Académique Documents
Professionnel Documents
Culture Documents
1
Materiales y reactivos
Desarrollo experimental
EXPERIENCIA A TEMPERATURA AMBIENTE
En un matraz de 50ml,
colocar 10 ml de KI y
0.7 ml de H2SO4
2
EXPERIENCIA A TEMPERATURA 1°C
RESULTADOS Y CALCULOS
3
Numero de Experimento 1: Experimento 2: Experimento 3:
medición Temperatura 5°C Temperatura 25°C Temperatura 45°C
278.15 °K 298.15°K 318.15°K
Volumen Tiempo Volumen Tiempo Volumen Tiempo
de de de Na2S2O3
(seg) (seg) (seg)
Na2S2O3 Na2S2O3
1 0.2 192.65s 0.2 0 0.4 18
2 0.3 120.5s 0.4 28 0.7 34
3 0.4 121.8s 0.6 44 1.0 49
4 0.5 129.5s 0.8 61 1.2 79
5 0.6 132s 1.0 71 1.4 113
6 0.7 144s 1.2 136 1.6 159
7 0.8 184.8s 1.4 180
8 0.9 193.2s
EXPERIMENTO 1
[𝑵𝒂𝟐 𝑺𝟐 𝑶𝟑 ]𝑽𝑵𝒂𝟐 𝑺𝟐 𝑶𝟑
[𝐊] =
𝑽𝒂𝒍𝒊𝒄𝒖𝒐𝒕𝒂
4
[0.1 𝑀][0.7 𝑚𝑙]
6. [𝐾] = [11.5 𝑚𝑙]
= 6.08𝑥10−3 𝑀 ln 6.08𝑋10−3 = -5.10
[0.1 𝑀][0.8 𝑚𝑙]
7. [𝐾] = [11.5 𝑚𝑙]
= 6.95𝑥10−3 𝑀 ln 6.95𝑋10−3 = -4.96
[0.1 𝑀][0.9 𝑚𝑙]
8. [𝐾] = [11.5 𝑚𝑙]
= 7.82𝑥10−3 𝑀 ln 7.82𝑋10−3 = -4.85
Pendiente = -K K= 0.2061
b.- Calcular la energía de activación y el factor de frecuencia a partir de la
ecuación de Arrehenius
△𝐻
m= 𝑅
∆H=mR
A=е6.3711= 584.70
5
Experimento 2: Temperatura: 25°C ó 298.15°K
[𝑵𝒂𝟐 𝑺𝟐 𝑶𝟑 ]𝑽𝑵𝒂𝟐 𝑺𝟐 𝑶𝟑
[𝐊] =
𝑽𝒂𝒍𝒊𝒄𝒖𝒐𝒕𝒂
[0.1 𝑀]0.4 𝑚𝑙
[K] = = 3.48𝑋10−3 M ------------- ln 3.48𝑋10−3 = -5.66
11.5 𝑚𝑙
[0.1 𝑀]0.6 𝑚𝑙
[K] = = 5.21𝑋10−3 M ------------- ln 5.21𝑋10−3 = -5.25
11.5 𝑚𝑙
[0.1 𝑀]0.8 𝑚𝑙
[K] = = 6.95𝑋10−3 M ------------- ln 6.95𝑋10−3 = -4.96
11.5 𝑚𝑙
[0.1 𝑀]1.0 𝑚𝑙
[K] = = 8.69𝑋10−3 M ------------ ln 0.01043 = -4.74
11.5 𝑚𝑙
[0.1 𝑀]1.2 𝑚𝑙
[K] = = 0.01043M --------------- ln 0.01043 = -4.56
11.5 𝑚𝑙
[0.1 𝑀]1.4 𝑚𝑙
[K] = = 0.01217M --------------- ln 0.01217 = -4.41
11.5 𝑚𝑙
6
Curva de Calibración para el 2° experimento
0
0 0.01 0.02 0.03 0.04
-1
-2
Ln K
-3 ln
Linear (ln)
-4
y = -41.484x - 4.2275
R² = 0.9817
-5
-6
1/T
∆H=mR
A=е4.2275= 68.54
7
Experimento 3: Temperatura: 45°C ó 318.15°K
[𝑵𝒂𝟐 𝑺𝟐 𝑶𝟑 ]𝑽𝑵𝒂𝟐 𝑺𝟐 𝑶𝟑
[𝐊] =
𝑽𝒂𝒍𝒊𝒄𝒖𝒐𝒕𝒂
[0.1 𝑀]0.4 𝑚𝑙
[K] = = 3.48𝑋10−3 M ln 3.48𝑋10−3 = -5.66
11.5 𝑚𝑙
[0.1 𝑀]0.7 𝑚𝑙
[K] = = 6.09𝑋10−3 M ln 6.09𝑋10−3 = -5.10
11.5 𝑚𝑙
[0.1 𝑀]1.0 𝑚𝑙
[K] = = 8.69𝑋10−3 M ln 8.69𝑋10−3 = -4.74
11.5 𝑚𝑙
[0.1 𝑀]1.2 𝑚𝑙
[K] = = 0.01043M ln 0.01043 = -4.56
11.5 𝑚𝑙
[0.1 𝑀]1.4 𝑚𝑙
[K] = = 0.01217M ln 0.01217 = -4.41
11.5 𝑚𝑙
[0.1 𝑀]1.6 𝑚𝑙
[K] = = 0.01391M ln 0.01391 = -4.27
11.5 𝑚𝑙
8
Curva de calibración para el 3er
experimento a 318.15°K
0
0 0.01 0.02 0.03 0.04 0.05 0.06
-1
-2
log [I] -3
y = 0.0037x - 2.3587
-4 R² = 0.7716
-5
-6
Tiempo (seg)
m=-k K=0.0037
△𝐻
Como m= entonces la energía de activación es: ∆H=mR
𝑅
A=е2.3587= 10.58