Applies to amended 6.8.2.2.10

= 1.6.4.51
= 1.6.4.52
= 1.6.4.53
1.6.3.52 Applies to new 6.8.2.2.11
= 1.6.4.54
Transitional measures: specific: tank-containers: type of
1.6.4.15 test („“P“ or“L“) on tank plate † 31.12.2018
Transitional measures: specific: portable tanks: portable
1.6.4.38 tank instruction † 31.12.2018
Transitional measures: specific: portable tanks: SP TP38 or
1.6.4.44 TP39 † 31.12.2018
Transitional measures: specific: vehicles
1.6.5.4 Prolongation until 31.12.2020
1.6.5.21 Applies to vehicles type EX/III for UN 0331, 0332
1.6.5.22 Applies to amended 9.7.3
1.8.3.1, DGSA: companies with Inclusion of consignor
1.8.3.3, obligation to appoint a DGSA as from 1st January 2023
1.8.3.18
1.9.5.2.2 Tunnel categories B: class 2: UN 3529

D: class 3: UN 3528
Note: necessary because of new 2nd indent in SP 363 (l)
8
Classification of articles as articles

2.1.5 containing dangerous goods, n.o.s. Applies to new UN 3537-3548
2.1.56 … …
2.2.41.4 Classification: class New:
4.1: list of currently PHOSPHORTHIOIC ACID, O-[(CYANOPHENYL-METHYLENE)-
assigned self- AZANYL] O,O-DIETHYL ESTER („Phoxim“)
reactive substances
= UN 3227 = type E liquid
2.2.51.1.7 Classification: class New section 39 in part III of the UN Manual Tests & Criteria
5.1 concerning solid fertilizer basing on AN
(= UN 2067 5.1 III resp. UN 2071 9 III)
UN 2071 9 III in bags: DG according to IMDG Code and IATA DGR only
2.2.52.4 Classification: class New:
5.2: list of currently - DIISOBUTYRYL PEROXIDE
assigned organic = UN 3119 = type F liquid temperature controlled
peroxides
- DI-(4-tert-BUTYLCYCLOHEXYL)PEROXYDICARBONATE
= UN 3116 = type D solid temperature controlled
- 1-PHENYLETHYL HYDROPEROXIDE
= UN 3109 = type F liquid
9
2.2.8 Classification: New: mixtures: concentration limits for skin corrosion for substances
class 8 without specific values:
except if corrosive to metals
mixture %
I II III
5
5
II
1 III III
1 if corrosive to metals if corrosive to metals
III
0 if corrosive to metals
I II III
substance in mixture
10
That means:
- Entries with specific concentration limits (11):
substance dangerous good

% class PG
ALKYL-/ARYLSULPHONIC ACIDS ≥5 8 II
<5 III
FORMIC ACID ≥ 85 8 II
5-85 III
<5 - -
AMMONIA ≥ 50 2.3 -
35-50 2.2 -
10-35 8 III
2,5-10 9 III
< 2,5 - -
ACETIC ACID ≥ 80 8 II
10-80 III
< 10 - -
HYDROFLUORIC ACID ≥ 60 8 I
< 60 II
FORMALDEHYDE ≥ 25 8 III
< 25 - -
HYDRAZINE > 37 8 I / II / III
≤ 37 6.1 III
NITRATING ACID with NITRIC ACID ≥ 50 8 I
< 50 II
PROPIONIC ACID ≥ 90 8 II
10-90 III
< 10 - -
NITRIC ACID ≥ 70 8 I
< 70 II
SULPHURIC ACID ≥ 51 8 II
< 51 III
Substance specific concentration limits have preference!
11
- Entries without specific concentration limits: the new general concentration limits for skin
corrosion applies:
example 1: sodium hydroxide PG II:
NaOH dangerous good hazardous mixture

% UN 1824
5 8 II H290 H314 1A
5
2 8 III H290 H314 1B

2
0,5 H290 H315 H319

0,5
0,1*) H290
0,1*)
*) Vgl. Stepanovsky, M. (Bundesanstalt für Kfz, Wien): Der Korrosionstest als Einstufungskriterium für die Klasse 8 ADR, in: Gefahrgut
Profi, 5. Jg. (1995), Nr. 1, S. 15.
12
- Entries without specific concentration limits: the new general concentration limits for skin
corrosion applies:
example 2: hydrochloric acid PG II:
HCl dangerous good hazardous mixture

% UN 1789
25 8 II H290 H314 1B H335

25
10 H290 H315 H319 H335

10
5
5
0,1*) 8 III H290

0,1*)
*) Vgl. Stepanovsky, M. (Bundesanstalt für Kfz, Wien): Der Korrosionstest als Einstufungskriterium für die Klasse 8 ADR, in: Gefahrgut
Profi, 5. Jg. (1995), Nr. 1, S. 15.
13
2.2.9.1.7 Classification: 3rd sentence:

class 9: lithium (a) UN Manual Tests & Criteria:
batteries - 38.3.2.1
- 38.3.2.3
- 38.3.3 (b) (c) (d) (e)
- 38.3.3.1 (= new tables 38.3.2 and 38.3.3)
- 38.3.5 (= summary of tests)
(f) Lithium batteries, containing both primary lithium

metal cells and rechargeable lithium ion cells, that are
not designed to be externally charged (see special
provision 387 of chapter 3.3) shall meet the following
conditions:
(i) The rechargeable lithium ion cells can only be charged from
the primary lithium metal cells;
(ii) Overcharge of the rechargeable lithium ion cells is precluded
by design;
(iii) The battery has been tested as a lithium primary battery;
(iv) Component cells of the battery shall be of a type proved to
meet the respective testing requirements of the Manual of Tests
and Criteria, part III, sub-section 38.3.
Note: = M296 since 18 Feb 2016
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(g) Manufacturers and subsequent distributors of cells or

batteries manufactured after 30 June 2003 shall make available
the test summary as specified in the Manual of Tests and
Criteria, part III, sub-section 38.3, paragraph 38.3.5.
Note: as from 1 January 2020
15
3.1.2.2 Selection of the When a combination of several distinct proper shipping names
correct proper are listed under a single UN number, and these are
shipping name - separated by conjunctions such us „and“ or „or“ are in lower case
or
- when segments of the name punctuated by commas,
the entire name of the entry need not necessarily only the most
appropriate shall be shown in the transport document and package
marks.
This is the case particularly when a combination of several
distinct entries are listed under a single UN number.
Examples illustrating the selection of the proper shipping name for
such entries are:
(a) UN 1057 LIGHTERS or LIGHTER REFILLS
The proper shipping name is the most appropriate of the following
possible combinations:
LIGHTERS
LIGHTER REFILLS
(b) …
Consequence: “either or” as from 2019

Applies to > 200 UN numbers
16
3.1.2.6 Substance to 2nd sentence: (b) Unless it is already included in capital letters in
stabilize the name indicated in the table A, the words “TEMPERATURE
CONTROLLED” shall be added as part of the proper shipping
name.
Example:
UN 2810 TOXIC LIQUID, ORGANIC. N.O.S. (…),
STABILIZED, TEMPERATURE CONTROLLED, …
3.1.2.6 1st sentence 3.1.2.6 2nd sentence (b)
CONTROL TEMPERATURE: … °C
EMERGENCY TEMPERATURE: … °C
5.4.1.1.16
(bc) …
17
3.2 List of DG in UN Amendments to existing entries:

numeric order - UN 0349, 0367, 0384, 0481: SP347
(“table A”) - UN 0509: MP24
- UN 1002, 1006, 1013, 1046, 1056, 1058, 1065, 1066, 1080, 1952, 1956,
2036, 3070, 3163, 3297, 3298, 3299: SP660
- UN 1011, 1049, 1075, 1954, 1965, 1969, 1971, 1972, 1978: SP660392, 674
- UN 1363, 1386, 1398, 1435, 2217, 2793: BK2
- UN 1744: TP10, TU43
- UN 1755 II III, 1778 II, 1779 II, 1788 II III, 1789 II III, 1791 II III, 1803 II, 1805
III, 1814 II III, 1819 II III, 1824 II III, 1830 II, 1832 II, 1840 III, 1906 II, 2031 II,
2581 III, 2582 III, 2586 III, 2693 III, 2796 II, 3264 II III: TU42
- UN 1796, 1826: CV24
- UN 2031: CV24
- UN 2067: SP186, 193, 307
- UN 2071: SP193
- UN 3090: SP387, P911, LP905, LP906
- UN 3091: SP387, SP636670
Note: = M303 / RID 1/2016 since 21 Feb 2017
P911, LP905, LP906
- UN 3166: SP312, 385388
- UN 3171: SP240388
- UN 3223, 3224: PP94 PP95
- UN 3302 2-DIMETHYLAMINOETHYL ACRYLATE, STABILIZED, 6.1 II:
SP38, V8, S4
18
- UN 3316:
-- delete entry for PG III
-- delete PG II in the remaining entry
-- SP671
- UN 3363: NOT SUBJECT TO ADR/RID/ADN (see also 1.1.3.1 (b)) SP301,
SP672, P907
- UN 3480: SP387, P911, LP905, LP906
- UN 3481: SP387, SP636670
P911, LP905, LP906
- UN 3528: SP667, (D)
- UN 3529: SP667, (B)
- UN 3530: SP667, (E)
New UN numbers (14):

19
UN PROPER SHIPPING NAME Label PG Special Provisions Packing Instructions

ADR RID IMDG IATA ADR IMDG IATA
Code DGR RID Code DGR
(1) (2) (3) (4) (5a) (5b) (5c) (5d) (6a) (6b) (6c)
3535 6.1+ I 274 274 274 - P002 P002 PI665; PI672
TOXIC SOLID, FLAMMABLE, INORGANIC, N.O.S.
4.1 II IBC99 IBC99 PI668/PIY644; PI675
3536 LITHIUM BATTERIES INSTALLED IN CARGO TRANSPORT UNIT 9 - 389 389 389 forbidden - - forbidden
lithium ion batteries or lithium metal batteries
3537 ARTICLES CONTAINING FLAMMABLE GAS, N.O.S. 2.1 - 274 274 274 A2 P006 P006 PI221
667 667 391 A333 LP03 LP03 only by approval of states, exemption of
673 legal authority and CAO
3538 ARTICLES CONTAINING NON-FLAMMABLE, NON TOXIC GAS, 2.2 - A2 P006 PI221
A333 LP03 only by approval of states, exemption of
N.O.S.
legal authority and CAO
3539 ARTICLES CONTAINING TOXIC GAS, N.O.S. 2.3 - A333 according to only by exemption of legal authority
competent authority
3540 ARTICLES CONTAINING FLAMMABLE LIQUID, N.O.S. 3 - A2 P006 PI379
3541 ARTICLES CONTAINING FLAMMABLE SOLID, N.O.S. 4.1 - A2 P006 PI400
3542 ARTICLES CONTAINING A SUBSTANCE LIABLE TO 4.2 - A333 according to only by exemption of legal authority
competent authority
SPONTANEOUS COMBUSTION, N.O.S.
3543 ARTICLES CONTAINING A SUBSTANCE WHICH EMITS 4.3 - A333 according to only by exemption of legal authority
competent authority
FLAMMABLE GAS IN CONTACT WITH WATER, N.O.S.
3544 ARTICLES CONTAINING OXIDIZING SUBSTANCE, N.O.S. 5.1 - A333 according to only by exemption of legal authority
competent authority
3545 ARTICLES CONTAINING ORGANIC PEROXIDE, N.O.S. 5.2 - A333 according to only by exemption of legal authority
competent authority
3546 ARTICLES CONTAINING TOXIC SUBSTANCE (if LC50  PG I), 6.1 - A2 according to only by exemption of legal authority
A333 competent authority
N.O.S.
3546 ARTICLES CONTAINING TOXIC SUBSTANCE (if LC50  PG II or A2 according to PI600
A333 competent authority only by approval of states, exemption of
III), N.O.S.
3547 ARTICLES CONTAINING CORROSIVE SUBSTANCE, N.O.S. 8 - A2 P006 PI877
3548 ARTICLES CONTAINING MISCELLANEOUS DANGEROUS GOODS, 9 - A2 P006 PI973
N.O.S.
3363 DANGEROUS GOODS IN MACHINERY 9 - 301 301 301 A48 P907 P907 PI962
DANGEROUS GOODS IN APPARATUS 672 672 A107
A332
20
Dangerous goods in articles1)

Does a single entry exist2)?
Yes2) No
single entry Is the dangerous good in the article in limited quantity only?
applies Yes No
 UN 3363 2.1  UN 3537 2.3  UN 3539
*) 2.2  UN 3538 4.2  UN 3542
3  UN 3540 4.3  UN 3543
4.1  UN 3541 5.1  UN 3544
6.1: if LC50 VG II/III  UN 3546 5.2  UN 3545
8  UN 3547 6.1: if LC50 VG I  UN 3546
9  UN 3548
ADR/RID/ADN: exempted3) as from 01.01.20234)
IMDG Code: as from 01.01.2020 as from 01.01.2020,
not but only according to competent
exempted authority5)
IATA DGR: as from 01.01.2019, as from 01.01.2019,
6)
but only by approval of states , but only by
7)
exemption of legal authority and CAO exemption of legal authority7)
1) machinery, apparatus, other devices
2) e.g. UN 2857, 3358, 3528-3530
3) SP 672 (replaces subsection 1.1.3.1 (b))
4) sub-section 1.6.1.46
5) SP 391
6) SP A2
7) SP A333
*) example: a pencil contains 5 ml of UN 1210 PRINTING INK 3 II  UN 3363

21
New UN 3537-3548: example:

Bsp.: device, containing printing ink
UN 1210 PRINTING INK 3 II
and ≤5l >5l
UN 3090 LITHIUM METAL BATTERY 9
(1) (2) (3)
ADR, RID, ADN
UN 3091 ** UN 3540
* resp. ** ***
Note: as from 01.01.2023 / excepted until 31.12.2022

IMDG Code,
IATA DGR
UN 3091 ** UN 3540
LITHIUM METAL BATTERIES ARTICLES CONTAINING FLAMMABLE LIQUID,
IN EQUIPMENT ** N.O.S. (motor spirit)
* resp. ** *** * bzw. **
* if ≤ 2 g Li, ** if > 2 g Li, *** if hazardous for the environment
22
New UN 3537-3548: example: filling station, containing a coolant:
contains 2,3,3,3-Tetrafluorpropene („R1234yf“) = UN 3161 2F=2.1, > 0
= UN 3537 ARTICLES CONTAINING FLAMMABLE GAS, N.O.S. (2,3,3,3-

Tetrafluorpropene), 2.1
23
New UN 3537-3548: example: gas chromatographe:
He = UN 1046 2.2, > 120 ml

Air = UN 1002 2.2, > 120 ml
H2 = UN 1049 2.1, > 0
= UN 3537 UN 3537 ARTICLES CONTAINING FLAMMABLE GAS, N.O.S.

(hydrogen, compressed), 2.1
ADR, 2.1.5.5 1st sentence, 2.2.2.1.3 3rd sentence
24
New UN 3537-3548: example: switch device, gas isolated:
contains SF6 = UN 1080 2A = 2.2, > 120 ml
= UN 3538 ARTICLES CONTAINING NON-FLAMMABLE, NON-TOXIC GAS,

N.O.S. (sulphur hexafluoride), 2.2
25
New UN 3537-3548: example: sodium vapour lamps:
- > 1 g sodium per each lamp (bulp)

- 408 pieces in 34 boxes = 12 pieces per each box x 3 g = 36 g per box
 1.1.3.10 (b) of ADR is not applicable
= UN 3543 ARTICLES CONTAINING A SUBSTANCE WHICH EMITS
FLAMMABLE GAS IN CONTACT WITH WATER, N.O.S. (sodium), 4.3
26
New UN 3537-3548: example: gearbox:
Contains UN 3082 9 III, > 5 l
= UN 3548 ARTICLES CONTAINING MISCELLANEOUS DANGEROUS

GOODS, N.O.S. (…), 9
27
Example: self-inflating recovery device:
28
Is this classification correct???
component UN Qty LQ
Carbon dioxide 1013 1 lb = 453,59 g 120 ml
Igniter 0454 0,035 g 0
Battery 3090 0,54 g [2 g] (SP 188)
Result UN 3363 is not applicable as UN 0454 is not accepted as LQ
Correct is UN 0349 ARTICLES, EXPLOSIVE, N.O.S., 1.4S
Additional marking with ???

29
3.3.1 Special Amendments to existing Special Provisions:

Provisions - 186/A89 (applies to UN 2067, 2071)
- 188 (applies to UN 3090, 3091, 3480, 3481)
(f): when in overpack, overpack has to be marked with „OVERPACK“.
Note: Packages containing lithium batteries packed in conformity with the provisions of Part 4,
Chapter 11, Packing Instructions 965 or 968, Section IB of the ICAO Technical Instructions for the
Safe Transport of Dangerous Goods by Air that bear the
• mark as shown in 5.2.1.9 (lithium battery mark) and
• label shown in 5.2.2.2.2, Model No. 9A
shall be deemed to meet the provisions of special provision 188.
Shipment is under SP188!

30
- 240/A21 (applies to UN 3171)

- 251/A44 (applies to UN 3316)
- 307/A79 (applies to UN 2067, 2071)
- 310 (applies to UN 3090, 3091, 3480, 3481: new LP905)
Note: = M306
- 312/A134 (applies to UN 3166)
- 363/A208 (applies to UN 3528-3530):
-- This entry may only be used when the conditions of this special provisios are met. No other
requirements of these regulations apply.
-- (g) The engine or machinery are not subject to any other requirements of these Regulations if the
following requirements are met:
-- (ig) …
-- (iih) …
-- (iiii) …
-- (ivj) …
-- (vk) …
-- (vil) … new: When the carriage is known beforehand to pass through a tunnel with restrictions for
carriage of dangerous goods, the transport unit shall display orange-coloured plates according to
section 5.3.2 and the tunnel restrictions according to section 8.6.4 apply
(for UN 3528 = D, for UN 3529 = B, for UN 3530 = E).
-- (m) The requirements specified in packing instruction P005 of 4.1.4.1 shall be met.
- 376 (applies to UN 3090, 3091, 3480, 3481: new P911, LP906)
Note: = M307
- 385/A207 (applies to UN 3166)
- 392 (applies to UN 1011, 1049, 1075, 1954, 1965, 1969, 1971, 1972, 1978)
31
- 636 (applies to UN 3090, 3091, 3480, 3481) (for UN 3091, 3481: new SP670)
- 660 (applies to UN 1011, 1049, 1075, 1954, 1965, 1969, 1971, 1972, 1978
1002, 1006, 1013, 1046, 1056, 1058, 1065, 1066, 1080, 1952, 1956, 2036,
3070, 3163, 3297, 3298, 3299)
- 666 (applies to UN 3166, 3171): SP240, 312, 385388
- 667 (applies to UN 3166, 3171, 3528-3530, new 3363, 3537-3548)
New Special Provisions:
- 193 (applies to UN 2067, 2071)
- 301 (applies to UN 3363)
- 387/A213 (applies to UN 3090, 3091, 3480): Lithium batteries in conformity with
2.2.9.1.7 (f) containing both primary lithium metal cells and rechargeable lithium ion cells shall be
assigned to UN Nos. 3090 or 3091 as appropriate. When such batteries are transported in
accordance with special provision 188, the total lithium content of all lithium metal cells contained
in the battery shall not exceed 1.5 g and the total capacity of all lithium ion cells contained in the
battery shall not exceed 10 Wh.
- 388/A214 (applies to UN 3166, 3171) (= replaces SP 312, 380 and
385)
- 389 (applies to new UN 3536):
This entry only applies to lithium ion batteries or lithium metal batteries installed in a
cargo transport unit and designed only to provide power external to the cargo transport
unit. … The batteries inside the cargo transport unit are not subject to marking or
labelling requirements. The CTU shall bear
- orange-coloured plates in accordance with sub-section 5.3.2.2
- placards in accordance with sub-section 5.3.1.1
on two opposing sides:
32
Note: IMDG Code:

- 390 (reserved)
- 391 (reserved)
- 660392 (applies to UN 1011, 1049, 1075, 1954, 1965, 1969, 1971, 1972,
1978)
- 670 (applies to UN 3091, 3481)
- 673 (applies to RID only)
- 674 (applies to UN 1011, 1075, 1965, 1969, 1978) (see 6.2.3.5.3 + 6.2.3.5.4)
33
4.1.4.1 Packagings: Amendments to existing Packing Instructions:

use: - P001:
P Composite packagings PG I
Plastics receptacle with outer steel or aluminium or 250 l
plastics drum (6HA1, 6HB1, 6HH1)
Plastics receptacle with outer fibre or plastics or 120 l
plywood drum (6HG1, 6HH1, 6HD1)
- P520: PP94, PP95
New Packing Instructions:
- P006 (applies to new UN 3537-3548)
- P907 (applies to UN 3363)
- P911 (applies to UN 3090, 3091, 3480, 3481 due to SP376 6th
sentence)
…/X/… + additional requirements, approved by tests
4.1.4.3 Packagings: Amendments to existing Packing Instructions:
use: LP902 (applies to UN 3268):
LP … Rigid large packagings conforming tot he PG III performance level,
made of:
- steel (50A)
- aluminium (50B)
- metal other than steel or aluminium (50N)
- rigid plastics (50H)
- natural wood (50C)
- plywood (50D)
34
- reconstituted wood (50F)

- rigid fibreboard (50G)
New Packing Instructions:
- LP03 (applies to new UN 3537-3548)
- LP905 (applies to UN 3090, 3091, 3480, 3481 due to SP310)
- LP906 (applies to UN 3090, 3091, 3480, 3481 due to SP376 6th
sentence)
…/X/… + additional requirements, approved by tests
35
4.2.5.3 Portable tanks, Amendment to an existing Special Provision:

MEGCs: use: Special TP10 (applies to UN 1744)
Provisions Note: = new TU43
4.3.5 ADR/RID tanks: New Special Provisions:
use: Special - TU42: Tanks with a shell constructed of aluminium alloy,
Provisions including those with a protective lining, shall only be used if the
pH value of the substance is not less than 5.0 and not more than
8.0
Notes:
Background: incident on 3rd July 2013 (!) in NL with UN 1789 HYDROCHLORIC ACID 8:
For
-- “protective lining”  1.2.1
-- transitional measure  1.6.3.48 resp. 1.6.4.50
- TU43 (applies to UN 1744)
Note: = amended TP10
36
5.2.1, Consignment Note: In accordance with the GHS, a GHS pictogram not required by
5.3 procedures: the DG regulations should only appear in transport as part of a
marking / complete GHS label and not independently (see GHS 1.4.10.4.4).
labelling / Example 1: packaging (gas cylinder):
placarding
packagings /
vehicles,
containers
etc.
37
Example 2: portable tank:
Note: Marking/Labeling of tanks according to GHS/CLP is NOT required by GHS/CLP.
38
Example 3: box container:
39
To avoid confusion:
40
5.2.1.3 Consignment Salvage packagings including large salvage packagings and salvage
procedures:
packagings: pressure receptacles shall additionally be marked with the word
marking „SALVAGE“.
5.2.2.2.1.1.2
Consignment … The minimum
procedures: - dimensions shall be 100 mm x 100 mm
packagings: - width of the line inside the edge forming the diamond shall be 2 mm.
5.2.2.2.1.1.3
labeling If the size of the package so requires the dimensions may be reduced
proportionally, provided the symbols and other elements of the label
remain clearly visible.
The line inside the edge shall remain 5 mm to the edge of the label.
The minimum width of the line inside the edge shall remain 2 mm.
Dimensions for cylinders shall comply with 5.2.2.2.1.2.
5.3.1.1.1 Consignment Shall be weather-resistant
procedures:
placards Note: IMDG Code: 5.3.1.1.1.2: 3 months in salt water
5.3.1.2 Consignment Flexible bulk-containers (BK3): 42 sides (as orange-coloured plates)
procedures:
placards
5.3.6.1 Consignment procedures:
mark for substances Not required, if mark on package is not required according to 5.2.1.8.1
hazardous for the
environment (max 5 l resp. 5 kg per package)
41
5.4.1.1.1 Consignment (f) NOTE 1: In the case of intended application of 1.1.3.6, the
procedures: - total quantity and
transport - the calculated value
document: of dangerous goods for each transport category shall be indicated in the
general transport document in accordance with 1.1.3.6.3 and 1.1.3.6.4.
provisions Note: example:
UN proper shipping name label PG TRC quantity package each transport category
0 1 2 3 4
UN 1965 Propane 2.1 (B/D) 5 cylinder 10 kg 50
UN 1203 Motor spirit, 3 II (D/E) 1 drum 200 l 200
environmentally hazardous
UN 1202 Diesel fuel, environmentally 3 III (D/E) 1 drum 200 l 200
hazardous
Total quantity per 250 200
each transport
category
Multiplier 1000 50*) 3 1 -
Product 750 200
[sum of products]**) [950]
**)
*) UN 0081, 0082, 0084, 0241, 0331, 0332, 0482, 1005, 1017: 20.
**) not required!
5.4.1.1.5 Consignment When dangerous goods are carried in a salvage packing including large
procedures:
transport salvage packaging or salvage pressure receptacle, the words “SALVAGE
document: special PACKAGING” or “SALVAGE PRESSURE RECEPTACLE” shall be added
provisions after the description of the goods in the transport document.
42
6.2.3.5.3 Pressure receptacles:

construction and
Over-moulded cylinders
6.2.3.5.4
testing Note:  SP674
6.8.2.1.23 Tank: construction: Lap joints / welds in the knuckle area of the tank ends
welding
For transitional measure: 1.6.3.51 resp. 1.6.4.53
6.8.2.2.3 Tank: construction: Flame arresters for breather devices
flame arresters
6.8.2.2.10 Tank: construction: Pressure (min/max) for rupture
bursting disc
6.8.2.2.11 Tank: construction: Made of glass or other fragile material
level-gauges
6.8.2.3.1 Tank: construction: Approval number for the type = distinguishing sign + registration number
type approval
(as for tank containers)
For transitional measure: 1.6.3.53
6.8.3.2.9 Tank: construction: Protection from entry of water
safety valves
43
7.1.7 Transport, Replaces

loading/unloading,
handling: special - 7.2.4 V8
provisions to - 8.5 S4
class 4.1 SR2,
class 5.2 P2 and
other substances
stabilized by
temperature
control
7.3.3.1 Transport, bulk Note: If in table A column (17) code
- VC1 is shown, a BK1 container may also be used
- VC2 is shown, a BK2 container may also be used
Example: UN 3432 9 II
7.5.7.4 Loading/unloading, Tank-containers, portable tanks, MEGCs not equipped with corner castings:
handling
see 9.7.3
9.7.3 Vehicles: Specification what is required in detail

fastenings
Notes:
Not applicable for twist lock tie-down devices according to ISO 1161
For transitional measure see 1.6.5.22.
44
Specific rail: RID:

[5.5.1.1.1 RID
Transport j) …
document
Example: wagon with a full load UN 1402:
option A: with hazard identification number:
„X423 UN 1402 CALCIUM CARBIDE 4.3 I“

45
Option B: without hazard identification number:
When the wagon is not marked with the hazard identification number, the
transport document shall not contain the hazard identification number:
„X423 UN 1402 CALCIUM CARBIDE 4.3 I“]
46
Specifics ocean: IMDG Code:

1.2.1 Definitions New: Tank of type IMO 9
Note: = battery vehicle; see new SP974
2.3.2.5 Classification: Flash point 23-60 °C, viscous: excepted if package ≤ 30450 litres
class 3 Note: as in 2.2.3.1.5.1 ADR/RID/ADN
3.1.4.4 Segregation groups The segregation groups are codified in segregation group codes
(„SGG“).
Do not mix up with the segregation codes of 7.2.8 (“SG”)!
1 = SGG1/1a
…
18 = SGG18
Note: = 7.2.5.2
3.1.4.4.3 3213 Ammonium bromate
3.1.4.4.7 1366 Diethylzinc
1370 Dimethylzinc
3.2 Dangerous Goods Amendments to existing entries:
List - classes 1-9: inclusion of the new segregation group codes SGG
- class 1: stowage category 04 05 03
- UN 0124, 0494: SW30
- UN 1016, 1046, 1049: SP974
- UN 1327, 1363, 1364, 1365, 1386, 1856, 2216, 2217, 2698, 3360:
SP973
- UN 2017: SP186193
47
- UN 2216: SP945308
- UN 2977, 2978: SG76, SG78
- UN 3363: SV301
- UN 3507: SG77
3.3.1 Special Provisions Amendments to existing SP:
- 186193 (applies to UN 2071)
- 945308 (applies to UN 2216)
New SP:
- 973 (applies to UN 1327, 1363, 1364, 1365, 1386, 1856, 2216,
2217, 2698, 3360)
- 974 (applies to UN 1016, 1046, 1049 in IMO tank type 9)
6.8.3.4 Road vehicles For compressed gases (IMO tank type 9, „battery vehicle“)
Note: applies to UN 1016, 1046, 1049 = new SP974
7.1.5 Stowage codes new: SW30 (applies to UN 0124, 0494)
7.2.5 Segregation group new: segregation group codes SGG1-SGG18
codes Note: = 3.1.4.4
7.2.8 Segregation codes Amendments to existing segregation codes:
- SG1
- several segregation codes SGXY are amended by the new
segregation group codes SGG XY
48
New segregation codes:

- SG76 (applies to UN 2977, 2978)
- SG77 (applies to UN 3507)
- SG78 (applies to UN 2977, 2978)
Index substance MP class UN
Dodecene (except 1-dodecene), see P 3 2850
1-dodecene - 3 2850
49
Liquids, flash point ≤ 60 °C, viscous:

PG ADR/RID/ADN IMDG Code IATA DGR
2.2.3.1.4: 2.3.2.2: 3.3.3.1.1:
I II  III
…/Z/… …/Z/… …/Z/… …/Z/…

UN …. UN …. UN …. UN ….
( ) ( ) ( )
H225 H225 H225 H225
≤ 450 l ≤ 30 l ≤ 30 l ≤ 100 l
„UN XXXX 3.3.3.1.1“ (8.1.6.11.6 IATA DGR)
2.2.3.1.5.1: 2.3.2.5: -
III
… …
UN …. UN ….
H226 H226
≤ 450 l ≤ 30450 l
„Transport in accordance with 2.3.2.5 of the
IMDG Code“
50
Specifics air: IATA DGR:

4.4 Special Provisions A59 (applies to tire assembly, unserviceable or damaged):
completely deflatedgauge pressure is less than 200 kPa at 20 °C
A67 (applies to UN 2800 = batteries, wet, non-spillable): test
criteria: vibration test and pressure differential test
A154 (applies to UN 3090 resp. 3480, damaged/defective, including
UN 3091 resp. 3481): clarification that the prohibition includes
cells/batteries that cannot be diagnosed as damaged/defective
prior to transport.
A201 (applies to UN 3090 resp. 3480: exemption from the prohibition
to transport lithium batteries on passenger aircraft: clarification that
the exemption is restricted to batteries under PI965 resp. PI968,
each section II.
51
until 2018 / 2020:
►shipper/packer/forwarding agents let train their employees according to resp.

personal category by an approved training company
as from 2019 (non mandatory) / 2021 (mandatory):
►Employer creates a training programme, reflecting the obligations as:

►shipper  1.3 IATA DGR
►packer  1.3 IATA DGR
►forwarding agent  1.3.3.2.6 IATA DGR
Germany: master training programme by German Association of
Forwarding Agents DSLV under preparation
►airlines  1.4 IATA DGR
►training programme has to be accepted by resp. national authority
►training company has to be approved by IATA / resp. national authority

Presentation Dangerous Goods 2019

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Presentation Dangerous Goods 2019

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1

Dangerous Goods Regulations Amendments 2019

„Orange Book“ 1920th edition 20152017

IMDG Code (Sea) Amendment 39-18 2019-01-01 2020-01-01

IATA DGR (Air) 60th Edition 2019 - 2019-01-01

ADR/RID/ADN: Amendments 2019:

c) All relevant requirements of ADR with regard to filling ratios

1.2.1 Definitions Amendment to an existing definition:

1.6.1.1 Transitional measures: general ADR/RID/ADN 20152017 applicable until

1.6.3.48 Applies to new special provision TU42: applicable for

1.6.3.49 Applies to amended 6.8.2.2.10

1.9.5.2.2 Tunnel categories B: class 2: UN 3529

Classification of articles as articles

except if corrosive to metals

- Entries with specific concentration limits (11):

substance dangerous good

example 1: sodium hydroxide PG II:

NaOH dangerous good hazardous mixture

2 8 III H290 H314 1B

0,5 H290 H315 H319

example 2: hydrochloric acid PG II:

HCl dangerous good hazardous mixture

25 8 II H290 H314 1B H335

10 H290 H315 H319 H335

0,1*) 8 III H290

2.2.9.1.7 Classification: 3rd sentence:

(f) Lithium batteries, containing both primary lithium

(g) Manufacturers and subsequent distributors of cells or

Note: as from 1 January 2020

Consequence: “either or” as from 2019

3.2 List of DG in UN Amendments to existing entries:

New UN numbers (14):

UN PROPER SHIPPING NAME Label PG Special Provisions Packing Instructions

Dangerous goods in articles1)

*) example: a pencil contains 5 ml of UN 1210 PRINTING INK 3 II  UN 3363

New UN 3537-3548: example:

Note: as from 01.01.2023 / excepted until 31.12.2022

* resp. ** *** * bzw. **

* if ≤ 2 g Li, ** if > 2 g Li, *** if hazardous for the environment

New UN 3537-3548: example: filling station, containing a coolant:

contains 2,3,3,3-Tetrafluorpropene („R1234yf“) = UN 3161 2F=2.1, > 0

= UN 3537 ARTICLES CONTAINING FLAMMABLE GAS, N.O.S. (2,3,3,3-

New UN 3537-3548: example: gas chromatographe:

He = UN 1046 2.2, > 120 ml

= UN 3537 UN 3537 ARTICLES CONTAINING FLAMMABLE GAS, N.O.S.

New UN 3537-3548: example: switch device, gas isolated:

contains SF6 = UN 1080 2A = 2.2, > 120 ml

= UN 3538 ARTICLES CONTAINING NON-FLAMMABLE, NON-TOXIC GAS,

New UN 3537-3548: example: sodium vapour lamps:

- > 1 g sodium per each lamp (bulp)

New UN 3537-3548: example: gearbox:

Contains UN 3082 9 III, > 5 l

= UN 3548 ARTICLES CONTAINING MISCELLANEOUS DANGEROUS

Example: self-inflating recovery device:

Is this classification correct???

Additional marking with ???

3.3.1 Special Amendments to existing Special Provisions:

Shipment is under SP188!

- 240/A21 (applies to UN 3171)

Note: IMDG Code:

4.1.4.1 Packagings: Amendments to existing Packing Instructions:

- reconstituted wood (50F)

4.2.5.3 Portable tanks, Amendment to an existing Special Provision:

Example 2: portable tank:

* resp. * * bzw. **

* if ≤ 2 g Li, if > 2 g Li, * if hazardous for the environment