Narayana Paper1

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CODE: TIGER
NARAYANA
GROUP OF EDUCATIONAL INSTITUTIONS
IIT JEE – 2010

GRAND TEST
Key, Hints & Solutions
(PAPER-I) DATE: 25 − 11 − 09
MATHS PHYSCIS CHEMISTRY

1 A 24 B 47 B
om
2 C 25 C 48 D
3 D 26 C 49 C
c
g.
4 C 27 A 50 D
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5 C 28 B 51 C
6 D 29 C 52
ye
B
7 A,D 30 B 53 D
.m
8 A,B,C 31 A,B,C 54 B,D

w
9 A,B,C,D 32 B,C,D 55 A,B,C,D

w
10 A,C,D 33 C,D 56 A,D

w
11 C 34 D 57
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B
12 C 35 A 58
tp
B
13 B 36 D 59
ht
D
14 A 37 C 60 C
15 B 38 D 61 B
16 D 39 C 62 D
17 C 40 A 63 D
18 B 41 A 64 D
19 C 42 C 65 B
20 D 43 B 66 B
21 C 44 A 67 D
22 C 45 B 68 C
23 C 46 B 69 C
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CODE: TIGER
MATHEMATICS
1) D1 for 3x2 + kx + 3 is k2 − 3y and D2 for x2 + kx − 1 is k2 + 4. From D1 and D2

there exist at least two real roots of (3x2 + kx + 3)(x2 + kx − 1) = 0
4x 2 + 3x + 5
2) Lim exist when in denominator power of x is more.
x →∞ x + 1 + x k −1
i.e., k−1 ≥ 2 ⇒ k ≥ 3.
∞ ∞ k ∞ ∞
 1 1 1  k
3) ∑∑ n+k
= ∑k k +1
+ k +2 + k +3 + .....  = ∑ k
=2
k =1 n =1 2 k =1 2 2 2  k =1 2
4) ( ( ) (
a 2 + b2 = 4R2 sin2 45o − θ + sin2 135o − θ ))
= 4R ( sin ( 45 − θ ) + cos ( 45 − θ) )
2 2 o 2 o
om
= 4R2 C
c
θ
g.
o
b θ 90 -θ
ng
a
ye
o o
45 o-θ 45o 45 +θ 45
A P B Q
.m
20 20 20
5) ∑ r.r! = ∑ (r +1 − 1).r! = ∑ [(r + 1)!− r !] = 21! − 1.
w
r =1 r =1 r =1
w
6) Domain of f is [−1, 1] as cos−1x ∈ [0, π]

w
Range of f is [a, a+bπ], hence a = −1 and a+2bπ = 1

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1 1
⇒ b = and b − a = +1
tp
π π
ht
7) (A) f(x) = log(1 + x2) − e −x + 1

2x
f ′(x) = 2
+ e− x is increasing ∀ x > 0
1+ x
2
f ′(x) = e− x +
1
x+
x
2
for x < 0, −1 < < 0 and e −x > 1
1
x+
x
2x
Hence, e − x + >0
1 + x2
(B) Limxlogxlog(1
+
+ x) (0. ∞)
x →0
logx = −t ⇒ x = e −t
as x → 0+, t → ∞
CODE: TIGER
−t(1 − t) t(t − 1)
∴ Lim = Lim =0
t →∞ et t →∞ et
x4 + x 2 + 5 x 4 + 2x 2 + 1 + 4 − x2 4 − x2
(C) f(x) = 4 = = 1 +
x + 2x 2 + 1 x 4 + 2x 2 + 1 x 4 + 2x2 + 1
4 − x2
Let g(x) = 2
(x + 1)2
( ) ( )
2
g′( x ) = x 2 +1 .(−2x) − (4 − x 2 )2 x 2 + 1 .2x = 0
= (x 2
+ 1) 2x ( − (x 2
+ 1) − 2 ( 4 − x ) )
2
x = 0 or x2 = 9 ⇒ x = 3 or −3
1
g(3) = −
20
1 19
Hence, minimum value of f(x) = 1 − =
20 20
(D) obviously true
om
∞ ∞
ndx tan−1(nx)
c
8) L = Lim ∫ = Limn.
n →∞ 1 + n 2x 2
g.
a
n →∞ n a
 π, a < 0
ng
π  π
= Lim  − tan −1 ( anx )  =  , a = 0
ye
n →∞  2  2
 0, a > 1
.m
9) Let f(t) = t3 − 9t2 + 15t + 6

w
f ′(t) = 3t 2 − 18t + 15 = 3(t − 1)(t − 5)

w
 x3 − 9x 2 + 15x + 6, 1 ≤ x < 5
w

g(x) =  −19, 5≤x≤6
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 x − 18 x >6

tp
From above one can observe all

ht
r r r r r r r r r
10) a × b = c and b × c = a ⇒ a, b, c are orthogonal to each other
r r r r r r r r r
a × b = c ⇒ a b = c and b c = a
r r r r r r r r r r2 r2
⇒ b = 1 and a = c also a ⋅ b × c = a b c = c or a
11) If it is acute triangle then, statement-1 is obviously true

Let A be obtuse say A = 150o, both angles < 30o and if C = 30o
now cotA and cot(B + C) will be of equal magnitude but opposite sign.
As cotθ is decreasing, hence, cotB + cotA alone is +ve
∴ cotA + cotB + cotC > 0.
12) Let f(x) = 12x5 − 15x4 + 20x3 − 30x2 + 60x + 1

(
f ′(x) = 60 x 4 − x 3 + x 2 − x +1 > 0 ∀ x ∈ R )
So, statement-1 is true.
CODE: TIGER
but if f(x)=tan −1x is defined for R and is strictly increasing but range is not R.
13) Statement-1: a3 + b3 + c3 − 3abc, a > b > c

⇒ a+b+c=0
⇒ x = 1 is root of the equation ax2 + bx + c = 0
⇒ roots are of opposite sign.
Statement-2 : obviously right as well as explain statement-1.
14) Statement-1 : S 1 − S2 = 0 ⇒ x + y − 7 = 0 ; centre of S2 lies on it

Also, statement-2 is correct but does not explain statement-1.
1 2 3 3  26 
15) 2 1 2 4  = 20  ⇒ 292 ≠ 202 + 262
    
2 2 3 5  29 
 3  5  3  15 
Similarly, Q 4 = 12 , and R 4  =  8 
   
       
om
5  13  5  17 
c
16) detP = 1, detQ = 1, detR = 1
g.
det(PQ) = 1, det(QR) = 1, det(RP) = 1
det(PQR) = 1
ng
17) (
Tr P + QT + 2R = 14)
ye
.m
2
18) y = e α+β x , passes through (1, 1)
w
⇒ 1 = e α+β ⇒ α + β = 0 ……… (1)

w
Also, 
dy 
 = −2
 dx (1,1)
w
://
2
⇒ e α+βx 2βx = −2
e α+β .2β(1) = −2 ⇒ β = −1 and α = 1
tp
⇒
  α  2  β 2 
ht
⇒ (α, β) = (1, −1) ⇒ 6    +    = 3

 2   2 
 
( 3)
2
19) S1 : (x − 1)2 + (y + 1)2 =
= (3 2 )
2
S2 : (x − 6)2 + (y − 11)2
( )
2
AB2 = l 2 = (C1C2)2 − (r1 + r2)2 = 169 − 4 3 = 121
⇒ AB = 11 S1 r1 B
l S2
r2
l
{ In the figure, r1 = 3 , r2 = 3 3 C1 C2
C1 (1, −1), C2 (6, 11) } r1
A
13
20) Simplifying f(x) = x2
CODE: TIGER
α 1
∫ f(x)d ( log x )dx = ∫x

2
d ( log x )dx
β −1
e
1
= ∫ x . dx =
2 e 2 − e −2 e4 − 1
= =
e 2 + 1 e2 − 1 ( )( )
1/e x 2 2e2 2e2
21), 22) & 23)

 x 2 + 10x + 8 , x≤2
 2
f(x) =  ax + bx + c , −2 < x < 0,a ≠ 0
 x 2 + 2x , x≥0

for continuous at x = 0 ⇒c=0
continuous at x = −2 ⇒ 2a − b = −4 ………(1)
no let the line y = mx +d is tangent to all the 3 curves
solving y = mx + d and y = x2 + 2x
⇒ x2 + (2 − m)x − d = 0
om
D = 0 ⇒ (2 − m)2 + 4d = 0 ………(2)
Again solving y = mx + d and y = x2 + 10x + 8
⇒ x2 + (10 − m)x + 8 − d = 0
c
g.
D = 0 ⇒ (10 − m)2 − 32 + 4d = 0 ……… (3)
From (2) and (3), we get
ng
m = 4, d = −1
Equation of line tangent to 1st and last curve is y = 4x − 1 ……… (4)
ye
Now solving this with y = ax2 + bx

ax2 + bx = 4x − 1 (as c = 0)
.m
ax + (b−4)x + 1 = 0
2
D = 0 ⇒ (b − 4)2 = 4a ………(5)
w
From (1) and (5) ⇒ a = 1, b = 6

w
−
f ′(0 ) = Lim2ax + b = b
w
x →0
://
+
f ′(0 ) = Lim2x + 2 = 2 ⇒ b = 2
x →0
tp
ht
CODE: TIGER
PHYSICS
24. For figure A, angle of refraction is very less then the corresponding critical
angle.
For C and D : refractive index of surrounding is more than glass
Only B is correct.
25. Driven wheel experiences forward friction.
4 kx 3
26. a = g; kx = mg
5 m 5
TB − TC TC − TA
27. =
3 2
28. ∆W = ∆U liquid is ideal U → gravitational P.E

4ω2 R 2
29. r = 2 = 4R
om
ωR
30. q1 > q2 ; E−lines diverging from +ve charge and terminate at −ve charge.
c
r ur
31. ∑ τ = 0 ; L = constant, collision is elastic hence kinetic energy will also
2l
g.
ng
conserve if the point of collision is distance below from the hinge them
3
impulse imported by hing will be zero hence momentum may also conserve.
ye
d2 x d2 y
32. = 0; = −g
.m
dt 2 dt 2
33. In the given situation image distance is greater then object distance, size of
w
image increases.
ur r ur
w
34. Net force on charge particle should be zero E = −v × B . Hence 1st statement is
incorrect but first is correct.
w
35. Velocity will be zero at max. displacement.

://
36. Centripetal acceleration.

r
tp
ur dv
37. E = −
ht
dr
hϕ
38. At equilibrium x =
k
39. Apply conservation of mechanical energy X max + x = 40 cm ; X max = 35 cm
40. Displacement of point A = 2 ( Xmax − x ) = 60cm
41. Apply equation of continuity.
42. ∆W = change the kinetic energy of water, + gain in P.E of water + gain in P.E
of piston
43. Decreases
44. e = B / ν
e
45. i = ; Current is independent of any local variable
R
46. Power = i 2R
CODE: TIGER
CHEMISTRY
47. B
Covalent character: NaF<MgF2<AlF3
Melting point : NaF<MgF2<AlF3 (Decided by Lattice energy as the
polarizability of F- is very low)
48. D
c om
g.
ng
ye
.m
w
w
w
://
tp
ht
49. C
50. D
CODE: TIGER
20 × 2 1
no. of mm of BrO −3 left = =
40 × 6 6
35 7
no. of mm of BrO −3 taken = =
30 6
7 1
no. of mm of BrO3- used = = − =1
6 6
om
nBrO − 2
3
=
nSeO2 − 5
c
3
g.
nSeO2 − = × 1 = 2.5
3 2
ng
51. C
The major product of dehydrohalogenation of 2-bromobutane is trans-but-
ye
2-ene which on anti addition of bromine gives meso-1,2-dibromobutane.

52. B
.m
Ea
- 0.001
e RT
= =10 -5
w
100
w
Ea
- =2.303×log10-5 =2.303×(-5)
w
RT
Ea = 2.303 × 5 × 2 × 300 = 6.91kcal/mol
://
tp
53. D
ht
54. B, D
55. A,B,C,D
H2SO4 + 2NH4OH  → (NH4)2SO4 + 2H2O
No. of mmoles 100x0.25 400x0.1
CODE: TIGER
56. A,D
From molecular orbital energy level diagram of O2 molecule it is clear that
energy level of filled M.O. is at higher energy level (anti bonding M.O.) than
the energy level of atomic orbital of oxygen atom. In case of nitrogen, energy
level of atomic orbitals are at higher level than the energy level of filled
bonding M. O. Hence I.E. of N2 molecule is greater than that of N atom.
om
57. B
After dimerization of BH3 molecules into B2H6, no vacant orbital at B atom
c
g.
is left to carry on further polymerization. However, in case of BeH2, after
ng
dimerization of BeH2 molecules into Be 2H4 each Be atom still contains one
empty 'p' orbital which brings further polymerization. However they are still
ye
electron deficient molecules.

.m
58. B
w
Suphate is tertrahedral while S52- is a polysulphide and has a zig−zag

w
structure.
w
://
59. D
− −
tp
C H 2 − C1 is more stable than C H2 − F due to d-orbital resonance(overlap of –

ve charge of carbon with empty d-orbitals of chlorine)
ht
F has higher electron withdrawing power than Cl.
60. C
CODE: TIGER
61. B
62. D
c om
g.
63. D
CO + 2H2 ? CH3OH
ng
q = ?H × 1000 ×60 = 6×104 × 500 ×2 = 6 ×107 cal
q= 60000 kcal
ye
64. D
.m
w
w
w
://
tp
ht
65. B
66. B
Under ordinary condition, H2O molecule can not approach to the vaccant
antibonding MO. of C-Cl bond (yet having low energy) due to steric
crowding over central carbon atom. C-Cl bond dissociation energy is not
very high as its magnitude is less than that of C-F.
CODE: TIGER
67. D
c om
68. C
In Basic Medium g.
ng
ye
.m
In Acidic Medium
w
w
w
://
tp
69. C
ht

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IIT JEE – 2010

MATHS PHYSCIS CHEMISTRY

8 A,B,C 31 A,B,C 54 B,D

9 A,B,C,D 32 B,C,D 55 A,B,C,D

10 A,C,D 33 C,D 56 A,D

1) D1 for 3x2 + kx + 3 is k2 − 3y and D2 for x2 + kx − 1 is k2 + 4. From D1 and D2

6) Domain of f is [−1, 1] as cos−1x ∈ [0, π]

Range of f is [a, a+bπ], hence a = −1 and a+2bπ = 1

7) (A) f(x) = log(1 + x2) − e −x + 1

9) Let f(t) = t3 − 9t2 + 15t + 6

f ′(t) = 3t 2 − 18t + 15 = 3(t − 1)(t − 5)

From above one can observe all

11) If it is acute triangle then, statement-1 is obviously true

12) Let f(x) = 12x5 − 15x4 + 20x3 − 30x2 + 60x + 1

13) Statement-1: a3 + b3 + c3 − 3abc, a > b > c

14) Statement-1 : S 1 − S2 = 0 ⇒ x + y − 7 = 0 ; centre of S2 lies on it

⇒ 1 = e α+β ⇒ α + β = 0 ……… (1)

⇒ (α, β) = (1, −1) ⇒ 6    +    = 3

20) Simplifying f(x) = x2

∫ f(x)d ( log x )dx = ∫x

21), 22) & 23)

Now solving this with y = ax2 + bx

From (1) and (5) ⇒ a = 1, b = 6

28. ∆W = ∆U liquid is ideal U → gravitational P.E

35. Velocity will be zero at max. displacement.

36. Centripetal acceleration.

2-ene which on anti addition of bromine gives meso-1,2-dibromobutane.

electron deficient molecules.

Suphate is tertrahedral while S52- is a polysulphide and has a zig−zag

C H 2 − C1 is more stable than C H2 − F due to d-orbital resonance(overlap of –

F has higher electron withdrawing power than Cl.

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