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Estimation of measurement uncertainty

for the determination of


using
for the concentration range:

calculated by:
Date: Signature:

Measurement of Uncertainty due to Bias using EQA data (EQAS)


EQA Reference Value Your Results Bias
Sample 1 0
Sample 2 0
Sample 3 0
Sample 4 0
Sample 5 0
Sample 6 0
Sample 7 0
Sample 8 0
Sample 9 0
Sample 10 0
Sample 11 0
Sample 12 0
#DIV/0!
Mean of EQA Reference Values #DIV/0!
Sum of Bias 2
0
n 12
Sum of Bias / n-1
2
0
Square root of (Sum of Bias / n-1)
2
0
Uncertainty due to Bias (UBIAS) #DIV/0!

Expanded Measurement of UncertaintyCALIBRATOR (if provided by manufacturer)


Confidence Interval (if provided by manufacturer) %
z value if Confidence Interval provided
Assumed Distribution (normal, rectangular, triangular)
Standard Measurement of UncertaintyCALIBRATOR (if Expanded Measurement of Uncertainty and Confidence Interval given)
Standard Measurement of UncertaintyCALIBRATOR (if Confidence Interval not given and extreme values not expected)
Standard Measurement of UncertaintyCALIBRATOR (if Confidence Interval not given and extreme values are expected)
Measurement of Uncertainty due to Calibrator Bias using Vitros Calibrator data
Calibrator Reference Value Your Results Bias
Sample 1 #DIV/0!
Sample 2 #DIV/0!
Sample 3 #DIV/0!
Sample 4 #DIV/0!
Sample 5 #DIV/0!
Sample 6 #DIV/0!
Sample 7 #DIV/0!
Sample 8 #DIV/0!
Sample 9 #DIV/0!
Sample 10 #DIV/0!
Sample 11 #DIV/0!
Sample 12 #DIV/0!
#DIV/0!
Mean of EQA Reference Values #DIV/0!
Sum of Bias 2
#DIV/0!
n 12
Sum of Bias squared/ n-1 #DIV/0!
Square root of (Sum of Bias squared/ n-1) #DIV/0!
Uncertainty due to Calibrator Bias (UCAL. BIAS) #DIV/0!
nt uncertainty

EQA data (EQAS)


Bias2
0
0
0
0
0
0
0
0
0
0
0
0

Total Combined Standard uncertainty u


Expanded Uncertainty U

d Confidence Interval given) #DIV/0!


e values not expected) 0
e values are expected) 0
ng Vitros Calibrator data
Bias2
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Measurement of Uncertainty due to Imprecision using
Replicates Month 1
run 1 run 2 run 3
Replicate 1
Replicate 2
Replicate 3
Mean of 3 replicates #DIV/0! #DIV/0! #DIV/0!
(1st replicate - mean of 3 replicates) 2 #DIV/0! #DIV/0! #DIV/0!
(2nd replicate - mean of 3 replicates)2 #DIV/0! #DIV/0! #DIV/0!
(3rd replicate - mean of 3 replicates)2 #DIV/0! #DIV/0! #DIV/0!
Sum of square of 3 replicates #DIV/0! #DIV/0! #DIV/0!
Sum of square of 3 replicates / 2 #DIV/0! #DIV/0! #DIV/0!
Grand Mean #DIV/0!
Day Mean - Grand Mean #DIV/0! #DIV/0! #DIV/0!
(Day Mean - Grand Mean) 2 #DIV/0! #DIV/0! #DIV/0!

Repeatabilty Variation #DIV/0!


Repeatabilty Sr #DIV/0!
Variation for 12 days #DIV/0!
Intermediate Precision Variation #DIV/0!
Intermediate Precision SD #DIV/0!
Coefficient of Variation of Repeatability #DIV/0!
Coefficient of Variation of Intermediate Precision #DIV/0!

Standard Measurement of UncertaintyIMPRECISION #DIV/0!

UBIAS #DIV/0! (UBIAS)2


UCALIBRATOR (If given) (UCALIBRATOR (If given))2
U BIAS CALIBRATOR #DIV/0! (U BIAS CALIBRATOR )2
U IMPRECISON #DIV/0! (U IMPRECISON )2
Total Combined Standard uncertainty u
Expanded Uncertainty U k Factor= 2
due to Imprecision using Quality Control data (QC)
Month 2 Month 3
run 4 run 5 run 6 run 7 run 8 run 9 run 10 run 11 run 12

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!


#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!


#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

#DIV/0!
0
#DIV/0!
#DIV/0!

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