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“UNIVERSIDAD NACIONAL DEL CENTR

FACULTAD DE INGENIERIA QUÍ


E.A.P INGENIERIA QUIMICA AMBIEN

CATEDRA: TERMODINAMICA DE LOS PROCESOS QUIMICOS II


CATEDRATICO: SALVADOR ORE VIDALON
ALUMNO: Fernndebaca Barrientos

SISTEMA ISOBARICO n-HEXANO (1)- BENCENO (2)

ECUACION DE VAN LAAR


A12 A 12
log γ 1= x1 A
x1 A 12 (
( )
( 1+
( 1+ )2 γ 1 =10
x2 A
x2 A 21
A 21
A21
log γ 2 = x2 A
x 2 A 21 ( ( 1+

(
( 1+
x 1 A 12
)2
) γ2 =10
x1 A

n-Hexano Benceno
P mmHg= 760

A 6.87776 6.90565
B 1171.53 1211.033
C 224.366 220.79

Parámetros de Van Laar: Cálculo del coeficiente de actividad:

TºC Presion TºK x1 x2


A 12= 0.2063 80.087008108 760 353.23700811 0.001 0.999
76.811030722 760 349.96103072 0.1 0.9
A 21 = 0.1467 74.616033486 760 347.76603349 0.2 0.8
73.038015869 760 346.18801587 0.3 0.7
71.844181564 760 344.99418156 0.4 0.6
70.912896625 760 344.06289663 0.5 0.5
70.178557027 760 343.32855703 0.6 0.4
69.606001561 760 342.75600156 0.7 0.3
69.177713673 760 342.32771367 0.8 0.2
68.887128422 760 342.03712842 0.9 0.1
68.735919805 760 341.88591981 0.999 0.001

DIAGONAL
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1
ACIONAL DEL CENTRO DEL PERÚ”

D DE INGENIERIA QUÍMICA
NIERIA QUIMICA AMBIENTAL

BENCENO (2)

VAN LAAR
A 12
x 1 A 12

=10
(( 1+
x 2 A 21
)2
)
1

A 21
x 2 A 21

=10
(( 1+
x 1 A 12
)2
)
2

A 12= A 21 = γ 1= γ 2= Pvp1 Pvp2 y1


0.2063 0.1467 1.6059070909 1.0000006675 1070.969242461 759.6960850336 0.0022629962
0.2063 0.1467 1.4266254259 1.0061877669 972.5714827883 686.0136807539 0.1825651587
0.2063 0.1467 1.2969812426 1.0231185607 910.6762565506 639.8761945032 0.3108236902
0.2063 0.1467 1.2031392072 1.0489267676 868.1067061136 608.245772808 0.4122841635
0.2063 0.1467 1.1348939525 1.0822997831 836.9446959345 585.1465971737 0.4999176179
0.2063 0.1467 1.0854992457 1.1222891904 813.247660882 567.6132909443 0.5807761332
0.2063 0.1467 1.0503584356 1.1681921777 794.9342582069 554.0830338641 0.6591836083
0.2063 0.1467 1.0262544751 1.2194749638 780.880472002 543.711791072 0.7381150727
0.2063 0.1467 1.0108813856 1.2757221338 770.4954669928 536.0547710874 0.8198731845
0.2063 0.1467 1.0025503102 1.3366023961 763.5111895817 530.9084430363 0.906463871
0.2063 0.1467 1.0000002403 1.4011717644 759.8965111979 528.2460329794 0.9988642068
y2 y1+y2
0.9986011783 1.0008641745
0.8174114686 0.9999766273
0.6891254854 0.9999491756
0.5876364351 0.9999205986
0.4999768699 0.9998944878
0.4190962242 0.9998723574
0.3406712979 0.9998549062
0.2617274671 0.9998425398
0.1799623517 0.9998355362
0.093370197 0.999834068
0.0009738992 0.999838106
N-HEXANO & BENCENO
1

0.9

0.8
fraccin molar de Y

0.7

0.6

0.5 Y1 Vs X1
diagonal
eXPERIMENTAL
0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
FRACCIN MOLAR DE X
N-HEXANO & BENCENO
354

352

350

348

346

T vs x
T

344
T vs Y
ESPERIMENTAL
342 EXPERIMENTAL

340

338

336

334
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1,Y1
ECUACION DE WILSON

Presión(bar)= 760
ln γ 1=−ln ( x 1+ Λ12 x 2 ) +x 2
[ Λ12

Λ21
x 1 + Λ12 x 2 Λ 21 x 1 +x 2 ] [
γ 1=exp −ln ( x 1 + Λ 12 x 2 ) +

ln γ2=−ln ( x 2+ Λ21 x1 )−x 1


[ Λ12

Λ 21
x 1+ Λ12 x 2 Λ21 x 1 +x 2 ] [
γ 2=exp −ln ( x 2+ Λ 21 x 1 )−

v 1= 57.939
v2 λ 12
v 2= 86.1 Λ 12=
v1
exp −
RT ( ) Λ 21 =
v1
v2
e

metanol 2-propanol
12  11  88.2 A 7.878663 6.6604
B 1473.11 813.055
12  22  -30.19 C 230 132.93

R= 1.987 TªC R Presion T (K) x1


82.1864335 1.987 760 355.33643345 0
78.0994055 1.987 760 351.24940553 0.1
77.7836933 1.987 760 350.93369335 0.2
75.1259302 1.987 760 348.27593018 0.3
73.920174 1.987 760 347.07017399 0.4
72.907177 1.987 760 346.057177 0.5
70.5275144 1.987 760 343.67751437 0.6
71.0517979 1.987 760 344.20179794 0.7
67.4933486 1.987 760 340.64334863 0.8
69.4782709 1.987 760 342.62827089 0.9
64.7491071 1.987 760 337.8991071 1

DIAGONAL
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1
WILSON

[
γ 1 =exp −ln ( x 1 + Λ 12 x 2) +x 2
[ Λ12

Λ 21
x 1+ Λ 12 x 2 Λ21 x 1 +x 2 ]
[
γ 2=exp −ln ( x 2+ Λ 21 x 1)−x 1
[ Λ 12

Λ21
x1 + Λ12 x2 Λ21 x 1+ x2 ]
v1 λ 21
Λ 21 =
v2
exp −
RT ( )

x2 v 1= v 2= 12  11  12  22  Λ12= Λ21=


1 57.939 86.1 88.2 -30.19 1.3115359943 0.7023243964
0.9 57.939 86.1 88.2 -30.19 1.3096310267 0.7026739093
0.8 57.939 86.1 88.2 -30.19 1.3094821435 0.7027012543
0.7 57.939 86.1 88.2 -30.19 1.3082187796 0.7029334614
0.6 57.939 86.1 88.2 -30.19 1.3076396527 0.703040006
0.5 57.939 86.1 88.2 -30.19 1.307150189 0.7031301042
0.4 57.939 86.1 88.2 -30.19 1.3059897568 0.7033438922
0.3 57.939 86.1 88.2 -30.19 1.3062467107 0.7032965312
0.2 57.939 86.1 88.2 -30.19 1.3044881751 0.7036209094
0.1 57.939 86.1 88.2 -30.19 1.3054733088 0.7034391201
0 57.939 86.1 88.2 -30.19 1.3031083741 0.7038758377
DIAGONAL:
0 0

0.2 0.2
0.4 0.4
0.6 0.6
0.8 0.8
1 1

γ 1= γ 2= Pvp1 Pvp2 y1 y2 y1+y2


1.0268302587 1 1445.36058911 759.9686644 0 0.9999587689 0.9999587689
1.0244838749 1.0001827347 1251.35767168 642.08970252 0.1686836521 0.7605083304 0.9291919826
1.0209974242 1.0008035886 1237.30569938 633.61149984 0.3324436663 0.6674954345 0.9999391009
1.0178372009 1.0020416919 1124.0548634 565.63013236 0.4516203378 0.5220387926 0.9736591304
1.0143552324 1.0040308373 1075.55756985 536.7265473 0.5742091835 0.4254394774 0.9996486609
1.0109122597 1.0069846157 1036.15323836 513.34458301 0.6891184287 0.3400855905 1.0292040192
1.0077362759 1.0113125294 948.233892721 461.54009131 0.754397125 0.2456638301 1.0000609551
1.0047192108 1.0168712671 967.056610348 472.58575619 0.8949134843 0.1896942934 1.0846077777
1.0023486405 1.0250973252 845.127121608 401.52442302 0.8916968646 0.1083162137 1.0000130783
1.0006331419 1.0345564358 911.468894397 440.04185727 1.0800544542 0.0599010705 1.1399555247
1 1.0492177969 760.009798295 352.69214599 1.0000128925 0 1.0000128925
N-HEXANO & BENCENO
1

0.9

0.8

0.7

0.6
T

Experimenta
0.5
l
DIAGONAL
X VS Y
0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1,Y1
N-HEXANO & BENCENO
354

352

350

348

346

T vs x
T

344 T vs Y
Experimenta
l
342 xperimental

340

338

336

334
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1,Y1
N-HEXANO BENCENO
P mmHg= 760

A 6.87776 6.90565
B 1171.53 1211.033
C 224.366 220.79

Parámetros de Van Laar: Cálculo del coeficiente de actividad:

TºC Presion TºK x1 x2 A 12=


A 12= 0.201 80.058601744 760 353.20860174 0.001 0.999 0.201
76.578096241 760 349.72809624 0.1 0.9 0.201
A 21 = 0.143 73.901108467 760 347.05110847 0.2 0.8 0.201
71.965961866 760 345.11596187 0.3 0.7 0.201
70.589056047 760 343.73905605 0.4 0.6 0.201
69.665123255 760 342.81512326 0.5 0.5 0.201
69.105599801 760 342.2555998 0.6 0.4 0.201
68.828859631 760 341.97885963 0.7 0.3 0.201
68.749125758 760 341.89912576 0.8 0.2 0.201
68.763047929 760 341.91304793 0.9 0.1 0.201
68.734945334 760 341.88494533 0.999 0.001 0.201

DIAGONAL
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1
A 21 = γ 1= γ 2= Pvp1 Pvp2 y1 y2 y1+y2
0.143 1.5875008596 1.0000005961 1070.0841631 759.03157705 0.0022352099 0.9977276283 0.9999628382
0.143 1.4866406371 1.005712852 965.85236555 680.99699836 0.1889309705 0.811050908 0.9999818785
0.143 1.3915153453 1.0219555346 891.19326862 625.38919579 0.3263445023 0.672757842 0.9991023444
0.143 1.3047941473 1.0475578123 840.08287246 587.47063729 0.4326849534 0.5668244986 0.9995094519
0.143 1.2276201266 1.0814737935 805.13134924 561.61467026 0.520208131 0.4795038536 0.9997119846
0.143 1.1607802227 1.122664526 782.32259393 544.77554729 0.5974372334 0.4023685405 0.9998057739
0.143 1.104831378 1.1699949844 768.75755056 534.77394837 0.6705374715 0.3293067565 0.999844228
0.143 1.0602249008 1.2221429307 762.11667008 529.88121759 0.7442244074 0.2556278622 0.9998522696
0.143 1.0274294261 1.2775208593 760.21166782 528.47813469 0.8221724607 0.1776689055 0.9998413661
0.143 1.0070568781 1.3342155563 760.54402757 528.7229118 0.9069999798 0.0928197808 0.9998197606
0.143 1.0000007297 1.389408371 759.87325975 528.22890933 0.9988341321 0.0009656917 0.9997998237
1

0.9

0.8
fraccin molar de Y

0.7

0.6
experimenta
l
0.5 Y1 Vs X1
diagonal

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
356

354

352

350
Axis Title

348

T vs Y
346 T vs X
experimenta
l
experimenta
344 l

342

340

338

336
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Axis Title
DATOS EXPERIMENTALES:
X Y T
0.0513 0.108 351.1
0.1216 0.216 349.1
0.2189 0.334 347
0.3108 0.422 345.6
0.3811 0.483 344.7
0.503 0.579 343.6
0.6031 0.657 342.9
0.7171 0.746 342.3
0.7982 0.814 342
0.8982 0.902 341.9
0.9402 0.942 341.8
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre"

Presion Total 1

DATOS EXPERIMENTALES:
x y T (K)
0 0 349.85
0.002 0.02 349.25
0.002 0.027 349
0.004 0.12 345.5
0.013 0.2415 340.75
0.017 0.264 340 Presion T x1 x2
0.03 0.333 335.15 1 345.79955166 0.001 0.999
0.0505 0.445 332.55 1 321.90168544 0.1 0.9
0.107 0.49 330.35 1 324.01678724 0.2 0.8
0.124 0.5 330.1 1 325.03754578 0.3 0.7
0.248 0.522 329.4 1 325.42651595 0.4 0.6
0.401 0.5365 328.95 1 325.51646079 0.5 0.5
0.505 0.5483 328.85 1 325.5160035 0.6 0.4
0.55 0.552 328.8 1 325.7511579 0.7 0.3
0.603 0.561 328.85 1 326.71862317 0.8 0.2
0.727 0.595 329.15 1 329.51356577 0.9 0.1
1 1 337.85 1 337.1684589 0.999 0.001

CALCULO DE LOS COEFICIENTES DE ACTIVIDAD:

  z    r    21 12 
ln 1  ln 1   q1 ln 1   2 l1  1 l2   q1 ln1  2 21   2 q1   
x
 1 2 
 1  r2        
 1 2 21 2 1 12  

  z    r   12  21 
ln 2  ln 2   q2 ln 2   1 l2  2 l1   q2 ln2  112  1q2   
x
 2 2 
 2  r1        
 2 1 12 1 2 21  

  a12 
 12  exp  
ri x qi xi  T 
z 
li   ri  qi    ri 1
 i  i
i 
 ` a 21 
NC NC

2  r j x j  q j x j  21  exp  
j j
 T 

r1= 1.43
r2= 3.33
q1= 1.43
q2= 2.82
a21 = 1127.95
a12 = -29.64

z= 10
l 1 l 2  1  2  1  2  12  21
-0.43 0.22 0.0004296746 0.9995703254 0.0005073423 0.9994926577 1.0894951206 0.0383170316
-0.43 0.22 0.0455414013 0.9544585987 0.0533383066 0.9466616934 1.0964501259 0.0300762284
-0.43 0.22 0.0969491525 0.9030508475 0.1125098348 0.8874901652 1.0957912903 0.0307721015
-0.43 0.22 0.1554347826 0.8445652174 0.1785268414 0.8214731586 1.0954765404 0.0311103572
-0.43 0.22 0.2225680934 0.7774319066 0.2526501767 0.7473498233 1.095357145 0.0312396653
-0.43 0.22 0.3004201681 0.6995798319 0.3364705882 0.6635294118 1.0953295787 0.0312695986
-0.43 0.22 0.3917808219 0.6082191781 0.4320241692 0.5679758308 1.0953297188 0.0312694464
-0.43 0.22 0.5005 0.4995 0.541959935 0.458040065 1.0952577236 0.0313477619
-0.43 0.22 0.6320441989 0.3679558011 0.6697892272 0.3302107728 1.0949626628 0.0316708347
-0.43 0.22 0.7944444444 0.2055555556 0.8202676864 0.1797323136 1.0941204223 0.032611964
-0.43 0.22 0.9976744186 0.0023255814 0.998029887 0.001970113 1.0918882956 0.0352475108

CALCULO DE LAS PRESIONES DE VAPOR:

METANOL TETRACLORURO DE CARBONO


VP_A= -8.54796 VP_A= -7.07139
VP_B= 0.76982 VP_B= 1.71497
VP_C= -3.1085 VP_C= -2.8993
VP_D= 1.54481 VP_D= -2.49466
Pc= 80.9 Pc= 45.6
Tc= 512.6 Tc= 556.4

VP_A VP_B VP_C VP_D Pc Tc x


-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3254007966
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3720216827
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3678954599
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3659041245
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3651453064
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3649698385
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3649707306
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3645119822
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3626246134
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3571721308
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3422386678
ln  1  ln  2  1  2  Pvp1 Pvp2 y1
4.3196057214 1.780036E-05 75.158988869 1.0000178005 1.3851092664 0.8967860255 0.1041034119
2.4435700928 0.0930254377 11.514073766 1.0974896526 0.5268285804 0.3986324863 0.6065943136
1.5833902672 0.2384013964 4.8714433415 1.2692185503 0.5775894383 0.4307496854 0.5627388446
1.0762278513 0.4045511978 2.9335927058 1.4986297608 0.6035206269 0.4469715773 0.5311451126
0.7312673443 0.5887472832 2.0777121163 1.8017299437 0.6136559388 0.4532798066 0.5100001518
0.482072057 0.7917074339 1.6194264721 2.2071617937 0.6160198482 0.4547485683 0.4987994247
0.2984708225 1.0154812115 1.3477962114 2.7606915544 0.6160078104 0.4547410913 0.4981517958
0.1648889463 1.2629884463 1.17926215 3.5359727782 0.6222241379 0.4585989497 0.5136357622
0.0729300219 1.5381735781 1.075655262 4.6560785366 0.6483561666 0.4747462045 0.5579261778
0.0183800449 1.8463784743 1.0185499975 6.3368289284 0.7290760004 0.523951315 0.6683403226
1.8806835E-06 2.1916472343 1.0000018807 8.9499436333 0.9943131006 0.6796839267 0.9933206556

METANOL (1) - TETRACLORURO DE CARBONO (2)


12 
 
2  112 
1
1
0.9
0.8
 21 
  0.7
   
2 21 
Y1

12 1 0.6 UNIQUAC
0.5 DAT. EXP.
DIAGONAL
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
VP_A VP_B VP_C VP_D Pc Tc x
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.3785054787
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4214563525
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4176549474
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4158203706
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4151212869
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4149596319
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4149604538
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4145378183
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4127990238
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4077757624
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.3940178668
DIAGONAL:
0 0
0.2 0.2
0.4 0.4
0.6 0.6
0.8 0.8
1 1

y2 y1+y2
0.8959051868 1.0000085987
0.393745526 1.0003398397
0.437372393 1.0001112376
0.4688914355 1.0000365482
0.4900126802 1.000012832
0.5018518329 1.0006512576
0.5021599561 1.0003117519
0.4864780207 1.0001137829
0.4420911227 1.0000173005
0.332018985 1.0003593076
0.0060831328 0.9994037884

DE CARBONO (2) METANOL (1) - TETRACLORURO DE CARBONO (2)

355
350
345
340
X1 v
UNIQUAC 335 (CA
T

DAT. EXP. Y1 v
330
DIAGONAL (CA
325 X1 v
320
315
310
305
0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y
E CARBONO (2)

X1 vs T
(CALC.)
Y1 vs T
(CALC.)
X1 vs T (EXP.)

.8 0.9 1
temperatura ln(presion en bar) presion en bar
300 =
VPA 48.521
VPB 5819.21
VPC -5.489
VPD 2910

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