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INVESTIGATORY
PROJECT
WORK(2014-15)
CONTENTS
Certificate
Acknowledgement
Introduction
Principle
Design
Power Consumption
Heating Efficiency
Microwave Safe Materials
Effects on Food and Nutrients
Hazards
Bibliography
CERTIFACTE
Subject Teacher
(Dr. Alka Gupta)
ACKNOWLEDGMENT
Microwave ovens are popular for reheating previously cooked foods and cooking
vegetables. They are also useful for rapid heating of otherwise slowly prepared
cooking items, such as hot butter, fats, and chocolate. Unlike conventional ovens,
microwave ovens usually do not directly brown or caramelize food, since they
rarely attain the necessary temperatures to produce Maillard reactions. Exceptions
occur in rare cases where the oven is used to heat frying-oil and other very oily
items (such as bacon), which attain far higher temperatures than that of boiling
water. The boiling-range temperatures produced in high-water-content foods give
microwave ovens a limited role in professional cooking, since it usually makes
them unsuitable for achievement of culinary effects where the flavors produced by
the higher temperatures of frying, browning, or baking are needed. However,
additional heat sources can be added to microwave ovens, or into combination
microwave ovens, to produce these other heating effects, and microwave heating
may cut the overall time needed to prepare such dishes. Some modern microwave
ovens may be part of an over-the-range unit with built-in extractor hoods.
Principle
A microwave oven heats food by passing microwave radiation through it.
Microwaves are a form of non-ionizing electromagnetic radiation with a frequency
higher than ordinary radio waves but lower than infrared light. Microwave ovens
use frequencies in one of the ISM (industrial, scientific, medical) bands, which are
reserved for this use, so they don't interfere with other vital radio services.
Consumer ovens usually use 2.45 gigahertz (GHz)—a wavelength of 12.2
centimeters (4.80 in)—while large industrial/commercial ovens often use 915
megahertz (MHz)—32.8 centimeters (12.9 in). Water, fat, and other substances in
the food absorb energy from the microwaves in a process called dielectric heating.
Many molecules (such as those of water) are electric dipoles, meaning that they
have a partial positive charge at one end and a partial negative charge at the other,
and therefore rotate as they try to align themselves with the alternating electric
field of the microwaves. Rotating molecules hit other molecules and put them into
motion, thus dispersing energy. This energy, when dispersed as molecular
vibration in solids and liquids (i.e., as both potential energy and kinetic energy of
atoms), is heat
The electric dipole consists of two charges of equal magnitude but opposite sign
separated by a distance 2a, as shown in Figure.
The electric dipole moment of this configuration is defined as the vector p directed
from –q to +q along the line joining the charges and having magnitude 2aq:
𝑝 = 2𝑞𝑎
Now suppose that an electric dipole is placed in a uniform electric field E, as
shown in Figure 26.20. We identify E as the field external to the dipole,
distinguishing it from the field due to the dipole. The field E is established by some
other charge distribution, and we place the dipole into this field. Let us imagine
that the dipole moment makes an angle θ with the field.
The electric forces acting on the two charges are equal in magnitude but opposite
in direction as shown in Figure 26.20 (each has a magnitude F = qE) Thus, the net
force on the dipole is zero. However, the two forces produce a net torque on the
dipole; as a result, the dipole rotates in the direction that brings the dipole moment
vector into greater alignment with the field. The torque due to the force on the
positive charge about an axis through O in Figure 26.20 is Fa sin θ, where a sin θ is
the moment arm of F about O. This force tends to produce a clockwise rotation.
The torque about O on the negative charge also is Fa sin θ ; here again, the force
tends to produce a clockwise rotation. Thus, the net torque about O is
It is convenient to express the torque in vector form as the cross product of the
vectors p and E:
We can write this expression for the potential energy of a dipole in an electric field
as the dot product of the vectors p and E:
In this case, once we rotate the dipole through angle θ, the system tends to return
to the original configuration when the object is released. The dipole begins to
rotate back toward the configuration in which it was aligned with the field.
Molecules are said to be polarized when a separation exists between the average
position of the negative charges and the average position of the positive charges in
the molecule. In some molecules, such as water, this condition is always present—
such molecules are called polar molecules. Molecules that do not possess a
permanent polarization are called nonpolar molecules.
Water p = 6.2×10-30 Cm
Microwave ovens take advantage of the polar nature of the water molecule. When
in operation, microwave ovens generate a rapidly changing electric field that
causes the polar molecules to swing back and forth, absorbing energy from the
field in the process. Because the jostling molecules collide with each other, the
energy they absorb from the field is converted to internal energy, which
corresponds to an increase in temperature of the food.
Design
A microwave oven consists of:
Modern microwave ovens use either an analog dial-type timer or a digital control
panel for operation. Control panels feature an LED, liquid crystal or vacuum
fluorescent display, numeric buttons for entering the cook time, a power level
selection feature and other possible functions such as a defrost setting and pre-
programmed settings for different food types, such as meat, fish, poultry,
vegetables, frozen vegetables, frozen dinners, and popcorn. In most ovens, the
magnetron is driven by a linear transformer which can only feasibly be switched
completely on or off. As such, the choice of power level does not affect the
intensity of the microwave radiation; instead, the magnetron is cycled on and off
every few seconds. Newer models have inverter power supplies that use pulse
width modulation to provide effectively continuous heating at reduced power, so
that foods are heated more evenly at a given power level and can be heated more
quickly without being damaged by uneven heating. The microwave frequencies
used in microwave ovens are chosen based on regulatory and cost constraints. The
first is that they should be in one of the industrial, scientific, and medical (ISM)
frequency bands set aside for noncommunication purposes. For household
purposes, 2.45 GHz has the advantage over 915 MHz in that 915 MHz is only an
ISM band in the ITU Region 2 while 2.45 GHz is available worldwide. Three
additional ISM bands exist in the microwave frequencies, but are not used for
microwave cooking. Two of them are centered on 5.8 GHz and 24.125 GHz, but
are not used for microwave cooking because of the very high cost of power
generation at these frequencies. The third, centered on 433.92 MHz,is a narrow
band that would require expensive equipment to generate sufficient power without
creating interference outside the band, and is only available in some countries. The
cooking chamber is similar to a Faraday cage (but there is no continuous metal-to-
metal contact around the rim of the door), and prevents the waves from coming out
of the oven. The oven door usually has a window for easy viewing, with a layer of
conductive mesh some distance from the outer panel to maintain the shielding.
Because the size of the perforations in the mesh is much less than the microwaves’
wavelength (12.2 cm for the usual 2.45 GHz), most of the microwave radiation
cannot pass through the door, while visible light (with its much shorter
wavelength) can.
A microwave oven converts only part of its electrical input into microwave energy.
An average consumer microwave oven consumes 1100 W of electricity in
producing 700 W of microwave power, an efficiency of 64%. The other 400 W are
dissipated as heat, mostly in the magnetron tube. Additional power is used to
operate the lamps, AC power transformer, magnetron cooling fan, food turntable
motor and the control circuits. Such wasted heat, along with heat from the product
being microwaved, is exhausted as warm air through cooling vents.
For cooking or reheating small amounts of food, the microwave oven may use less
energy than a cook stove. Although microwave ovens are touted as the most
efficient appliance,[19] the energy savings are largely due to the reduced heat mass
of the food’s container.[20] The amount of energy used to heat food is generally
small compared to total energy usage in typical residences in the United States.
Heating Efficiency
Microwave heating is more efficient on liquid water than on frozen water, where
the movement of molecules is more restricted. Dielectric heating of liquid water is
also temperature-dependent: At 0 °C, dielectric loss is greatest at a field frequency
of about 10 GHz, and for higher water temperatures at higher field frequencies.
Compared to liquid water, microwave heating is less efficient on fats and sugars
(which have a smaller molecular dipole moment. Sugars and triglycerides (fats and
oils) absorb microwaves due to the dipole moments of their hydroxyl groups or
ester groups. However, due to the lower specific heat capacity of fats and oils and
their higher vaporization temperature, they often attain much higher temperatures
inside microwave ovens. This can induce temperatures in oil or very fatty foods
like bacon far above the boiling point of water, and high enough to induce some
browning reactions, much in the manner of conventional broiling (UK: grilling) or
deep fat frying. Foods high in water content and with little oil rarely exceed the
boiling temperature of water.
Microwave heating can cause localized thermal runaways in some materials with
low thermal conductivity which also have dielectric constants that increase with
temperature. An example is glass, which can exhibit thermal runaway in a
microwave to the point of melting if preheated. Additionally, microwaves can melt
certain types of rocks, producing small quantities of synthetic lava. Some ceramics
can also be melted, and may even become clear upon cooling. Thermal runaway is
more typical of electrically conductive liquids such as salty water.
A common misconception is that microwave ovens cook food “from the inside
out”, meaning from the center of the entire mass of food outwards. This idea arises
from heating behavior seen if an absorbent layer of water lies beneath a less
absorbent drier layer at the surface of a food; in this case, the deposition of heat
energy inside a food can exceed that on its surface. This can also occur if the inner
layer has a lower heat capacity than the outer layer causing it to reach a higher
temperature, or even if the inner layer is more thermally conductive than the outer
layer making it feel hotter despite having a lower temperature. In most cases,
however, with uniformly structured or reasonably homogenous food item,
microwaves are absorbed in the outer layers of the item at a similar level to that of
the inner layers. Depending on water content, the depth of initial heat deposition
may be several centimetres or more with microwave ovens, in contrast to
broiling/grilling (infrared) or convection heating—methods which deposit heat
thinly at the food surface. Penetration depth of microwaves is dependent on food
composition and the frequency, with lower microwave frequencies (longer
wavelengths) penetrating further.
The previous paragraph notwithstanding, the interior of small food items can reach
a higher temperature than the surface because the interior is thermally insulated
from the air. It is possible to burn the inside of a cookie while the exterior remains
unbrowned.
Microwave Safe Materials
In most home kitchens, we'll find an assortment of different materials used in our
containers ranging from glass to plastic to ceramic to metals. But are all food grade
materials similar? Should we care if a container is marked Microwave Safe? Let's
take a closer look at some common materials used in food containers and if they
are microwave safe.
Food safe ceramic uses glazes that are made from harmless materials like silica,
dolomite, kaolin, feldspar, ball clay, and others. In these glazes, the inevitable
leaching that occurs is only a functional and aesthetic issue and has no health
impact. Glazes that contain metals such as lithium, lead, or barium may present a
health issue. Ceramic containers made with such glazes cannot be sold in the
United States without either a permanent marking stating it is "Not for Food Use -
May Poison Food" or have a hole in the container (presumably rendering it useless
for food preparation). If you make your own ceramics, make sure you use a food
grade glaze if you plan to use it in your kitchen.
Plastics
Food grade plastics are made from a specific list of plastics approved by the FDA
(which may include dyes and recycled plastic that have not been determined to be
harmful to humans). Once a plastic container has been used to store non-food items
(like detergent or paint), it can no longer be considered food grade. Plastics
containers that are not food grade may leach plasticizers into food on contact. Due
to the nature of plastics, they have a high affinity for fats. Plastics that come in
contact with an oil-based substance will almost always be irrevocably altered and
the plastic may never become truly clean once again. Contact to foods that are high
in fat may cause leaching of the original oil-based substance into the food even if
the plastic was originally food grade.
Microwave safe plastics are food grade plastics (which do not leach plasticizers)
that are known to be able to withstand higher than normal temperatures. Plastics
that are not microwave safe may leach harmful substances when heated in a
microwave oven. (There was an internet e-mail scare/hoax that was passed around
claiming the USDA or FDA and independent researchers showed that dioxin (a
plasticizer) leached out of plastic wrap onto food being microwaved. This is untrue
since all microwave safe plastics are dioxin free. Saran and Ziploc both maintain
that their product lines are completely plasticizer free. The temperatures necessary
to create dioxin (around 1500°F) are beyond the normal operating conditions of
household microwave ovens.)
Lexan is a food grade polycarbonate plastic that has gained a large following in the
food service community. It is hard, durable, and resistant to reacting with oils
resulting in a virtually stain and odor proof material. It is capable of handling a
range of temperatures from below freezing to boiling.
Recently, Sierra magazine published a report claiming that polycarbonate plastics
leach an endocrine disruptor called Bisphenol-A (BPA). Unfortunately, the studies
the article was based on cannot be directly related to use in the food industry since
the tests were performed on non-food grade polycarbonate mouse cages (which
affected the growth cycle of the mice). No evidence of food grade polycarbonates
(such as Lexan) being a health hazard has been uncovered.
The S.C. Johnson Company says that the larger Ziploc brand bags are microwave
safe. All Ziploc bags are made of microwave safe materials, but bags smaller than
1 quart size may be too thin to withstand the temperature of the food being
microwaved.
Effects on food and nutrients
Several studies have shown that microwaves negatively impact food’s nutritional
value. Some excellent scientific data has been gathered regarding the detrimental
effects of microwaves on the nutrients in your food:
A study published in the November 2003 issue of The Journal of the Science
of Food and Agriculture5 found that broccoli "zapped" in the microwave
with a little water lost up to 97 percent of its beneficial antioxidants. By
comparison, steamed broccoli lost 11 percent or fewer of its antioxidants.
There were also reductions in phenolic compounds and glucosinolates, but
mineral levels remained intact.
A 1999 Scandinavian study of the cooking of asparagus spears found that
microwaving caused a reduction in vitamin C.
In a study of garlic, as little as 60 seconds of microwave heating was enough
to inactivate its allinase, garlic's principle active ingredient against cancer.
A Japanese study by Watanabe showed that just 6 minutes of microwave
heating turned 30-40 percent of the B12 in milk into an inert (dead) form.
A recent Australian study9 showed that microwaves cause a higher degree of
"protein unfolding" than conventional heating.
Microwaving can destroy the essential disease-fighting agents in breast milk
that offer protection for your baby. In 1992, Quan found that microwaved
breast milk lost lysozyme activity, antibodies, and fostered the growth of
more potentially pathogenic bacteria
Another study about breast milk/infant formula by Lee in 198911 found
vitamin content becomes depleted by microwaving, and certain amino acids
are converted into other substances that are biologically inactive. Some
altered amino acids are poisons to the nervous system and kidneys.
Other studies show that, if properly used, microwave cooking does not affect the
nutrient content of foods to a larger extent than conventional heating, and that there
is a tendency towards greater retention of many micronutrients with microwaving,
probably due to the reduced preparation time.
Nutrients are leached from food during any form of cooking, especially
when the food is cooked for a long period of time with high amounts of
water. So, for example, boiling carrots might strip nutrients much more
drastically than microwaving them, because the carrots’ nutrients might get
washed away with the boiling water.
Availability of some amino acids in food materials might be improved, since
no surface browning occurs. And microwave heating might lead to
destruction of trypsin inhibitors in beans.
Closed containers, such as eggs, can explode when heated in a microwave oven
due to the increased pressure from steam. Insulating plastic foams of all types
generally contain closed air pockets, and are generally not recommended for use in
a microwave, as the air pockets explode and the foam (which can be toxic if
consumed) may melt.
"Hot spots" in microwaved food can be hot enough to cause burns—or build up to
a "steam explosion." This has resulted in admonitions to new mothers about NOT
using the microwave to heat up baby bottles, since babies have been burned by
super-heated formula that went undetected. Another problem with microwave
ovens is that carcinogenic toxins can leach out of your plastic and paper
containers/covers, and into your food.
Any object containing pointed metal can create an electric arc (sparks) when
microwaved. This includes cutlery, crumpled aluminium foil (though some foil
used in microwaves are safe, see below), twist-ties containing metal wire, the metal
wire carry-handles in paper Chinese take-out food containers, or almost any metal
formed into a poorly conductive foil or thin wire; or into a pointed shape. The
electric arc has the effect of exceeding the dielectric breakdown of air, about 3
megavolts per meter (3×106 V/m). The air forms a conductive plasma, which is
visible as a spark. When dielectric breakdown occurs in air, some ozone and
nitrogen oxides are formed, both of which are unhealthy in large quantities. The
effect of microwaving thin
metal films can be seen
clearly on a Compact Disc or
DVD (particularly the factory
pressed type). The
microwaves induce electric
currents in the metal film,
which heats up, melting the
plastic in the disc and leaving a visible pattern of concentric and radial scars.
Similarly, porcelain with thin metal films can also be destroyed or damaged by
microwaving.
Some magnetrons have ceramic insulators with beryllium oxide (beryllia) added.
The beryllium in such oxides is a serious chemical hazard if crushed and ingested
(for example, by inhaling dust). In addition, beryllia is listed as a confirmed human
carcinogen by the IARC; therefore, broken ceramic insulators or magnetrons
should not be handled. This is obviously a danger only if the microwave oven
becomes physically damaged, such as if the insulator cracks, or when the
magnetron is opened and handled directly, and as such should not be a concern
during normal usage.