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Photovoltaic Materials
Dr. Tan Swee Ching
Lecture Notes - Week 9
Silicon Solar Cells Fabrication
e-
MLE4208 9, p.2
Texturing
Etch Solution:
Potassium Hydroxide (KOH)
Isopropyl Alcohol (IPA)
Water (H2O)
Texturing
Pyramid texture on mono-Si-wafer after the as-cut Si-wafer was etched for 25
min in a standard KOH-IPA solution at 80oC.
MLE4208 9, p.4
In alkaline medium, the Si (100) crystalline orientation has the highest etching rate
as compared to other planes which leads to the formation of pyramids
MLE4208 9, p.6
Doping Methods
1. Ion implantation
2. Thermal Diffusion – Employed by Solar Cells
Industry
3. Spin on Dopants
MLE4208 9, p.10
A Diffusion Furnace
PSG Removal
• Phosphosilicate glass (PSG) is formed on the surface of silicon
wafer after the thermal diffusion process
• PSG is an insulator
• It has to be removed by
1. Dipping a HF solution.
2. DI rinse
3. Drying (slow pull and air knife)
MLE4208 9, p.15
Solution:
Laser-based equipment
Laser Edge Isolation
Anti-Reflection Coating
n = 1.85 – 3.3
MLE4208 9, p.20
Distinguishing Texturing, Anti-Reflection Coating
and Texturing + Anti-Reflection Coating
Texturing and Anti-Reflection Coating
Anti-Reflection
Coating
+
Anti-Reflection
Coating
MLE4208 9, p.21
Advantages:
• A large metal height to width aspect ratio
• Reduction of metal grid and contact
resistance
• Shading loos is reduced from 15%
(conventional method) to 3% (this
method)
MLE4208 9, p.25
Optical properties:
1) very low reflectivity
2) Correspondingly high absorption of
visible and infrared wavelengths
MLE4208 9, p.30
• Not all solar cells are created equal, especially when multi-
crystalline
• Testing of finished solar cell done by I-V, end up with bins of
similar performance solar cells or grades
• Also want to test during the process
– Don’t want to continue processing if there is no chance of a good
solar cell
– Identify any problems in the process flow easily and quickly
• Movement towards techniques such as
photoluminescence to check quality of feedstock
MLE4208 9, p.31
I I I
V V V
MLE4208 9, p.34
Effect of Shading
I I I
V V V
MLE4208 9, p.35
V
Currents add.
I
V
I
V
MLE4208 9, p.36
Summary
1.
2.
3.
4.
5.