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Ring opening reactions

O 0132 DOI: 10.1002/chin.201519048


Highly Enantioselective Ring-Opening Reactions of Aziridines with Indole and
19- 048 Its Application in the Building of C3-Halogenated Pyrroloindolines. — A magne-
sium-catalyzed asymmetric ring-opening reaction of aziridine with indole is realized
by employing commercially available chiral ligands. The ring-opening product can
be further transformed to various types of enantioenriched C3-halogenated-pyrrolo-
indolines. — (YANG, D.; WANG, L.; HAN, F.; LI, D.; ZHAO, D.; CAO, Y.; MA, Y.;
KONG, W.; SUN, Q.; WANG*, R.; Chem. - Eur. J. 20 (2014) 50, 16478-16483,
http://dx.doi.org/10.1002/chem.201404354 ; Sch. Life Sci., Lanzhou Univ., Lanzhou,
Gansu 730000, Peop. Rep. China; Eng.) — U. Scheffler

ChemInform 2015, 46, issue 19 © 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim