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Solutions to JEE(Main)-2018 Test Booklet Code
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JEE-MAIN-MPC-2018-2
PART A – MATHEMATICS
1. If the curves y2 = 6x, 9x2 + by2 = 16 intersect each other at right angles, then the value of b is :
9
(1) (2) 6
2
7
(3) (4) 4
2
Sol. (1)
Let the point of intersection be (x1, y1) finding slope of both the curves at point of intersection
for y2 = 6x, 9x2 + by2 = 16
dy 6
2y 6 , m1
dx 2y1
dy 18x1
18x 2by 0 , m2
dx 2by1
m1m2 = –1
6 18x1
1
2y1 2by1
6 18 x1 9
1 b
4b 6x1 2
2. Let u be a vector coplanar with the vectors a 2iˆ 3 ˆj kˆ and b ˆj kˆ . If u is perpendicular to a and
2
u b 24 , then u is equal to :
(1) 84 (2) 336
(3) 315 (4) 256
Sol. (2)
u 1a 2 b
u a 1a a 2 a b
0 1 4 9 1 2 3 1
2 71
u b 1a b 2 b b
24 = 1(2) + (–71)(2)
24 = –121 1 = –2
2 = 14
u 2 2iˆ 3jˆ kˆ 14 ˆj kˆ = 4iˆ 8jˆ 16kˆ
2
u 336
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JEE-MAIN-MPC-2018-3
Sol. (4)
1 2 15
lim x ......
x 0 x x x
1 2 15 1 2 15
= lim x ..... .....
x 0 x x x x x x
1 15
= lim 1 2 ..... 15 x ..... = 120
x 0 x x
Sol. (3)
Vectors along the given lines L1, L2 are
ˆi ˆj kˆ
n̂ 2 2 3 iˆ ˆj
1 L1 = 0 L2 = 0
1 1 1
ˆi ˆj kˆ
and n̂ 2 1 2 1 3iˆ 5jˆ 7kˆ
3 1 2
Putting y = 0 in 1st two equation
2x 3z 2
2x 2z 2
z4
Point on the plane is (–5, 0, 4) and normal vector of required plane is
ˆi ˆj kˆ
1 1 0 7iˆ 7ˆj 8kˆ
3 5 7
Hence, equation of plane is –7x + 7y – 8z – 3 = 0
3 1
Perpendicular distance is
162 3 2
2
sin 2 x
5. The value of 1 2
x
dx is :
2
(1) (2)
4 8
(3) (4) 4
2
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JEE-MAIN-MPC-2018-4
Sol. (1)
2
sin 2 x
Let I 1 2
x
dx
2
2
sin 2 x
I 1 2
x
dx
2
2 2
2
xdx 2sin 2 xdx
2I sin
0
2
2
2I 1 cos 2x dx 2
0
I
4
6. Let g(x) = cos x2, f (x) = x , and , ( < ) be the roots of the quadratic equation 18x2 9x + 2 = 0.
Then the area (in sq. units) bounded by the curve y = (gof ) (x) and the lines x = , x = and y = 0, is :
1 1
(1)
2
2 1 (2)
2
3 1
1 1
(3)
2
3 1 (4)
2
3 2
Sol. (2)
Y
3
3 1
Required area = cos x dx y = cos x
2
6
O X
6 3
1
*7. If sum of all the solutions of the equation 8cos x cos x cos x 1 in [0, ] is k , then k is
6 6 2
equal to :
20 2
(1) (2)
9 3
13 8
(3) (4)
9 9
Sol. (3)
1
8cos x cos x cos x 1
6 6 2
1
8cos x cos 2 sin 2 x 1
6 2
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JEE-MAIN-MPC-2018-5
1 1 f x
8. Let f x x 2 2
and g x x , x R {1, 0, 1}. If h(x) = , then the local minimum value
x x g x
of h(x) is :
(1) 2 2 (2) 3
(3) 3 (4) 2 2
Sol. (1)
1 1
f(x) = x2 + 2
g(x) = x –
x x
1
x2
f x x2
h(x) =
g x 1
x
x
2
1
x 2
x
1
x x
1 2
h(x) = x
x x 1
x
1 2
h x 1 2 1
x 1
2
x
x
1
h x 0 at x 2
x
1
x 2 point of local minima
x
Hence, local minimum value is 2 2
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sin 2 x cos 2 x
9. The integral 2
dx is equal to :
sin 5 3 2 3 2
x cos x sin x sin x cos x cos x 5
1 1
(1) C (2) C
1 cot x 3
3 1 tan 3 x
1 1
(3) C (4) C
3 1 tan x 3
1 cot 3 x
(where C is a constant of integration)
Sol. (3)
sin 2 x cos 2 x
2
dx
sin 5
x cos3 x sin 2 x sin 3 x cos 2 x cos5 x
sin 2 x cos 2 x
= 2
dx
sin 3
x cos3 x
tan 2 x sec 2 x
=
2
dx
1 tan x 3
put 1 + tan3x = t
1 dt 1
=
3 t 2
+c
3t
1
= +c
3 1 tan 3 x
10. A bag contains 4 red and 6 black balls. A ball is drawn at random from the bag, its colour is observed and
this ball along with two additional balls of the same colour are returned to the bag. If now a ball is drawn at
random from the bag, then the probability that this drawn ball is red, is :
3 3
(1) (2)
4 10
2 1
(3) (4)
5 5
Sol. (3)
Initially 4 Red balls and 6-Black balls
4 6 6 4 2
Required probability = =
10 12 10 12 5
*11. Let the orthocentre and centroid of a triangle be A(3, 5) and B(3, 3) respectively. If C is the circumcentre
of this triangle, then the radius of the circle having line segment AC as diameter, is :
3 5
(1) (2) 10
2
5
(3) 2 10 (4) 3
2
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JEE-MAIN-MPC-2018-7
Sol. (4)
Orthocentre A (–3, 5) centroid B (3, 3)
2 1
A(–3, 5) B(3, 3) C(6, 2)
AC = 3 10
3 10 5
Radius = 3
2 2
*12. If the tangent at (1, 7) to the curve x 2 = y 6 touches the circle x2 + y2 + 16x + 12y + c = 0 then the value of
c is :
(1) 95 (2) 195
(3) 185 (4) 85
Sol. (1)
Equation tangent at (1, 7)
2x – y + 5 = 0
perpendicular (–8, –6) to line
2 8 6 5
= 82 62 c
5
5 82 6 2 c
c = 95.
*13. If , C are the distinct roots, of the equation x2 x + 1 = 0, then 101 + 107 is equal to :
(1) 2 (2) 1
(3) 0 (4) 1
Sol. (4)
x2 – x + 1 = 0
Roots (–, –2), = –, = –2
107
101 107
101
2 =1
*14. PQR is a triangular park with PQ = PR = 200m. A T.V. tower stands at the mid-point of QR. If the angles
of elevation of the top of the tower at P, Q and R are respectively 45°, 30° and 30°, then the height of the
tower (in m) is :
(1) 50 2 (2) 100
(3) 50 (4) 100 3
Sol. (2)
Let ST = h (height of tower) P S
PT = ST = h 45º
ST 200 m
tan 30º 200 m
QT h
QT h 3 30º
Q 30º
Now PT2 + QT2 = 2002 T R
4h2 = 2002
h = 100
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JEE-MAIN-MPC-2018-8
9 9
2
*15. If x 5 9 and x 5
i 1
i
i 1
i 45 , then the standard deviation of the 9 items x1, x2 , …… , x9 is :
(1) 3 (2) 9
(3) 4 (4) 2
Sol. (4)
xi – 5 = yi
2
y 2
i
y i
=
45 9
2
2
9 9 9 9
5 5
*16. The sum of the co-efficients of all odd degree terms in the expansion of x x 3 1 x x 3 1 ,
(x > 1) is :
(1) 2 (2) 1
(3) 0 (4) 1
Sol. (1)
2
= 2 5 C0 x5 5 C2 x 3 x 3 1 5 C4 x x 3 1
= 2 x 10 x x 5 x x 1 2x
5 6 3 6 3
*17. Tangents are drawn to the hyperbola 4x2 y2 = 36 at the points P and Q. If these tangents intersect at the
point T(0, 3) then the area (in sq. units) of PTQ is :
(1) 36 5 (2) 45 5
(3) 54 3 (4) 60 3
Sol. (2)
Chord of contact is y = – 12
4x2 = y2 + 36 x2 = 45
1
= 6 5 15 45 5
2
*18. From 6 different novels and 3 different dictionaries, 4 novels and 1 dictionary are to be selected and
arranged in a row on a shelf so that the dictionary is always in the middle. The number of such
arrangements is :
(1) at least 750 but less than 1000 (2) at least 1000
(3) less than 500 (4) at least 500 but less than 750
Sol. (2)
Dictionary can be chosen in 3C1 = 3 ways
Novels can be arranged in 6C4 4! = 360 ways
N = 3 360 = 1080
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JEE-MAIN-MPC-2018-9
Sol. (3)
For non–zero solution D = 0
1 k 3
3 k 2 0
2 4 3
1(–3k + 8) – k(–9 + 4) + 3(12 – 2k) = 0
–3k + 8 + 5k + 36 – 6k = 0
– 4k + 44 = 0
k = 11
hence equations are x + 11y + 3z = 0
3x + 11y – 2z = 0
and 2x + 4y – 3z = 0
let z = t
5 t
then we get, x = t and y =
2 2
5
t t
xz 2
thus, 2 2 = 10
y t
4
x 4 2x 2x
20. If 2 x x 4 2x = (A + Bx) (x A)2, then the ordered pair (A, B) is equal to :
2x 2x x4
(1) (4, 5) (2) (4, 5)
(3) (4, 3) (4) (4, 5)
Sol. (4)
1 2x 2x
(5x – 4) 1 x 4 2x
1 2x x 4
1 2x 2x
= (5x – 4) 0 (x 4) 0
0 0 x 4
= (5x – 4)(x + 4)2 = (A + Bx)(x – A)2
A = – 4, B = 5
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Sol. (3)
A a, b : a 4, 6 , b 4, 6 b (6, 7)
b=6
B a, b : 4 a 6 2
9 b 5 36
2
b=4
2 2
a 6 b 5 (6, 3)
1 a
9 4 a=4 a=6
AB
*22. Tangent and normal are drawn at P(16, 16) on the parabola y2 = 16x, which intersect the axis of the
parabola at A and B, respectively. If C is the centre of the circle through the points P, A and B and CPB =
, then a value of tan is :
4 1
(1) (2)
3 2
(3) 2 (4) 3
Sol. (3)
Focus will be centre of Circumcircle of PAB P(16, 16)
B : (24, 0)
C : (4, 0)
16 4
mCP , mPB = –2 C B
12 3 (4, 0)
A
4
2
tan 3 2
8
1
3
23. Let S = {t R : f (x) = |x | . (e|x| 1) sin|x| is not differentiable at t}. Then the set S is equal to :
(1) {0, } (2) (an empty set)
(3) {0} (4) {}
Sol. (2)
x
S = {t : R : f(x) = |x – | e 1 sin x is not diff. at t}
|x|
f(x) = |x – | (e – 1) sin|x|
at x = 0,
f(0 ) lim
+
h e h 1 sin h
lim
h e h 1 sin h
0
h 0 h h 0 h
f(0 ) = lim
–
h e h 1 sin h
=0
h 0 h
+
f( ) lim
h e h 1 sin h
h e h 1 sinh
0
h 0 h hlim
0 h
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f( ) = lim
–
h e h 1 sinh
h 0 h 0
f(x) is diff. for all x R
Sol. (2)
(~p ~q) (~p q) = ~p (~q q) = ~p
Alternate solution
p q pq ~p ~pq ~(p q) ~(p q) (~p q)
T T T F F F F
T F T F F F F
F T T T T F T
F F F T F T T
*25. A straight line through a fixed point (2, 3) intersects the coordinate axes at distinct points P and Q. If O is
the origin and the rectangle OPRQ is completed, then the locus of R is :
(1) 3x + 2y = 6xy (2) 3x + 2y = 6
(3) 2x + 3y = xy (4) 3x + 2y = xy
Sol. (4)
Let the point R(a, b) y
x y R(a, b)
then equation of line be 1 Q(0, b)
a b
2 3
1 x
a b O P(a, 0)
2 3
Locus of R is 1
x y
i.e. 2y + 3x = xy
*26. Let A be the sum of the first 20 terms and B be the sum of the first 40 terms of the series
12 + 2.22 + 32 + 2.42 + 52 + 2.62 + …..
If B 2A = 100, then is equal to :
(1) 496 (2) 232
(3) 248 (4) 464
Sol. (3)
A = (12 + 22 + 32 + … 202) + (22 + 42 + … 202)
= (12 + 22 + 32 + … 202) + 22(12 + 22 + 32 + … 102)
20 21 41 4 10 11 21
=
6 6
= 4410
B = (12 + 22 + 32 + … 402) + (22 + 42 + 62 + … 402)
= 12 + 22 + 32 + … 402 + 4(12 + 22 + …. 202)
40 41 81 4 20 21 41
6 6
= 33620
B – 2A = 33620 – 8820 = 24800
= 100
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JEE-MAIN-MPC-2018-12
= 248
Alternate solution
2
n n 1
Sn , n is even.
2
412 212
B – 2A = 40 40
2 2
100 = 400 62 = 248
dy
27. Let y = y(x) be the solution of the differential equation sin x y cos x 4 x , x (0, ). If y 0 ,
dx 2
then y is equal to :
6
4 4
(1) 2 (2) 2
9 9 3
8 2 8
(3) (4) 2
9 3 9
Sol. (4)
d
(y sinx) = 4x
dx
x2
y sinx = 4 +c
2
y sinx = 2x2 + c
given y (/2) = 0
c = – 2 /2
Thus y sin x = 2x2 – 2/2
8
now y(/6) = 2
9
28. The length of the projection of the line segment joining the points (5, 1, 4) and (4, 1, 3) on the plane,
x + y + z = 7 is :
2 2
(1) (2)
3 3
2 1
(3) (4)
3 3
Sol. (1)
D.R’s of AB = (1, 0, 1) B(4, –1, 3)
D.R’s of normal to plane = (1, 1, 1)
1 1 2 A(5, –1, 4)
cos sin
2 2 3 3
AB 2
P:x+y+z=7
2
Length of projection = AB cos
3
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JEE-MAIN-MPC-2018-13
12
*30. Let a1, a2, a3, ….. , a49 be in A.P. such that a 4 k 1 416 and a9 + a43 = 66. If a12 a22 ..... a17
2
= 140m,
k 0
then m is equal to :
(1) 33 (2) 66
(3) 68 (4) 34
Sol. (4)
12
a
k 0
4k 1 416 (let common difference of A.P. be d)
12
a
k 0
1 4 kd = 416
a1 + 24d = 32
Given a9 + a43 = 66 a1 + 25d = 33
d = 1, a1 = 8
17 17
2
a 2r 7 r = 4760 = 140m
r 1 r 1
m = 34
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JEE-MAIN-MPC-2018-14
PART B – PHYSICS
ALL THE GRAPHS/DIAGRAMS GIVEN ARE
SCHEMATIC AND NOT DRAWN TO SCALE
31. Three concentric metal shells A, B and C of respective radii a, b and c (a < b < c) have surface charge
densities + , – and + respectively. The potential of shell B is :
b 2 c2 a 2 b2
(1) a (2) c
0 c 0 a
a 2 b2 b 2 c2
(3) c (4) a
0 b 0 b
Sol. (3)
VB VB I VBII VB III
*32. Seven identical circular planar disks, each of mass M and radius R are
welded symmetrically as shown. The moment of inertia of the arrangement P
about the axis normal to the plane and passing through the point P is :
181 19
(1) MR 2 (2) MR 2 O
2 2
55 73
(3) MR 2 (4) MR 2
2 2
Sol. (1)
2
I I cm 7M 3R
MR 2 MR 2 2 2 81 MR 2
6 M 2R 7M 3R =
2 2 2
*33. From a uniform circular disc of radius R and mass 9M, a small disc
R
of radius is removed as shown in the figure. The moment of
3
inertia of the remaining disc about an axis perpendicular to the plane 2R
of the disc and passing through centre of disc is : 3
37
(1) MR 2 (2) 4 MR2
9
R
40
(3) MR 2 (4) 10 MR2
9
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Sol. (2)
2 2
9MR 2 M R 2R 2
I M 4 MR
2 2
3 3
34. The reading of the ammeter for a silicon diode in the given circuit 200
is :
(1) 13.5 mA (2) 0
(3) 15 mA (4) 11.5 mA
3V
Sol. (4)
3 0.7 0.7 V 200
I= A 11.5 mA
200
3V
35. Unpolarized light of intensity I passes through an ideal polarizer A. Another identical polarizer B is placed
I
behind A. The intensity of light beyond B is found to be . Now another identical polarizer C is placed
2
I
between A and B. The intensity beyond B is now found to be . The angle between polarizer A and C is :
8
(1) 60 (2) 0
(3) 30 (4) 45
Sol. (4)
I I 2
cos 2
8 2
1
cos
2
= 45
1
36. For an RLC circuit driven with voltage of amplitude vm and frequency 0 = the current exhibits
LC
resonance. The quality factor, Q is given by :
CR 0 L
(1) (2)
0 R
0 R R
(3) (4)
L 0 C
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Sol. (2)
1 2 1 L 0 L 1
Q [ here 02 ]
0 R C R LC
Alternate solution
0 L
is the only dimensionless quantity, hence must be the quality factor.
R
m1g
Sol. (3)
T = 5g
10 m g 5g
5
10 m
0 15
m 23.33 kg
The minimum value from the options, satisfying the above condition is, m = 27.3 kg
*38. In a collinear collision, a particle with an initial speed v0 strikes a stationary particle of the same mass. If
the final total kinetic energy is 50% greater than the original kinetic energy, the magnitude of the relative
velocity between the two particles, after collision, is :
v v
(1) 0 (2) 0
2 4
v
(3) 2 v0 (4) 0
2
Sol. (3)
kf = 1.5 ki v0 rest v1 v2
v12 v 22 1.5v 20
From conservation of momentum m m m m
v1 + v2 = v0
Before collision After collision
from (i) and (ii)
2v1v2 = –0.5 v02
So, v 2 v1 v 22 v12 2v1 v 2 1.5v 02 0.5v 02 2 v 0
*39. A particle is moving with a uniform speed in a circular orbit of radius R in a central force inversely
proportional to the nth power of R. If the period of rotation of the particle is T, then :
(1) T Rn/2 (2) T R3/2 for any n.
n
1
(3) T R 2 (4) T R(n+1)/2
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Sol. (4)
1
F
Rn
1
v n 1
R 2
2R
T
v
n 1
1
2
TR
n 1
2
TR
40. Two batteries with e.m.f 12 V and 13 V are connected in parallel across a load resistor of 10 . The
internal resistances of the two batteries are 1 and 2 respectively. The voltage across the load lies
between :
(1) 11.7 V and 11.8 V (2) 11.6 V and 11.7 V
(3) 11.5 V and 11.6 V (4) 11.4 V and 11.5 V
Sol. (3)
The circuit may be drawn as shown 12 V 1
in the figure.
i
ri 13 V
eq = 11.56 V 2
1
ri
0V 10
41. In an a.c. circuit, the instantaneous e.m.f. and current are given by
e = 100 sin 30 t
i = 20 sin 30 t
4
In one cycle of a.c., the average power consumed by the circuit and the wattless current are, respectively :
(1) 50, 0 (2) 50, 10
1000 50
(3) , 10 (4) ,0
2 2
Sol. (3)
e0
0 I0 cos 100 20 cos 4 1000 = 45
P watt
2 2 2
20 1 i0
Wattless current = Irms sin = 10A
2 2
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42. An EM wave from air enters a medium. The electric fields are
z
E1 E 01 xˆ cos 2 t in air and
c
E 2 E 02 xˆ cos k 2z ct in medium, where the wave number k and frequency v refer to their values
in air. The medium is non-magnetic. If r1 and r2 refer to relative permittivities of air and medium
respectively, which of the following options is correct ?
r 1 r
1 1
(1) (2) 4
r 2 r
2 2
r1 r1 1
(3) 2 (4)
r2 r2 4
Sol. (4)
vair c 0 0 r r
2 2
= 2
vmed c/2 0 0 r r
1 1
r1 1
r2 4
43. A telephonic communication service is working at carrier frequency of 10 GHz. Only 10% of it is utilized
for transmission. How many telephonic channels can be transmitted simultaneously if each channel
requires a bandwidth of 5 kHz ?
(1) 2 106 (2) 2 103
4
(3) 2 10 (4) 2 105
Sol. (4)
0.1 10 109
No. of telephonic channels that can be transmitted simultaneously = 2 105
5 103
*44. A granite rod of 60 cm length is clamped at its middle point and is set into longitudinal vibrations. The
density of granite is 2.7 103 kg/m3 and its Young’s modulus is 9.27 1010 Pa. What will be the
fundamental frequency of the longitudinal vibrations ?
(1) 7.5 kHz (2) 5 kHz
(3) 2.5 kHz (4) 10 kHz
Sol. (2)
Y
Wave velocity (v) = 5.86 103 m/s
For fundamental mode, 1.2 m
v
fundamental frequency = 4.88 kHz 5 kHz
*45. It is found that if a neutron suffers an elastic collinear collision with deuterium at rest, fractional loss of its
energy is pd; while for its similar collision with carbon nucleus at rest, fractional loss of energy is pc. The
values of pd and pc are respectively :
(1) (0, 1) (2) (89, 28)
(3) (28, 89) (4) (0, 0)
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Sol. (2)
Before collision After collision
K0
K1
Neutron (1) Neucleus (A) (1) (A) K2
46. The density of a material in the shape of a cube is determined by measuring three sides of the cube and its
mass. If the relative errors in measuring the mass and length are respectively 1.5% and 1%, the maximum
error in determining the density is:
(1) 6% (2) 2.5%
(3) 3.5% (4) 4.5%
Sol. (4)
m 3 a
100 100 100
m a
= 4.5%
*47. Two moles of an ideal monoatomic gas occupies a volume V at 27°C. The gas expands adiabatically to a
volume 2 V. Calculate (a) the final temperature of the gas and (b) change in its internal energy.
(1) (a) 195 K (b) 2.7 kJ
(2) (a) 189 K (b) 2.7 kJ
(3) (a) 195 K (b) –2.7 kJ
(4) (a) 189 K (b) – 2.7 kJ
Sol. (4)
T1 V1 1 T2 V2 1
T2 189 K
U n Cv T = – 2.7 kJ
*48. A solid sphere of radius r made of a soft material of bulk modulus K is surrounded by a liquid in a
cylindrical container. A massless piston of area a floats on the surface of the liquid, covering entire cross
section of cylindrical container. When a mass m is placed on the surface of the piston to compress the
dr
liquid, the fractional decrement in the radius of the sphere, , is:
r
mg Ka
(1) (2)
Ka mg
Ka mg
(3) (4)
3mg 3Ka
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Sol. (4)
V 3r
V r
P
K
V / V
r mg
r 3Ka
49. A parallel plate capacitor of capacitance 90 pF is connected to a battery of emf 20 V. If a dielectric material
5
of dielectric constant K is inserted between the plates, the magnitude of the induced charge will be :
3
(1) 0.9 n C (2) 1.2 n C
(3) 0.3 n C (4) 2.4 n C
Sol. (2)
Q KCV
Qinduced Q 1 1/ K
Qinduced 1.2 n C
50. The dipole moment of a circular loop carrying a current I, is m and the magnetic field at the centre of the
loop is B1 . When the dipole moment is doubled by keeping the current constant, the magnetic field at the
B1
centre of the loop is B2 . The ratio is:
B2
1
(1) (2) 2
2
(3) 3 (4) 2
Sol. (4)
m I r 2
2
2m I r
r 2r
I B r
B 0 1 2
2r B2 r
51. An electron from various excited states of hydrogen atom emit radiation to come to the ground state. Let
n , g be the de Broglie wavelength of the electron in the nth state and the ground state respectively. Let
n be the wavelength of the emitted photon in the transition from the nth state to the ground state. For large
n, (A, B are constants)
B
(1) 2n (2) n A 2
n
(3) n A B n (4) 2n A B 2n
Sol. (2)
2r n n
2r 2r0 n 2
n 2r0 n …(1)
n n
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1 1 1
R 2 2
n 1 n
1 1
n 1
R n 2 1
1 1
n 1 2 n 1 …(2)
R n
1 42 r02 B
From equation (1) and (2) n 1 2 A 2
R n n
*52. The mass of a hydrogen molecule is 3.32 1027 kg. If 1023 hydrogen molecules strike, per second, a fixed
wall of area 2 cm 2 at an angle of 45° to the normal, and rebound elastically with a speed of 103 m/s, then
the pressure on the wall is nearly:
(1) 4.70 10 2 N / m 2 (2) 2.35 103 N / m 2
(3) 4.70 103 N / m 2 (4) 2.35 10 2 N / m 2
Sol. (2)
2mv cos 45 n (P Pressure, A Area)
P
A
1
2 3.32 10 27 103 10 23
2
2 104
2.35 10 N / m 2
3
*53. All the graphs below are intended to represent the same motion. One of them does it incorrectly. Pick it up.
(1) velocity (2) velocity
time position
time time
Sol. (3)
In graph ‘3’ initial slope is zero which is not possible, since initial velocity is non zero in all other three
graphs.
54. An electron, a proton and an alpha particle having the same kinetic energy are moving in circular orbits of
radii re, rp, r respectively in a uniform magnetic field B. The relation between re, rp, r is:
(1) re r rp (2) re rp r
(3) re rp r (4) re rp r
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Sol. (3)
2Km
r (K Kinetic energy)
qB
m
r
q
So re rp r
55. On interchanging the resistances, the balance point of a meter bridge shifts to the left by 10 cm. The
resistance of their series combination is 1 k. How much was the resistance on the left slot before
interchanging the resistances?
(1) 910 (2) 990
(3) 505 (4) 550
Sol. (4)
R1
…(i)
R 2 100
R2 10
and …(ii)
R1 100 10
From (i) and (ii)
55 cm.
R1 55
…(i)
R 2 45
and R1 R 2 1000 …(iii)
from (i) and (iii)
R1 550
56. In a potentiometer experiment, it is found that no current passes through the galvanometer when the
terminals of the cell are connected across 52 cm of the potentiometer wire. If the cell is shunted by a
resistance of 5 , a balance is found when the cell is connected across 40 cm of the wire. Find the internal
resistance of the cell.
(1) 2.5 (2) 1
(3) 1.5 (4) 2
Sol. (3)
When the cell is shunted by a resistance of 5
i
5 r
ir 40
Now
52
r 3
5 r 13
r 1.5
57. If the series limit frequency of the Lyman series is L, then the series limit frequency of the Pfund series is:
(1) L/25 (2) 25 L
(3) 16 L (4) L/16
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Sol. (1)
Series limit frequency of the Lyman series is given by
1 1
L RcZ 2 2 2
1
L RcZ 2 …(1)
1 1
Series limit frequency of the Pfund series P RcZ 2 2 2
5
P L
25
58. The angular width of the central maximum in a single slit diffraction pattern is 60°. The width of the slit is
1 m. The slit is illuminated by monochromatic plane waves. If another slit of same width is made near it,
Young’s fringes can be observed on a screen placed at a distance 50 cm from the slits. If the observed
fringe width is 1 cm, what is slit separation distance?
(i.e. distance between the centres of each slit.)
(1) 100 m (2) 25 m
(3) 50 m (4) 75 m
Sol. (2)
b 1106
sin 30 5 10 7 m
b 2 2
D D 5 107 0.5
Fringe width, d
d 1102
d = 25 m
k
*59. A particle is moving in a circular path of radius a under the action of an attractive potential U . Its
2 r2
total energy is:
3 k k
(1) 2 (2)
2a 4a 2
k
(3) (4) Zero
2a 2
Sol. (4)
k dU k
Given U 2
Fr 3
2r dr r
Since the particle moves in a circular path of radius ‘a’
mv 2 k k
3 mv 2 2 …(1)
a a a
1 k
Kinetic Energy = mv 2 2
2 2a
k k
Total Energy = 2 2 0
2a 2a
60. A silver atom in a solid oscillates in simple harmonic motion in some direction with a frequency of
1012/sec. What is the force constant of the bonds connecting one atom with the other? (Mole wt. of
silver = 108 and Avagadro number = 6.02 × 1023 gm mole–1)
(1) 5.5 N/m (2) 6.4 N/m
(3) 7.1 N/m (4) 2.2 N/m
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Sol. (3)
Given frequency f 1012 / sec.
Angular frequency 2f 2 1012 / sec
Force constant k m2
108 103
42 1024
6.02 1023
k = 7.1 N/m
PART C – CHEMISTRY
61. For 1 molal aqueous solution of the following compounds, which one will show the highest freezing
point?
(1) [Co(H2O)3 Cl 3].3H2O (2) [Co(H2O)6] Cl3
(3) [Co(H2O)5 Cl] Cl2.H2O (4) [Co(H2O)4 Cl 2] Cl.2H2O
Sol. (1)
The complex giving least number of ions will have lowest depression in freezing point and therefore
highest freezing point. Hence, option 1 is correct. (Van’t Hoff factor = 1)
*62. Hydrogen peroxide oxidises [Fe(CN)6]4 to [Fe(CN)6]3 in acidic medium but reduces [Fe(CN)6]3 to
[Fe(CN)6]4 in alkaline medium. The other products formed are, respectively
(1) H2O and (H2O + OH) (2) (H2O + O2) and H2O
(3) (H2O + O2) and (H2O + OH) (4) H2O and (H2O + O2)
Sol. (4)
In acidic medium
Oxidation number decreases
4 3
2 1
3 2
Fe CN 6 H 2 O 2
Fe CN 6 H 2 O
Oxidation number increases
In alkaline medium
Oxidation number increases
3 4
3 1
2 0
Fe CN 6 H 2 O 2
Fe CN 6 O 2
Oxidation number decreases
*63. Which of the following compounds will be suitable for Kjeldah1’s method for nitrogen estimation?
(1) N2 Cl (2)
N
(3) NH 2 (4) NO 2
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Sol. (3)
Kjeldahl’s method is not used in the case of nitro, azo compounds and also to the compounds containing
nitrogen in the ring e.g. Pyridine.
CHO CH3
(CHOH)4 HI
(CH2)4
CH2OH CH3
Glucose n-hexane
*65. An alkali is titrated against an acid with methyl orange as indicator, which of the following is a correct
combination?
Base Acid End point
(1) Strong Strong Pink to colourless
(2) Weak Strong Colourless to pink
(3) Strong Strong Pinkish red to yellow
(4) Weak Strong Yellow to pinkish red
Sol. (4)
Methyl orange is weak organic base. It is used in the titration of WB vs SA
MeOH Me OH
Unionized form Ionized form
Yellow Red
In basic medium, equilibrium lies in backward direction and therefore it shows yellow colour.
In acidic medium, equilibrium shifts in forward direction and therefore, colour changes from yellow to red.
66. The predominant form of histamine present in human blood is (pKa, Histidine = 6.0)
(1) H (2) H
N N
NH3 NH2
N N
(3) H (4) H
N N
NH3 NH2
N N
H H
Sol. (1)
N
NH3
H N
The N-atoms present in the ring will have same pKa values (6.0), while N atom outside the ring will have
different pKa value (pKa > 7.4)
Therefore, two N-atoms inside the ring will remain in unprotonated form in human blood because their
pKa(6.0) < pH of blood (7.4), while the N-atom outside the ring will remain in protonated form because its
pKa > pH of blood (7.4).
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NH
(1) (d) < (b) < (a) < (c) (2) (a) < (b) < (c) < (d)
(3) (b) < (a) < (c) < (d) (4) (b) < (a) < (d) < (c)
Sol. (4)
Order of basicity is
NH2
NH NH 2
< < NHCH 3 < NH
(b) (a) (d) (c)
*68. Which of the following lines correctly show the temperature dependence of equilibrium constant K, for an
exothermic reaction?
ln K A
B
1
(0, 0) TK
C
D
Sol. (2)
G 0 RT ln K
H 0 TS0 RT ln K
H0 S0
ln K
RT R
1 H 0
Therefore ln K vs graph will be a straight line with slope equal to . Since reaction is
T R
exothermic, therefore H0 itself will be negative resulting in positive slope.
69. How long (approximate) should water be electrolysed by passing through 100 amperes current so that the
oxygen released can completely burn 27.66 g of diborane?
(Atomic weight of B = 10.8 u)
(1) 1.6 hours (2) 6.4 hours
(3) 0.8 hours (4) 3.2 hours
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Sol. (4)
B2 H 6 3O 2
B2 O 3 3H 2 O
According to balanced equation:
27.66 g B2H6 i.e. 1 mole B2H6 requires 3 mole of O2. Now this oxygen is produced by electrolysis of water.
4F
2H 2 O 2H 2 O 2
1 mole O2 is produced by 4 F charge
3 mole O2 will be produced by 12 F charge
Now applying
Q = It
12 96500 C = 100 t (s)
12 96500
t hours
100 3600
t = 3.2 hours
Sol. (3)
Br Br Br
H3N Br Br Br H3N Br
Br
Co Co Co
H3 N NH3 H 3N Br
Br
Co Co
H3 N NH3 H 3N NH3
Br Br
trans-isomer mer-isomer (only)
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71. Phenol reacts with methyl chloroformate in the presence of NaOH to form product A. A reacts with Br2 to
form product B. A and B are respectively:
(1) OH
OH
and
OCH3
OCH3
Br O
O
(3) Br OH
OH
and
OCH3
OCH3
O
O
(3) O O O O
and
O O
Br
(4) O O O O
and
O O
Br
Sol. (4)
OH O
O O
NaOH Cl C O CH3
Nucleophilic acyl substitution
Cl C OMe
OPh
O
Cl
O C OMe
O
Br2
EAS
Ph O C OMe
o, p directing group
A
Br
Major product
B
*72. An aqueous solution contains an unknown concentration of Ba2+. When 50 mL of a 1 M solution of
Na2SO4 is added, BaSO4 just begins to precipitate. The final volume is 500 mL. The solubility product of
BaSO4 is 1 10–10. What is the original concentration of Ba2+?
(1) 1.0 10–10 M (2) 5 10–9 M
–9
(3) 2 10 M (4) 1.1 10–9 M
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Sol. (4)
Ba 2 Na 2SO 4
BaSO 4 2Na
450 mL 50 mL,1M
*73. At 5180C the rate of decomposition of a sample of gaseous acetaldehyde initially at a pressure of 363 Torr,
was 1.00 Torr s–1 when 5% had reacted and 0.5 Torr s–1 when 33% had reacted. The order of the reaction is
(1) 0 (2) 2
(3) 3 (4) 1
Sol. (2)
CH 3CHO
CO CH 4
Pi 363 torr
Now we know that
r PRn … (1)
Where PR reactant pressure
n = order of reaction
5
Now rate of reaction is 1.00 torr s-1, when reactant pressure is 363 363 torr = 344.85 torr,
100
33
Similarly rate of reaction is 0.5 torr s-1, when reactant pressure is 363 363 torr 243.21 torr
100
Therefore, applying equation (1)
n
1 344.85
0.5 243.21
n
2 = (1.418)
21/ n 1.418
n 2
*74. The combustion of benzene (l) gives CO2(g) and H2O(l). Given that heat of combustion of benzene at
constant volume is –3263.9 kJ mol–1 at 250C; heat of combustion (in kJ mol–1) of benzene at constant
pressure will be
(R = 8.314 JK–1 mol–1)
(1) –3267.6 (2) 4152.6
(3) –452.46 (4) 3260
Sol. (1)
15
C6 H 6 6CO 2 g 3H 2 O \
O 2 g
2
15 3
n g 6
2 2
H U n g RT
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3
H 3263900 8.314 298 J
2
3267616 J
3267.616 kJ
75. The ratio of mass percent of C and H of an organic compound (CXHYOZ) is 6 : 1. If one molecule of the
above compound (CXHYOZ) contains half as much oxygen as required to burn one molecule of compound
CXHY completely to CO2 and H2O. The empirical formula of compound CXHYOZ is
(1) C2H4O3 (2) C3H6O3
(3) C2H4O (4) C3H4O2
Sol. (1)
Ratio of mass % of C and H in C x H y Oz is 6 : 1.
Therefore,
Ratio of mole % of C and H in C x H y Oz will be 1 : 2.
Therefore x : y = 1 : 2, which is possible in options 1, 2 and 3.
Now oxygen required to burn CxHy
y y
Cx H y x O 2 xCO 2 H 2 O
4 2
Now z is half of oxygen atoms required to burn C x H y .
y
2x y
2
z x
2 4
Now putting values of x and y from the given options:
Option (1), x = 2, y = 4
4
z 2 3
4
Option 2, x = 3, y = 6
6
z 3 4.5
4
Therefore correct option is 1 (C2H4O3)
Sol. (4)
Na/Liq. NH3 reduces alkynes into trans alkene (trans addition).
*77. Which of the following are Lewis acids?
(1) BCl3 and AlCl3 (2) PH3 and BCl3
(3) AlCl3 and SiCl4 (4) PH3 and SiCl4
Sol. (1 or 3)
Both BCl3 and AlCl3 are Lewis acids as both ‘B’ and ‘Al’ has vacant p-orbitals. SiCl4 is also a Lewis acid
as silicon atom has vacant 3d-orbital.
78. When metal ‘M’ is treated with NaOH, a white gelatinous precipitate ‘X’ is obtained, which is soluble in
excess of NaOH. Compound ‘X’ when heated strongly gives an oxide which is used in chromatography as
an adsorbent. The metal ‘M’ is
(1) Fe (2) Zn
(3) Ca (4) Al
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Sol. (4)
2Al OH 3 3H 2
2Al 6H 2 O
X
Na Al OH 4
Al OH 3 NaOH
So lub le
*79. According to molecular orbital theory, which of the following will not be a viable molecule?
(1) H 22 (2) He 22
(3) He 2 (4) H 2
Sol. (1)
Species Bond order
1
(1) H 22 B. O. 2 2 0 (does not exist)
2
1
(2) He 22 B. O. 2 0 1 (exists)
2
1
(3) He 2 B. O. 2 1 0.5 (exists)
2
1
(4) H 2 B. O. 2 1 0.5 (exists)
2
O HI
Heat
O
(1) (2)
I OH
OH OH
(3) (4)
I OH
I I
Sol. (1)
CH3 CH3 CH3
CH3
CH3 CH3
I
O O
HI
I
H
O CH3 I OH
O CH3 OH
H H3C OH
C 2 H 5I
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81. Phenol on treatment with CO2 in the presence of NaOH followed by acidification produces compound X as
the major product. X on treatment with (CH3CO)2O in the presence of catalytic amount of H2SO4
produces:
(1) CO2H (2) O
O CH3
CO2H
O CH3 CO2H
O
(3) O (4) O O CH3
C
O
O CH3 OH
CO2H
Sol. (2)
O
OH OH O
O C CH3
C OH O C OH
O H (catalyst)
i NaOH H3C C 2
ii CO , 4 7 atm, 1250 C
2 O
iii H (acetylation)
Kolbe's reaction
(X) Acetyl salicylic acid (Asprin)
Sol. (4)
KCl contains only ionic bond between K+ and Cl ions (K+Cl) while other structures have covalent bonds
as follows:
O
H H H
P
B B S O O
H H
H H H , HO OH H
O , ,
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83. Which type of ‘defect’ has the presence of cations in the interstitial sites?
(1) Metal deficiency defect (2) Schottky defect
(3) Vacancy defect (4) Frenkel defect
Sol. (4)
In Frenkel defect, smaller ion displaces from its actual lattice site into the interstitial sites.
OMe OMe
(1) (2)
(3) (4)
Sol. (3)
It follows E2 mechanism.
Br
NaOMe NaBr MeOH
MeOH
85. The compound that does not produce nitrogen gas by the thermal decomposition is
(1) (NH4)2SO4 (2) Ba(N3)2
(3) (NH4)2Cr2O7 (4) NH4NO2
Sol. (1)
NH 4 2 SO 4 2NH 3 g H 2SO 4
Ba N 3 2 s Ba 3N 2 g
NH4 2 Cr2 O7 s N 2 g Cr2 O3 s 4H 2 O
NH 4 NO2 N 2 g 2H2 O
*86. An aqueous solution contains 0.10 M H2S and 0.20 M HCl. If the equilibrium constants for the formation
of HS– from H2S is 1.0 10–7 and that of S2- from HS– ions is 1.2 10–13 then the concentration of S2- ions
in aqueous solution is
(1) 5 10–19 (2) 5 10–8
–20
(3) 3 10 (4) 6 10–21
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Sol. (3)
2H S2 ,
H 2S aq. K a K a1 K a 2 1.2 1020
0.1 x 2x 0.20 x
0.1 0.2
2
20
0.2 S2
1.2 10
0.1
2 20
S 3 10
K 2 Cr CN 2 O 2 O 2 NH 3 respectively are:
(1) +3, 0 and +4 (2) +3, +4 and +6
(3) +3, +2 and +4 (4) +3, 0 and +6
Sol. (4)
Compound Oxidation state of Cr
[Cr(H2O)6]Cl3 +3
[Cr(C6H6)2] 0
K2[Cr(CN)2(O)2 (O2) (NH3)] +6
(Potassium amminedicyanodioxoperoxochromate (VI)]
*88. The recommended concentration of fluoride ion in drinking water is up to 1 ppm as fluoride ion is required
to make teeth enamel harder by converting [3Ca3 (PO4)2.Ca(OH)2] to
(1) [3{Ca(OH)2}. CaF2] (2) [CaF2]
(3) [3(CaF2). Ca(OH)2] (4) [3Ca3(PO4)2. CaF2]
Sol. (4)
3Ca 3 PO 4 2 . Ca OH 2 2F
3Ca 3 PO 4 2 .CaF2 2OH
*89. Which of the following salts is the most basic in aqueous solution?
(1) Pb(CH3COO)2 (2) Al(CN)3
(3) CH3COOK (4) FeCl3
Sol. (3)
CH3COOK is most basic among the given salts.
Sol. (4)
I I I
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JEE-MAIN-MPC-2018-35
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