Concentracion de miliesteres formados (mol/L)

Tiempo 20grados 28grados 35grados 44grados 50grados

0 0 0 0 0 0
2 0.136 0.057 0.099 0.181 0.25
5 0.325 0.153 0.275 0.374 0.525
10 0.692 0.303 0.452 0.643 0.824
15 0.916 0.426 0.625 0.825 1.07
20 1.069 0.497 0.742 0.943 1.247

Concentracion Vs Tiempo

Concentracion de mi l i esteres forma dos (mol /L)

Col umn D
Col umn E
Col umn F
Col umn G
1.4
1.2
1
0.8
0.6
0.4
0.2
0
0 5 10 15 20 25
 Tabla 11 Concentracion de trigliceridos consumidos (mol/L)
Tiempo 20grados 28grados 35grados 44grados 50grados
0 0.711 0.712 0.711 0.711 0.711
2 0.666 0.693 0.678 0.651 0.628
5 0.603 0.661 0.619 0.587 0.536
10 0.481 0.611 0.56 0.497 0.437
15 0.406 0.57 0.502 0.436 0.342
20 0.355 0.546 0.464 0.397 0.297

Concentración Vs Tiempo
Tabl a 11 Concentraci on de tri gl i ceri dos consumi dos (mol /L)
Col umn D
Col umn E
Col umn F
Col umn G
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
2 4 6 8 10 12 14 16 18 20 22
 20grados
Tiempo ConcentracioIn(Ct)
0 0.711 -0.3410828 Tiempo
2 0.666 -0.4064656 0
5 0.603 -0.5058381 2
10 0.481 -0.731888 5
15 0.406 -0.9014021 10
20 0.355 -1.0356375 15
20
In Ct Vs Tiempo a 20 0
0 5 10
0
0 5 10 15 20 25
-0.1
-0.2

-0.2
-0.4 f(x) = - 0.0359386613x - 0.3422506282
R² = 0.9942092618
-0.3
-0.6
f(x) = - 0.0137421913x - 0.3442872803
-0.8 -0.4 R² = 0.9913415243

-1 -0.5

-1.2 -0.6

-0.7
 35 Grados
Tiempo ConcentracioIn(Ct)
28grados In(Ct) 0 0.711 -0.3410828
0.712 -0.3396774 2 0.678 -0.388608
0.693 -0.3667253 5 0.619 -0.47965
0.661 -0.4140014 10 0.56 -0.5798185
0.611 -0.4926583 15 0.502 -0.6891552
0.57 -0.5621189 20 0.464 -0.7678707
0.546 -0.6051363

5 10 15 20 25 In Ct Vs Tiempo a 35

0
0 5 10 15
-0.1
-0.2
-0.3
-0.4 f(x) = - 0.0215432558x - 0.3543226547
(x) = - 0.0137421913x - 0.3442872803 R² = 0.9922430803
R² = 0.9913415243 -0.5
-0.6
-0.7
-0.8
-0.9
Col umn P Li near (Col umn
 44grados
Tiempo ConcentracioLn(Ct)
0 0.711 -0.3410828
2 0.651 -0.4292456
5 0.587 -0.5327305
10 0.497 -0.6991653
15 0.436 -0.830113
20 0.397 -0.923819

Ct Vs Tiempo a 35 In Ct Vs Tiempo a 44
Col umn W Linear (Col umn W)

10 15 20 25 0
0 5 10 15 20 25
-0.1
-0.2
-0.3
0.3543226547 -0.4 f(x) = - 0.0293028052x - 0.3720683933
-0.5 R² = 0.9854627441
-0.6
-0.7
-0.8
-0.9
ol umn P Li near (Col umn P)
-1
 50grados
Tiempo ConcentracioLn(Ct)
0 0.711 -0.3410828
2 0.628 -0.4652151
5 0.536 -0.6236211
10 0.437 -0.8278221
15 0.342 -1.0729445
20 0.297 -1.2140231

44 In Ct Vs Tiempo a 50
ol umn W) Col umn AC Li near (Col umn AC)
0
20 25 0 5 10 15 20 25
-0.2

-0.4
f(x) = - 0.043892014x - 0.3770540193
R² = 0.9911015616
-0.6

-0.8

-1

-1.2

-1.4
Tabla Constantes de rapidez de primer Orden
Temperatura K (min-1) R*R
20 0.0359 0.9942
28 0.0137 0.9913
35 0.0215 0.9922
44 0.0293 0.9855
50 0.0439 0.9911
 20grados
Tiempo Cocentracion1/Ct Tiempo
0 0.711 1.40646976 0
2 0.666 1.5015015 2
5 0.603 1.65837479 5
10 0.481 2.07900208 10
15 0.406 2.46305419 15
20 0.355 2.81690141 20

1/Ct VS Tiempo a 20 1/Ct Vs Tiemp

3 2
f(x) = 0.0725805706x + 1.3585190099 1.8
2.5 R² = 0.9958844333 f(x) = 0.022123852x + 1.4054106389
1.6 R² = 0.9951942897
2 1.4
1.2
1.5 1
0.8
1
0.6
0.5 0.4
0.2
0 0
0 5 10 15 20 25 0 5 10
Col umn D Li nea r (Col umn D) Col umn J
 28 Grados 35 Grados
Concentracio1/Ct Tiempo Concentracio1/Ct
0.712 1.40449438 0 0.711 1.40646976
0.693 1.44300144 2 0.678 1.47492625
0.661 1.5128593 5 0.619 1.61550889
0.611 1.63666121 10 0.56 1.78571429
0.57 1.75438596 15 0.502 1.99203187
0.546 1.83150183 20 0.464 2.15517241

1/Ct Vs Tiempo A 28 1/Ct Vs Tiempo a 35

2.5
0.022123852x + 1.4054106389
9951942897 2 f(x) = 0.0378351519x + 1.4103992625
R² = 0.9982895065

1.5

0.5

0
5 10 15 20 25 0 5 10 15 20
Col umn J Li nea r (Col umn J) Col umn P Li near (Col umn P)
 44 Grados
Tiempo Concentracio1/Ct
0 0.711 1.40646976
2 0.651 1.53609831
5 0.587 1.70357751
10 0.497 2.01207243
15 0.436 2.29357798
20 0.397 2.51889169

iempo a 35 1/Ct Vs Tiempo a 44

3

5 2.5
f(x) = 0.0563066551x + 1.4237902705
R² = 0.9973695618
2

1.5

0.5

0
15 20 25 0 5 10 15 20 25
Li near (Col umn P) Col umn V Li near (Col umn V)
 50 Grados
Tiempo Concentracio1/Ct Tabla Constantes de rapidez de Seg
0 0.711 1.40646976 Temperatura
2 0.628 1.59235669 20
5 0.536 1.86567164 28
10 0.437 2.28832952 35
15 0.342 2.92397661 44
20 0.297 3.36700337 50

1/Ct Vs Tiempo a 50
4
3.5
f(x) = 0.0991750028x + 1.381117907
3 R² = 0.9962799415
2.5
2
1.5
1
0.5
0
0 25 0 5 10 15 20 25
) Col umn AB Li near (Col umn AB)
abla Constantes de rapidez de Segundo Orden
K (min-1) R*R
0.0726 0.9959
0.0221 0.9952
0.0378 0.9983
0.0563 0.9974
0.0992 0.9963
Metodo diferencial
Tiempo 20grados Delta Ca/DeltIn Ca
0 0.711
2 0.666 0.0225 -0.4064656 In Ca Vs In Ra a 20
5 0.603 0.021 -0.5058381
10 0.481 0.0244 -0.731888
15 0.406 0.015 -0.9014021
f(x) = - 0.0680890072x^2 - 0.0795463205x + 0.000344549
20 0.355 0.0102 -1.0356375 R² = 0.8959649167

In Ca Vs In Ra a 20
-1.1 -1 0.03-0.9 -0.8 -0.7 -0.6 -0.5
Col umn D Pol ynomi a l (Co
0.025
f(x) = 0.0179635863x + 0.0314863515
R² = 0.6465904553 0.02

0.015

0.01

0.005

0
-1.1 -1 -0.9 -0.8 -0.7 -0.6 -0.5 -0.4 -0.3
Col umn D Li near (Col umn D)
 In Ca Vs In Ra a 20
0.03

0.025
072x^2 - 0.0795463205x + 0.0003445491
7 0.02

0.015

0.01

0.005

0
-0.8 -0.7 -0.6 -0.5 -0.4 -0.3
ol umn D Pol ynomi a l (Col umn D)