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• Enthalpy
• For high-speed flows, enthalpy and kinetic energy are
combined into stagnation enthalpy h0
Stagnation Properties
• Steady adiabatic flow through duct
with no shaft/electrical work and no
change in elevation and potential
energy
cancel Neglect
H.O.T.
Speed of Sound and Mach Number
• Energy balance ein = eout
cancel Neglect
cancel
H.O.T.
Speed of Sound and Mach Number
• Using the thermodynamic relation
• Since
– R is constant
– k is only a function of T
– Speed of sound is only a
function of temperature
Speed of Sound and Mach Number
• Second important
parameter is the Mach
number Ma
• Ratio of fluid velocity to
the speed of sound
Ma < 1 : Subsonic
Ma 1 : Transonic • Flow regimes classified
Ma = 1 : Sonic in terms of Ma
Ma > 1 : Supersonic
Ma >> 1 : Hypersonic
One-Dimensional Isentropic Flow
• For flow through nozzles,
diffusers, and turbine
blade passages, flow
quantities vary primarily
in the flow direction
– Can be approximated as 1D
isentropic flow
• Consider example of
Converging-Diverging
Duct
Examples:
Air enters a diffuser with a velocity of 200 m/s. Determine (a) the speed of sound and (b)
the Mach number at the diffuser inlet when the air temperature is 30°C.
Carbon dioxide flows steadily through a varying cross-sectional area duct such as a
nozzle at a mass flow rate of 3 kg/s. The carbon dioxide enters the duct at a
pressure of 1400 kPa and 200°C with a low velocity, and it expands in the nozzle to
a pressure of 200 kPa. The duct is designed so that the flow can be approximated as
isentropic. Determine the density, velocity, flow area, and Mach number at each
location along the duct that corresponds to a pressure drop of 200 kPa.
Use cp = 0.846 kJ/kg · K and γ=1.289 throughout the calculations, which are the constant-
pressure specific heat and specific heat ratio values of carbon dioxide at room temperatures.
The gas constant of carbon dioxide is R =0.1889 kJ/kg · K.
One-Dimensional Isentropic Flow
• Ma = 1 at the location of the
smallest flow area, called the
throat
• Velocity continues to increase
past the throat, and is due to
decrease in density
• Area decreases, and then
increases. Known as a
converging - diverging nozzle.
Used to accelerate gases to
supersonic speeds.
One-Dimensional Isentropic Flow
• Continuity
One-Dimensional Isentropic Flow
Variation of Fluid Velocity with Flow Area
Variation of Pressure with Flow Area
We visualize a nozzle as a converging duct. However, the highest velocity we can achieve by a
converging nozzle is the sonic velocity, which occurs at the exit of the nozzle.
The fluid first passes through a subsonic (converging) section, where the Mach number
increases as the flow area of the nozzle decreases, and then reaches the value of unity at the
nozzle throat. The fluid continues to accelerate as it passes through a supersonic (diverging)
section.
Large decrease in density makes acceleration in the diverging section possible. An example
of this type of flow is the flow of hot combustion gases through a nozzle in a gas turbine.
One-Dimensional Isentropic Flow
Variation of Fluid Velocity with Flow Area
Comparison of flow properties in subsonic and supersonic nozzles and diffusers
• Substituting T and P
Conservation of energy
Conservation of momentum
Increase in entropy
Shock Waves and Expansion Waves
Normal Shocks
• Combine conservation of mass
and energy into a single equation
and plot on h-s diagram
– Fanno Line : locus of states that
have the same value of h0 and
mass flux
• Combine conservation of mass
and momentum into a single
equation and plot on h-s diagram
– Rayleigh line
• Points of maximum entropy
correspond to Ma = 1.
– Above / below this point is
subsonic / supersonic
Shock Waves and Expansion Waves
Normal Shocks
• There are 2 points where the
Fanno and Rayleigh lines intersect
: points where all 3 conservation
equations are satisfied
– Point 1: before the shock
(supersonic)
– Point 2: after the shock
(subsonic)
• The larger Ma is before the shock,
the stronger the shock will be.
• Entropy increases from point 1 to
point 2 : expected since flow
through the shock is adiabatic but
irreversible
Shock Waves and Expansion Waves
Normal Shocks
• Equation for the Fanno line for an
ideal gas with constant specific
heats can be derived
The stagnation pressure decreases across the • Combining this gives the
shock because of the irreversibilities, while the intersection points
ordinary (static) temperature rises drastically
because of the conversion of kinetic energy into
enthalpy due to a large drop in fluid velocity
Shock Waves and Expansion Waves
Oblique Shocks
-Ma relationship
Shock Waves and Expansion Waves
Oblique Shocks
• If wedge half angle > max, a
detached oblique shock or bow
wave is formed
• Much more complicated that
straight oblique shocks.
• Requires CFD for analysis.
X-Momentum equation
Duct Flow with Heat Transfer and Negligible Friction
Energy equation
– CV involves no shear, shaft, or other forms of work, and potential energy
change is negligible.
Entropy change
– In absence of irreversibilities such as friction, entropy changes by heat
transfer only
Duct Flow with Heat Transfer and Negligible Friction
X-Momentum equation
Adiabatic Duct Flow with Friction
Duct Flow with Heat Transfer and Negligible Friction
Energy equation
– CV involves no heat or work, and potential energy change is negligible
Entropy change
• “… all normal or Newtonian fluids (air, water, oil, honey) follow the same
scientific laws. On the other hand, there are also fluids that do not follow
the Newtonian flow laws. These non-Newtonian fluids, for example mayo,
paint, molten plastics, foams, clays, and many other fluids, behave in a
wide variety of ways. The science of studying these types of unusual
materials is called rheology”
*Faith Morrison, “The News and Information Publication of The Society of Rheology”, Vol 73(1) Jan 2004, pp 8-10
Examples of Complex Fluids
• Foods
– Emulsions (mayonaisse, ice cream)
Personal Care Products
Suspensions (nail polish, face
An emulsion is a mixture of two or scrubs)
more liquids that are normally Solutions/Gels (shampoos,
immiscible (unmixable or conditioners)
unblendable) Foams (shaving cream)
– Foams (ice cream, whipped cream) Electronic and Optical Materials
A foam is a substance that is formed Liquid Crystals (Monitor displays)
by trapping pockets of gas in a liquid Melts (soldering paste)
or solid Pharmaceuticals
– Suspensions (mustard, chocolate) Gels (creams, particle precursors)
Emulsions (creams)
A suspension is a heterogeneous Aerosols (nasal sprays)
mixture containing solid particles
that are sufficiently large for Polymers
sedimentation
– Gels (cheese)
Gel is a solid jelly-like material that
can have properties ranging from soft
and weak to hard and tough
• Biofluids
– Suspension (blood)
– Gel (mucin)
– Solutions (spittle)
Rheology’s Goals
• Establishing the relationship between applied
forces and geometrical effects induced by these
forces at a point (in a fluid).
– The mathematical form of this relationship is called the
rheological equation of state, or the constitutive
equation.
– The constitutive equations are used to solve
macroscopic problems related to continuum mechanics
of these materials.
– Any equation is just a model of physical reality.
Rheological Properties
• Stress: Shear stress, Normal stress, Normal Stress differences
• Viscoelastic Modulus:
Viscoelasticity is the property of materials that exhibit both viscous and
elastic characteristics when undergoing deformation.
Viscous materials, like honey, resist shear flow and strain linearly with time
when a stress is applied.
Elastic materials strain when stretched and quickly return to their original
state once the stress is removed.
Elasticity is usually the result of bond stretching along crystallographic
planes in an ordered solid, viscosity is the result of the diffusion of atoms or
molecules inside an amorphous material
– G’ – storage modulus
– G” – loss modulus
The storage and loss modulus in viscoelastic materials measure the stored
energy, representing the elastic portion, and the energy dissipated as heat,
representing the viscous portion.
du z
rz
dr
Non-Newtonian Fluid
du z
rz
dr
η is the apparent viscosity and is not constant for non-Newtonian fluids.
η - Apparent Viscosity
The shear rate dependence of η categorizes non-
Newtonian fluids into several types.
Power Law Fluids:
Pseudoplastic – η (viscosity) decreases as shear rate increases (shear rate thinning)
Dilatant – η (viscosity) increases as shear rate increases (shear rate thickening)
Bingham Plastics:
η depends on a critical shear stress (t0) and then becomes constant
Non-Newtonian Fluids
Bingham Plastic: sludge, paint, blood, ketchup
Newtonian
Dilatant: quicksand
Modeling Power Law Fluids
Oswald - de Waele
Dv
p g τ
Dt
du z n
du z du z
n 1
rz K K
dr dr dr
where:
K = flow consistency index
n = flow behavior index eff
Note: Most non-Newtonian fluids are pseudoplastic n<1.
Common Non-Newtonian Behavior
• shear thinning
• shear thickening
• yield stress
• viscoelastic effects
– Weissenberg effect
– Fluid memory
– Die Swell
72
Shear Thinning and Shear Thickening
• shear thinning – tendency of some materials to decrease in viscosity
when driven to flow at high shear rates, such as by higher pressure
drops
73
Shear Thickening
• shear thickening – tendency of some materials to
increase in viscosity when driven to flow at high shear
rates
74
Quicksand – A Non-Newtonian Fluid
• Quicksand is a colloid hydrogel (sand, clay and salt
water).
• When undisturbed behaves as a solid gel
– Minor changes in the stress will cause a sudden decrease
in its viscosity
• After the initial perturbation, water and sand
separate and dense regions of sand sediment
– High volume fraction regions -> viscosity increases
• Sufficient pressure must be applied to reintroduced
water into the compacted sand.
• The forces required to remove a foot from quicksand
at a speed of 1 cm/s are about
– Same as “that needed to lift a medium-sized car.”
75
Elastic and Viscoelastic Effects
• Weissenberg Effect (Rod Climbing Effect): Phenomenon that
occurs when a spinning rod is inserted into a solution of elastic
liquid. Instead of being thrown outward, the solution is drawn
towards the rod and rises up around it.
Elastic and Viscoelastic Effects
• Viscoelastic fluids subjected to a stress deform
– when the stress is removed, it does not instantly vanish
– internal structure of material can sustain stress for some time
– this time is known as the relaxation time, varies with materials
– due to the internal stress, the fluid will deform on its own, even when
external stresses are removed
– important for processing of polymer melts, casting, etc..
τ
τ
v vT τ v v E u uT
T
t t