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Revision date: 15/10/2016
SAFETY DATA SHEET Version: 9

according to Regulation (EC) No. 1907/2006 (REACH) Language: en-GB,IE
and Regulation (EU) No 2015/830 Date of print: 1/3/2016
Zinc sulphate monohydrate (USP)

Material number Z006 Page: 1 of 59
SECTION 1: Identification of the substance/mixture and of the

SECTION 1: Identification of the substance/mixture and of the
company/undertaking
company/undertaking
1.1 Product identifier
Trade name: Zinc sulphate monohydrate (USP)
REACH registration No.: 01-2119474684-27-0000
CAS-Number: 7446-19-7
EC-number: 231-793-3
EU index number: 030-006-00-9
1.2 Relevant identified uses of the substance or mixture and uses advised against
General use: Chemical basic material.
For industrial purposes only
Identified uses: Industrial use:
0 Generic exposure scenario: Industrial use of primary or secondary Page 11
zinc bearing material in manufacture of Zinc sulphate in several
process steps, collection of the substance
SU 0,2a,3,8,9,10; PROC 2,3,5,8b,9,22,26; PC 19,20,21; ERC 1
1 Generic exposure scenario: Industrial use of Zinc sulphate Page 16

formulation of preparations by mixing thoroughly, dry or solvent, the
starting materials with potentially pressing, pelletising, sintering
possibly followed by packing
SU 2a,3,8,9,10; PROC 1,2,3,4,5,8b,9,13,14,15,22; ERC 1,2
2 Generic exposure scenario: Industrial use of Zinc sulphate and Zinc Page 21
sulphate-composition manufacture of other inorganic or organic zinc
substances in a solvent-based matrix with potentially filtering and
packaging
SU 0,3,8,9,10,14,15,17; PROC 1,2,3,4,8b,9,13,15,21,22,23,26; PC 7,14,19,20,21,24,29,39;
AC 2,7,12-2; ERC 1,2,5,6a
3 Generic exposure scenario: Professional use and industrial use of Page 26

Zinc sulphate, use as laboratory reagent, in organic materials, water,
for analysis and Chemicals which are used in the chemicals industry
for synthesis processes
SU 3,10,22,24; PROC 1,2,3,4,5,8a,8b,9,10,15; PC 19,21,28,39; ERC 1,2,4,6a,6b,8a,8b,8d,9a
sulphate-formulation of preparations as a component for the
manufacture of solid blends and matrices for downstream user
SU 1,3,4,5,8,9,10,11,12,13,14,20; PROC 1,2,3,4,5,8b,9,13,14,15,22;
PC 1,8,9a,9b,9c,12,14,15,18,20,21,26,28,29,32,35,37,39; ERC 1,2,3,4,5,7,8a,8b,8d,10a,10b
sulphate. component for the manufacture of dispersions, pastes, or
other viscous or polymerised matrices
SU 3,4,5,6b,7,8,9,10,18,20; PROC 1,2,3,4,5,6,8b,9,10,13,14,15;
PC 2,8,9a,9b,12,14,15,18,19,20,21,23,24,25,28,29,32,34,35,39,40; AC 1,2,7;
ERC 1,2,3,4,5,6a,6b,6d,8a,8b,8d,9a,9b,10a,10b,11a
6 Generic exposure scenario: Industrial and professional use of solid Page 42

substrates with < 25 % w/w Zinc sulphate.
SU 3,5,6b,9,10,22; PROC 4,5,6,8b,9,10,11,13,19; PC 1,8,9a,9b,9c,14,15,18,20,21,28,29,35,39;
AC 0; ERC 8a,8d,10a,11a

Professional use:
3 Generic exposure scenario: Professional use and industrial use of Page 26
Zinc sulphate, use as laboratory reagent, in organic materials, water,
for analysis and Chemicals which are used in the chemicals industry
for synthesis processes
SU 3,10,22,24; PROC 1,2,3,4,5,8a,8b,9,10,15; PC 19,21,28,39; ERC 1,2,4,6a,6b,8a,8b,8d,9a
6 Generic exposure scenario: Industrial and professional use of solid Page 42

substrates with < 25 % w/w Zinc sulphate.
SU 3,5,6b,9,10,22; PROC 4,5,6,8b,9,10,11,13,19; PC 1,8,9a,9b,9c,14,15,18,20,21,28,29,35,39;
AC 0; ERC 8a,8d,10a,11a
7 Generic exposure scenario: Industrial and professional use of Page 51

dispersions, pastes and polymerised substrates with < 25 % w/w Zinc
sulphate
SU 9,20,22; PROC 8b,9,10,11,13; PC 8,20,21,28,29,35,39; ERC 8a
Consumer use:
8 Generic exposure scenario, consumers: combined for all exposure Page 58
routes
SU 21
Summary of registered and identified uses and their respective exposure scenarios:
IU 1, Manufacture of Zinc sulphate, wet: GESZnSO4 0
IU 5, Component for production of inorganic zinc compounds: GESZnSO4 2
IU 6, Electro-galvanising: GESZnSO4 2
IU 7, Electroplating: GESZnSO4 2
IU 8, Zinc production by electrowinning: GESZnSO4 2
IU 9, Use as laboratory reagent: GESZnSO4 3
IU 10, Ore dressing (mining metallurgy): GESZnSO4 0, GESZnSO4 1
IU 11, Zinc production by pyrometallurgy: GESZnSO4 2
IU 12, Component for production of organic zinc compounds: GESZnSO4 2
IU 13, Component for production of inorganic pigments, i.e. Lithopones: GESZnSO4 1,
GESZnSO4 4
IU 14, Component for production of coatings/paints, inks, enamels, varnishes:
GESZnSO4 1, GESZnSO4 4
IU 15, Component for production of surface treatment preparations: GESZnSO4 1,
GESZnSO4 4
IU 16, Component for paper coating: GESZnSO4 1, GESZnSO4 5
IU 17, Use of ZnSO4-containing paper coatings: GESZnSO4 6
IU 18, Component for textile and leather coating/treatment: GESZnSO4 1, GESZnSO4 5
IU 19, Use of ZnSO4-containing textile and leather coatings: GESZnSO4 6
IU 20, Additive for the production of lubricants/grease/metal working fluids: GESZnSO4
1, GESZnSO4 5
IU 21, Use of ZnSO4-containing lubricants/grease/metal working fluids: Generic
consumer/environment
IU 22, Use of ZnSO4-containing catalysts: GESZnSO4 1, GESZnSO4 5
IU 23, Additive for the formulation of animal feedstuffs, nutrients: GESZnSO4 1,
IU 24, Additive for the formulation of biocidal products: GESZnSO4 1, GESZnSO4 4,
GESZnSO4 5
IU 25, Additive for the formulation of cleaning products: GESZnSO4 1, GESZnSO4 4,
GESZnSO4 5
IU 26, Use of ZnSO4-containing cleaning products: GESZnSO4 6, GESZnSO4 7, Generic
IU 27, Additive for the formulation of fertilizers: GESZnSO4 1, GESZnSO4 4, GESZnSO4 5
IU 28, Use of ZnSO4-containing fertilizer's formulations: Generic consumer/environment
IU 29, Additive in the formulation of cosmetics: GESZnSO4 1, GESZnSO4 4, GESZnSO4 5
IU 30, Use of cosmetics: GESZnSO4 6, GESZnSO4 7, Generic consumer/environment
IU 31, Additive in the formulation of pharma/veterinary products: GESZnSO4 1,
IU 32, Use of pharma/veterinary products: GESZnSO4 6, GESZnSO4 7, Generic

1.3 Details of the supplier of the safety data sheet

Company name: RT Chemtronics Chemikalien GmbH
Street/POB-No.: Hu yssenallee 76
Postal Code, city: 45128 Essen
Germany
WWW: rtchemtronics.de
mail: rtc@rtchemtronics.de
Telephone: +49 201 24531-0
Dept. responsible for information:
Telephone: +49 201-24531-0, Mr. Markus Schulzki
Emergency telephone number
InfraServ GmbH & Co. Höchst KG, Frankfurt, Germany
(in German and English)
Telephone: +49 69 3056418
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to EC regulation 1272/2008 (CLP)
Acute Tox. 4; H302 Harmful if swallowed.
Eye Dam. 1; H318 Causes serious eye damage.
Aquatic Acute 1; H400 Very toxic to aquatic life. M-factor = 1
Aquatic Chronic 1; H410 Very toxic to aquatic life with long lasting effects. M-factor = 1
2.2 Label elements

Labelling (CLP)
Signal word: Danger

Hazard statements: H302 Harmful if swallowed.
H318 Causes serious eye damage.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements: P273 Avoid release to the environment.

P301+P312 IF SW ALLOW ED: Call a POISON CENTER/doctor if you feel unwell.
P351 Rinse cautiously with water for several minutes.
2.3 Other hazards
No risks worthy of mention.
SECTION 3: Composition / information on ingredients

3.1 Substances
Chemical characterisation: Zn SO4 * H2O
CAS-Number: 7446-19-7
EC-number: 231-793-3
EU index number: 030-006-00-9
Customs tariff number: 2833 29 20

SECTION 4: First aid measures

4.1 Description of first aid measures
In case of inhalation: Move victim to fresh air. Care for immobility and protect against heat loss.
In case of irregular breathing or respiratory arrest provide artificial respiration.
Following skin contact: Change contaminated clothing. Remove residues with water.
After eye contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. Subsequently consult an ophthalmologist.
After swallowing: Rinse mouth immediately and drink plenty of water.
Seek medical attention.
4.2 Most important symptoms and effects, both acute and delayed
In case of inhalation: May cause irritations.
Cough, sore throat, shortage of breath.
In case of ingestion: Abdominal pain, diarrhoea, nausea, vomiting.
After contact with skin: Irritation and redness may occur.
4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media:
Product is non-combustible. Extinguishing materials should therefore be selected

according to surroundings.
5.2 Special hazards arising from the substance or mixture
May form dangerous gases and vapours in case of fire.
5.3 Advice for firefighters
Special protective equipment for firefighters:
Wear self-contained breathing apparatus.
Additional information: Hazchem-Code: 2Z
Do not allow fire water to penetrate into surface or ground water.
SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Avoid generation of dust. Do not breathe dust. Provide adequate ventilation. W ear
personal protection equipment.
6.2 Environmental precautions
Do not allow to penetrate into soil, waterbodies or drains.
6.3 Methods and material for containment and cleaning up
Take up mechanically, placing in appropriate containers for disposal.
6.4 Reference to other sections
Refer additionally to section 8 and 13.
printed by Grillo-W erke with Qualisys SUMDAT




SECTION 7: Handling and storage

7.1 Precautions for safe handling
Advices on safe handling: Provide adequate ventilation, and local exhaust as needed. Avoid generation of dust.
Avoid contact with the substance.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storerooms and containers:
Keep container tightly closed.
Storage class: 13 = Non-combustible solids
7.3 Specific end use(s)
No information available.
SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Additional information: Contains no substances with occupational exposure limit values.
DNEL/DMEL: DNEL workers and consumers:
DNEL oral, Zn soluble: 0.83 mg Zn/kg bw/d
DNEL oral, Zn insoluble: 0.83 mg Zn/kg bw/d
DNEL dermal, Zn soluble: 8.3 mg Zn/kg bw/d
DNEL dermal, Zn insoluble: 83 mg Zn/kg bw/d
DNEL workers, inhalative, Zn soluble: 1 mg Zn/m³ DNEL
workers, inhalative, Zn insoluble: 5 mg Zn/m³ DNEL
consumers, inhalative, Zn soluble: 1.3 mg Zn/m³ DNEL
consumers, inhalative, Zn insoluble: 2.5 mg Zn/m³
PNEC: PNEC water (freshwater): 20.6 µg Zn/L
PNEC water (marine water): 6.1 µg Zn/L
PNEC sediment (freshwater): 235.6 mg Zn/kg dw
PNEC sediment (marine water): 113 mg Zn/kg dw
PNEC soil: 106.8 mg Zn/kg dw
PNEC sewage treatment plant: 52 µg Zn/L
8.2 Exposure controls
Use local exhaust complete with an appropriate filter system. Air cyclones for dust
collection.
use in contained systems
Personal protection equipment
Occupational exposure controls
Respiratory protection: In case of dust formation: Particulates filter P2 according to EN 143.
Hand protection: Protective gloves according to EN 374.
Glove material: nitrile rubber-Layer thickness: 0.11 mm
Breakthrough time: >480 min.
Observe glove manufacturer's instructions concerning penetrability and breakthrough time.
Eye protection: Tightly sealed goggles according to EN 166.
Body protection: W ear suitable protective clothing.
General protection and hygiene measures:
When using do not eat, drink or smoke. W ash hands before breaks and after work.


SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance: Form: solid, powder
Colour: white
Odour: odourless
Odour threshold: no data available
pH value: no data available
Melting point/freezing point: 1013 hPa, Air: > 229 °C (Decomposition)
Initial boiling point and boiling range: no data available
Flash point/flash point range: not combustible
Evaporation rate: no data available
Flammability: no data available
Explosion limits: no data available
Vapour pressure: no data available
Vapour density: no data available
Density: at 20 °C: 3.35 g/cm³
Water solubility: at 20 °C: 210 g/L
Partition coefficient: n-octanol/water: no data available
Auto-ignition temperature: no data available
Thermal decomposition: > 240 °C: Zinc sulphate, anhydrous
> 680 °C: Formation of Sulphur trioxide
Viscosity, kinematic: no data available
Explosive properties: no data available
Oxidizing characteristics: no data available
9.2 Other information

Bulk density: approx. 1400 kg/m³
Additional information: Molar mass: 179.45 g/mol
SECTION 10: Stability and reactivity

10.1 Reactivity
No dangerous reactions are known.
10.2 Chemical stability
Product is stable under normal storage conditions.
10.3 Possibility of hazardous reactions
No dangerous reactions are known.
10.4 Conditions to avoid
Protect from excessive heat.
10.5 Incompatible materials
no data available
10.6 Hazardous decomposition products
In case of fire may be liberated: Sulphur oxides
Thermal decomposition: > 240 °C: Zinc sulphate, anhydrous
> 680 °C: Formation of Sulphur trioxide


SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity: LD50 Rat, oral: 574 - 2949 mg/kg
LD50 Rat, dermal: > 2000 mg/kg
Toxicological effects: Acute toxicity (oral): Acute Tox. 4; H302 = Harmful if swallowed.
Acute toxicity (dermal): Based on available data, the classification criteria are not met.
Acute toxicity (inhalative): Based on available data, the classification criteria are not met.
Skin corrosion/irritation: Based on available data, the classification criteria are not met.
Eye damage/irritation: Eye Dam. 1; H318 = Causes serious eye damage.
Sensitisation to the respiratory tract: Based on available data, the classification criteria
are not met.
Skin sensitisation: Based on available data, the classification criteria are not met.
Germ cell mutagenicity/Genotoxicity: Based on available data, the classification criteria
are not met.
Carcinogenicity: Based on available data, the classification criteria are not met.
Reproductive toxicity: Based on available data, the classification criteria are not met.
Effects on or via lactation: Based on available data, the classification criteria are not met.
Specific target organ toxicity (single exposure): Based on available data, the classification
criteria are not met.
Specific target organ toxicity (repeated exposure): Based on available data, the
classification criteria are not met.
Aspiration hazard: Based on available data, the classification criteria are not met.
Symptoms
In case of inhalation: May cause irritations.
Cough, sore throat, shortage of breath.
In case of ingestion: Abdominal pain, diarrhoea, nausea, vomiting.
After contact with skin: Irritation and redness may occur.
SECTION 12: Ecological information

12.1 Toxicity
Aquatic toxicity: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
pH < 7: EC50 Ceriodaphnia dubia: 1.13 mg/Zn/L/48h (US EPA 821-R-02-012)
pH > 7: EC50 Selenastrum capricornutum: 3.73 mg/Zn/L/72h (OECD 201)
M-factor: 1
12.2. Persistence and degradability
Further details: Methods for the determination of biodegradability are not applicable to inorganic
substances.
12.3 Bioaccumulative potential
Significant bioaccumulation potential is not to be expected.
Partition coefficient: n-octanol/water:
no data available
12.4 Mobility in soil
Kp solids-water: 158.5 L/kg


12.5 Results of PBT and vPvB assessment

This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
12.6 Other adverse effects
General information: Do not allow to enter into ground-water, surface water or drains.
Danger to drinking water.
SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product
Waste key number: 06 03 13* = Solid salts and solutions containing heavy metals
* = Evidence for disposal must be provided.
Recommendation: Incinerate according to applicable local, state and federal regulations.
Contaminated packaging
Recommendation: Dispose of waste according to applicable legislation.
Additional information
Discharge into the environment must be avoided.
SECTION 14: Transport information

14.1 UN number
ADR/RID, IMDG, IATA-DGR:
UN 3077
14.2 UN proper shipping name

UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Zinc sulphate monohydrate)
14.3 Transport hazard class(es)
ADR/RID: Class 9, Code: M7
IMDG: Class 9, Subrisk -
IATA-DGR: Class 9
14.4 Packing group
III
14.5 Environmental hazards
Marine pollutant: yes


14.6 Special precautions for user

Land transport (ADR/RID)
Warning board: ADR/RID: Kemmler-number 90, UN number UN 3077
Hazard label: 9
Special provisions: 274 335 375 601
Limited quantities: 5 kg
EQ: E1
Contaminated packaging - Instructions: P002 IBC08 LP02 R001
Contaminated packaging - Special provisions: PP12 B3
Special provisions for packing together: MP10
Portable tanks - Instructions: T1 BK1 BK2
Portable tanks - Special provisions: TP33
Tank coding: SGAV LGBV
Tunnel restriction code: E
Sea transport (IMDG)
EmS: F-A, S-F
Special provisions: 274, 335, 966, 967, 969
Limited quantities: 5 kg
EQ: E1
Contaminated packaging - Instructions: P002, LP02
Contaminated packaging - Provisions: PP12
IBC - Instructions: IBC08
IBC - Provisions: B3
Tank instructions - IMO: -
Tank instructions - UN: T1, BK2, BK2, BK3
Tank instructions - Provisions: TP33
Stowage and handling: Category A. SW 23
Properties and observations: -
Air transport (IATA)
Hazard: Miscellaneous
EQ: E1
Passenger Ltd.Qty.: Pack.Instr. Y956 - Max. Net Qty/Pkg. 30 kg G
Passenger: Pack.Instr. 956 - Max. Net Qty/Pkg. 400 kg
Cargo: Pack.Instr. 956 - Max. Net Qty/Pkg. 400 kg
Special Provisioning: A97 A158 A179 A197
ERG: 9L
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
no data available
SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
National regulations - Great Britain
Hazchem-Code: 2Z
No data available


National regulations - EC member states

Labelling of packaging with <= 125mL content
Hazard statements: H302 Harmful if swallowed.

H318 Causes serious eye damage.
Precautionary statements: P301+P312 IF SW ALLOW ED: Call a POISON CENTER/doctor if you feel unwell.
P351 Rinse cautiously with water for several minutes.
15.2 Chemical Safety Assessment
For this substance a chemical safety assessment has been carried out.
SECTION 16: Other information

Further information

Reason of change:Changes in section 2: classification
26/6/2011
Date of first version:
Department issuing data sheet

Contact person: see section 1: Dept. responsible for information
For abbreviations and acronyms, see: ECHA Guidance on information requirements and
chemical safety assessment, chapter R.20 (Table of terms and abbreviations).
The above information describes exclusively the safety requirements of the product and is based on
our present-day knowledge. The information is intended to give you advice about the safe handling of
the product named in this safety data sheet, for storage, processing, transport and disposal. The
information cannot be transferred to other products. In the case of mixing the product stated in this
safety data sheet with other products or in the case of processing the information in this safety data
sheet cannot be transferred to the new material unless specifically stated otherwise in the text.

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Revision date: 15/10/2016

SAFETY DATA SHEET Version: 9

Zinc sulphate monohydrate (USP)

SECTION 1: Identification of the substance/mixture and of the

1 Generic exposure scenario: Industrial use of Zinc sulphate Page 16

3 Generic exposure scenario: Professional use and industrial use of Page 26

6 Generic exposure scenario: Industrial and professional use of solid Page 42

Zinc sulphate monohydrate (USP)

6 Generic exposure scenario: Industrial and professional use of solid Page 42

7 Generic exposure scenario: Industrial and professional use of Page 51

Zinc sulphate monohydrate (USP)

1.3 Details of the supplier of the safety data sheet

SECTION 2: Hazards identification

2.2 Label elements

Signal word: Danger

Precautionary statements: P273 Avoid release to the environment.

SECTION 3: Composition / information on ingredients

Zinc sulphate monohydrate (USP)

SECTION 4: First aid measures

SECTION 5: Firefighting measures

Product is non-combustible. Extinguishing materials should therefore be selected

SECTION 6: Accidental release measures

printed by Grillo-W erke with Qualisys SUMDAT

Zinc sulphate monohydrate (USP)

printed by Grillo-W erke with Qualisys SUMDAT

Zinc sulphate monohydrate (USP)

SECTION 7: Handling and storage

SECTION 8: Exposure controls/personal protection

printed by Grillo-W erke with Qualisys SUMDAT

Zinc sulphate monohydrate (USP)

SECTION 9: Physical and chemical properties

9.2 Other information

SECTION 10: Stability and reactivity

printed by Grillo-W erke with Qualisys SUMDAT

Zinc sulphate monohydrate (USP)

SECTION 11: Toxicological information

SECTION 12: Ecological information

printed by Grillo-W erke with Qualisys SUMDAT

Zinc sulphate monohydrate (USP)

12.5 Results of PBT and vPvB assessment

SECTION 13: Disposal considerations

SECTION 14: Transport information

14.2 UN proper shipping name

printed by Grillo-W erke with Qualisys SUMDAT

Zinc sulphate monohydrate (USP)

14.6 Special precautions for user

SECTION 15: Regulatory information

printed by Grillo-W erke with Qualisys SUMDAT

Zinc sulphate monohydrate (USP)

National regulations - EC member states

Hazard statements: H302 Harmful if swallowed.

SECTION 16: Other information

printed by Grillo-W erke with Qualisys SUMDAT

Department issuing data sheet

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