E [mV vs ESH]

150
Titanio cp
Aleación Cr-Ni

100

50

-50
0 50 100 150 200
t [min]
 concentración [mM]
Na+ K+ Mg 2+ Ca2+ Cl- HCO3- HPO42- pH
HBSSa 141,7 5,8 0,9 1,3 147,7 4,2 0,78 7,2
Plasma Humanob 142,0 5,0 1,5 2,5 103,0 27,0 1,0 variable
a
[Fon98]
b
[Li94]
Duración del tratamiento [h]

Duración del tratamiento [h]

4 4
Ti_800_4 Ti_850_4 Ti64_850_4 Ti64_900_4

1 1
Ti_800_1 Ti_850_1 Ti64_850_1 Ti64_900_1

800 850 850 900

Temperatura de tratamiento [ºC] Temperatura de tratamiento [ºC]
a) b)

Potenciostato

V G

1 2 3

1. Muestra de trabajo
2. Electrodo de referencia
3. Contraelectrodo (Pt)
Célula
V. Voltímetro
electroquímica
G. Amperímetro
 Rp
R
Cp
 E [V] (SCE) E [V] (SCE)
0,00 0,0

-0,05
-0,10 -0,1

-0,15 Ti6Al4V NT
-0,2 Ti64_850_1
-0,20 Titanio NT Ti64_850_4
-0,25 Ti_800_1 Ti64_900_1
Ti_800_4 Ti64_900_4
-0,30 Ti_850_1 -0,3
-0,35 Ti_850_4

-0,40 -0,4
-0,45
-0,50 -0,5
0 2500 5000 7500 10000 12500 15000 0 2500 5000 7500 10000 12500 15000
t [seg] t [seg]
a) b)
 E [V] (SCE) E [V] (SCE)
3,0 3,0

2,0 2,0

1,0 1,0

0,0 0,0

-1,0 -1,0
1E-9 1E-8 1E-7 1E-6 1E-5 1E-4 1E-3 1E-9 1E-8 1E-7 1E-6 1E-5 1E-4 1E-3
2 2
a) i [A/cm ] d) i [A/cm ]

E [V] (SCE) E [V] (SCE)

3,0 3,0

2,0 2,0

1,0 1,0

0,0 0,0

-1,0 -1,0
1E-9 1E-8 1E-7 1E-6 1E-5 1E-4 1E-3 1E-9 1E-8 1E-7 1E-6 1E-5 1E-4 1E-3
2 2
b) i [A/cm ] e) i [A/cm ]

E [V] (SCE)
3,0

2,0

1,0

0,0

-1,0
1E-9 1E-8 1E-7 1E-6 1E-5 1E-4 1E-3
2
c) i [A/cm ]
 E [V] (SCE) E [V] (SCE)
3,0 3,0

2,0 2,0

1,0 1,0

0,0 0,0

-1,0 -1,0
1E-9 1E-8 1E-7 1E-6 1E-5 1E-4 1E-3 1E-9 1E-8 1E-7 1E-6 1E-5 1E-4 1E-3
2
2
d) i [A/cm ]
a) i [A/cm ]

E [V] (SCE) E [V] (SCE)

3,0 3,0

2,0 2,0

1,0 1,0

0,0 0,0

-1,0 -1,0
1E-9 1E-8 1E-7 1E-6 1E-5 1E-4 1E-3 1E-9 1E-8 1E-7 1E-6 1E-5 1E-4 1E-3
e)
2
2
i [A/cm ] i [A/cm ]
b)

E [V] (SCE)
3,0

2,0

1,0

0,0

-1,0
1E-9 1E-8 1E-7 1E-6 1E-5 1E-4 1E-3
2
c) i [A/cm ]
 Intensidad (A/cm2)
0—500 mV 1000 mV 2000 mV 3000 mV
Ti_NT 1,65·10-5–1,67·10-5 1,62·10-5 2,59·10-5 3,21·10-5
Ti_800_1 2,72·10-7–6,65·10-7 2,15·10-6 7,49·10-5 7,11·10-4
-7 -7
Ti_800_4 6,46·10 –8,45·10 2,90·10-6 5,72·10-5 2.92·10-4
-6 -6
Ti_850_1 3,73·10 –5,33·10 1,67·10-5 1,18·10-4 8,79·10-4
-7 -6
Ti_850_4 5,45·10 –3,68·10 9,64·10-6 4,71·10-5 9,04·10-4
-6 -5
Ti64_NT 9,32·10 –3,11·10 2,88·10-5 3,80·10-5 6,29·10-5
Ti64_850_1 2,59·10-5–2,88·10-5 1,59·10-4 1,85·10-4 6,49·10-4
-5 -5
Ti64_850_4 3,45·10 –6,65·10 5,47·10-5 5,82·10-5 7,94·10-4
-5 -5
Ti64_900_1 1,18·10 –1,41·10 7,90·10-5 1,02·10-4 2,45·10-4
-5 -5
Ti64_900_4 8,50·10 –2,00·10 1,43·10-4 1,75·10-4 3,80·10-4

d ( E) ba bc
Rp
di E 0 2,303 ba bc icorr
 E [mV] (SCE) E [mV] (SCE)
-600 -280

-610 -290

E (I = 0)
-620 -300 E (I = 0)

-630 -310

-640 -320

-650 -330
-0,25 -0,20 -0,15 -0,10 -0,05 0,00 0,05 0,10 0,15 -0,2 -0,1 0,0 0,1 0,2
2 2
i [ A/cm ] d) i [ A/cm ]
a)

E [mV] (SCE) E [mV] (SCE)

-370 -200

-380 -210

-390 -220
E (I = 0)
E (I = 0)

-400 -230

-410 -240

-420 -250
-0,06 -0,04 -0,02 0,00 0,02 0,04 0,06 -0,08 -0,06 -0,04 -0,02 0,00 0,02 0,04 0,06 0,08
2
2
i [ A/cm ]
b) i [ A/cm ] e)

E [mV] (SCE)
-460

-470

-480
E (I = 0)

-490

-500

-510
-0,10 -0,05 0,00 0,05 0,10
2
c) i [ A/cm ]
 E [mV] (SCE) E [mV] (SCE)
-330 -400

-340 -410

-350 E (I = 0) -420
E (I = 0)

-360 -430

-370 -440

-380 -450
-0,3 -0,2 -0,1 0,0 0,1 0,2 0,3 -1,5 -1,0 -0,5 0,0 0,5 1,0 1,5
2
2
i [ A/cm ] i [ A/cm ]
a) d)

E [mV] (SCE) E [mV] (SCE)

-540 -580

-550 -590

-560 -600
E (I = 0)
E (I = 0)
-570 -610

-580 -620

-590 -630
-1,5 -1,0 -0,5 0,0 0,5 1,0 1,5 -0,8 -0,6 -0,4 -0,2 0,0 0,2 0,4 0,6 0,8
2
2
i [ A/cm ] e) i [ A/cm ]
b)

E [mV] (SCE)
-360

-370

-380
E (I = 0)
-390

-400

-410
-0,4 -0,2 0,0 0,2 0,4
2
c) i [ A/cm ]
 2
Icorr [ A·cm ]
5,0
Icorr-Rp
Icorr-VI
4,0

3,0

2,0

1,0

0,0

(Rb, C b) Cp

Rb
HBSS Rp
Cb
R HBSS

Cp

Titanio TiO 2

(Rn, Cn) (Rb, Cb)

Cp Rn
Rb
HBSS Cn Rp
Cb
RHBSS

Cp

Titanio TiN TiO2

 log |Z| [ ] fase [º] log |Z| [ ] fase [º]
7 0 7 0
0 días 0 días
7 días -10
6 7 días
6
14 días -20 14 días -20
5 -30 5
-40 -40
4 4
-50

3 -60 3 -60
-70
2 2
-80 -80
1 -90 1
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
a) log (f) [Hz] d) log (f) [Hz]

log |Z| [ ] fase [º] log |Z| [ ] fase [º]

8 0 7 0
0 días 0 días
7 días -10 -10
7 7 días
6
14 días -20 14 días -20
6
-30 5 -30
5 -40 -40
4
4 -50 -50
-60 3 -60
3
-70
-70
2 2
-80
-80
1 -90
-3 -2 -1 0 1 2 3 4 5 1 -90
-3 -2 -1 0 1 2 3 4 5
b) log (f) [Hz]
e) log (f) [Hz]

log |Z| [ ] fase [º]

7 0
0 días
7 días -10
6
14 días -20

5 -30

-40
4
-50

3 -60

-70
2
-80

1 -90
-3 -2 -1 0 1 2 3 4 5
c) log (f) [Hz]
 log |Z| [ ] fase [º] log |Z| [ ] fase [º]
7 0 7 0
0 días 0 días
-10 -10
7 días 7 días
6 6
14 días -20 14 días -20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
log (f) [Hz] log (f) [Hz]
a) d)

log |Z| [ ] fase [º] log |Z| [ ] fase [º]

7 0 7 0
0 días 0 días
7 días -10 7 días -10
6 6
14 días -20 14 días -20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
log (f) [Hz]
b) log (f) [Hz] e)

log |Z| [ ] fase [º]

7 0
0 días
7 días -10
6
14 días -20

5 -30

-40
4
-50

3 -60

-70
2
-80

1 -90
-3 -2 -1 0 1 2 3 4 5
log (f) [Hz]
c)
 log |Z| [ ] fase [º]
7 0
Experimental
Simulación -10
6
-20

5 -30

-40
4
-50

3 -60

-70
2
-80

1 -90
-3 -2 -1 0 1 2 3 4 5
log (f) [Hz]

RHBSS [ ] Cp [F] Rp [ ] Rb [ ] Qb [F] nQb Rn [ ] Q n [F] nQb chi-2

Ti_NT_1 3,89E+01 4,08E-06 2,49E+01 1,50E+06 2,06E-05 7,82E-01 — — — 4,70E-04
Ti_NT_2 3,33E+01 2,35E-06 1,11E+01 4,23E+06 2,54E-05 8,42E-01 — — — 2,21E-04
Ti_NT_3 2,32E+01 3,09E-06 3,59E+01 1,26E+06 2,07E-05 7,15E-01 — — — 3,48E-03
Ti_800_1_1 5,35E+01 1,02E-06 3,02E+01 5,87E+06 8,54E-06 7,79E-01 2,43E+04 2,22E-05 8,26E-01 6,71E-04
Ti_800_1_2 4,50E+01 2,86E-06 3,62E+01 3,50E+06 3,50E-04 1,00E+00 6,99E+05 1,12E-05 7,45E-01 1,39E-03
Ti_800_1_3 3,22E+01 4,07E-06 2,80E+01 2,04E+06 7,61E-05 7,62E-01 3,47E+05 1,78E-05 7,49E-01 8,24E-04
Ti_800_4_1 5,10E+01 3,58E-06 2,30E+01 8,34E+06 2,89E-05 9,00E-01 1,10E+05 1,97E-04 7,01E-01 3,28E-04
Ti_800_4_2 5,25E+01 3,60E-07 2,22E+01 8,65E+06 2,87E-05 8,93E-01 1,10E+05 1,97E-04 7,01E-01 5,04E-04
Ti_800_4_3 5,30E+01 8,42E-06 2,12E+01 1,84E+06 3,73E-05 9,13E-01 1,10E+05 1,97E-04 7,01E-01 6,28E-03
Ti_850_1_1 4,94E+01 3,63E-07 1,94E+01 1,00E+07 2,31E-05 8,40E-01 8,20E+03 6,96E-05 7,37E-01 2,49E-04
Ti_850_1_2 3,37E+01 1,63E-07 3,31E+01 7,94E+06 2,96E-05 8,55E-01 1,51E+04 1,35E-04 7,15E-01 5,43E-04
Ti_850_1_3 4,83E+01 2,02E-07 3,39E+01 1,69E+06 3,95E-05 8,65E-01 1,66E+04 1,54E-04 7,59E-01 6,80E-04
Ti_850_4_1 5,80E+01 5,27E-08 4,24E+01 4,11E+06 1,65E-05 8,73E-01 2,26E+01 4,13E-06 8,75E-01 7,71E-04
Ti_850_4_2 4,67E+01 8,54E-08 4,81E+01 7,26E+06 1,73E-05 8,79E-01 5,96E+01 4,21E-06 7,82E-01 3,26E-04
Ti_850_4_3 4,39E+01 8,10E-08 4,39E+01 4,93E+06 2,11E-05 8,96E-01 5,96E+01 4,21E-06 7,82E-01 1,07E-03

RHBSS [ ] C p [F] Rp [ ] Rb [ ] Qb [F] nQb Rn [ ] Q n [F] nQb chi-2

Ti_NT_1 3,37E+01 2,63E-06 3,08E+01 3,01E+06 1,82E-05 7,36E-01 — — — 1,78E-03
Ti_NT_2 4,76E+01 1,14E-06 7,77E+01 5,11E+06 1,73E-05 7,25E-01 — — — 1,33E-03
Ti_NT_3 4,15E+01 5,15E-06 8,96E+01 1,40E+06 2,29E-05 5,62E-01 — — — 1,05E-02
Ti_800_1_1 6,05E+01 4,15E-06 3,75E+00 1,00E+08 8,75E-04 8,44E-01 2,03E+03 7,01E-04 5,46E-01 1,32E-04
Ti_800_1_2 6,27E+01 7,92E-06 1,21E+01 9,70E+05 1,47E-03 9,06E-01 3,68E+03 1,31E-03 5,85E-01 2,00E-04
Ti_800_1_3 6,88E+01 8,00E-06 1,21E+01 2,21E+04 2,76E-03 9,54E-01 3,68E+03 1,31E-03 5,85E-01 1,37E-03
Ti_800_4_1 5,39E+01 5,29E-07 1,65E+01 1,00E+08 2,80E-05 5,60E-01 2,39E+02 4,63E-05 8,86E-01 4,15E-04
Ti_800_4_2 3,73E+01 1,53E-06 2,49E+01 1,13E+07 8,76E-05 7,41E-01 5,72E+01 4,63E-05 8,86E-01 9,61E-04
Ti_800_4_3 5,33E+01 1,36E-06 8,46E+00 4,01E+05 1,16E-04 6,65E-01 1,23E+01 4,63E-05 8,86E-01 2,36E-03
Ti_850_1_1 1,08E+02 1,40E-05 6,88E+00 6,49E+05 1,83E-04 7,52E-01 7,02E+00 1,00E-09 1,00E+00 7,30E-04
Ti_850_1_2 6,82E+01 5,21E-07 6,77E+00 3,54E+05 2,05E-04 8,02E-01 7,02E+00 1,00E-09 1,00E+00 1,53E-03
Ti_850_1_3 5,72E+01 3,17E-07 9,84E+00 1,34E+05 2,43E-04 7,77E-01 9,86E+00 1,00E-09 1,00E+00 2,93E-03
Ti_850_4_1 9,54E+01 5,81E-06 7,45E+00 1,00E+08 2,37E-04 8,30E-01 1,36E+01 1,00E-09 1,00E+00 1,11E+02
Ti_850_4_2 6,25E+01 1,05E-07 9,93E+01 1,00E+08 4,01E-04 8,59E-01 1,36E+01 1,00E-09 1,00E+00 2,82E-03
Ti_850_4_3 4,17E+01 6,16E-07 4,89E+00 1,27E+05 3,47E-04 8,17E-01 1,36E+01 1,00E-09 1,00E+00 8,32E-03
 Pte.Catódica Pte. anódica Icorr
Rtr [M ] de Tafel [mV] de Tafel [mV] [A·cm -2]
Ti_NT 1,26 146 200 2,91·10-8
Ti_800_1 2,39 158 343 1,97·10-8
Ti_800_4 1,95 183 318 2,59·10-8
Ti_850_1 1,71 218 149 2,25·10-8
Ti_850_4 4,93 228 427 1,31·10-8
Ti64_NT 1,40 299 263 4,34·10-8
Ti64_850_1 0,03 459 261 2,41·10-6
Ti64_850_4 0,40 210 215 1,15·10-7
Ti64_900_1 0,13 105 125 1,91·10-7
Ti64_900_4 0,13 159 167 2,72·10-7

Rtransfer [M ] Rtransfer [M ]
10 100
Ti_NT T64_NT
9
Ti_800_1 90 Ti64_850_1
8 Ti_800_4 Ti64_850_4
7 Ti_850_1 12 Ti64_900_1
Ti_850_4 Ti64_900_4
6 10
5 8
4
6
3
4
2
1 2

0 0
0 2 4 6 8 10 12 14 0 2 4 6 8 10 12 14
tinmersión [días] tinmersión [días]
 A
C
d
 log |Z| [ ] fase [º]
log |Z| [ ] fase [º] 7 0
7 0
Experimental Experimental
-10 Simulación -10
Simulación 6
6
-20 -20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
log (f) [Hz]
a) a) log (f) [Hz]

log |Z| [ ] log |Z| [ ] fase [º]

fase [º] 7 0
7 0
Experimental Experimental
-10 Simulación -10
Simulación 6
6
-20 -20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5

b) log (f) [Hz] b) log (f) [Hz]

log |Z| [ ] fase [º] log |Z| [ ] fase [º]

7 0 7 0
Experimental Experimental
Simulación -10 -10
6 Simulación
6
-20 -20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
c) log (f) [Hz] c) log (f) [Hz]
 log |Z| [ ] fase [º] log |Z| [ ] fase [º]
7 0 7 0
Experimental
Experimental
-10 Simulación -10
6 Simulación 6
-20 -20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
a) log (f) [Hz] a) log (f) [Hz]

log |Z| [ ] fase [º] log |Z| [ ] fase [º]

7 0 7 0
Experimental Experimental
-10 Simulación -10
6 Simulación 6
-20 -20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
b) log (f) [Hz] b) log (f) [Hz]

log |Z| [ ] fase [º]

7 0 log |Z| [ ] fase [º]
7 0
Experimental Experimental
Simulación -10 -10
6 Simulación
6
-20 -20
5 -30 5 -30
-40 -40
4 4
-50 -50
3 -60 3 -60
-70 -70
2 2
-80 -80
1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
c) log (f) [Hz]
c) log (f) [Hz]
 log |Z| [ ] fase [º] log |Z| [ ] fase [º]
7 0 7 0
Experimental Experimental
Simulación -10 Simulación -10
6 6
-20 -20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
a) log (f) [Hz] a) log (f) [Hz]

log |Z| [ ] fase [º] log |Z| [ ] fase [º]

7 0 7 0
Experimental Experimental
-10 Simulación -10
Simulación 6
6
-20 -20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90
1 -90 -3 -2 -1 0 1 2 3 4 5
-3 -2 -1 0 1 2 3 4 5
log (f) [Hz] b) log (f) [Hz]
b)

log |Z| [ ] fase [º] log |Z| [ ] fase [º]

7 0 7 0
Experimental Experimental
Simulación -10 Simulación -10
6 6
-20 -20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
c) log (f) [Hz] c) log (f) [Hz]
 log |Z| [ ] fase [º] log |Z| [ ] fase [º]
7 0 7 0
Experimental Experimental
Simulación -10 Simulación -10
6 6
-20 -20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
a) log (f) [Hz]
a) log (f) [Hz]

log |Z| [ ] fase [º]

log |Z| [ ] fase [º] 7 0
7 0
Experimental
Experimental
Simulación -10
Simulación -10
6
6
-20
-20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
log (f) [Hz]
b) log (f) [Hz] b)

log |Z| [ ] fase [º] log |Z| [ ] fase [º]

7 0 7 0
Experimental Experimental
Simulación -10 -10
6 Simulación
6
-20 -20
5 -30 5 -30
-40 -40
4 4
-50 -50
3 -60 3 -60
-70 -70
2 2
-80 -80
1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
c) log (f) [Hz] c) log (f) [Hz]
 log |Z| [ ] fase [º] log |Z| [ ] fase [º]
7 0 7 0
Experimental Experimental
Simulación -10 Simulación -10
6 6
-20 -20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
log (f) [Hz] a) log (f) [Hz]
a)

log |Z| [ ] fase [º] log |Z| [ ] fase [º]

7 0 7 0
Experimental Experimental
-10 Simulación -10
Simulación 6
6
-20 -20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
b) log (f) [Hz] b) log (f) [Hz]

log |Z| [ ] fase [º] log |Z| [ ] fase [º]

7 0 7 0
Experimental Experimental
-10 Simulación -10
Simulación
6 6
-20 -20

5 -30 5 -30

-40 -40
4 4
-50 -50

3 -60 3 -60

-70 -70
2 2
-80 -80

1 -90 1 -90
-3 -2 -1 0 1 2 3 4 5 -3 -2 -1 0 1 2 3 4 5
c) log (f) [Hz] c) log (f) [Hz]