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GURU HARKRISHAN PUBLIC SCHOOL, VASANT VIHAR

CLASS XI CHEMISTRY ASSIGNMENT


Ch 3 : CLASSIFICATION OF ELEMENTS AND PERIODICITY IN ELEMENTS
1. Write the name and symbol for the elements with atomic number 117 and
119.
2. What kind of subshell is being filled in
i. Group 1 and Group 2
ii. Group 13 to 18
iii. Transition metals
iv. Lanthanoids and Actinoids
3. Write down the general outer electronic configuration of
i. p-block elements
ii. d-block elements
iii. f-block elements
4. Why are Group 1 elements called Alkali metals and Group 17 elements are
called halogens?
5. Which is smaller in size? Li or F and Why.
6. Out of Na and Mg, which has a higher second ionization enthalpy?
7. Consider the electronic configuration of the elements A, B and C
A: 1s2 , 2s2 , 2p3
B: 1s2 , 2s2 , 2p6 , 3s1
C: 1s2 , 2s2 , 2p6
i. Which has highest ionisation enthalpy?
ii. Which has lowest ionisation enthalpy?
8. Give reasons
i. The radius of cation is less than that of the parent atom.
ii. Anion is larger in size than the parent atom.
9. What are isoelectronic species? The following species are isoelectronic with
the noble gas. Arrange these in order of increasing size : K+ , S-2 , Cl- , Ca2+
10. Explain why the ionisation enthalpy of oxygen is smaller than nitrogen.
11.Account for the following
i. Chlorine has a greater electron gain enthalpy than bromine.
ii. Electron gain enthalpy of Fluorine is unexpectedly lower than that of
Chlorine.
12.Give two characteristics each of the s-block elements, p-block elements and
d-block elements
13.Lanthanoids and actinoids are placed in Separate rows at the bottom of the
periodic table. Why?
14.Why are the electron gain enthalpy of Be and Mg positive?
15.Why noble gases have positive electron gain enthalpy.

GURU HARKRISHAN PUBLIC SCHOOL, VASANT VIHAR


CLASS XI CHEMISTRY ASSIGNMENT
Ch 4 : CHEMICAL BONDING AND MOLECULAR STRUCTURE
1. Write the Lewis structure of
i. NO2
ii. BF3
2. What are the factors on which formation of ionic bonds depends?
3. Define Lattice enthalpy and how is it related to the stability of ionic compound.
4. What is a polar covalent bond? Give 2 examples.
5. Define Electronegativity. How does it differ from Electron affinity?
6. Predict the shapes of the following molecules using the VSEPR theory : BeCl 2 , SiCl4 , H2S
and PH3
7. What types of hybridisation is associated with the central atom when the atoms
attached to it form.
i. An equilateral Triangle
ii. A regular tetrahedron
iii. A trigonal Pyramidal
8. Explain why BeH2 molecule has a zero dipole moment although the Be-H bonds are
polar?
9. Predict the dipole moment of a molecule of the type.
i. AX4 having a square planar geometry
ii. AX5 having a square pyramidal shape.
iii. AX6 having an octahedral geometry.
10. Name the molecular shapes associated with the following hybridisation.
i. dsp3
ii. sp3d2
11. Using VSEPR theory account for the shape of
i. H2O molecule
ii. NF3molecule
12. Why is it that in the SF4 molecule, the lone pair of electrons occupies an equatorial
position in the trigonal bipyramidal arrangement in preference to the actual position?
13. Why is that ClF3 is a T shape molecule while BF3?
14. On the basis of hybridisation explain the bonding and shape in Ethene molecule and
Ethyne molecule?
15. What do you understand by coordinate covalent bond?
16. Which hybridisation is presumed for P in PF5 and F in SF6? Give reasons for your answer.
17. How does the structure of PCl5 responsible for its high reactivity?
18. Explain why the bond order of N2 is greater than N2+ , but the bond order of O2 is less
than that of O2+.
19. Compare the relative stability of the following species and indicate their magnetic
properties (Diamagnetic or paramagnetic): O2, O2+, O2- and O22- ions.
20. Define bond order. How is it related to bond order? Calculate the bond order of N 2
molecule. Why is this molecule not paramagnetic?

GURU HARKRISHAN PUBLIC SCHOOL, VASANT VIHAR


CLASS XI CHEMISTRY ASSIGNMENT
Ch 5 : STATES OF MATTER
1. State Boyle’s law. What is the volume of a sample of oxygen at a pressure
of 2.5atm, If its volume is 3.15L at 1.0atm? The temperature remains
constant.
2. State Charle’s law. What is the increase in volume, when the temperature
of 600mL of air increases from 27oC to 47oC under constant pressure?
3. A sample of hydrogen gas is found to occupy 906cm3 of volume at 300K
calculate the temperature at which it will occupy 500cm3 of volume?
(Assuming amount and pressure remains constant )
4. A quantity of hydrogen is confined in a chamber of constant volume. When
the chamber is immersed in a bath of melting ice, the pressure of the gas is
1000 torr. What is the temperature in Celsius, when the pressure in
manometer is 400 torr.
5. Under what conditions is the ideal gas equation most accurate.
6. State Dalton’s law of partial pressure.
7. How do you account for the observation that an automobile tyre is inflated
with less air in summer than in winter.
8. A balloon contains 5.41 dm3 of helium at 24oC and 101.5 kPa. Suppose the
gas in the balloon is heated to 35oC so that the pressure of helium gas is
now 102.8 kPa, what is its volume?
9. The maximum safe pressure that a 4.0L vessel can hold is 3.5atm if the
vessel contains 0.410 mole of gas, what is the maximum temp (in oC) to
which this vessel can be subjected?
10.Calculate the temperature of 4.0 moles of a gas occupying 5.0 dm3 at 3.32
bar.
11.Define vapour pressure of a liquid
12.Why it is difficult to soften food at hills.
13.Define surface tension. Give its unit.
14.When a mercury thermometer bulb breaks mercury spreads in small
spherical globules. Explain.
15.The boiling point of acetone is 329.5K and that of ether is 308K. In which
liquid are the intermolecular attractive forces stronger?
16.What makes ice less dense than liquid water?
17.Explain why evaporation leads to the cooling of the liquid.
18.Why water has abnormally high boiling point (373K) as compared to H2S
(211K)?
19.Glycerine is less volatile than water. Why/
20.Which will cool to room temperature faster- a closed container of water at
100oC or Open container of water at 100oC? Explain?

GURU HARKRISHAN PUBLIC SCHOOL, VASANT VIHAR


CLASS XI CHEMISTRY ASSIGNMENT
Ch 14 : ENVIRONMENTAL CHEMISTRY
1. What is environmental pollution?
2. What is Primary and Secondary pollutants?
3. Name the oxides of carbon which are atmospheric air pollutants?
4. What are the harmful effects of CO?
5. What are the harmful effects of CO2?
6. What are particulates? Name its types.
7. What is smog? What are its types?
8. Distinguish between classical and photochemical smog.
9. Explain BOD.
10.What is COD?
11.What is acid rain? What is its cause? How is it harmful to the environment?
12.Why is acid rain considered a threat to Taj Mahal?
13.What do you understand by greenhouse? What are the major greenhouse
gases?
14.What do you understand by Eutrophication? How does it threatens the
development of fish?
15.List five major water pollutants giving their sources.

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