componenente Zf D XDI B Xbi

iC4 15 0.02737226 15 0.0414823 0 0

nC4 (LK) 350 0.63868613 343 0.94856195 7 0.0375536481
IC5 (HK) 120 0.2189781 3.6 0.00995575 116.4 0.6244635193
nC5 28 0.05109489 0 0 28 0.1502145923
C6 35 0.06386861 0 0 35 0.1877682403
548 361.6 186.4

Calculando la presión de operación de la torre, defiendo la temperatura de burbuja a 50°C

323.15 TEMP. 501.340154 PRESIÓN (kPa4.94784263 Presion (atm)
T burbuja pi xdi kdi yi
iC4 684.425037 0.0414823 1.36519094 0.05663126
nC4 (LK) 496.441282 0.94856195 0.99022845 0.93929302
IC5 (HK) 205.205173 0.00995575 0.40931326 0.00407502
nC5 159.266937 0 0.31768239 0
C6 54.2532721 0 0.10821649 0
0.99999931

Como la presión es menor a 15 atm, se usa un condensador total con agua a una presión igual a P=501.34kPa

Diseñar la columna
componenente Zf D XDI B Xbi
iC4 15 0.02737226 15 0.0414823 0 0
nC4 (LK) 350 0.63868613 343 0.94856195 7 0.0375536481
IC5 (HK) 120 0.2189781 3.6 0.00995575 116.4 0.6244635193
nC5 28 0.05109489 0 0 28 0.1502145923
C6 35 0.06386861 0 0 35 0.1877682403
548 361.6 186.4

Calcular la temperatura de rocío

Trocío (K) 323.631305 501.34 P (kPa) 50.4813049
componentespi xd (es yi, por ki xi (xd/ki) alfai,HK
iC4 692.542028 0.0414823 1.38138195 0.03002957 3.3275172
nC4 (LK) 502.703721 0.94856195 1.00272015 0.94598871 2.41538449
IC5 (HK) 208.125755 0.00995575 0.41513894 0.02398174 1
nC5 161.642318 0 0.32242055 0 0.77665697
C6 55.1914309 0 0.11008783 0 0.26518309
1.00000002

Calcular la temperatura de burbuja

Trocío (K) 367.113866 562.135 P (kPa) 93.9638663 5.54784111
componentespi xbi ki ybi (xbi*ki) alfai,HK
iC4 1773.16294 0 3.15433649 0 2.80656141
nC4 (LK) 1356.2256 0.03755365 2.41263326 0.09060318 2.14663319
IC5 (HK) 631.791964 0.62446352 1.12391501 0.70184392 1
nC5 515.640416 0.15021459 0.91728929 0.13779024 0.81615539
C6 208.851172 0.18776824 0.37153206 0.06976192 0.33056953
0.99999926

Calculando Nmin mediante la ecuación de Fensky

Nmin= 8.95382418 ���;�� = (���,�� ���� ∗ ���,�� ����o)^ 1/ 2 2.27704732
Asumiendo que q entra como m
q
Calculando Rmin y R mediante la ecuación de Underwood (1era forma)
teta 1.25637836
componentesalfa promedi zi alfa*zi alfa-teta alfa*zi/alfa-teta
Asumir una teta inicial
iC4 3.05595834 0.02737226 0.08364849 1.79957998 0.04648223 entre las alfas promedio
del clave ligero y clave
nC4 (LK) 2.27704732 0.63868613 1.45431855 1.02066896 1.424868 pesado
IC5 (HK) 1 0.2189781 0.2189781 -0.2563784 -0.8541209
nC5 0.79616127 0.05109489 0.04067977 -0.4602171 -0.0883926
C6 0.29607676 0.06386861 0.01891001 -0.9603016 -0.0196917
0.50914506

Calculando Rmin
componentesalfa promedi xi alfa*xdi alfa-teta alfa*xd/alfa-teta
iC4 3.05595834 0.0414823 0.12676818 1.79957998 0.07044321
nC4 (LK) 2.27704732 0.94856195 2.15992044 1.02066896 2.11618117
IC5 (HK) 1 0.00995575 0.00995575 -0.2563784 -0.0388323
nC5 0.79616127 0 0 -0.4602171 0
C6 0.29607676 0 0 -0.9603016 0
2.14779211
Rmin= 1.14779211
R= 1.72168816

Cálculo del número total de etapas mediante la ecuaci

Con la 1era forma
X= 0.21086033
Nmin= 8.95382418
A= 0.45124546
N= 17.1389371 18

Cálculo de la etapa de alimentación

Nr/Na= 1.20920596
Na= 8.1477238
Nr= 9.8522762
 Nfeed= 10

VALIDACIÓN DEL BALANCE DE MASA

dr/br 0.03092784
alfa prom bi calculadosdi (calculadobi supuesto di supuesto
3.05595834 0.02193721 14.9780628 0 15
2.27704732 7 343 7 343
1 116.4 3.6 116.4 3.6
0.79616127 27.8879667 0.11203331 28 0
0.29607676 34.99998 0.00002002 35 0

BALA
Cp
TEMPERATURAS Componente C1 C2 C3
T °K °C iC4 172370 -1783.9 14.759
T Rocío (D) 323.631305 50.4813049 nC4 (LK) 191030 -1675 12.5
T burbuja (B) 367.113866 93.9638663 IC5 (HK) 108300 146 -0.292
T (TR) 323.631305 50.4813049 nC5 159080 -270.5 0.99537
T Alim. (F) 342.265 69.115 C6 172120 -183.78 0.88734

Landas
iC4 c1 c2 c3 c4 Tc Tr Landa
nC4 (LK) 3.19E+07 0.39006 407.8 0.7936030036 17227073.6
IC5 (HK) 3.62E+07 0.8337 -0.82274 0.39613 460.4 0.7029350671 20958799.4
nC5 3.76E+07 0.39173 469.7 0.6890170425 23790123.1
C6 4.45E+07 0.39002 507.6 0.6375715226 29983139.2

C R=RminC N Qc(w) QR(w) H D(m) AR

1.05 1.2186003 18 5276130 7941666 0.7986593713
 constantes de antoine
ComponenteC1 C2 C3 C4 C5
iC4 108.43 -5039.9 -15.012 2.27E-02 1
nC4 (LK) 66.343 -4363.2 -7.046 9.45E-06 2
IC5 (HK) 71.308 -4976 -7.7169 8.73E-06 2
nC5 78.741 -5420.3 -8.8253 9.62E-06 2
C6 104.65 -6995.5 -12.702 1.24E-05 2

e burbuja a 50°C

ón igual a P=501.34kPa

Calculando temp de alimentación

t burb 335.03 t 342.265

t rocio 349.5

t 335.032556 Pprom 531.7375

xf pi ki
0.02737226 906.560234
0.63868613 669.022501
0.2189781 287.071726
0.05109489 226.331783
0.06386861 81.4176238
xi yi
1.7049018254 0.01605504 0.04666702
1.2581819047 0.50762623 0.80358333
0.5398748925 0.40560898 0.11822078
0.4256457055 0.12004089 0.02174832
0.1531161971 0.41712513 0.00977932
1.46645626 0.99999877
sumiendo que q entra como mezcla liquido-vapor
0.5 Calcular Rmin utilizando alfas con temperatura promedio
Calculando Rmin y R mediante la ecuación de Underwood (Con Temps prom)
Tprom 345.372586 501.34 P (kPa) teta
componentespi ki alfa promedio zi alfa*zi alfa-teta
iC4 1139.9025 2.27371144 3.0266957449 0.02737226 0.08284751 1.77191135
nC4 (LK) 852.383692 1.70021082 2.2632690999 0.63868613 1.44551859 1.0084847
IC5 (HK) 376.616149 0.75121903 1 0.2189781 0.2189781 -0.2547844
nC5 300.596813 0.59958673 0.7981516818 0.05109489 0.04078147 -0.4566327
C6 112.812754 0.22502245 0.2995430616 0.06386861 0.0191314 -0.9552413

Calculando Rmin
componentesalfa promedi xi alfa*xdi alfa-teta alfa*xd/alfa-teta
iC4 3.02669574 0.0414823 0.1255543036 1.77191135 0.07085812
nC4 (LK) 2.2632691 0.94856195 2.1468509437 1.0084847 2.1287888
IC5 (HK) 1 0.00995575 0.0099557522 -0.2547844 -0.0390752
nC5 0.79815168 0 0 -0.4566327 0
C6 0.29954306 0 0 -0.9552413 0
2.16057172
Rmin= 1.16057172
R= 1.74085757

s mediante la ecuación de MOLOKANOV

Con Temperaturas promedio
X= 0.2117169
Nmin= 8.95382418
A= 0.45052439
N= 17.1151338 18

tapa de alimentación
Nr/Na= 1.20920596
Na= 8.1477238
Nr= 9.8522762
 BALANCE DE ENERGÍA
Rocío Burbuja Alimentación
C4 C5 Cp T1 Cp T1
-0.047909 0.00005805 0 6453170.57
-0.03874 4.61E-05 0 6249477.59
0.00151 0 0 7118849.82
0 0 0 7058086.94
0 0 0 8214507.09

v 0.34211862

Costo fjo Costo de energía

Ac CT CR Cc CH2O Cvapor
Con Temps prom)
1.2547844
alfa*zi/alfa-teta
0.04675601
1.43335698
-0.8594643
-0.0893091
-0.0200278
0.5113117
componentes Zf D XDI B Xbi
C2H4 5 0.05 5 0.23255814 0 0
HCl 5 0.05 5 0.23255814 0 0
C2H6 (LK) 10 0.1 9.9 0.46046512 0.1 0.00127389
C2H5Cl (HK) 80 0.8 1.6 0.0744186 78.4 0.99872611
100 21.5 78.5

Calculando la presión de operación de la torre, defiendo la temperatura de burbuja a 50°C

323.15 TEMP. 7705.66634 PRESIÓN (kPa 76.049014 Presion (atm)
T burbuja pi xdi kdi yi
C2H4 11344.13282 0.23255814 1.47218064 0.34236759
HCl 8103.929577 0.23255814 1.05168446 0.24457778
C2H6 (LK) 6855.84477 0.46046512 0.88971472 0.40968259
C2H5Cl (HK) 348.9983136 0.0744186 0.04529113 0.0033705
0.99999847

Como la presión es mayor a 15 atm, calcular el punto de rocío a 50°C

Diseñar la columna
componentes Zf D XDI B Xbi
C2H4 5 0.05 5 0.23255814 0 0
HCl 5 0.05 5 0.23255814 0 0
C2H6 (LK) 10 0.1 9.9 0.46046512 0.1 0.00127389
C2H5Cl (HK) 80 0.8 1.6 0.0744186 78.4 0.99872611
100 21.5 78.5

Calcular la temperatura de rocío

Trocío (K) 270 3034.0179 P (kPa) 29.9434286 -3.15 Trocío (K)
componentespi xd (es yi, por ki xi (xd/ki) alfai,HK componentes
C2H4 3814.849016 0.23255814 1.25735877 0.18495766 70.0330594 C2H4
HCl 2357.436891 0.23255814 0.77700164 0.29930199 43.2778642 HCl
C2H6 (LK) 2211.000206 0.46046512 0.7287367 0.63186761 40.5895772 C2H6 (LK)
C2H5Cl (HK) 54.47211716 0.0744186 0.01795379 4.14500832 1 C2H5Cl (HK)
5.26113558
Como la presión es mayor a 25 atm utilizar condensador parcial con refrigerante a p=28 atm, más las consideraciones de p e
Calcular la temperatura de burbuja
Tburbuja (K) 345.1001806 637.476369 P (kPa) 8.8615532 71.9501806
componentespi xbi ki ybi (xbi*ki) alfai,HK
C2H4 16839.59433 0 26.4160291 0 26.9290538
HCl 12501.07521 0 19.6102567 0 19.9911067
C2H6 (LK) 10158.64807 0.00127389 15.935725 0.02030029 16.2452121
C2H5Cl (HK) 625.3318231 0.99872611 0.98094903 0.97969941 1
0.9999997
Calculando Nmin mediante la ecuación de Fensky
Nmin= 2.685844636 ���;�� = (���,�� ���� ∗ ���,�� ����o)^ 1/ 2

Calculando Rmin y R mediante la ecuación de Underwood

teta 12.5153698 29.4138131
componentesalfa promedio zi alfa*zi alfa-teta alfa*zi/alfa-teta q
C2H4 39.58855644 0.05 1.97942782 27.0731867 0.07311396
HCl 27.27354921 0.05 1.36367746 14.7581795 0.09240147 Asumir una teta inicial
entre las alfas
C2H6 (LK) 23.5677097 0.1 2.35677097 11.0523399 0.21323729 promedio del clave
ligero y clave pesado
C2H5Cl (HK) 1 0.8 0.8 -11.51537 -0.0694724
0.30928034

Calculando Rmin
componentesalfa promedio xi alfa*xdi alfa-teta alfa*xd/alfa-teta
C2H4 39.58855644 0.23255814 9.20664103 27.0731867 0.34006492
HCl 27.27354921 0.23255814 6.34268586 14.7581795 0.42977427
C2H6 (LK) 23.5677097 0.46046512 10.8521082 11.0523399 0.98188332
C2H5Cl (HK) 1 0.0744186 0.0744186 -11.51537 -0.0064625
1.74525996
Rmin= 0.74525996
R= 0.96883795

Cálculo del número total de etapas mediante la ecuación de MOLOKANOV

X= 0.11355835
Nmin= 2.68584464
A= 0.54007646
N= 7.01403788 7

Cálculo de la etapa de alimentación

Nr/Na= 0.37504059
Na= 5.0907588
Nr= 1.9092412

Nfeed= 2

VALIDACIÓN DEL BALANCE DE MASA

dr/br 0.02040816
alfa prom bi calculadosdi (calculadobi supuesto di supuesto
 43.4272268 0.00976209 4.99023791 0 5
29.4138131 0.02769828 4.97230172 0 5
25.678518 0.0795866 9.9204134 0.1 9.9
1 78.4 1.6 78.4 1.6

Cp
TEMPERATURAS Componente C1 C2
T °K °C C2H4 247390 -44284
T Rocío (D) 280 6.85 HCl 47300 90
T burbuja (B) 345.100181 71.9501806 C2H6 (LK) 44.009 89,718
T (TR) 280 6.85 C2H5Cl (HK) 127900 -345.15
 constantes de antoine
ComponenteC1 C2 C3 C4 C5
C2H4 53.963 -2443 -5.5643 1.91E-05 2
HCl 104.27 -3731.2 -15.047 3.13E-02 1
C2H6 (LK) 51.857 -2598.7 -5.1283 1.49E-05 2
C2H5Cl (HK) 65.988 -4661.3 -6.8586 7.94E-06 2

de burbuja a 50°C

Calculando temperatura de entrada

Trocío (K) 407.77351805 2837.1 P (kPa) 28
componentespi zf ki xi (xd/ki) alfai,HK
C2H4 48591.859653 0.05 17.12729888 0.0029193161 174.53325368
HCl 38120.490552 0.05 13.4364282372 0.003721227 136.92197203
C2H6 (LK) 27759.482458 0.1 9.7844568248 0.0102202914 99.7070873306
C2H5Cl (HK) 2308.6063722 0.8 0.8137204794 0.9831385841 8.2921004566
0.9999994187

280 837.101878 P (kPa) 8.2615532

pi xd (es yi, por ki xi (xd/ki) alfai,HK
4780.87342 0.23255814 5.7112205117 0.04071952 58.1993637986
3056.57802 0.23255814 3.6513811562 0.06369046 37.2088697759
2808.65492 0.46046512 3.3552127764 0.13723872 34.1908088814
82.1464893 0.0744186 0.0981320093 0.75835199 1
1.00000069
más las consideraciones de p en d y b, es decir, P=28.6 atm
 0.3

MOLOKANOV
 BALANCE DE ENERGÍA
Cp Rocío Burbuja
C3 C4 C5 Cp T1 Cp Tref Cp T1 Cp Tref
40.936 -0.1697 0.00026816 1379621.37 1379621.3725 1951353.748 1379621.3725
0 0 0 47300.3214 47300.321429 47300.260794 47300.321429
918.77 -1886 0 106814.886 106814.88592 87696.816872 106814.88592
0.915 0 0 199634.767 199634.76732 236870.13308 199634.76732
 Para el cálculo de Cp de C2H6
t,rocío t,burbuja t,ref Tr, rocío Tr, burbuja Tr, ref Tc, etano
0.08292939 -0.1302901 0.08292939 0.91707061 1.13029012 0.91707061 305.32