Hints & Solutions: Chemistry Part - A

Hints & Solutions
Chemistry
PART – A
1. A (Concept Code: C120608)

Sol. For I. i  1   
2
 1
1   1   0.5
2 2
 = iCRT = 0.5  2RT
II. i = 1 +  = 2
 = 2  0.5  RT
So both are isotonic
2. C (Concept Code: C111903)

Sol. Hneutralization = Hn(SA/SB) + Hi
-13.2 = -13.7 + Hionization
Hionization = 0.5 or 5  10–1
3. D (Concept Code: C120207)

Sol. HgCl2 is covalent halide.
4. C (Concept Code: C120205)

Sol. AgBr shows both Schottky and Frenkel defect.
5. ABCD (Concept Code: C120601)

Sol. based on Raoult’s law PT  PA0 X0A  PB0 XB0
6. ABC (Concept Code: C120504)

Sol. Nernst equation for half-cell reaction
Mn  ne  M
2.303RT 1
Ered  Ered
o
 log n
nF M 
On addition of CN– (AgCN ppt and Ag+ conc. dec)
7. ABCD (Concept Code: C120308)

Sol. Fact based.
8. ACD (Concept Code: C110504)

Sol. Except B(Strong base + salt of strong acid & strong base) all are buffer (weak acid + salt of weak
acid & strong base).
9. ABC (Concept Code: C120201)

Sol.  A  3HgS  6HCl  2HNO3  3HgCl2  3S  4H2
B  Hg  Cl2  HgCl2
 C Hg2Cl2  Hg  2HgCl2
10. AC (Concept Code: C113616)
Sol. Si has vacant d-orbitals and lone pairs over nitrogen is involved in back bonding(d - p).
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
2
Ai TS – 3 ( XII ) | SET – A | APT – 3 | Page |1
PART – B
1. A  PQT B  PST C  RS DP
(Concept Code: C124602, C121402, C122833)
2. A  PR BQ CQ D  S (Concept Code:

C123201)
Sol. A  PR : for reversible isothermal process
V P
W = 2.303nRT log 2 = 2.303 nRTlog 1
V1 P2

B  Q : for adiabatic process PV = constant
nR
CQ: W  T2  T1  for adiabatic process also PV = constant
 1
D  S : Irrversible isothermal process
3. AQ BR CS D  Q (Concept Code:

C120609)
Sol. A  i = 1 +  = 2  Tb = iKb = 2Kb
B  i = 1 + 2  0.75 = 2.5 Tb = 2.5 Kb
C  i = 1 + 4  0.5 = 3 Tb = 3 Kb
D  i = 1 + 4  0.25 = 2 Tb = 2 Kb
4. AT BR C  PS DPQ (Concept Code:C120201)

Sol. AT
B  (These dissolve as soluble nitrate in 50% HNO3)
C  (50% HNO3)
Pb2  I  PbI2 

2 2  Yellow
Pb  CrO4   PbCrO4  
D  2BiCl3  3Na2SnO2  6NaOH   2Bi  3Na2SnO2  6NaCl  3H2O
Bi3  3KI 
 BiI3
Black
PART – C
1. 0 (Concept Code: C123204)
Sol. For isothermal reversible process
q q
Suniverse  Ssystem  Ssurrounding  rev  rev  0
T T

0.0591 0.1 10 x
Sol. ECell  log
n 1011
0.0591
0.48  log1010 x
1
Solving x = 2

Sol. Black coloured sulphides (PbS, CuS, HgS & Ag2S, NiS, CoS)

Sol. C.No. 12, No. of atoms = 4
12
Ratio  3
4

Sol. Buna-S, Nylon-2-Nylon-6, Bakelite are co-polymers
2
2

Sol.  = iCRT
2.69 = i  0.1  0.082  298
i =1.1
For monobasic acid HA H  A 
i=1+
 = 0.1
So [H+] = C  = 0.1  0.1 = 10–2
 pH = -log(10–2) = 2
Mathematics
PART – A
1.  
Any point on the given parabola is t 2 ,2t . The equation of the tangent at (1, 2) is
x  y  1 0 .
h  t 2 k  2t 2 t  2t  1
2
 
 2

The image (h, k) of the point t ,2t in x  y  1  0 is given by
1

1

1 1
 h  t 2  t 2  2t  1  2t  1
and k  2t  t 2  2t  1  t 2  1
Eliminating t from h = 2t – 1 and k  t 2  1
We get, h  1  4 k  1
2
The required equation of reflection is  x  1  4  y  1

2
2. Let   x   A  Bx  Cx2  Dx3  .....

0 1 0
  0  0 1 0  0  A  0
1 0 0
1 0 0 0 1 0 0 1 0
 ' 0  0 1 0  0 1 1  0 1 0  1
1 0 0 1 0 0 0 1 0
 B 1
 Then   x   x  Cx2  Dx3  .....
   x  is divisible by x.
By property, adj A T   adj A   O* null matrix.

T
3.
4.  
f '  x   ex  1  x  1 sin x  cos x  sin x
Sign scheme of f '  x  is
+
+ + – + –
 0  1  5 2

2 4 4
    5      5 
Clearly, f  x  is increasing in   ,   1,     , 2  and decreasing in  , 1   ,
4 
.
 2 4  4  4  
1
5. We have p q r  
 a b c  
 
Therefore, p q r   0
 
2
p q r 
 a  x  0, x ab c     2 (Using AM  GM )
x
(b) similarly, use AM  GM
6. We have,
D  b  c   4a  a  b  c   0
2
 b2  c 2  2bc  4a2  4ab  4ac  0

 c 2   4a  2b c  4a2  4ab  b2  0 for all c  R
Discriminant of the above expression in c must be negative.

Hence,  4a  2b   4 4a2  4ab  b2  0
2

 4a2  4ab  b2  4a2  4ab  b2  0
 a a  b  0
 a  0 and a  b  0 or a  0 and a  b  0
 b  a  0 or b  a  0
1
7. 2cos   x 
x
x  2x cos   1  0
2
 x
2cos    4cos 2
4   cos   isin 
2
i
Let x  e
Similarly y  ei
Alternate (A) :
x y
  e   e  
i   i 
y x
 2cos     
Alternate (B) :
1
 e
i mn 
e 
 i mn 
xm yn  n m
x y
 2cos m  n
Alternate (C):
xm yn
 m  e
i mn 
e 
 i mn 
n
y x
 2cos m  n
Alternate (D):
1
 e    e    2cos     
i  i 
xy 
xy
6 2i 3 6
8. Let   12 3  8i 3 2  6i
18 2  12 i 27  2i
Applying R2  R2  2 R1 and R3  R3  3 R1
6 2i 3 6
 0 3 i 6  12  6  6  
0 2 2i  18
= –6 (real and rational)
2
9. Since the greatest integer function is discontinuous at integral values of x, then for a given limit to
exist both left and right hand limit must be equal.
L.H.L = lim  2  x  a  x  1  a  x  1  b 1  x 
x 1
 2  1  a  1  b 1  1  a  b
R.H.L. = lim  2  x  a  x  1  b 1  x 
x 1
 2  1  a  0   b  2  1  2b
On comparing we have – a = b
10. Use basic properties of log.
PART – B
F'  x    x  1 x  2 and F is continuously differentiable throughout R. F'  x   0
2
1.
 x  1, x  2 . For x  1, F'  x   0 and for x  1, F'  x   0 .
Hence x = 1 is point of minimum. Moreover F increases on 1,   and decreases on  ,  1 . At x
= 2, F’ (x) does not change sign, so there is no extremum at x = 2. The minimum value
F 1    t  1 t  2 dt   t  t  1 dt
1 2 0 2
0 1
17
   4,  1
12
y dV
2. Putting V  , we obtain V  x  V  tan V
x dx
dx
  cot V dV
x
Integrating log x  logsin V  Const.
y
 x  C sin
x

Putting x  1, y  , we have C = 1
2
y
Thus, x  sin    y  x sin1 x  f  x 
x
   
f is defined on  1, 1 and the range of f is  ,  .
 2 2

Clearly, f is continuous on its domain which is  1, 1 and f  x    2 for all x   1,1
2
3.
(A) a  b  a  2b
 a2  b2  2a.b  a2  4b2  4a.b
 2a.b  3b2  0
Hence, angle between a and b is obtuse.
(B) a  b  a  2b
 a2  b2  2a.b  a2  4b2  4a.b
 6a.b  3b2
Hence, angle between a and b is acute.
(C) ab  ab

 a.b  0
2
 a is perpendicular to b .
(D)  
c  a  b lies in the plane of vector a and b . A vector perpendicular to this plane is parallel to
a  b . Hence, angle is 0o .
4. Let X = the number of steps taken in the forward direction, then X ~ B n, p  with n = 11, p = 0.4.
p1  P  X  5   P  X  6 
 11C5 p5 q6  11C6 p6q5
 11C5 pq  11C5  0.24 
5 5
p3  P  X  4   P  X  7 
 11C4 p4q7  11C7 p7q4
 11C4 pq 1  3pq
4
 11C4  0.24   0.28 

4
p10  0 and p11  P  X  0   P  X  11

  0.4    0.6 
11 11
PART – C
3iz2
1. Let  k, where k  R
5z1
z 5i
 2   k  ai (say)
z1 3
3z1  7z2 3  7ai
Now, 5 5 5
3z1  7z2 3  7ai
2. The given circle S  x,y   x2  y2  x  y  6  0 ……….(i)

 1 1
has centre at C   , 
2 2
x+y–2=0
According to the required conditions, the given point P    1,   1 must lie inside the given circle,
i.e. S    1,   1  0
   1     1     1     1  6  0
2 2

 2    2  0, i.e.,    2   1  0
 1    2 (Using sign scheme from algebra) ………..(ii)
L  x,y   x  y  2  0 ………..(iii)
 1 1 1 1
Since L  ,     2  0 ,
2 2 2 2
i.e. ,  1 ………….(iv)
2
Inequalities (ii) and (iv) together give the perimissible values of  as 1    1

a x3  6x 2  11x  6
3. Let f  x    0 where f  x   3
30 x  x 2  10x  8

 x  1 x  2 x  3 
 x  1 x  2 x  4 

 x  3  , x  1,2,  4
x4
 2 1
Range of f  x   R  1,  ,  
 5 6
So, the equation does not have solution if
a 2 1
 1, ,
30 5 6
 a = – 30, 12, 5
4. Let I  
5x  4x  dx 4 5
 x  x  1
2
5
Dividing above and below by x10 , we get

 5 4
 x 6  x 5  dx
I   
2
 1 1
  
x 4 x 5 
1

1 1
Putting 1  4  5  t,
x x
 4 5 
  x5  x 6  dx  dt
 
 4 5 
or  5  6  dx  dt, we get
x x 
dt 1 1
I   2   C  C
t t  1 1
 1  x 4  x5 
 
5
x
 5 C

x  x 1 
1
f 1 
3
8
5. Given, y  1 
x2
Here, y is always positive. So, the curve lies above the x – axis.
4 4 8
Required area   ydx    1  2  dx
2 2
 x 
4
 8
 x    4
 x 2
a
a  8  8
If x  a bisects the area, we have 2 1  x2  dx   x  x  2
 8  4
 a   2  4  
 a  2
8
 a 0
a
2
 a2  8
 a  2 2
Since, a  2, a  2 2 .
6. If the given points are A, B and C then AB  k BC  

 2iˆ  8jˆ  k  a  12 ˆi  16jˆ 
Comparing the coefficients of î and ĵ , we get –8 = 16k
1
k 
2
1
2  k  a  12     a  12 
2
a8
Physics
PART – A
1. D P120409
Sol. m r  eE
2
e2rdr
a
 V   E.dr  
0
m
2. B P120405

Sol. Q
R
3. A P111826
Sol. Velocity of point P
= (v  v cos)2  (v sin )2 v
v
 
= 2v sin   v
2 P
4. B P120305
mv 0 2mv 0
Sol. d= 
qB 2qB
5. ABD P111822
Sol. By conservation of angular momentum,
I 1i  I 1  I 2  f
 f  1 / 3
1
Ei  I 1i2
2
E f  I1  I 2 2f
1
2
Ei  E f 2
Ratio of the heat produced to initial kinetic energy  
Ei 3
6. ABD P120406
Sol. The power delivered by magnetic field is zero. Hence, loss of energy in conducting rod is equal to
heat dissipated in the resistor.
7. ABD P111010
Sol. Bernoulli’s theorem for an orifice at depth ‘x’ in liquid ‘3d’.
2
 H  1
Po +  dg  3dg.x  = Po +  3d  v z …(1)
 2  2
H 1 2
 x  gt …(2)
2 2
R = Vt …(3)
Solve for R and apply maxima/minima.
8. BD P121705
Sol. At time t, the distance traveled by the rod is
ED  vt
A
AD
tan   or AD  EDtan  
ED E D
AD  vt tan 
DC 90–
tan(90  )  or DC  at cot 
ED C
So, AC  AD  DC  vt(tan   cot )
Induced emf = Bvl  Bv(AC)
 Bv.vt(tan   cot )
Induced emf  Bv 2 t(tan   cot )
Hence, Induced emf  t and v 2
Therefore, choices (B) and (D) are correct and choices (A)
and (C) are wrong.
9. AC P121720
Sol. I
E
R

1  eRt/L ; 
dt L

dI E Rt/L
e  
10. BD P120308
Sol. In both case (b) and (d), Fnet  0 so it passes the region undeviated.
PART – B
1. AP B  PQS C  QS D  QRS
P120414
2. A  PR B  PR C  QS D  PQRS
P120305
Sol. Time varying magnetic field produces electric field and this electric field can apply force on a
stationary charge.
3. A T BS CR DT

P120216
t

Sol. q  CV  (CV  qo ) e CR
CV  qo  CRt
i= e
CR
q2
U
2C
4. AR BS CP DQ

P111820
mg 3 mg
Sol. (A) T  T
2 4 4 6
2
Ai TS – 3 ( XII ) | SET – A | APT – 3 | P a g e | 10
3
(B) fr  mg
2
mg 4 2mg
(C) N  =
2 7 7
mg mg mg
(D) N  
2 6 3
PART – C
1. 4 P110603
2
mA
Sol. 2
3
mB
mA
 3
mB
mB
xCM  
mA  mB 4
2. 8 P110502
1
Sol F.x  m1gx  kx 2  0
2
kx = m2g for just shifting m2
1
F.x  m1gx  m2gx  0
2
F    m1  2  g  0.4  1    10  = 8N
m 2
 2   2
3. 2 P120410
Sol. At any time length of each wire  l  2vt
Induced emf  4 B v l  2vt 
4B v  l  2vt  Bv  Bv  B2 v
Induced current   , F  B   l  2v t   l  2v t 
4 l  2vt     
 2
2
5
 15  2  5  1 = 200 N
0.5
4. 3 P120306
Sol. Initially the rod will be in equilibrium if
2To  Mg with To = kxo …(i)
when the current I is passed through the rod, it will experience a force
F = BIL vertically up,
In equilibriums
2T + BIL = Mg with T = kx …(ii)
from (i) & (ii)
T Mg  BIL x BIL
 i.c.  1
To Mg xo Mg
Mg  xo  x 
or, B 
I L x0
Putting the values we get B  1.5  102 T .
5. 1 P120413
Sol. d  (2xdx)kxt 2
2
  kt 2 x 3 x dx
3
R
d 4ktx3

dt 3
2
Ai TS – 3 ( XII ) | SET – A | APT – 3 | P a g e | 11
4ktx 3 2 2 2  Q
E2x  ; E ktx ; d   ktx 2  2 (2xdx)x
3 3  3  R
R 5
4 ktQ 4 4 ktQ R
 d  3 R2 0 x dx  =
3 R2 5
At t = 15sec,  = 1 N-m
6. 4 P120401
Sol. Let any instant of time, velocity of the rod is v towards
right. i d
a
The current in the circuit is i. In the figure,
Va  Vb  Vd  Vc
i.e. Ldi  Bldx Fm v0 x
Integrating, we get Li  Blx
Magnetic force on the rod at this instant is
B2l2 b c
Fm  ilB  x … (i)
L
Since, this force is in opposite direction of v , so from Newton’s second law we can write,
 d2 x  B2l2
m 2    x
 dt  L
Comparing this with equation of SHM, i.e.
d2 x
 2 x … (ii)
dt 2
Bl
We have,  
mL
2 mL 82
So T   2  2  4 sec.
 Bl 2

Hints & Solutions: Chemistry Part - A

Transféré par

Informations du document

Description originale:

Titre original

Copyright

Formats disponibles

Partager ce document

Partager ou intégrer le document

Options de partage

Avez-vous trouvé ce document utile ?

Ce contenu est-il inapproprié ?

Droits d'auteur :

Formats disponibles

Hints & Solutions: Chemistry Part - A

Transféré par

Droits d'auteur :

Formats disponibles

Hints & Solutions

2. C (Concept Code: C111903)

3. D (Concept Code: C120207)

4. C (Concept Code: C120205)

5. ABCD (Concept Code: C120601)

6. ABC (Concept Code: C120504)

7. ABCD (Concept Code: C120308)

8. ACD (Concept Code: C110504)

9. ABC (Concept Code: C120201)

2. A  PR BQ CQ D  S (Concept Code:

3. AQ BR CS D  Q (Concept Code:

4. AT BR C  PS DPQ (Concept Code:C120201)

2. 2 (Concept Code: C120504)

3. 6 (Concept Code: C120201)

4. 3 (Concept Code: C120308)

5. 3 (Concept Code: C121701)

6. 2 (Concept Code: C120609)

The required equation of reflection is  x  1  4  y  1

2. Let   x   A  Bx  Cx2  Dx3  .....

By property, adj A T   adj A   O* null matrix.

 b2  c 2  2bc  4a2  4ab  4ac  0

(C) ab  ab

 11C4  0.24   0.28 

p10  0 and p11  P  X  0   P  X  11

2. The given circle S  x,y   x2  y2  x  y  6  0 ……….(i)

Inequalities (ii) and (iv) together give the perimissible values of  as 1    1

Dividing above and below by x10 , we get

6. If the given points are A, B and C then AB  k BC  

3. A T BS CR DT

4. AR BS CP DQ

Vous aimerez peut-être aussi