Narayana IIT Academy: India

Narayana IIT Academy
INDIA
Sec: Sr. IIT-IZ(L25) Date: 02-09-18
Time: 09.00 PM to 12.00 PM Max. Marks:183
Name of the Student: ___________________ H.T. NO:

2017_PAPER-II
JEE-ADVANCE-2017-P2-Model
Time: 02:00 to 05:00 PM IMPORTANT INSTRUCTIONS Max Marks: 183
CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 7) Questions with Single Correct Options +3 -1 7 21
One of More Correct Options Type
Sec – II (Q.N : 8 – 14) +4 -2 7 28
(partial marking scheme) (+1)
Questions with Comprehension Type
Sec – III (Q.N : 15 – 18) +3 0 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Total 18 61
PHYSICS
Sec – II (Q.N : 26 – 32) +4 -2 7 28
Sec – III (Q.N : 33 – 36) +3 0 4 12
Total 18 61
MATHEMATICS
Sec – II (Q.N : 44 – 50) +4 -2 7 28
Sec – III (Q.N : 51 – 54) +3 0 4 12
Total 18 61
NarayanaIIT Academy 02-09-18_Sr.IIT-IZ(L25)JEE-Adv_(2017_P2) _Q'P
PHYSICS Max. Marks: 61
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
1. Two sources S1 and S2 emitting coherent light waves of wavelength  in the
same phase are situated as shown. The minimum distance OP, so that the
light intensity detected at P is equal to that at O is(D>>  )
P
2
S1 S2
O
Screen
A) D 2 B) D / 2 C) D 3 D) D / 3
2. A Young’s double slit experiment is conducted in water  1  as shown in the
figure, and a glass plate of thickness t and refractive index  2 is placed in the
path of S2 . The magnitude of the phase difference at O is: (Assume that '  ' is
the wavelength of light in air)
S1 Water
Water 1 O
S2
t
 μ2  2π μ  2π 2π 2π
A)   1 t B)  1  1 t C)  μ 2  μ1  t D)  μ 2  1 t
 μ1  λ  μ2  λ λ λ
I max  I min
3. Two coherent sources with intensity ratio  interfere. Then the ratio
I max  I min
is
2  2 4 
A) 2 B) C) D)
1  1  1 
Sec: Sr. IIT-IZ(L25) space for rough work Page 2

4. An engine whistling at a constant frequency n 0 and moving with a constant
velocity goes past a stationary observer. As the engine crosses him, the
frequency of the sound heard by him changes by a factor f. The actual
difference in the frequencies of sound heard by him before and after the
engine crosses him is
2
1 1 1 f  1 f  1  1 f 
A)
2

n0 1  f 2
 B) n0 
2  f
 C) n 0  
1 f 
D) n0 
2 1 f 


5. A rope hangs from a rigid support. A pulse is set by jiggling the bottom end.
We want to design a rope in which velocity  of pulse is independent of z, the
distance of the pulse from fixed end of the rope. If the rope is very long the
desired function for mass per unit length  (z) in terms of 0 (mass per unit
length of the rope at the top (z = 0) is given by
gz gz 2 
 
 2
 2  g   gz 
A)  (z) = 0 e v
B)  ( z )  0e v
C)  ( z )  0 log e  2  z D)   z   0e  
 
6. A point mass m and a thin uniform rod of mass M and length l are located
along a straight line as shown in figure what is the potential energy of
gravitational interaction of this system.
GMm  a  GMm  l GMm  a  GMm
A)  ln  1   B)  ln  1   C)   1   D) 
l  l l  a l  l (a  l / 2)
7. A string of mass m and length l is hanging from ceiling as shown in the figure.
Wave in string move upward. vA and vB are the speed of wave at A and B
respectively. Then vB is
B
3L
4 A L
4
A) 3v A B) vA C)  v A D) 2v A
SECTION-II
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 7 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of which
ONE or MORE THAN ONE are correct.
Marking scheme: +4 for all correct options, 0 if not attempted and -2 in all wrong cases.
8. White light is used to illuminate the two slits in Young’s double slit
experiment. The separation between the slits is b band the screen is at a
distance d (>b) from the slits. At a point on the screen directly in front of one
of the slits, certain wavelength are missing. Some of these missing
wavelengths are
b2 2b 2 2b 2 b2
A)   B)   C)   D)  
d d 3d 3d
9. Two coherent point light sources are placed at x =  d/2 and x = d/2 . These
sources are surrounded by a spherical screen having equation
x 2 + y 2 + z 2 = R 2  R >> d  . The sources emit monochromatic light of wavelength
λ = d/3
A) The number of maxima produced on the screen are 7
2πR 5
B) The shape and length of second order maxima is circle,
3
C) If radius of screen is doubled the intensity of maxima will become one
fourth
D) All maxima are equally spaced along x-axis
10. Which of the following functions of x and t represent a progressive wave
1 1
A) y  sin  4t  3x  B) y  2
C) y  D) y  3x 2  4t
4   4t  3x  4t  3 x  6tx
11. Assuming Earth, an uniform sphere of mass M and radius R. At a point P
inside Earth at a distance r measured from centre of Earth (r < R)
3  r 2  Gm
1
8  R 2   R3
A) Pressure (p) caused by gravitational compression is
3  r 2  GM 2
1
8  R 2   R 4
B) Pressure (p) caused by gravitational compression is
3 GM
2
C) Gravitational field Intensity at the centre is 2 R
D) Gravitational field Intensity at the centre is zero.
12. A particle of mass m is moving in an elliptical orbit about a bigger mass M,
which is at one of its focus. v A , vB , vC and vD are the velocities of the particle at
the points A,B,C and D and rA , rB , rC and rD are the distances of the points A, B,
C and D from the bigger mass respectively. Which of the following relation
is/are incorrect

2 2 2 2
GMm mv A GMm mvB GMm mvC GMm mvD
A)  B)  C)  D) 
rA2 rA rB2 rB rC2 rC rD2 rD
13. A block of mass m is kept on a horizontal platform of mass M. The platform is
performing SHM in a horizontal plane with angular frequency  . There is no slipping
between the block and platform due to friction. If at any time, displacement of platform from mean
position is x then
A) Friction force acting on the block is directly proportional to x
2
B) Total contact force exerted by platform on the block is m 2 g 2   m 2 x 
C) Net contact force acting on platform is Mg
D) Net contact force acting on block is Mg
14. The energy of a particle executing simple harmonic motion is given by
E  Ax 2  Bv 2 where x is the displacement from mean position x  0 and v is the velocity of
the particle at x then choose the correct statement(s)
2E
A) Amplitude of SHM is
A
E
B) Maximum velocity of the particle during SHM is
B
B
C) Time period of motion is 2
A
D) Displacement of the particle is proportional to the velocity of the particle
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
PASSAGE 1
0
In figure light of wave length   5000 A is incident on the slits S1 & S2 ( in a
horizontally fixed place) Here d = 1 mm and D = 1m. Take origin at O any xy
plane as shown in figure. The screen is free to move under action of gravity, it
is released from rest from the initial position as shown.  g  10 m / s 2 

15. The velocity of central maxima at t = 5S is

A) 50 ms 1 along y - axis B) 50 ms 1 along negative y – axis
C) 25 ms 1 along y - axis D) 3 108 ms 1 along y – axis
16. Velocity of 2nd maxima with respect to central maxima at t = 2S is
A) 8cms 1 iˆ  20 ms 1 ˆj B) 8 cms 1iˆ
C) 2cms 1iˆ D) 86 ms 1 ˆj
PASSAGE 2
In a modified YDSE the region between the screen and slits is immersed in a
5 T 
liquid whose refractive index varies with time as l     until it reaches a
2 4
steady state value 5/4. A glass plate of thickness 36  m and refractive index
3/2 is introduced in front of one of the slits S2 as shown in fig. The distance
between the slits is d = 2mm and the distance between slits and screen is D =
1m (O is located symmetrically with respect to S1 and S2 )
17. The position of central maxima at T = 0 from the point O is

A) 1.8 mm B) 3.6mm C) 7.2 mm D) 14.4 mm
18. The time when central maxima reaches O is
A) 1Sec B) 2Sec C) 3Sec D) 4Sec
CHEMISTRY Max. Marks: 61

SECTION – I
19. If for 2 A2 B  g   2 A2  g   B2  g  , K p  TOTAL PRESSURE (at equilibrium) and starting the

dissociation from 4 mol of A2 B then:
A) Degree of dissociation of A2 B will be (2/3)
B) Total no. of moles at equilibrium will be (14/3)
C) At equilibrium the no. of moles of A2 B are not equal to the no. of mole of B2
D) At equilibrium the no. of moles of A2 B are equal to the no. of moles of A2
20. For the equilibrium,
SrCl2 .6 H 2O  s   SrCl2 .2 H 2O  s   4 H 2O  g 
The equilibrium constant Kp  16 10 12 atm 4 at 1o C . If one litre of air saturated with water
vapour at 1o C is exposed to a large quantity of SrCl2 .2 H 2O  s  , what weight of water
vapour will be absorbed? Saturated vapour pressure of water at 1o C  7.6 torr.
A) 6.4 mg B) 3.25mg C) 2.3mg D) 8.5mg
21. At 1000 K, solid carbon, CaO and CaCO3 are mixed and allowed to attain following
equilibrium:
CaCO3  s   CaO  s   CO2  g  ; K p  4  102 atm
C  s   CO2  g   2CO  g  ; K p  2atm
What is the pressure of CO at equilibrium (in atom) ?
2
A) 0.04 atm B) 5 2 C) 50 atm D) atm
5
22. An aqueous solution is 0.3 M in Al3+ and 3 M in Mg2+. Select the only INCORRECT
option.
Given:  K sp  Al OH   3 1034 ,  K sp Mg OH   3 1012 M 3
3 2
A) At pH = 9 both Al(OH)3 and Mg(OH)2 will precipitate

B) At pOH = 12 neigher Al(OH)3 nor Mg(OH)2 will precipitate
C) For selective precipitation of Al(OH)3 only, pH of solution should be 3 to 8.
D) Mg (OH)2 will precipitate at maximum pH = 8
23. Which of the following combinations regarding
True (T) and False (F) nature of following statement is correct?
Statement-1 : pH of water at any temperature will be 7.
Statement-2 : Acid dissociation constant of water at 298 K is equal to 10 -14.
Statement-3: For any aqueous acid solution (pH + pOH) will be equal to 14 at 298 K.
Statement-4: Degree of dissociation of water at 308 K will be greater than 1.6 107 % .
Statement-5: On increasing dilution extent of dissociation of HCl will increase.
A) TFTTT B) FTTFF C) TTFFT D) FFTTF
24. In aqueous solution the ionization constants for carbonic acid are:
K1  4.2  107 and K 2  4.8  1011
Select the CORRECT statement for a saturated 0.034 M solution of the carbonic acid.
A) The concentration of CO32 is 0.034 M
B) The concentration of CO32 is greater than that of HCO3
C) The concentration of H  and HCO3 are approximately equal
D) The concentration of H  is double that of CO32
25. A water sample from a municipal water supply was found to have a pH = 7.0. On
evaporating 2 L of this water, 2.016 g of white solid was left behind in the evaporation
vessel, i.e., the Total Dissolved Solid (TDS) content of this water was 1008 mg L-1
However, addition of soap to a bucket of this water did not produce any visible
scum. Based on these findings, one can conclude that:
A) There are no Ca 2 or Mg 2 ion in the water
B) There are no CO32 or HCO3 ion in the water
C) Concentration of any ion in the water is lower than 0.038 M
D) Water may be containing Na+ ions in concentration > 0.04 M
SECTION-II
26. Choose the CORRECT options:

A) Favorable conditions for formation of graphite are high pressure and low temperature
from equilibrium diamond  d  3.5 g / ml   graphite  d  2.3g / ml  ; H  1.9kJ / mole
Kp
B) For reaction N 2O4  g   2 NO2 ,  g  ; degree of dissociation   is where P is
4P  K p
equilibrium pressure.
C) For reaction Cl2  g   3F2  g   2ClF3  g  ; H  329kJ , dissociation of ClF3  g  will be
favoured by addition of inert gas at constant pressure
D) Reaction stops at equilibrium (microscopically)

27. For a gaseous reaction : A  g   3B  g   C  g  , H is positive and the reaction attains
equilibrium at 1 bar total pressure and 400 K. Identify the INCORRECT statement(s)
regarding the above reaction:
A) On increase of temperature, equilibrium will be shifted in forward direction.
B) When inert gas is introduced into a rigid container containing above equilibria
equilibrium shifts towards left.
o
C) G400  0 , for the above reaction.
D) If volume of vessel containing the above equilibria is increased without change in
temperature then partial pressure of B decreases as compared to original equilibrium
partial pressure of B.
28. Choose INCORRECT option (s) for the given reactions :
A) A  s   B  g   C  g   D  g  : At equilibrium, if pressure is increased, no effect on
equilibrium.
B) X  g   Y  g   Z  g  , if total pressure of the system is decreased at equilibrium, it will
shift in forward direction.
C) H 2O  g   CO  g   H 2  g   CO  g  : inert gas is added at constat volume at equilibrium,
so total pressure will increase and no effect on equilibrium.
D) I 2  g   3Cl2  g   2 ICI3  g   heat ; if temperature is increased, equilibrium will shift in
backward direction but equilibrium constant will not change.
29. In which of the following solutions, the solubility of AgCN will be greater than that in
pure water?
(Given: K sp  AgCN   4 1016 , K a  HCN   5 1010 )
A) 0.01 M Ag NO3 solution B) A buffer solution of pH = 12
C) 0.2 M NH3 solution D) A buffer solution of pH = 5
30. Buffer solution ‘A’ of a weak monoprotic acid and it’s sodium salt in concentration ratio
X : Y has pH= (pH)1 and buffer solution ‘B’ of the same acid and it’s sodium salt in the
concentration ratio Y: X has pH = (pH)2. If (pH)2 - (pH)1 = 1 unit and (pH)1+(pH)2=9.5
units, then :
X X
A) pKa  4.75 B)  2.36 C)  3.162 D) pKa  5.25
Y Y
31. A solution containing a maxture of 0.05 M NaCl and 0.05 M NaI is taken
( K sp of AgCl  1010 and K sp of AgI  4 1018 ) . When AgNO3 is added to such a solution:
A) The concentration of Ag+ that can just precipitate Cl   2 10 9 mol / L .
B) The concentration of Ag+ that can just precipitate I   8 1015 mol / L .
C) AgCl and Agl will be precipitated together.
D) First AgI will be precipitated.
32. Equal volumes of following solutions are mixed. In which case the pH of resulting
solution will be average value of pH of two solutions?
A) Aqueous HCl of pH=2, aqueous NaOH of pH = 12
B) Aqueous HCl of pH = 2, aqueous HCl of pH = 4
C) Aqueous NaOH of pH= 12, aqueous NaOH of pH = 10
D) Aqueous CH3COOH of pH = 5, aqueous NH3 of pH = 9. [Ka(CH3COOH) = Kb
(NH3)]
SECTION – III
(PARAGRAPH TYPE)
Paragraph 1
According to Le Chatelier’s principle, on applying any external force to disturb
equilibrium, the reaction moves in that direction in which effect of external force is
minimized as far as possible. A container whose volume is V contains an equilibrium
mixture that contains 2 moles each of PCl5, PCl3, and Cl2 (all gases). The pressure is 3
atm and temperature is T. A certain amount of Cl2  g  is now introduced keeping the pressure
and temperature constant until the equilibrium volume changes to 2V.
PCl5  g   PCl3  g   Cl2  g 
33. The moles of Cl2 that was added is:

10 8 20
A) 2 B) C) D)
7 3 3
34. The equilibrium constant K of the reaction:
A) 1 B) 2 C) 3 D) 4
Paragraph 2:

The pH of basic buffer mixtures is given by : pH  pK a  log

 Base , whereas pH of acidic
 Salt 
buffer mixtures is given by : pH  pK a  log

 Salt  . Addition of little acid or base
 Acid 
although shows no appreciable change in pH for all practical purposes, but since the
ration
 Base or  Salt  changes, a slight decrease or increase in pH results.
 Salt   Acid 
35. The amount of  NH 4 2 SO4 to be added to 500 mL of 0.01 M NH 4OH solution (pKa
for NH 4 is 9.26) to prepare a buffer of pH 8.26 is:

A) 0.05 mole B) 0.025 mole C) 0.10 mole D) 0.005 mole
36. The ratio of pH of solution (I) containing 1 mole of CH 3COONa and 1 mole of HCl
solution, (II) containing 1 mole of CH 3COONa and 1 mole of acetic acid in one litre is:
A) 1 : 2 B) 2 : 1 C) 1 : 3 D) 3 : 1
MATHS Max.Marks:61
SECTION – I
 5200 
37. If {x} represents the fractional part of x, then   is
 8 
1 1 3 5
A) B) C) D)
4 8 8 8
38. The coefficient of x50 in the expansion of

1000 999 998
1  x   2 x 1  x   3x 2 1  x   .....  1001 x1000
A) 1000C50 B) 1001C50 C) 1002C50 D) 21001

 k
6
39. The sum  3
k 1
k
 2  3k 1  2k 1 
k

A) 1 B) 2 C) 3 D) 4
2 2
40.  ,  are the roots of ax  bx  c  0 and  ,  are the roots of px  qx  r  0 and D1 , D2 be
the respective discriminants of these equations. If  ,  ,  and  are in A.P. then D1 : D2 
(where  ,  ,  ,   R & a, b, c, p, q, r  R )
A) a2 : p 2 B) a 2 : b 2 C) c 2 : r 2 D) a 2 : r 2
2
41. Let f  x   x 2  5 x  6 , then the number of real roots of  f  x    5 f  x   6  x  0 is
A) 1 B) 2 C) 3 D) 0
33 46 13  19  a
42. If sin 1  sin  1 
  cos  cos
 1 
  tan   tan
 1 
  cot  cot  

 
 7   7   8    8  b
Where a and b are in their lowest form, then (a + b) equal to
A) 17 B) 20 C) 23 D)None of these
43. Sum to infinite terms of the series
 3  3  3
cot 1  12    cot 1  2 2    cot 1  32    .........
 4  4  4 is

A) B) tan 1 2 C) tan 1 3 D) cot 1 3
4
SECTION-II
  7 
   14 
7
 k  r  14   n n
44. The value of   14    k   r   , where   denotes C r , is
k 0 rk    r
  
 k 
A) 67 B) greater than 76 C) 87 D) greater than 78
n
45. If  4  15   1  f , where n is an odd natural number, I is an integer and 0 < f < 1, then
A) I is natural number B) I is an even integer
n
C) (I + f) (I – f) = 1 D) I  f   4  5 
3 4 5
46. Let f  x     , then f  x   0 has
x2 x3 x4
A) exactly one real root in  2,3 B) exactly one real root in  3, 4 
C) at least one real root in  2,3 D) None of these
47. Let x, y , z be positive reals. Then

4 9 16 x y z 3
A) x  y  z  81 if x  y  z  1 B)  
y z z x x y 2

1 1 1
C) If x y z  1, then 1  x 1  y 1  z   8 D) If x  y  z  1, then    9
x y z
48. The value (s) of x satisfying the equation sin 1 sin x  sin 1 sin x is/are given by (n is
any integer)
A) n B) n  1 C) n  1 D) 2n  1
6
  (m  1)   m 
49. For 0   
2
, the solution(s) of  cos ec  
m 1 4
 cos ec   
  4
  4 2 is/are

   5
A) B) C) D.
4 6 12 12
th
50. If the first and  2n  1 terms of an A.P , G.P and H.P of positive terms are equal and
their nth terms are a,b,c respectively , then
A) a=b=c B) a  b  c C) b 2  ac D) a  c  2b
SECTION – III
(PARAGRAPH TYPE)
Comprehension -1 (51 & 52)
Consider the expansion of (a + b + c +d)10
51. The number of terms in the expansion is
A) 14 c4 B) 14 c3 C) 13 c4 D) 13c3
52. The greatest coefficient in the expansion is
A) 25200 B) 14400 C) 22500 D) 32400
Comprehension -2 (53 & 54)
If roots of the equation x
4
 12 x 3  bx 2  cx  81  0 are positive, then
53. Value of b is
A) -54 B) 54 C) 27 D) -27
54. Value of c is
A) 108 B) -108 C) 54 D) -54

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Name of the Student: ___________________ H.T. NO:

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