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2. Hazards identification
GHS Classification
Skin corrosion, Category 1A H314: Causes severe skin burns and eye damage.
Acute toxicity, Category 4, Oral H302: Harmful if swallowed.
Corrosive to metals H290: May be corrosive to metals.
EC Classification
C; R35
Xn; R22
For the full text of the R-phrases mentioned in this Section, see Section 16.
3. Composition/information on ingredients
Formula KOH HKO (Hill)
CAS-No. 1310-58-3
Index-No. 019-002-00-8
EC-No. 215-181-3
Molar mass 56,11 g/mol
5. Fire-fighting measures
The Safety Data Sheets for catalog items are also available at www.merck-chemicals.com
Page 1 of 7
Safety Data Sheet
according to Regulation (EC) No. 1907/2006
Personal precautions
Avoid substance contact. Avoid generation of dusts; do not inhale dusts.
Environmental precautions
Do not empty into drains.
Methods for cleaning up
Take up carefully. Forward for disposal. Clean up affected area.
Storage
Further information on storage conditions
Requirements for storage areas and containers
No aluminium, tin, or zinc containers.
Tightly closed. Dry.
Store at +5°C to +30°C.
Colour colourless
Odour odourless
pH ca. 14
at 56 g/l
20 °C
Vapour pressure at 20 °C
not applicable
The Safety Data Sheets for catalog items are also available at www.merck-chemicals.com
Page 3 of 7
Safety Data Sheet
according to Regulation (EC) No. 1907/2006
Conditions to avoid
no information available
Materials to avoid
Risk of explosion with:
Violent reactions possible with:
Metals, Light metals, ammonium compounds, Alkaline earth metals, halogens, halogen-halogen
compounds, Halogenated hydrocarbon, nonmetallic oxyhalides, halogen oxides, organic nitro
compounds, phosphorus, nonmetallic oxides, Hydrocarbons, anhydrides, Strong acids, azides
Hazardous decomposition products
no information available
Further information
strongly hygroscopic, exothermic dissolution process with water
incompatible with:
glass, animal/vegetable tissues, various plastics, Metals
The Safety Data Sheets for catalog items are also available at www.merck-chemicals.com
Page 4 of 7
Safety Data Sheet
according to Regulation (EC) No. 1907/2006
Eye irritation
rabbit
Result: Causes burns.
(IUCLID) Risk of blindness!
Sensitisation
Sensitization test: guinea pig
Result: negative
(IUCLID)
Genotoxicity in vitro
Ames test
Escherichia coli
Result: negative
(IUCLID)
Further information
Handle in accordance with good industrial hygiene and safety practice.
The Safety Data Sheets for catalog items are also available at www.merck-chemicals.com
Page 5 of 7
Safety Data Sheet
according to Regulation (EC) No. 1907/2006
ADR/RID
UN 1813 POTASSIUM HYDROXIDE, SOLID, 8, II
IATA
UN 1813 POTASSIUM HYDROXIDE, SOLID, 8, II
IMDG
UN 1813 POTASSIUM HYDROXIDE, SOLID, 8, II
EmS F-A S-B
The transport regulations re cited according to international regulations and in the form applicable
in Germany. Possible national deviations in other countries are not considered.
Signal word
Danger
Hazard statements
H314: Causes severe skin burns and eye damage.
H302: Harmful if swallowed.
H290: May be corrosive to metals.
Precautionary statements
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P330 + P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P309 + P310: IF exposed or if you feel unwell: Immediately call a POISON CENTER or
doctor/physician.
Signal word
Danger
Hazard statements
H314: Causes severe skin burns and eye damage.
Precautionary statements
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P330 + P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
The Safety Data Sheets for catalog items are also available at www.merck-chemicals.com
Page 6 of 7
Safety Data Sheet
according to Regulation (EC) No. 1907/2006
Index-No. 019-002-00-8
Labelling according to EC Directives
Symbol(s): C Corrosive
National legislation
Storage class VCI: 8 B Non combustible, corrosive substances
Major Accident Hazard 96/82/EC Update: 2003
Legislation: Directive 96/82/EC does not apply
Other regulations: Take note of Dir 94/33/EC on the protection of young people at
work. Take note of Dir 92/85/EEC on the safety and health at work
of pregnant workers.
Regional representation: This information is given on the authorised Safety Data Sheet for
your country.
The information contained herein is based on the present state of our knowledge. It characterizes the product with
regard to the appropriate safety precautions. It does not represent a guarantee of the properties of the product.
The Safety Data Sheets for catalog items are also available at www.merck-chemicals.com
Page 7 of 7