Test : Organic Chemistry

 Time : 5 Minute
Topic : Hydrogen Bonding Total Marks : 40

Instruction : Each Questions Contains 4 Marks and No Negative Marking in this Test

1. Acidic Nature of Performic acid (x) is less than formic acid (y) due to
(a) Better resonance in anion of ‘x’
(b) No resonance in anion of ‘x’
(c) Intra molecular hydrogen bonding in ‘x’
(d) Both are (b) & (c)
2. Maximum B.P. is of
OH
|
(a) CH2 == CH — CH2 OH (b) CH3  CH  CH3

(c) CH3CH2CH2OH (d) none of these

KOH (aq)
3. Final Product of reaction CHCl3 →

(a) HCOOH (b) HCOOK

(c) Mixture of HCOOH & HCOOK (d) K2CO3
4. B.P. is maximum in
(a) Para-Nitrophenol (b) ortho-nitrophenol
(c) meta-nitrophenol (d) All of these
COOH


5. A + CO2. A is
COOH
COOH

(a) (b)
COOH
COOH

(c) (d)
COOH

1
6. B.P. is maximum in
O O
|| ||
(a) (b)

O
(c) || (d) All of these
OH
7. Which is unstable
(a) 2, 2, 2 Trifluro ethandiol (b) Gem ethantriol
(c) Vicinal ethandiol (d) All of these
8. NaF and NaHF2 both are correct due to
(a) Hydrogen bonding in HF to form H2F2
(b) Polarising power of H—F
(c) High electropositive nature of Na
(d) Dipole formation by NaF
9. Number of Hydrogen bonds in H2O are
(a) 1 (b) 2
(c) 3 (d) 4
10. B.P. order is correct
(A) CH3COOH > CH3 CH2OH > CH3 CHO
(B) CH3 CH2 CH2 NH2 > CH3 NHCH2 CH3 > (CH3)3N

(C)
CH3 OH > CH2OH

(D) CH3—CH == CH—OH > CH2 == CH — CH2OH

(a) A, B, C, D (b) A & B
(c) A, B, C (d) C & D

ANSWER KEY
1. (d) 2. (c) 3. (c) 4. (a) 5. (b)

6. (c) 7. (b) 8. (a) 9. (d) 10. (a)