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Structure of soaps
Soap consists of sodium/potassium cations and soap anions.
When a sodium/potassium soap is dissolve in water, it will form
soap anions and sodium ion, Na+ or potassium ion, K+
Hydrophobic Hydrophilic
[hydrocarbon chains] [carboxilate group]
COO−
Soap anions
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From the diagram above shows that the structure of soap anions
consists of,
hydrocarbon chains known as hydrophobic part
carboxylate/ionic group known as hydrophilic part
Structure of detergent
Detergent of sodium cations and detergent anions.
When a detergent is dissolve in water, it will form detergent anions
and sodium ion, Na+.
Hydrophobic Hydrophilic
[hydrocarbon/alkyl chains] [sulphate ions]
OSO3−
From the diagram above shows that the structure of alkyl sulphate
anions consists of,
i. hydrocarbon/alkyl chains known as hydrophobic part
ii. sulphate/ionic group known as hydrophilic part
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2 CLEANSING ACTIVITY
i) Sodium alkyl benzene sulphonate detergent
O
CH3 CH2 CH2 CH2 CH2 CH2 CH2 ║
CH2 ׀
─S─O−
Na +
CH2 CH2 CH2 CH2 CH2 CH2 ║
O
Hydrophobic Hydrophilic
[hydrocarbon/alkyl benzene chains] [sulphonate ions]
SO3−
From the diagram above shows that the structure of alkyl benzene
sulphonate anions consists of,
i. hydrocarbon/alkyl benzene chains known as hydrophobic
part
ii. sulphonate/ionic group known as hydrophilic part
Remember this;
In water, soap and detergent dissolves to form soap anions and
detergent anions. The anions will carry out the cleansing action,
because these anions consists of hydrophobic and hydrophilic part.
Why?
• Hydrophobic is water-hating part, is soluble in oil/grease/dirt,
but insoluble in water.
• Hydrophilic is water-loving part, is soluble in water but
insoluble in oil/grease/dirt.
• Both of the properties of anions, makes soap and detergent act
as an effective cleansing agent.
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2 CLEANSING ACTIVITY
How soap and detergent carry out the cleansing action?
+ + ─ + ─
Sodium ion
─ +
─ ─ +
Soap/detergent ion
─ ─ +
Grease/dirt +
+
+
─ ─
Dirt cloth
+ +
+ + +
+
+ Hydrophilic part +
─ ─ ─ ─ ─
─ ─ ─
+
─
Hydrophobic
part
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2 CLEANSING ACTIVITY
+
+ +
+
+
─ ─ ─
+
─ ─ ─ ─ ─
+
─ ─
+ ─ ─
─ ─ ─
+ +
+ +
+
+
─ ─ ─
─ ─ ─
─ ─ ─ ─ ─ ─ +
─ + ─ ─
─ ─ ─
─ ─ ─ ─ ─ +
─ ─ ─ ─
─ ─ ─
+ +
Advantages of soap
1. Soap are effective cleaning agent in soft water.
- Soft water did not contains Mg2+ ions and Ca2+ ions.
- Example: rain water, tap water
Disadvantage of soap
1. Soap is not suitable for use in hard water.
2+ 2+
- Hard water contains Mg ions and Ca ions.
- Example: Sea water, river water
Advantage of detergent
1. Detergent is effective in hard and soft water.
- Detergent do not form scum with hard water.
- Detergent form soluble substances with calcium or
magnesium ions.
Disadvantage of detergent
1. Detergent can cause pollution to environment
- Detergents not biodegradable, so that it cannot be
decomposed by bacteria
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2 CLEANSING ACTIVITY
Additives in detergent
The main substance in detergent is sodium alkyl benzene
sulphonate and sodium alkyl sulphate. Example of detergent is
shampoo, clothes washing powder and dishes washing liquid.
additives Function
React as bleach agent to vanished the colour
Whitening agent
stain but did not fade the colour of the
(sodium perborate)
clothes.
React to substance that in organic properties
Biological enzymes
like blood, food and water. Enzymes
(amilase, lipase,
dissolve and change it to substance that can
protease, selulase)
dissolve in water.
Fluorescent agent Make the clothes more white, shiny and
(Blancophor) bright.
Buildup agent
Soften hard water, expel ion Mg2+ dan Ca2+ .
(sodium
increase the pH value
tripoliphosphate)
Drying agent
Ensured that the detergent is always in a dry
(sodium sulphate,
condition.
Sodium silicate)
Stabilizers To prevent the formation of foam
Perfumes To make clothes smell fresh and clean.
End
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