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(
( 1+
x 1 A 12
)2
) γ2 =10
x1 A
n-Hexano Benceno
P mmHg= 760
A 6.87776 6.90565
B 1171.53 1211.033
C 224.366 220.79
DIAGONAL
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1
ACIONAL DEL CENTRO DEL PERÚ”
D DE INGENIERIA QUÍMICA
NIERIA QUIMICA AMBIENTAL
BENCENO (2)
VAN LAAR
A 12
x 1 A 12
=10
(( 1+
x 2 A 21
)2
)
1
A 21
x 2 A 21
=10
(( 1+
x 1 A 12
)2
)
2
0.9
0.8
fraccin molar de Y
0.7
0.6
0.5 Y1 Vs X1
diagonal
eXPERIMENTAL
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
FRACCIN MOLAR DE X
N-HEXANO & BENCENO
354
352
350
348
346
T vs x
T
344
T vs Y
ESPERIMENTAL
342 EXPERIMENTAL
340
338
336
334
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1,Y1
ECUACION DE WILSON
Presión(bar)= 760
ln γ 1=−ln ( x 1+ Λ12 x 2 ) +x 2
[ Λ12
−
Λ21
x 1 + Λ12 x 2 Λ 21 x 1 +x 2 ] [
γ 1=exp −ln ( x 1 + Λ 12 x 2 ) +
v 1= 57.939
v2 λ 12
v 2= 86.1 Λ 12=
v1
exp −
RT ( ) Λ 21 =
v1
v2
e
metanol 2-propanol
12 11 88.2 A 7.878663 6.6604
B 1473.11 813.055
12 22 -30.19 C 230 132.93
DIAGONAL
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1
WILSON
[
γ 1 =exp −ln ( x 1 + Λ 12 x 2) +x 2
[ Λ12
−
Λ 21
x 1+ Λ 12 x 2 Λ21 x 1 +x 2 ]
[
γ 2=exp −ln ( x 2+ Λ 21 x 1)−x 1
[ Λ 12
−
Λ21
x1 + Λ12 x2 Λ21 x 1+ x2 ]
v1 λ 21
Λ 21 =
v2
exp −
RT ( )
0.2 0.2
0.4 0.4
0.6 0.6
0.8 0.8
1 1
0.9
0.8
0.7
0.6
T
Experimenta
0.5
l
DIAGONAL
X VS Y
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1,Y1
N-HEXANO & BENCENO
354
352
350
348
346
T vs x
T
344 T vs Y
Experimenta
l
342 xperimental
340
338
336
334
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1,Y1
N-HEXANO BENCENO
P mmHg= 760
A 6.87776 6.90565
B 1171.53 1211.033
C 224.366 220.79
DIAGONAL
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1
A 21 = γ 1= γ 2= Pvp1 Pvp2 y1 y2 y1+y2
0.143 1.5875008596 1.0000005961 1070.0841631 759.03157705 0.0022352099 0.9977276283 0.9999628382
0.143 1.4866406371 1.005712852 965.85236555 680.99699836 0.1889309705 0.811050908 0.9999818785
0.143 1.3915153453 1.0219555346 891.19326862 625.38919579 0.3263445023 0.672757842 0.9991023444
0.143 1.3047941473 1.0475578123 840.08287246 587.47063729 0.4326849534 0.5668244986 0.9995094519
0.143 1.2276201266 1.0814737935 805.13134924 561.61467026 0.520208131 0.4795038536 0.9997119846
0.143 1.1607802227 1.122664526 782.32259393 544.77554729 0.5974372334 0.4023685405 0.9998057739
0.143 1.104831378 1.1699949844 768.75755056 534.77394837 0.6705374715 0.3293067565 0.999844228
0.143 1.0602249008 1.2221429307 762.11667008 529.88121759 0.7442244074 0.2556278622 0.9998522696
0.143 1.0274294261 1.2775208593 760.21166782 528.47813469 0.8221724607 0.1776689055 0.9998413661
0.143 1.0070568781 1.3342155563 760.54402757 528.7229118 0.9069999798 0.0928197808 0.9998197606
0.143 1.0000007297 1.389408371 759.87325975 528.22890933 0.9988341321 0.0009656917 0.9997998237
1
0.9
0.8
fraccin molar de Y
0.7
0.6
experimenta
l
0.5 Y1 Vs X1
diagonal
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
356
354
352
350
Axis Title
348
T vs Y
346 T vs X
experimenta
l
experimenta
344 l
342
340
338
336
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Axis Title
DATOS EXPERIMENTALES:
X Y T
0.0513 0.108 351.1
0.1216 0.216 349.1
0.2189 0.334 347
0.3108 0.422 345.6
0.3811 0.483 344.7
0.503 0.579 343.6
0.6031 0.657 342.9
0.7171 0.746 342.3
0.7982 0.814 342
0.8982 0.902 341.9
0.9402 0.942 341.8
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre"
Presion Total 1
DATOS EXPERIMENTALES:
x y T (K)
0 0 349.85
0.002 0.02 349.25
0.002 0.027 349
0.004 0.12 345.5
0.013 0.2415 340.75
0.017 0.264 340 Presion T x1 x2
0.03 0.333 335.15 1 345.79955166 0.001 0.999
0.0505 0.445 332.55 1 321.90168544 0.1 0.9
0.107 0.49 330.35 1 324.01678724 0.2 0.8
0.124 0.5 330.1 1 325.03754578 0.3 0.7
0.248 0.522 329.4 1 325.42651595 0.4 0.6
0.401 0.5365 328.95 1 325.51646079 0.5 0.5
0.505 0.5483 328.85 1 325.5160035 0.6 0.4
0.55 0.552 328.8 1 325.7511579 0.7 0.3
0.603 0.561 328.85 1 326.71862317 0.8 0.2
0.727 0.595 329.15 1 329.51356577 0.9 0.1
1 1 337.85 1 337.1684589 0.999 0.001
z r 21 12
ln 1 ln 1 q1 ln 1 2 l1 1 l2 q1 ln1 2 21 2 q1
x
1 2
1 r2
1 2 21 2 1 12
z r 12 21
ln 2 ln 2 q2 ln 2 1 l2 2 l1 q2 ln2 112 1q2
x
2 2
2 r1
2 1 12 1 2 21
a12
12 exp
ri x qi xi T
z
li ri qi ri 1
i i
i
` a 21
NC NC
2 r j x j q j x j 21 exp
j j
T
r1= 1.43
r2= 3.33
q1= 1.43
q2= 2.82
a21 = 1127.95
a12 = -29.64
z= 10
l 1 l 2 1 2 1 2 12 21
-0.43 0.22 0.0004296746 0.9995703254 0.0005073423 0.9994926577 1.0894951206 0.0383170316
-0.43 0.22 0.0455414013 0.9544585987 0.0533383066 0.9466616934 1.0964501259 0.0300762284
-0.43 0.22 0.0969491525 0.9030508475 0.1125098348 0.8874901652 1.0957912903 0.0307721015
-0.43 0.22 0.1554347826 0.8445652174 0.1785268414 0.8214731586 1.0954765404 0.0311103572
-0.43 0.22 0.2225680934 0.7774319066 0.2526501767 0.7473498233 1.095357145 0.0312396653
-0.43 0.22 0.3004201681 0.6995798319 0.3364705882 0.6635294118 1.0953295787 0.0312695986
-0.43 0.22 0.3917808219 0.6082191781 0.4320241692 0.5679758308 1.0953297188 0.0312694464
-0.43 0.22 0.5005 0.4995 0.541959935 0.458040065 1.0952577236 0.0313477619
-0.43 0.22 0.6320441989 0.3679558011 0.6697892272 0.3302107728 1.0949626628 0.0316708347
-0.43 0.22 0.7944444444 0.2055555556 0.8202676864 0.1797323136 1.0941204223 0.032611964
-0.43 0.22 0.9976744186 0.0023255814 0.998029887 0.001970113 1.0918882956 0.0352475108
12 1 0.6 UNIQUAC
0.5 DAT. EXP.
DIAGONAL
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
VP_A VP_B VP_C VP_D Pc Tc x
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.3785054787
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4214563525
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4176549474
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4158203706
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4151212869
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4149596319
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4149604538
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4145378183
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4127990238
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4077757624
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.3940178668
DIAGONAL:
0 0
0.2 0.2
0.4 0.4
0.6 0.6
0.8 0.8
1 1
y2 y1+y2
0.8959051868 1.0000085987
0.393745526 1.0003398397
0.437372393 1.0001112376
0.4688914355 1.0000365482
0.4900126802 1.000012832
0.5018518329 1.0006512576
0.5021599561 1.0003117519
0.4864780207 1.0001137829
0.4420911227 1.0000173005
0.332018985 1.0003593076
0.0060831328 0.9994037884
355
350
345
340
X1 v
UNIQUAC 335 (CA
T
DAT. EXP. Y1 v
330
DIAGONAL (CA
325 X1 v
320
315
310
305
0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y
E CARBONO (2)
X1 vs T
(CALC.)
Y1 vs T
(CALC.)
X1 vs T (EXP.)
.8 0.9 1
temperatura ln(presion en bar) presion en bar
300 =
VPA 48.521
VPB 5819.21
VPC -5.489
VPD 2910